JP4880144B2 - 吸収体およびそれを用いた吸収性物品 - Google Patents
吸収体およびそれを用いた吸収性物品 Download PDFInfo
- Publication number
- JP4880144B2 JP4880144B2 JP2001284740A JP2001284740A JP4880144B2 JP 4880144 B2 JP4880144 B2 JP 4880144B2 JP 2001284740 A JP2001284740 A JP 2001284740A JP 2001284740 A JP2001284740 A JP 2001284740A JP 4880144 B2 JP4880144 B2 JP 4880144B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- absorbent resin
- weight
- absorbent
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 230000002745 absorbent Effects 0.000 title claims description 96
- 239000006096 absorbing agent Substances 0.000 title claims description 25
- 229920005989 resin Polymers 0.000 claims description 140
- 239000011347 resin Substances 0.000 claims description 140
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 109
- 238000010521 absorption reaction Methods 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 23
- 239000000835 fiber Substances 0.000 claims description 17
- 239000002504 physiological saline solution Substances 0.000 claims description 13
- 238000004132 cross linking Methods 0.000 claims description 9
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 150000001447 alkali salts Chemical class 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 229920000578 graft copolymer Polymers 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
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- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 25
- 230000008961 swelling Effects 0.000 description 25
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- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- HDPLHDGYGLENEI-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COC(C)COCC1CO1 HDPLHDGYGLENEI-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
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- 239000004641 Diallyl-phthalate Substances 0.000 description 2
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
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| JP6990888B1 (ja) | 2021-05-12 | 2022-02-03 | 株式会社日本触媒 | ポリ(メタ)アクリル酸(塩)系吸水性樹脂、及び吸収体 |
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| JP2538547B2 (ja) * | 1984-03-05 | 1996-09-25 | 花王株式会社 | 使い捨ておむつ |
| US4654039A (en) * | 1985-06-18 | 1987-03-31 | The Proctor & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
| JPH0696619B2 (ja) * | 1989-09-28 | 1994-11-30 | 三洋化成工業株式会社 | 高吸水性ポリマー組成物及びその製造方法ならびにそれからなる高吸水性物品 |
| DE4020780C1 (enExample) * | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
| FI934466A0 (fi) * | 1991-04-12 | 1993-10-11 | Procter & Gamble | Absorberande strukturer innehaollande en specifik partikelstroleksfoerdelning av superabsorberande hydrogelbildande material |
| CA2076945C (en) * | 1991-09-11 | 2002-10-08 | Shannon Kathleen Byerly | Absorbent composites and absorbent articles containing same |
| US5599335A (en) * | 1994-03-29 | 1997-02-04 | The Procter & Gamble Company | Absorbent members for body fluids having good wet integrity and relatively high concentrations of hydrogel-forming absorbent polymer |
| DE19529348C2 (de) * | 1995-08-09 | 1997-11-20 | Stockhausen Chem Fab Gmbh | Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung |
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| JPWO2020122211A1 (ja) * | 2018-12-12 | 2021-10-21 | 住友精化株式会社 | 吸水性樹脂粒子 |
| JP6990888B1 (ja) | 2021-05-12 | 2022-02-03 | 株式会社日本触媒 | ポリ(メタ)アクリル酸(塩)系吸水性樹脂、及び吸収体 |
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