JP4607122B2 - ナノスケールの結晶質シリコン粉末 - Google Patents
ナノスケールの結晶質シリコン粉末 Download PDFInfo
- Publication number
- JP4607122B2 JP4607122B2 JP2006540274A JP2006540274A JP4607122B2 JP 4607122 B2 JP4607122 B2 JP 4607122B2 JP 2006540274 A JP2006540274 A JP 2006540274A JP 2006540274 A JP2006540274 A JP 2006540274A JP 4607122 B2 JP4607122 B2 JP 4607122B2
- Authority
- JP
- Japan
- Prior art keywords
- silicon powder
- sih
- crystalline silicon
- silane
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011863 silicon-based powder Substances 0.000 title claims abstract description 39
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910021419 crystalline silicon Inorganic materials 0.000 title claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 12
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 10
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 8
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 7
- 229910052692 Dysprosium Inorganic materials 0.000 claims abstract description 7
- 229910052691 Erbium Inorganic materials 0.000 claims abstract description 7
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 7
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052689 Holmium Inorganic materials 0.000 claims abstract description 7
- 229910052765 Lutetium Inorganic materials 0.000 claims abstract description 7
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract description 7
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 7
- 229910052775 Thulium Inorganic materials 0.000 claims abstract description 7
- 229910052769 Ytterbium Inorganic materials 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 7
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052796 boron Inorganic materials 0.000 claims abstract description 7
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims abstract description 7
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 7
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052738 indium Inorganic materials 0.000 claims abstract description 7
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 7
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims abstract description 7
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 239000011574 phosphorus Substances 0.000 claims abstract description 7
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 7
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 7
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052688 Gadolinium Inorganic materials 0.000 claims abstract description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052772 Samarium Inorganic materials 0.000 claims abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 6
- 239000010941 cobalt Substances 0.000 claims abstract description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims abstract description 6
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims abstract description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052737 gold Inorganic materials 0.000 claims abstract description 6
- 239000010931 gold Substances 0.000 claims abstract description 6
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 6
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052762 osmium Inorganic materials 0.000 claims abstract description 6
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 6
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 6
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 6
- 239000010948 rhodium Substances 0.000 claims abstract description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 6
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052709 silver Inorganic materials 0.000 claims abstract description 6
- 239000004332 silver Substances 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 229910000077 silane Inorganic materials 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 10
- 239000011261 inert gas Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 6
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910003902 SiCl 4 Inorganic materials 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052754 neon Inorganic materials 0.000 claims description 2
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 2
- -1 In that case Substances 0.000 claims 1
- TVYNCCPJWWBXRT-UHFFFAOYSA-N [Sm].[Gd] Chemical compound [Sm].[Gd] TVYNCCPJWWBXRT-UHFFFAOYSA-N 0.000 claims 1
- 239000004411 aluminium Substances 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 4
- 239000011164 primary particle Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000005004 MAS NMR spectroscopy Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000001036 glow-discharge mass spectrometry Methods 0.000 description 2
- 229910000064 phosphane Inorganic materials 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000005922 Phosphane Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- AFRJJFRNGGLMDW-UHFFFAOYSA-N lithium amide Chemical compound [Li+].[NH2-] AFRJJFRNGGLMDW-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QYQOQELPNQXQCY-UHFFFAOYSA-N n-phosphanylmethanamine Chemical compound CNP QYQOQELPNQXQCY-UHFFFAOYSA-N 0.000 description 1
- 150000003002 phosphanes Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
- C01B33/021—Preparation
- C01B33/027—Preparation by decomposition or reduction of gaseous or vaporised silicon compounds other than silica or silica-containing material
- C01B33/03—Preparation by decomposition or reduction of gaseous or vaporised silicon compounds other than silica or silica-containing material by decomposition of silicon halides or halosilanes or reduction thereof with hydrogen as the only reducing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
- C01B33/021—Preparation
- C01B33/027—Preparation by decomposition or reduction of gaseous or vaporised silicon compounds other than silica or silica-containing material
- C01B33/029—Preparation by decomposition or reduction of gaseous or vaporised silicon compounds other than silica or silica-containing material by decomposition of monosilane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Silicon Compounds (AREA)
- Catalysts (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
− 少なくとも1の蒸気状もしくは気体状のシランおよび場合により少なくとも1の蒸気状もしくは気体状のドープ材料および不活性ガスおよび、
− 水素、
− をホットウォール反応器中で加熱し、
− 反応混合物を冷却するか、または冷却させ、
− 反応生成物を気体状の物質から粉末の形で分離し、
− その際、シランの割合はシラン、ドープ材料、水素および不活性ガスの合計に対して0.1〜90質量%であり、
− その際、水素の割合が、水素、シラン、不活性ガスおよび場合によりドープ材料の合計に対して1モル%〜96モル%の範囲である
ことを特徴とする、本発明によるシリコン粉末を製造する方法を提供する。
分析技術:BET表面積はDIN66131に従って測定される。ドープの度合いはグロー放電質量分析法(GDMS)を使用して測定される。水素負荷率は1H−MAS−NMR分光分析法により測定される。
長さ200cmおよび直径6cmを有する管をホットウォール反応器として使用する。これは石英ガラスまたは石英ガラスのライナを有するSi/SiCからなる。該管を長さ100cmにわたり抵抗加熱を使用して外部から1000℃に加熱する。
Claims (10)
- 凝集した結晶質シリコン粉末において、20〜150m2/gのBET表面積を有し、リン、ヒ素、アンチモン、ビスマス、ホウ素、アルミニウム、ガリウム、インジウム、タリウム、ユーロピウム、エルビウム、セリウム、プラセオジム、ネオジム、サマリウム、ガドリニウム、テルビウム、ジスプロシウム、ホルミウム、ツリウム、ルテチウム、リチウム、イッテルビウム、ゲルマニウム、鉄、ルテニウム、オスミウム、コバルト、ロジウム、イリジウム、ニッケル、パラジウム、白金、銅、銀、金又は亜鉛によりドープされていることを特徴とする、凝集した結晶質シリコン粉末。
- BET表面積が40〜120m2/gであることを特徴とする、請求項1記載の凝集した結晶質シリコン粉末。
- ドープ成分のリン、ヒ素、アンチモン、ビスマス、ホウ素、アルミニウム、ガリウム、インジウム、タリウム、ユーロピウム、エルビウム、セリウム、プラセオジム、ネオジム、サマリウム、ガドリニウム、テルビウム、ジスプロシウム、ホルミウム、ツリウム、イッテルビウムおよびルテチウムの割合が1質量%までであることを特徴とする、請求項1記載の凝集した結晶質シリコン粉末。
- 水素負荷率が10モル%までであることを特徴とする、請求項1から3までのいずれか1項記載の凝集した結晶質シリコン粉末。
- 請求項1から4までのいずれか1項記載の凝集した結晶質シリコン粉末の製造方法において、
− 少なくとも1の蒸気状もしくは気体状のシランおよび少なくとも1の蒸気状もしくは気体状のドープ材料、不活性ガスおよび、
− 水素、
− をホットウォール反応器中で加熱し、
− 反応混合物を冷却するか、または冷却させ、かつ
− 反応生成物を気体状の物質から粉末の形で分離し、
− その際、シランの割合は、シラン、ドープ材料、水素および不活性ガスの合計に対して0.1〜90質量%であり、
− その際、水素の割合は、水素、シラン、不活性ガスおよびドープ材料の合計に対して1モル%〜96モル%の範囲であり、
その際、リン、ヒ素、アンチモン、ビスマス、ホウ素、アルミニウム、ガリウム、インジウム、タリウム、ユーロピウム、エルビウム、セリウム、プラセオジム、ネオジム、サマリウム、ガドリニウム、テルビウム、ジスプロシウム、ホルミウム、ツリウム、イッテルビウム、ルテチウム、リチウム、ゲルマニウム、鉄、ルテニウム、オスミウム、コバルト、ロジウム、イリジウム、ニッケル、パラジウム、白金、銅、銀、金、亜鉛の水素を含有する化合物の群からドープ材料を選択する
ことを特徴とする、請求項1から4までのいずれか1項記載の凝集した結晶質シリコン粉末の製造方法。 - 化合物SiH4、Si2H6、ClSiH3、Cl2SiH2、Cl3SiHおよび/またはSiCl4の群からシランを選択する、請求項5記載の方法。
- 化合物N(SiH3)3、HN(SiH3)2、H2N(SiH3)、(H3Si)2NN(SiH3)2、(H3Si)NHNH(SiH3)、H2NN(SiH3)2の群から、使用すべきシランを選択することを特徴とする、請求項5記載の方法。
- ドープ材料がリチウムアミド(LiNH2)であることを特徴とする、請求項5から7までのいずれか1項記載の方法。
- 不活性ガスとして窒素、ヘリウム、ネオン、アルゴンを使用することを特徴とする、請求項5から8までのいずれか1項記載の方法。
- 電子部品、電子回路および電気的に活性な充填剤を製造するための、請求項1から4までのいずれか1項記載のシリコン粉末の使用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10353995A DE10353995A1 (de) | 2003-11-19 | 2003-11-19 | Nanoskaliges, kristallines Siliciumpulver |
PCT/EP2004/012890 WO2005049492A1 (en) | 2003-11-19 | 2004-11-13 | Nanoscale crystalline silicon powder |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007511460A JP2007511460A (ja) | 2007-05-10 |
JP4607122B2 true JP4607122B2 (ja) | 2011-01-05 |
Family
ID=34559699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006540274A Active JP4607122B2 (ja) | 2003-11-19 | 2004-11-13 | ナノスケールの結晶質シリコン粉末 |
Country Status (11)
Country | Link |
---|---|
US (3) | US7776304B2 (ja) |
EP (1) | EP1685066B1 (ja) |
JP (1) | JP4607122B2 (ja) |
KR (1) | KR100769442B1 (ja) |
CN (1) | CN100404416C (ja) |
AT (1) | ATE517059T1 (ja) |
DE (1) | DE10353995A1 (ja) |
IL (1) | IL175701A (ja) |
RU (1) | RU2006121436A (ja) |
UA (1) | UA87672C2 (ja) |
WO (1) | WO2005049492A1 (ja) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6599631B2 (en) | 2001-01-26 | 2003-07-29 | Nanogram Corporation | Polymer-inorganic particle composites |
US20090075083A1 (en) | 1997-07-21 | 2009-03-19 | Nanogram Corporation | Nanoparticle production and corresponding structures |
US8568684B2 (en) | 2000-10-17 | 2013-10-29 | Nanogram Corporation | Methods for synthesizing submicron doped silicon particles |
US7226966B2 (en) | 2001-08-03 | 2007-06-05 | Nanogram Corporation | Structures incorporating polymer-inorganic particle blends |
ATE358706T1 (de) * | 2001-11-13 | 2007-04-15 | Degussa | Härtbare und wieder lösbare klebeverbindungen |
DE102004012682A1 (de) * | 2004-03-16 | 2005-10-06 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels Lasertechnik und Auftragen eines Absorbers per Inkjet-Verfahren |
DE102004016766A1 (de) * | 2004-04-01 | 2005-10-20 | Degussa | Nanoskalige Siliziumpartikel in negativen Elektrodenmaterialien für Lithium-Ionen-Batterien |
WO2006011290A1 (ja) * | 2004-07-29 | 2006-02-02 | Sumitomo Titanium Corporation | 二次電池用SiO粉末およびその製造方法 |
DE102004041747A1 (de) * | 2004-08-28 | 2006-03-02 | Degussa Ag | Indium-Zinn-Mischoxidpulver |
DE102004041746A1 (de) * | 2004-08-28 | 2006-03-02 | Degussa Ag | Kautschukmischung, enthaltend nanoskalige, magnetische Füllstoffe |
WO2006025194A1 (ja) * | 2004-09-01 | 2006-03-09 | Sumitomo Titanium Corporation | SiO蒸着材、SiO原料用Si粉末およびSiOの製造方法 |
DE102005049136A1 (de) * | 2004-12-01 | 2006-06-08 | Degussa Ag | Zubereitung, enthaltend ein polymerisierbares Monomer und/oder ein Polymer und darin dispergiert ein superparamagnetisches Pulver |
DE102005011940A1 (de) * | 2005-03-14 | 2006-09-21 | Degussa Ag | Verfahren zur Herstellung von beschichteten Kohlenstoffpartikel und deren Verwendung in Anodenmaterialien für Lithium-Ionenbatterien |
CN101137701B (zh) * | 2005-04-18 | 2011-02-09 | 赢创罗姆有限公司 | 由含纳米级无机粒子的热塑性塑料构成的模塑材料和模制品、所述模塑材料和模制品的制备方法及其用途 |
GB0515357D0 (en) * | 2005-07-27 | 2005-08-31 | Psimedica Ltd | Silicon package material |
EP1760045A1 (en) | 2005-09-03 | 2007-03-07 | Degussa GmbH | Nanoscale silicon particles |
DE102005049718A1 (de) * | 2005-10-14 | 2007-04-19 | Degussa Gmbh | Durch Schweißen im elektromagnetischen Wechselfeld erhältliche Kunststoffverbundformkörper |
DE102005056286A1 (de) * | 2005-11-24 | 2007-05-31 | Degussa Gmbh | Schweißverfahren mittels elektromagnetischer Strahlung |
DE102005059405A1 (de) * | 2005-12-13 | 2007-06-14 | Degussa Gmbh | Zinkoxid-Ceroxid-Kompositpartikel |
DE102005060121A1 (de) * | 2005-12-16 | 2007-06-21 | Degussa Gmbh | Verfahren zur Herstellung von Zinkoxidpulver |
DE102006007564A1 (de) * | 2006-02-16 | 2007-08-30 | Röhm Gmbh | Nanoskalige superparamagnetische Poly(meth)acrylatpolymere |
US9263771B2 (en) * | 2006-03-30 | 2016-02-16 | Sanyo Electric Co., Ltd. | Lithium secondary battery and method of manufacturing the same |
DE102006059318A1 (de) * | 2006-12-15 | 2008-06-19 | Evonik Degussa Gmbh | Poröses Silicium |
US8632702B2 (en) | 2007-01-03 | 2014-01-21 | Nanogram Corporation | Silicon/germanium particle inks, doped particles, printing and processes for semiconductor applications |
JP5040717B2 (ja) * | 2007-03-19 | 2012-10-03 | Jnc株式会社 | 高純度シリコンの製造方法 |
EP2090638A1 (de) | 2008-02-12 | 2009-08-19 | Evonik Degussa GmbH | Lumineszierende Silicium-Nanopartikel |
WO2009151489A2 (en) * | 2008-02-25 | 2009-12-17 | Corning Incorporated | Nanomaterial and method for generating nanomaterial |
DE102009033251A1 (de) | 2008-08-30 | 2010-09-23 | Universität Duisburg-Essen | Einlagerung von Silizium und/oder Zinn in poröse Kohlenstoffsubstrate |
DE102009024667A1 (de) | 2009-02-27 | 2010-09-02 | Universität Duisburg-Essen | Verfahren zur Herstellung eines Halbleiters sowie Halbleiter und elektrisches Element |
US20100243963A1 (en) * | 2009-03-31 | 2010-09-30 | Integrated Photovoltaics, Incorporated | Doping and milling of granular silicon |
US8895962B2 (en) | 2010-06-29 | 2014-11-25 | Nanogram Corporation | Silicon/germanium nanoparticle inks, laser pyrolysis reactors for the synthesis of nanoparticles and associated methods |
DE102011008815B4 (de) | 2011-01-19 | 2024-06-20 | Volkswagen Ag | Verfahren zur Herstellung von einem Kohlenstoffträger mit auf der Oberfläche befindlichen nanoskaligen Siliciumpartikeln |
DE102011008814A1 (de) | 2011-01-19 | 2012-07-19 | Volkswagen Ag | Verfahren zur Herstellung von einem Kohlenstoffträger mit auf der Oberfläche befindlichen nanoskaligen Siliciumpartikeln sowie ein entsprechender Kohlenstoffträger insbesondere für den Einsatz in Akkumulatoren |
US20140225030A1 (en) * | 2012-08-14 | 2014-08-14 | Hemlock Semiconductor Corporation | Method of controlling the crystallinity of a silicon powder |
US20150280222A1 (en) * | 2012-10-17 | 2015-10-01 | Institutt For Energiteknikk | Method, powder, film & lithium ion battery |
WO2014189886A1 (en) | 2013-05-24 | 2014-11-27 | Nanogram Corporation | Printable inks with silicon/germanium based nanoparticles with high viscosity alcohol solvents |
DE102013014627A1 (de) | 2013-08-30 | 2015-03-05 | Volkswagen Aktiengesellschaft | Pre-lithiierung von Siliziumpartikeln |
RU2561380C2 (ru) * | 2013-12-24 | 2015-08-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технический университет им. А.Н. Туполева-КАИ" (КНИТУ-КАИ) | Способ получения микротрубок |
CN104928761B (zh) * | 2014-03-19 | 2018-02-23 | 新特能源股份有限公司 | 一种硅片母合金的制备方法 |
EP3025701A1 (de) * | 2014-11-28 | 2016-06-01 | Evonik Degussa GmbH | Nanokristalline siliciumpulver, verfahren zu dessen herstellung als auch deren verwendung |
CN105399099B (zh) * | 2015-11-17 | 2018-06-15 | 大连理工大学 | 一种掺杂纳米硅材料的制备方法及其在光超级电容器领域的应用 |
KR101675469B1 (ko) | 2016-03-24 | 2016-11-14 | 주식회사 코스메카코리아 | 미세먼지를 함유한 인공대기환경 조성장치 |
CN105839182A (zh) * | 2016-04-11 | 2016-08-10 | 西安隆基硅材料股份有限公司 | 晶体硅及其制备方法 |
CN108883942A (zh) * | 2016-04-21 | 2018-11-23 | 株式会社德山 | 金属粉末的制造方法 |
JP7068034B2 (ja) | 2018-05-18 | 2022-05-16 | 株式会社トクヤマ | シリコン微粒子及びその製造方法 |
CN111908472B (zh) * | 2020-06-30 | 2023-05-16 | 山东天岳先进科技股份有限公司 | 一种掺杂稀土元素的碳化硅粉料及其制备方法与应用 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3012861A (en) * | 1960-01-15 | 1961-12-12 | Du Pont | Production of silicon |
US3900660A (en) * | 1972-08-21 | 1975-08-19 | Union Carbide Corp | Manufacture of silicon metal from a mixture of chlorosilanes |
US4292344A (en) * | 1979-02-23 | 1981-09-29 | Union Carbide Corporation | Fluidized bed heating process and apparatus |
US4341749A (en) * | 1981-08-14 | 1982-07-27 | Union Carbide Corporation | Heating method for silane pyrolysis reactor |
DE3610713A1 (de) | 1985-09-07 | 1987-03-19 | Hoechst Ag | Verfahren zur herstellung von silicium und dessen verbindungen in feinstteiliger form |
JPS6287408A (ja) * | 1985-09-07 | 1987-04-21 | ヘキスト・アクチエンゲゼルシヤフト | 特定の粒形を有する珪素の製造方法 |
US4994107A (en) * | 1986-07-09 | 1991-02-19 | California Institute Of Technology | Aerosol reactor production of uniform submicron powders |
US4826668A (en) * | 1987-06-11 | 1989-05-02 | Union Carbide Corporation | Process for the production of ultra high purity polycrystalline silicon |
JPH01239014A (ja) * | 1988-03-22 | 1989-09-25 | Nkk Corp | 多結晶シリコンの製造方法及び装置 |
NO165288C (no) | 1988-12-08 | 1991-01-23 | Elkem As | Silisiumpulver og fremgangsmaate for fremstilling av silisiumpulver. |
CA2058809A1 (en) * | 1991-01-07 | 1992-07-08 | Jitendra S. Goela | Chemical vapor deposition silicon and silicon carbide having improved optical properties |
FR2698683B1 (fr) * | 1992-12-01 | 1995-02-17 | Europ Propulsion | Dispositif de chargement de four spatial automatique. |
US5576248A (en) * | 1994-03-24 | 1996-11-19 | Starfire Electronic Development & Marketing, Ltd. | Group IV semiconductor thin films formed at low temperature using nanocrystal precursors |
GB9611437D0 (en) * | 1995-08-03 | 1996-08-07 | Secr Defence | Biomaterial |
US5695617A (en) | 1995-11-22 | 1997-12-09 | Dow Corning Corporation | Silicon nanoparticles |
US8568684B2 (en) * | 2000-10-17 | 2013-10-29 | Nanogram Corporation | Methods for synthesizing submicron doped silicon particles |
DE19735378A1 (de) * | 1997-08-14 | 1999-02-18 | Wacker Chemie Gmbh | Verfahren zur Herstellung von hochreinem Siliciumgranulat |
DE10140089A1 (de) | 2001-08-16 | 2003-02-27 | Degussa | Superparamagnetische oxidische Partikel, Verfahren zu deren Herstellung und ihre Verwendung |
US6723421B2 (en) * | 2001-10-05 | 2004-04-20 | Energy Conversion Devices, Inc. | Semiconductor with coordinatively irregular structures |
DE10153547A1 (de) | 2001-10-30 | 2003-05-22 | Degussa | Dispersion, enthaltend pyrogen hergestellte Abrasivpartikel mit superparamagnetischen Domänen |
ATE358706T1 (de) | 2001-11-13 | 2007-04-15 | Degussa | Härtbare und wieder lösbare klebeverbindungen |
DE10235758A1 (de) | 2002-08-05 | 2004-02-26 | Degussa Ag | Dotiertes Zinkoxidpulver, Verfahren zu seiner Herstellung und Verwendung |
DE10343728A1 (de) | 2003-09-22 | 2005-04-21 | Degussa | Zinkoxidpulver |
DE10353996A1 (de) * | 2003-11-19 | 2005-06-09 | Degussa Ag | Nanoskaliges, kristallines Siliciumpulver |
DE102004010504B4 (de) | 2004-03-04 | 2006-05-04 | Degussa Ag | Hochtransparente lasermarkierbare und laserschweißbare Kunststoffmaterialien, deren Verwendung und Herstellung sowie Verwendung von Metallmischoxiden und Verfahren zur Kennzeichnung von Produktionsgütern |
PL1722984T3 (pl) | 2004-03-04 | 2009-05-29 | Evonik Degussa Gmbh | Środkami barwiącymi przezroczyście, przeświecająco lub kryjąco zabarwione, zgrzewalne laserem materiały z tworzywa sztucznego |
DE102004012682A1 (de) | 2004-03-16 | 2005-10-06 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels Lasertechnik und Auftragen eines Absorbers per Inkjet-Verfahren |
DE102004041746A1 (de) | 2004-08-28 | 2006-03-02 | Degussa Ag | Kautschukmischung, enthaltend nanoskalige, magnetische Füllstoffe |
US7371227B2 (en) * | 2004-12-17 | 2008-05-13 | Ethicon Endo-Surgery, Inc. | Trocar seal assembly |
US7704586B2 (en) | 2005-03-09 | 2010-04-27 | Degussa Ag | Plastic molded bodies having two-dimensional and three-dimensional image structures produced through laser subsurface engraving |
CN101137701B (zh) | 2005-04-18 | 2011-02-09 | 赢创罗姆有限公司 | 由含纳米级无机粒子的热塑性塑料构成的模塑材料和模制品、所述模塑材料和模制品的制备方法及其用途 |
DE102005040157A1 (de) | 2005-08-25 | 2007-03-01 | Degussa Ag | Paste aus nanoskaligem Pulver und Dispergiermittel |
DE102005059405A1 (de) | 2005-12-13 | 2007-06-14 | Degussa Gmbh | Zinkoxid-Ceroxid-Kompositpartikel |
DE102005060121A1 (de) | 2005-12-16 | 2007-06-21 | Degussa Gmbh | Verfahren zur Herstellung von Zinkoxidpulver |
-
2003
- 2003-11-19 DE DE10353995A patent/DE10353995A1/de not_active Withdrawn
-
2004
- 2004-11-13 CN CNB2004800341316A patent/CN100404416C/zh active Active
- 2004-11-13 KR KR1020067009677A patent/KR100769442B1/ko active IP Right Grant
- 2004-11-13 RU RU2006121436/15A patent/RU2006121436A/ru not_active Application Discontinuation
- 2004-11-13 JP JP2006540274A patent/JP4607122B2/ja active Active
- 2004-11-13 UA UAA200606737A patent/UA87672C2/uk unknown
- 2004-11-13 US US10/579,460 patent/US7776304B2/en active Active
- 2004-11-13 AT AT04797876T patent/ATE517059T1/de not_active IP Right Cessation
- 2004-11-13 WO PCT/EP2004/012890 patent/WO2005049492A1/en active Application Filing
- 2004-11-13 EP EP04797876A patent/EP1685066B1/en active Active
-
2006
- 2006-05-17 IL IL175701A patent/IL175701A/en not_active IP Right Cessation
-
2010
- 2010-04-13 US US12/759,346 patent/US8043593B2/en active Active
- 2010-07-02 US US12/829,464 patent/US7927570B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP1685066A1 (en) | 2006-08-02 |
US20070094757A1 (en) | 2007-04-26 |
US20100193746A1 (en) | 2010-08-05 |
US7776304B2 (en) | 2010-08-17 |
CN1882503A (zh) | 2006-12-20 |
RU2006121436A (ru) | 2008-01-10 |
US7927570B2 (en) | 2011-04-19 |
DE10353995A1 (de) | 2005-06-09 |
EP1685066B1 (en) | 2011-07-20 |
JP2007511460A (ja) | 2007-05-10 |
KR100769442B1 (ko) | 2007-10-22 |
CN100404416C (zh) | 2008-07-23 |
US20100264377A1 (en) | 2010-10-21 |
ATE517059T1 (de) | 2011-08-15 |
WO2005049492A1 (en) | 2005-06-02 |
IL175701A (en) | 2012-04-30 |
KR20060096448A (ko) | 2006-09-11 |
US8043593B2 (en) | 2011-10-25 |
UA87672C2 (uk) | 2009-08-10 |
IL175701A0 (en) | 2006-09-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4607122B2 (ja) | ナノスケールの結晶質シリコン粉末 | |
KR100769441B1 (ko) | 나노스케일, 결정성 실리콘 분말 | |
Yasar-Inceoglu et al. | Silicon nanocrystal production through non-thermal plasma synthesis: a comparative study between silicon tetrachloride and silane precursors | |
TWI541375B (zh) | SiC成形體及SiC成形體之製造方法 | |
US20100221544A1 (en) | Nanoscale silicon particles | |
JP2015107916A (ja) | 多結晶シリコン | |
US20160152836A1 (en) | Use of silicon-containing particles for protection of industrial materials from uv radiation | |
JPS6225605B2 (ja) | ||
JP5823058B2 (ja) | ポリシリコンの製造方法 | |
JP7427848B1 (ja) | 多結晶SiC成形体及びその製造方法 | |
Zhou et al. | Fabrication and characterization of Zn-doped CdTe nanowires | |
EP4190748A1 (en) | Method of manufacturing high-purity sic crystal | |
EP3025701A1 (de) | Nanokristalline siliciumpulver, verfahren zu dessen herstellung als auch deren verwendung | |
JP6144161B2 (ja) | 窒化ケイ素膜原料、およびこの原料から得られた窒化ケイ素膜 | |
WO2015058285A1 (en) | Solid source and method for the synthesis of silicon- containing precursors for chemical vapor deposition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090618 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20090918 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20090930 |
|
RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20091006 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091016 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100323 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100622 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100928 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20100928 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20101006 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4607122 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20131015 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |