BRPI0407404A - processo para oxidação de alquil-benzenos para produzir hidroperóxidos - Google Patents
processo para oxidação de alquil-benzenos para produzir hidroperóxidosInfo
- Publication number
- BRPI0407404A BRPI0407404A BRPI0407404-1A BRPI0407404A BRPI0407404A BR PI0407404 A BRPI0407404 A BR PI0407404A BR PI0407404 A BRPI0407404 A BR PI0407404A BR PI0407404 A BRPI0407404 A BR PI0407404A
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl benzene
- oxidation
- produce hydroperoxides
- hydroperoxides
- produce
- Prior art date
Links
- 150000004996 alkyl benzenes Chemical class 0.000 title abstract 4
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
- C07C409/10—Cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
- C07C39/04—Phenol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA OXIDAçãO DE ALQUIL-BENZENOS PARA PRODUZIR HIDROPERóXIDOS". Um processo para oxidação de alquil-benzenos para produzir hidroperóxidos compreendendo: proporcionar uma alimentação de oxidação consistindo essencialmente de uma fase orgânica, a citada alimentação de oxidação compreendendo um ou mais alquil-benzenos e uma quantidade de base neutralizadora possuindo um pH de 8 a 12,5 em uma solução aquosa de 1% a 10% em peso, a citada alimentação de oxidação compreendendo uma quantidade de água de até 400 ppm a 2% em peso.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44752603P | 2003-02-14 | 2003-02-14 | |
US10/761,641 US7141703B2 (en) | 2003-02-14 | 2004-01-21 | Process for producing phenol and ketone using neutralizing base |
PCT/US2004/004010 WO2004074241A1 (en) | 2003-02-14 | 2004-02-11 | Process for producing alkylbenzene hydroperoxides |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0407404A true BRPI0407404A (pt) | 2006-02-21 |
Family
ID=32853507
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0407404-1A BRPI0407404A (pt) | 2003-02-14 | 2004-02-11 | processo para oxidação de alquil-benzenos para produzir hidroperóxidos |
Country Status (8)
Country | Link |
---|---|
US (1) | US7141703B2 (pt) |
EP (1) | EP1594838A1 (pt) |
JP (1) | JP4912870B2 (pt) |
KR (1) | KR20050097550A (pt) |
BR (1) | BRPI0407404A (pt) |
MY (1) | MY139447A (pt) |
TW (1) | TW200508188A (pt) |
WO (1) | WO2004074241A1 (pt) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007106747A (ja) * | 2005-09-15 | 2007-04-26 | Sumitomo Chemical Co Ltd | アルキルベンゼンハイドロパーオキサイドの製造方法 |
US7326815B2 (en) * | 2005-12-27 | 2008-02-05 | Exxonmobil Chemical Patents Inc. | Selective oxidation of alkylbenzenes |
CN101511784A (zh) * | 2006-08-03 | 2009-08-19 | 埃克森美孚化学专利公司 | 烷基芳族化合物的氧化方法 |
EP2103584B1 (en) | 2006-11-21 | 2014-12-31 | Mitsui Chemicals, Inc. | Method for producing alkylated aromatic compound and method for producing phenol |
TW200846312A (en) * | 2007-02-22 | 2008-12-01 | Exxonmobil Chem Patents Inc | Oxidation of sec-butylbenzene and production of phenol and methyl ethyl ketone |
ES2363571T3 (es) * | 2007-02-23 | 2011-08-09 | Mitsui Chemicals, Inc. | Proceso para preparar un compuesto aromático alquilado. |
US8487138B2 (en) * | 2007-08-22 | 2013-07-16 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
KR101257988B1 (ko) * | 2007-10-31 | 2013-04-24 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 탄화수소의 산화 |
WO2009058531A1 (en) * | 2007-10-31 | 2009-05-07 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
US8658835B2 (en) | 2007-10-31 | 2014-02-25 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
WO2009150973A1 (ja) | 2008-06-10 | 2009-12-17 | 三井化学株式会社 | アルキル化芳香族化合物の製造方法およびフェノールの製造方法 |
WO2010027562A1 (en) * | 2008-08-26 | 2010-03-11 | Exxonmobil Chemical Patents Inc. | Process for producing alkylbenzene hydroperoxides |
EP2356087A4 (en) * | 2008-10-10 | 2015-09-02 | Exxonmobil Chem Patents Inc | OXIDATION OF HYDROCARBONS |
JP5574968B2 (ja) * | 2008-10-23 | 2014-08-20 | 三井化学株式会社 | アルキル化芳香族化合物の製造方法、クメンの製造方法およびフェノールの製造方法 |
KR20110086162A (ko) | 2008-12-15 | 2011-07-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 알킬방향족 화합물의 산화 |
CN102333745B (zh) | 2009-03-19 | 2014-04-09 | 三井化学株式会社 | 烷基化芳香族化合物的制造方法以及苯酚的制造方法 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2632773A (en) * | 1947-04-01 | 1953-03-24 | Hercules Powder Co Ltd | Manufacture of peroxidic compounds |
US3187055A (en) * | 1948-03-19 | 1965-06-01 | Hercules Powder Co Ltd | Manufacture of peroxidic compounds |
US2632026A (en) * | 1950-02-18 | 1953-03-17 | Hercules Powder Co Ltd | Oxidation of aromatic hydrocarbons |
US2757209A (en) * | 1951-04-26 | 1956-07-31 | Allied Chem & Dye Corp | Recovery of phenol and alphamethylstyrene from cumene oxidation reaction mixtures |
NL136649C (pt) * | 1966-11-03 | |||
US3907901A (en) * | 1969-07-14 | 1975-09-23 | Allied Chem | Continuous process for preparing cumene hydroperoxide |
US4016213A (en) * | 1971-05-03 | 1977-04-05 | Allied Chemical Corporation | Recovery of phenol, acetone and dimethyl phenyl carbinol from cumene oxidation product |
FR2182802A1 (en) | 1972-01-10 | 1973-12-14 | Union Carbide Corp | Sec butylbenzolhydroperoxide prepn - with subsequent prodn of phenol and methylethyl ketone |
US4358618A (en) * | 1981-06-22 | 1982-11-09 | Allied Corporation | Decomposition of cumene oxidation product |
US4431849A (en) * | 1981-10-21 | 1984-02-14 | The Goodyear Tire & Rubber Company | Process for preparing a methyl phenol |
JPH0635407B2 (ja) * | 1985-02-21 | 1994-05-11 | 三井石油化学工業株式会社 | 2,6−ジイソプロピルナフタレンの酸化方法 |
JP2686490B2 (ja) * | 1988-09-05 | 1997-12-08 | 三菱化学株式会社 | クメンヒドロペルオキシドの精製方法 |
US4950794A (en) * | 1989-05-24 | 1990-08-21 | Arco Chemical Technology, Inc. | Ethylbenzene oxidation |
JP3061394B2 (ja) | 1990-04-02 | 2000-07-10 | 三井化学株式会社 | クメンハイドロパーオキサイドの製造方法 |
TW226011B (pt) * | 1991-12-26 | 1994-07-01 | Sumitomo Chemical Co | |
TW237445B (pt) * | 1992-07-07 | 1995-01-01 | Sumitomo Chemical Co | |
US5254751A (en) * | 1992-09-14 | 1993-10-19 | General Electric Company | Method for the decomposition of cumene hydroperoxide by acidic catalyst to phenol and acetone |
RU2108318C1 (ru) * | 1994-03-01 | 1998-04-10 | Закошанский Владимир Михайлович | СПОСОБ ПОЛУЧЕНИЯ ФЕНОЛА, АЦЕТОНА И α МЕТИЛСТИРОЛА |
US5767322A (en) * | 1996-06-27 | 1998-06-16 | General Electric Company | Cumene oxidation process |
JP3391644B2 (ja) * | 1996-12-19 | 2003-03-31 | 住友化学工業株式会社 | ハイドロパーオキシドの抽出方法 |
US6077977A (en) * | 1998-06-01 | 2000-06-20 | General Electric Company | Method for preparing hydroperoxides by oxygenation |
AU6135999A (en) | 1998-09-04 | 2000-03-27 | Illa International L.L.C. | High selective method of phenol and acetone production |
KR100839680B1 (ko) * | 2000-12-27 | 2008-06-19 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 오염물량이 감소된 유기 하이드로과산화물을 제조하는 방법 |
US6465695B1 (en) * | 2001-07-27 | 2002-10-15 | General Electric Company | Method and system for manufacturing cumene hydroperoxide |
US6486365B1 (en) * | 2002-04-04 | 2002-11-26 | General Electric Company | Production and purification of phenol: hydroxyacetone removal by hydrotalcite |
-
2004
- 2004-01-21 US US10/761,641 patent/US7141703B2/en not_active Expired - Fee Related
- 2004-02-11 MY MYPI20040415A patent/MY139447A/en unknown
- 2004-02-11 BR BRPI0407404-1A patent/BRPI0407404A/pt not_active IP Right Cessation
- 2004-02-11 EP EP04710252A patent/EP1594838A1/en not_active Withdrawn
- 2004-02-11 JP JP2006503496A patent/JP4912870B2/ja not_active Expired - Fee Related
- 2004-02-11 WO PCT/US2004/004010 patent/WO2004074241A1/en active Search and Examination
- 2004-02-11 KR KR1020057014920A patent/KR20050097550A/ko not_active Application Discontinuation
- 2004-02-11 TW TW093103185A patent/TW200508188A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
US7141703B2 (en) | 2006-11-28 |
JP2006517968A (ja) | 2006-08-03 |
WO2004074241A1 (en) | 2004-09-02 |
TW200508188A (en) | 2005-03-01 |
KR20050097550A (ko) | 2005-10-07 |
MY139447A (en) | 2009-10-30 |
JP4912870B2 (ja) | 2012-04-11 |
EP1594838A1 (en) | 2005-11-16 |
US20040162448A1 (en) | 2004-08-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08L | Patent application lapsed because of non payment of annual fee [chapter 8.12 patent gazette] |
Free format text: REFERENTE AO NAO RECOLHIMENTO DAS 9A E 10A ANUIDADES. |
|
B08I | Publication cancelled [chapter 8.9 patent gazette] |
Free format text: ANULADA A PUBLICACAO CODIGO 8.12 NA RPI NO 2258 DE 15/04/2014 POR TER SIDO INDEVIDA. |
|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 9A, 10A, 11A, 12A, 13A, 14A, 15A E 16A ANUIDADES. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2602 DE 17-11-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |