JP4495464B2 - 集積回路の製造方法 - Google Patents
集積回路の製造方法 Download PDFInfo
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- JP4495464B2 JP4495464B2 JP2003562972A JP2003562972A JP4495464B2 JP 4495464 B2 JP4495464 B2 JP 4495464B2 JP 2003562972 A JP2003562972 A JP 2003562972A JP 2003562972 A JP2003562972 A JP 2003562972A JP 4495464 B2 JP4495464 B2 JP 4495464B2
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Images
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KR100498464B1 (ko) * | 2002-11-22 | 2005-07-01 | 삼성전자주식회사 | 불소 함유 감광성 폴리머, 이를 포함하는 레지스트 조성물및 레지스트 조성물을 이용한 패턴 형성 방법 |
US7514709B2 (en) * | 2003-04-11 | 2009-04-07 | Silecs Oy | Organo-silsesquioxane polymers for forming low-k dielectrics |
TWI220774B (en) * | 2003-11-03 | 2004-09-01 | Univ Nat Sun Yat Sen | Method for patterning low dielectric constant film and method for manufacturing dual damascene structure |
US8053159B2 (en) | 2003-11-18 | 2011-11-08 | Honeywell International Inc. | Antireflective coatings for via fill and photolithography applications and methods of preparation thereof |
DE602004030379D1 (de) * | 2003-12-23 | 2011-01-13 | Silecs Oy | Adamantylmonomere und polymere für low-k-dielektrik anwendungen |
CN101044604B (zh) * | 2004-08-31 | 2011-11-16 | 西雷克斯有限公司 | 新聚有机硅氧烷介电材料 |
US7332822B2 (en) * | 2004-11-12 | 2008-02-19 | Delphi Technologies, Inc. | Flip chip system with organic/inorganic hybrid underfill composition |
US20060199301A1 (en) * | 2005-03-07 | 2006-09-07 | Basheer Rafil A | Methods of making a curable composition having low coefficient of thermal expansion and an integrated circuit and a curable composition and integrated circuit made there from |
TW200736855A (en) * | 2006-03-22 | 2007-10-01 | Quanta Display Inc | Method of fabricating photoresist thinner |
JP4407673B2 (ja) * | 2006-07-10 | 2010-02-03 | セイコーエプソン株式会社 | バンク構造、電子回路、及び電子デバイスの製造方法、並びにパターン形成方法 |
US7501353B2 (en) * | 2006-12-22 | 2009-03-10 | International Business Machines Corporation | Method of formation of a damascene structure utilizing a protective film |
TWI434891B (zh) * | 2007-02-22 | 2014-04-21 | Silecs Oy | 積體電路用高矽含量矽氧烷聚合物 |
KR100881458B1 (ko) * | 2007-02-23 | 2009-02-06 | 삼성전자주식회사 | 마이크로렌즈 보호패턴을 갖는 촬상소자, 카메라모듈, 및그 제조방법 |
US8642246B2 (en) | 2007-02-26 | 2014-02-04 | Honeywell International Inc. | Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof |
US20080206997A1 (en) * | 2007-02-26 | 2008-08-28 | Semiconductor Energy Laboratory Co., Ltd. | Method for Manufacturing Insulating Film and Method for Manufacturing Semiconductor Device |
JP5330697B2 (ja) * | 2007-03-19 | 2013-10-30 | 株式会社リコー | 機能素子のパッケージ及びその製造方法 |
JP2011511881A (ja) | 2007-06-28 | 2011-04-14 | アドバンスド テクノロジー マテリアルズ,インコーポレイテッド | 二酸化ケイ素ギャップ充填材のための前駆体 |
US8084862B2 (en) | 2007-09-20 | 2011-12-27 | International Business Machines Corporation | Interconnect structures with patternable low-k dielectrics and method of fabricating same |
US7709370B2 (en) * | 2007-09-20 | 2010-05-04 | International Business Machines Corporation | Spin-on antireflective coating for integration of patternable dielectric materials and interconnect structures |
US8618663B2 (en) * | 2007-09-20 | 2013-12-31 | International Business Machines Corporation | Patternable dielectric film structure with improved lithography and method of fabricating same |
KR101371998B1 (ko) | 2008-01-25 | 2014-03-07 | 삼성전자주식회사 | 절연체 형성용 조성물 및 이를 이용하는 유기 절연체 |
US8029971B2 (en) * | 2008-03-13 | 2011-10-04 | International Business Machines Corporation | Photopatternable dielectric materials for BEOL applications and methods for use |
TWI491657B (zh) | 2008-04-28 | 2015-07-11 | Basf Se | 可由雙聚合得到之低k介電質 |
JP5096233B2 (ja) * | 2008-05-30 | 2012-12-12 | 信越化学工業株式会社 | 有機酸化ケイ素系微粒子及びその製造方法、多孔質膜形成用組成物、多孔質膜及びその形成方法、並びに半導体装置 |
US20110068332A1 (en) * | 2008-08-04 | 2011-03-24 | The Trustees Of Princeton University | Hybrid Dielectric Material for Thin Film Transistors |
KR20110039454A (ko) * | 2008-08-04 | 2011-04-18 | 더 트러스티즈 오브 프린스턴 유니버시티 | 박막 트랜지스터용 하이브리드 유전 재료 |
US7968975B2 (en) * | 2008-08-08 | 2011-06-28 | International Business Machines Corporation | Metal wiring structure for integration with through substrate vias |
US8557877B2 (en) | 2009-06-10 | 2013-10-15 | Honeywell International Inc. | Anti-reflective coatings for optically transparent substrates |
US8864898B2 (en) | 2011-05-31 | 2014-10-21 | Honeywell International Inc. | Coating formulations for optical elements |
JP5675581B2 (ja) * | 2011-12-27 | 2015-02-25 | 東レ・ダウコーニング株式会社 | 有機珪素化合物の製造方法 |
KR101567702B1 (ko) * | 2014-06-27 | 2015-11-10 | 재단법인 다차원 스마트 아이티 융합시스템 연구단 | 듀얼 애퍼처 필터 및 그 제작 방법 |
US9711351B2 (en) * | 2014-09-11 | 2017-07-18 | Asm Ip Holding B.V. | Process for densifying nitride film |
WO2016167892A1 (en) | 2015-04-13 | 2016-10-20 | Honeywell International Inc. | Polysiloxane formulations and coatings for optoelectronic applications |
KR20230117645A (ko) | 2017-04-26 | 2023-08-08 | 오티아이 루미오닉스 인크. | 표면의 코팅을 패턴화하는 방법 및 패턴화된 코팅을포함하는 장치 |
JP6848825B2 (ja) * | 2017-11-20 | 2021-03-24 | 信越化学工業株式会社 | 光硬化性組成物およびその硬化物 |
US11086048B1 (en) | 2020-02-07 | 2021-08-10 | HyperLight Corporation | Lithium niobate devices fabricated using deep ultraviolet radiation |
US11899293B2 (en) | 2020-02-07 | 2024-02-13 | HyperLight Corporation | Electro optical devices fabricated using deep ultraviolet radiation |
Family Cites Families (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5760330A (en) * | 1980-09-27 | 1982-04-12 | Fujitsu Ltd | Resin composition |
DE3278567D1 (en) * | 1981-10-03 | 1988-07-07 | Japan Synthetic Rubber Co Ltd | Solvent-soluble organopolysilsesquioxanes, processes for producing the same, and compositions and semiconductor devices using the same |
US4507384A (en) * | 1983-04-18 | 1985-03-26 | Nippon Telegraph & Telephone Public Corporation | Pattern forming material and method for forming pattern therewith |
US4983419A (en) * | 1988-08-05 | 1991-01-08 | Siemens Aktiengesellschaft | Method for generating thin layers on a silicone base |
JPH0821579B2 (ja) * | 1989-04-19 | 1996-03-04 | 旭硝子株式会社 | 半導体素子・集積回路装置 |
JP2718231B2 (ja) | 1990-01-10 | 1998-02-25 | 三菱電機株式会社 | 高純度末端ヒドロキシフェニルラダーシロキサンプレポリマーの製造方法および高純度末端ヒドロキシフェニルラダーポリシロキサンの製造方法 |
US5449553A (en) * | 1992-03-06 | 1995-09-12 | The United States Of America As Represented By The Secretary Of The Navy | Nontoxic antifouling systems |
JP4082626B2 (ja) * | 1996-11-19 | 2008-04-30 | 松下電器産業株式会社 | 層間絶縁膜形成用材料及び層間絶縁膜 |
EP0849796A3 (en) * | 1996-12-17 | 1999-09-01 | Texas Instruments Incorporated | Improvements in or relating to integrated circuits |
JP3919862B2 (ja) * | 1996-12-28 | 2007-05-30 | Azエレクトロニックマテリアルズ株式会社 | 低誘電率シリカ質膜の形成方法及び同シリカ質膜 |
US6051321A (en) * | 1997-10-24 | 2000-04-18 | Quester Technology, Inc. | Low dielectric constant materials and method |
US6126733A (en) * | 1997-10-31 | 2000-10-03 | Alliedsignal Inc. | Alcohol based precursors for producing nanoporous silica thin films |
JP2000077399A (ja) * | 1998-01-21 | 2000-03-14 | Nippon Steel Corp | シリカ系多孔質膜およびその製造方法 |
US20060258176A1 (en) * | 1998-02-05 | 2006-11-16 | Asm Japan K.K. | Method for forming insulation film |
US6068884A (en) * | 1998-04-28 | 2000-05-30 | Silcon Valley Group Thermal Systems, Llc | Method of making low κ dielectric inorganic/organic hybrid films |
US6448655B1 (en) * | 1998-04-28 | 2002-09-10 | International Business Machines Corporation | Stabilization of fluorine-containing low-k dielectrics in a metal/insulator wiring structure by ultraviolet irradiation |
JPH11322992A (ja) * | 1998-05-18 | 1999-11-26 | Jsr Corp | 多孔質膜 |
EP1026213B1 (en) | 1998-09-01 | 2014-11-05 | JGC Catalysts and Chemicals Ltd. | Coating fluid for forming low-permittivity silica-based coating film and substrate with low-permittivity coating film |
US6281115B1 (en) * | 1998-11-16 | 2001-08-28 | Industrial Technology Research Institute | Sidewall protection for a via hole formed in a photosensitive, low dielectric constant layer |
JP4739473B2 (ja) | 1999-01-28 | 2011-08-03 | 日立化成工業株式会社 | シリカ系被膜形成用塗布液、シリカ系被膜及びこれを用いた半導体装置 |
JP2001049184A (ja) * | 1999-06-01 | 2001-02-20 | Jsr Corp | 膜形成用組成物、膜の形成方法および低密度化膜 |
JP2001049176A (ja) * | 1999-06-01 | 2001-02-20 | Jsr Corp | 膜形成用組成物、膜の形成方法および低密度化膜 |
JP2001049179A (ja) * | 1999-06-01 | 2001-02-20 | Jsr Corp | 膜形成用組成物、膜の形成方法および低密度化膜 |
US6696538B2 (en) * | 1999-07-27 | 2004-02-24 | Lg Chemical Ltd. | Semiconductor interlayer dielectric material and a semiconductor device using the same |
JP4427840B2 (ja) * | 1999-09-17 | 2010-03-10 | ソニー株式会社 | 半導体装置及びその製造方法 |
JP4022802B2 (ja) * | 1999-09-29 | 2007-12-19 | Jsr株式会社 | 膜形成用組成物、膜の形成方法および絶縁膜 |
US6440550B1 (en) * | 1999-10-18 | 2002-08-27 | Honeywell International Inc. | Deposition of fluorosilsesquioxane films |
JP2001164184A (ja) * | 1999-12-10 | 2001-06-19 | Fujitsu Ltd | 被覆形成用塗布液及び被覆膜及びそれを用いた半導体装置 |
US20040038048A1 (en) * | 2000-02-02 | 2004-02-26 | Lg Chemical Ltd. | Semiconductor interlayer dielectric material and a semiconductor device using the same |
JP2001287910A (ja) | 2000-04-04 | 2001-10-16 | Asahi Kasei Corp | 多孔質ケイ素酸化物塗膜の製造方法 |
JP2002003784A (ja) * | 2000-04-17 | 2002-01-09 | Jsr Corp | 膜形成用組成物、膜の形成方法およびシリカ系膜 |
JP4840547B2 (ja) | 2000-04-17 | 2011-12-21 | Jsr株式会社 | 絶縁膜形成用組成物、絶縁膜の形成方法およびシリカ系膜 |
JP2001329216A (ja) | 2000-05-22 | 2001-11-27 | Jsr Corp | 膜形成用組成物、膜の形成方法およびシリカ系膜 |
JP2002026121A (ja) * | 2000-06-30 | 2002-01-25 | Tokyo Electron Ltd | 半導体装置およびその製造方法、絶縁膜の形成方法 |
KR100738774B1 (ko) * | 2000-08-28 | 2007-07-12 | 제이에스알 가부시끼가이샤 | 화학 기계 연마 스토퍼막, 그의 제조 방법 및 화학 기계연마 방법 |
US6569349B1 (en) * | 2000-10-23 | 2003-05-27 | Applied Materials Inc. | Additives to CMP slurry to polish dielectric films |
US6383912B1 (en) * | 2000-10-23 | 2002-05-07 | Honeywell International, Inc. | Fabrication method of integrated circuits with multiple low dielectric-constant intermetal dielectrics |
JP4863182B2 (ja) * | 2002-01-31 | 2012-01-25 | 東ソー株式会社 | 有機シラン化合物を含んでなる絶縁膜用材料、その製造方法および半導体デバイス |
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AU2003216067A1 (en) | 2003-09-02 |
KR100985272B1 (ko) | 2010-10-04 |
KR20040075089A (ko) | 2004-08-26 |
US7479462B2 (en) | 2009-01-20 |
EP1490454A4 (en) | 2010-03-17 |
EP1490454B1 (en) | 2012-08-15 |
US20060131753A1 (en) | 2006-06-22 |
JP2005516391A (ja) | 2005-06-02 |
US20030186494A1 (en) | 2003-10-02 |
US6974970B2 (en) | 2005-12-13 |
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