JP4816861B2 - 有機溶媒分散無機酸化物ゾルの製造方法 - Google Patents
有機溶媒分散無機酸化物ゾルの製造方法 Download PDFInfo
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- JP4816861B2 JP4816861B2 JP2004360686A JP2004360686A JP4816861B2 JP 4816861 B2 JP4816861 B2 JP 4816861B2 JP 2004360686 A JP2004360686 A JP 2004360686A JP 2004360686 A JP2004360686 A JP 2004360686A JP 4816861 B2 JP4816861 B2 JP 4816861B2
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- Prior art keywords
- inorganic oxide
- organic solvent
- sol
- oxide sol
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229910052809 inorganic oxide Inorganic materials 0.000 title claims description 46
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 72
- 239000010703 silicon Substances 0.000 claims description 61
- -1 silicon alkoxide Chemical class 0.000 claims description 61
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 54
- 239000002904 solvent Substances 0.000 claims description 52
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000002245 particle Substances 0.000 claims description 29
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 28
- 125000003545 alkoxy group Chemical group 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 28
- 239000003960 organic solvent Substances 0.000 claims description 26
- 238000006467 substitution reaction Methods 0.000 claims description 23
- 238000004821 distillation Methods 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 230000001476 alcoholic effect Effects 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- 150000003138 primary alcohols Chemical class 0.000 claims description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 8
- 239000002612 dispersion medium Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- XVJZLRKWIPWUNZ-UHFFFAOYSA-N dihydroxy(phenylmethoxy)silane Chemical compound O[SiH](O)OCC1=CC=CC=C1 XVJZLRKWIPWUNZ-UHFFFAOYSA-N 0.000 claims description 3
- CVQVSVBUMVSJES-UHFFFAOYSA-N dimethoxy-methyl-phenylsilane Chemical compound CO[Si](C)(OC)C1=CC=CC=C1 CVQVSVBUMVSJES-UHFFFAOYSA-N 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- GWNBXFBULXQYMV-UHFFFAOYSA-N hydroxy-dimethoxy-phenylsilane Chemical compound CO[Si](O)(OC)C1=CC=CC=C1 GWNBXFBULXQYMV-UHFFFAOYSA-N 0.000 claims description 3
- YXRQUPWITJCURW-UHFFFAOYSA-N benzhydryloxy(hydroxy)silane Chemical compound C=1C=CC=CC=1C(O[SiH2]O)C1=CC=CC=C1 YXRQUPWITJCURW-UHFFFAOYSA-N 0.000 claims description 2
- KJMVZEFHDTXJEQ-UHFFFAOYSA-N benzyl-hydroxy-methoxysilane Chemical compound C1(=CC=CC=C1)C[SiH](O)OC KJMVZEFHDTXJEQ-UHFFFAOYSA-N 0.000 claims description 2
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 42
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 39
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 28
- 238000009835 boiling Methods 0.000 description 24
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 13
- 229910004298 SiO 2 Inorganic materials 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000000377 silicon dioxide Substances 0.000 description 11
- 230000005484 gravity Effects 0.000 description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 8
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 7
- 238000002296 dynamic light scattering Methods 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 6
- 229910044991 metal oxide Inorganic materials 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- 239000012046 mixed solvent Substances 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 150000004703 alkoxides Chemical class 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 5
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 5
- 229910001887 tin oxide Inorganic materials 0.000 description 5
- 238000005809 transesterification reaction Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 3
- WQVJKRKRRMJKMC-UHFFFAOYSA-N diethoxy-methyl-octylsilane Chemical compound CCCCCCCC[Si](C)(OCC)OCC WQVJKRKRRMJKMC-UHFFFAOYSA-N 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 description 3
- 229940035429 isobutyl alcohol Drugs 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- SCPWMSBAGXEGPW-UHFFFAOYSA-N dodecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OC)(OC)OC SCPWMSBAGXEGPW-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 description 2
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- HTJNDQNBKKHPAQ-UHFFFAOYSA-N oxotin zirconium Chemical compound [Sn]=O.[Zr] HTJNDQNBKKHPAQ-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 125000004665 trialkylsilyl group Chemical group 0.000 description 2
- FZMJEGJVKFTGMU-UHFFFAOYSA-N triethoxy(octadecyl)silane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OCC)(OCC)OCC FZMJEGJVKFTGMU-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- WCAMSVKDDYEFRO-UHFFFAOYSA-N 2,2-dimethoxyethoxy(hydroxy)silane Chemical compound COC(CO[SiH2]O)OC WCAMSVKDDYEFRO-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- GJARAYDQMCLHME-UHFFFAOYSA-N 3-[dihydroxy(methoxy)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](O)(O)CCCOC(=O)C(C)=C GJARAYDQMCLHME-UHFFFAOYSA-N 0.000 description 1
- FSYKYQSPSAAEKT-UHFFFAOYSA-N 3-[hydroxy(dimethoxy)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](O)(OC)CCCOC(=O)C(C)=C FSYKYQSPSAAEKT-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- DWRZCEQVOVRYOS-UHFFFAOYSA-N C(CCCCCCCCCCC)[SiH](O)OC Chemical compound C(CCCCCCCCCCC)[SiH](O)OC DWRZCEQVOVRYOS-UHFFFAOYSA-N 0.000 description 1
- QZUVZGSWABXTCC-UHFFFAOYSA-N CCO[Si](OCC)(OCC)O[Si](OCC)(OCC)[SiH2]O Chemical compound CCO[Si](OCC)(OCC)O[Si](OCC)(OCC)[SiH2]O QZUVZGSWABXTCC-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 238000003109 Karl Fischer titration Methods 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- ZTVDQDQXXMXXIC-UHFFFAOYSA-N [Sb]=O.[Si]=O Chemical compound [Sb]=O.[Si]=O ZTVDQDQXXMXXIC-UHFFFAOYSA-N 0.000 description 1
- DYMZDAIWSZNFPM-UHFFFAOYSA-N [Si]=O.[W]=O.[Sn]=O Chemical compound [Si]=O.[W]=O.[Sn]=O DYMZDAIWSZNFPM-UHFFFAOYSA-N 0.000 description 1
- FRGRTEXUKXPDBB-UHFFFAOYSA-N [ethoxy(dihydroxy)silyl] triethyl silicate Chemical compound CCO[Si](O)(O)O[Si](OCC)(OCC)OCC FRGRTEXUKXPDBB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- VPKDITZOLGAWIS-UHFFFAOYSA-N but-3-enoxy(dihydroxy)silane Chemical compound C(=C)CCO[SiH](O)O VPKDITZOLGAWIS-UHFFFAOYSA-N 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- BRXOKRLIIVYICJ-UHFFFAOYSA-N butoxy(trihydroxy)silane Chemical compound CCCCO[Si](O)(O)O BRXOKRLIIVYICJ-UHFFFAOYSA-N 0.000 description 1
- HONVZHGOWSOUOV-UHFFFAOYSA-N butyl-dihydroxy-methoxysilane Chemical compound CCCC[Si](O)(O)OC HONVZHGOWSOUOV-UHFFFAOYSA-N 0.000 description 1
- SGJPATCCPLZYOY-UHFFFAOYSA-N butyl-hydroxy-dimethoxysilane Chemical compound CCCC[Si](O)(OC)OC SGJPATCCPLZYOY-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- YEVNIVFDDHCRNT-UHFFFAOYSA-N decyl-dihydroxy-methoxysilane Chemical compound CCCCCCCCCC[Si](O)(O)OC YEVNIVFDDHCRNT-UHFFFAOYSA-N 0.000 description 1
- QNJATABPLMKNKY-UHFFFAOYSA-N decyl-hydroxy-dimethoxysilane Chemical compound CCCCCCCCCC[Si](O)(OC)OC QNJATABPLMKNKY-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 1
- RHXIYCXNOQKKMZ-UHFFFAOYSA-N diethoxy(dihydroxy)silane Chemical compound CCO[Si](O)(O)OCC RHXIYCXNOQKKMZ-UHFFFAOYSA-N 0.000 description 1
- YHVQGXXUSXAPPS-UHFFFAOYSA-N diethoxy-[2-[ethoxy(dihydroxy)silyl]ethyl]-hydroxysilane Chemical compound CCO[Si](O)(O)CC[Si](O)(OCC)OCC YHVQGXXUSXAPPS-UHFFFAOYSA-N 0.000 description 1
- RGRLWCADSJMLBE-UHFFFAOYSA-N diethoxy-[ethoxy(dihydroxy)silyl]oxy-hydroxysilane Chemical compound CCO[Si](O)(O)O[Si](O)(OCC)OCC RGRLWCADSJMLBE-UHFFFAOYSA-N 0.000 description 1
- BGRJAAHZADSEPR-UHFFFAOYSA-N diethoxy-hydroxy-(2-triethoxysilylethyl)silane Chemical compound CCO[Si](O)(OCC)CC[Si](OCC)(OCC)OCC BGRJAAHZADSEPR-UHFFFAOYSA-N 0.000 description 1
- YJFFJAVQGZIFEG-UHFFFAOYSA-N diethoxy-hydroxy-methoxysilane Chemical compound CCO[Si](O)(OC)OCC YJFFJAVQGZIFEG-UHFFFAOYSA-N 0.000 description 1
- FBAKIIRRRSHFTJ-UHFFFAOYSA-N diethoxy-hydroxy-octadecylsilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](O)(OCC)OCC FBAKIIRRRSHFTJ-UHFFFAOYSA-N 0.000 description 1
- CXCLIHKKLJBBSO-UHFFFAOYSA-N diethoxy-hydroxy-octylsilane Chemical compound CCCCCCCC[Si](O)(OCC)OCC CXCLIHKKLJBBSO-UHFFFAOYSA-N 0.000 description 1
- PSUILUFZVWFSCP-UHFFFAOYSA-N diethoxy-hydroxy-propylsilane Chemical compound CCC[Si](O)(OCC)OCC PSUILUFZVWFSCP-UHFFFAOYSA-N 0.000 description 1
- VGWJKDPTLUDSJT-UHFFFAOYSA-N diethyl dimethyl silicate Chemical compound CCO[Si](OC)(OC)OCC VGWJKDPTLUDSJT-UHFFFAOYSA-N 0.000 description 1
- ONCIQCKBUSMDIK-UHFFFAOYSA-N dihydroxy(dimethoxy)silane Chemical compound CO[Si](O)(O)OC ONCIQCKBUSMDIK-UHFFFAOYSA-N 0.000 description 1
- JWBDZHPSYDOAPO-UHFFFAOYSA-N dihydroxy-methoxy-(2-phenylethyl)silane Chemical compound CO[Si](O)(O)CCC1=CC=CC=C1 JWBDZHPSYDOAPO-UHFFFAOYSA-N 0.000 description 1
- AWSFUCVGQBUMLQ-UHFFFAOYSA-N dihydroxy-methoxy-methylsilane Chemical compound CO[Si](C)(O)O AWSFUCVGQBUMLQ-UHFFFAOYSA-N 0.000 description 1
- UKJCMWLBAFAGQH-UHFFFAOYSA-N dihydroxy-methoxy-octadecylsilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](O)(O)OC UKJCMWLBAFAGQH-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- FKITXAXUPAKOAM-UHFFFAOYSA-N dodecyl-hydroxy-dimethoxysilane Chemical compound CCCCCCCCCCCC[Si](O)(OC)OC FKITXAXUPAKOAM-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- KALRZBLZMYZNEL-UHFFFAOYSA-N ethoxy-[1-[ethoxy(dihydroxy)silyl]ethyl]-dihydroxysilane Chemical compound CCO[Si](O)(O)C(C)[Si](O)(O)OCC KALRZBLZMYZNEL-UHFFFAOYSA-N 0.000 description 1
- FBDJFBQFXFEDDS-UHFFFAOYSA-N ethoxy-dihydroxy-octadecylsilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](O)(O)OCC FBDJFBQFXFEDDS-UHFFFAOYSA-N 0.000 description 1
- LJDQNJXRANQKOI-UHFFFAOYSA-N ethoxy-dihydroxy-propylsilane Chemical compound CCC[Si](O)(O)OCC LJDQNJXRANQKOI-UHFFFAOYSA-N 0.000 description 1
- YMUQUFDKQGVJSN-UHFFFAOYSA-N ethoxy-hydroxy-methyl-octylsilane Chemical compound CCCCCCCC[Si](C)(O)OCC YMUQUFDKQGVJSN-UHFFFAOYSA-N 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- OUKZIVNTDYMJHE-UHFFFAOYSA-N ethyl-dihydroxy-methoxysilane Chemical compound CC[Si](O)(O)OC OUKZIVNTDYMJHE-UHFFFAOYSA-N 0.000 description 1
- GVUGIFZLJMQKGZ-UHFFFAOYSA-N ethyl-hydroxy-dimethoxysilane Chemical compound CC[Si](O)(OC)OC GVUGIFZLJMQKGZ-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- JGVVLDHHKJPGDD-UHFFFAOYSA-N hexyl-dihydroxy-methoxysilane Chemical compound CCCCCC[Si](O)(O)OC JGVVLDHHKJPGDD-UHFFFAOYSA-N 0.000 description 1
- PAVKUAUCYRVKSU-UHFFFAOYSA-N hexyl-hydroxy-dimethoxysilane Chemical compound CCCCCC[Si](O)(OC)OC PAVKUAUCYRVKSU-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- NDJGGFVLWCNXSH-UHFFFAOYSA-N hydroxy(trimethoxy)silane Chemical compound CO[Si](O)(OC)OC NDJGGFVLWCNXSH-UHFFFAOYSA-N 0.000 description 1
- BQMXFEXLJKRQGL-UHFFFAOYSA-N hydroxy-dimethoxy-(2-phenylethyl)silane Chemical compound CO[Si](O)(OC)CCC1=CC=CC=C1 BQMXFEXLJKRQGL-UHFFFAOYSA-N 0.000 description 1
- HXPLDADFOLJSKO-UHFFFAOYSA-N hydroxy-dimethoxy-methylsilane Chemical compound CO[Si](C)(O)OC HXPLDADFOLJSKO-UHFFFAOYSA-N 0.000 description 1
- MZNPMYXEIZZZHR-UHFFFAOYSA-N hydroxy-dimethoxy-octadecylsilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](O)(OC)OC MZNPMYXEIZZZHR-UHFFFAOYSA-N 0.000 description 1
- FPMRWEIDCWFCHY-UHFFFAOYSA-N hydroxy-methoxy-dimethylsilane Chemical compound CO[Si](C)(C)O FPMRWEIDCWFCHY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- WDTDSLYQFFOBFK-UHFFFAOYSA-N tributoxy(hydroxy)silane Chemical compound CCCCO[Si](O)(OCCCC)OCCCC WDTDSLYQFFOBFK-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- FOQJQXVUMYLJSU-UHFFFAOYSA-N triethoxy(1-triethoxysilylethyl)silane Chemical compound CCO[Si](OCC)(OCC)C(C)[Si](OCC)(OCC)OCC FOQJQXVUMYLJSU-UHFFFAOYSA-N 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- NMNFUJCFGCJREP-UHFFFAOYSA-N triethoxy-[2-[ethoxy(dihydroxy)silyl]ethyl]silane Chemical compound CCO[Si](O)(O)CC[Si](OCC)(OCC)OCC NMNFUJCFGCJREP-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- GYTROFMCUJZKNA-UHFFFAOYSA-N triethyl triethoxysilyl silicate Chemical compound CCO[Si](OCC)(OCC)O[Si](OCC)(OCC)OCC GYTROFMCUJZKNA-UHFFFAOYSA-N 0.000 description 1
- FXSGDOZPBLGOIN-UHFFFAOYSA-N trihydroxy(methoxy)silane Chemical compound CO[Si](O)(O)O FXSGDOZPBLGOIN-UHFFFAOYSA-N 0.000 description 1
- UBMUZYGBAGFCDF-UHFFFAOYSA-N trimethoxy(2-phenylethyl)silane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC=C1 UBMUZYGBAGFCDF-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
- Colloid Chemistry (AREA)
- Silicon Compounds (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
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| JP2007063117A (ja) | 2005-08-02 | 2007-03-15 | Nissan Chem Ind Ltd | 有機溶媒分散シリカゾル及びその製造方法 |
| EP2308803A4 (en) | 2008-07-17 | 2013-07-17 | Nissan Chemical Ind Ltd | COLLOIDAL PARTICLE DISPERSION FLOOR OF ANHYDROUS ZINC ANTIMONIATE IN A HYDROPHOBIC ORGANIC SOLVENT AND PROCESS FOR PRODUCING THE SAME |
| ES2644759T3 (es) * | 2008-07-18 | 2017-11-30 | Evonik Degussa Gmbh | Dispersión de partículas de dióxido de silicio hidrofobizadas y granulado de la misma |
| HUE035111T2 (en) | 2010-01-19 | 2018-05-02 | Nissan Chemical Ind Ltd | Fine metal oxide particles coated with silane and a process for their preparation |
| JP5615620B2 (ja) * | 2010-08-09 | 2014-10-29 | 日東電工株式会社 | 金属酸化物粒子の製造方法 |
| JP6064338B2 (ja) * | 2012-02-22 | 2017-01-25 | 日本アエロジル株式会社 | 酸化チタンの非極性有機溶媒分散液の製造方法 |
| US10501637B2 (en) | 2014-08-07 | 2019-12-10 | Nissan Chemical Industries, Ltd. | Silane-treated forsterite fine particles and production method therefor, and organic solvent dispersion of silane-treated forsterite fine particles and production method therefor |
| JP6590566B2 (ja) * | 2015-07-21 | 2019-10-16 | 国立大学法人茨城大学 | 表面修飾ｉｔｏ粒子の製造方法 |
| TWI741600B (zh) | 2019-05-14 | 2021-10-01 | 日商日產化學股份有限公司 | 分散於酮系溶劑之二氧化矽溶膠及樹脂組成物 |
| CN114531854B (zh) | 2020-07-07 | 2023-07-07 | 日产化学株式会社 | 分散在烃中而得到的无机氧化物溶胶和其制造方法 |
| JP7093064B1 (ja) | 2020-11-04 | 2022-06-29 | 日産化学株式会社 | 窒素含有溶媒に分散したアルミニウム含有シリカゾル及び樹脂組成物 |
| TW202313469A (zh) | 2021-08-06 | 2023-04-01 | 日商日產化學股份有限公司 | 經疏水性有機溶劑分散之二氧化矽溶膠及其製造方法 |
| CN118076561A (zh) | 2021-08-06 | 2024-05-24 | 日产化学株式会社 | 酯分散二氧化硅溶胶及其制造方法 |
| CA3230465A1 (en) | 2021-08-31 | 2023-03-09 | Satoru Murakami | Dispersion of surface-treated silica-containing inorganic oxide particles and method for producing same |
| KR20250130363A (ko) * | 2023-01-06 | 2025-09-01 | 닛산 가가쿠 가부시키가이샤 | 무용매계 유기무기 하이브리드 수지 조성물 및 경화막 |
| CN120603783A (zh) | 2023-02-10 | 2025-09-05 | 日产化学株式会社 | 疏水性硅溶胶、涂布组合物及其制造方法 |
| WO2025089213A1 (ja) * | 2023-10-27 | 2025-05-01 | 日産化学株式会社 | 疎水性が向上したシリカ粒子、及びエナメル線被覆用組成物 |
| CN120359185A (zh) | 2023-11-29 | 2025-07-22 | 日产化学株式会社 | 包含有机酸的含氮有机溶剂中分散的二氧化硅溶胶和绝缘性树脂组合物 |
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| JPH0798655B2 (ja) * | 1988-09-13 | 1995-10-25 | 信越化学工業株式会社 | 表面修飾シリカの製造方法 |
| JP2646150B2 (ja) * | 1990-08-27 | 1997-08-25 | 出光興産 株式会社 | 撥水性シリカゾルおよびその製造方法 |
| JPH06298519A (ja) * | 1993-04-13 | 1994-10-25 | Idemitsu Kosan Co Ltd | 撥水性シリカゾルの製造方法 |
| JP4032503B2 (ja) * | 1997-05-26 | 2008-01-16 | 日産化学工業株式会社 | 疎水性オルガノシリカゾルの製造方法 |
| JP4631119B2 (ja) * | 2000-01-28 | 2011-02-16 | Ｊｓｒ株式会社 | 疎水化コロイダルシリカの製造方法 |
| JP4803630B2 (ja) * | 2003-05-21 | 2011-10-26 | 扶桑化学工業株式会社 | 高純度疎水性有機溶媒分散シリカゾルの製造方法 |
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