JP4489841B2 - スピネル型リチウム遷移金属酸化物 - Google Patents

スピネル型リチウム遷移金属酸化物 Download PDF

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Publication number
JP4489841B2
JP4489841B2 JP2009503345A JP2009503345A JP4489841B2 JP 4489841 B2 JP4489841 B2 JP 4489841B2 JP 2009503345 A JP2009503345 A JP 2009503345A JP 2009503345 A JP2009503345 A JP 2009503345A JP 4489841 B2 JP4489841 B2 JP 4489841B2
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Prior art keywords
transition metal
metal oxide
spinel
lithium transition
type lithium
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Japanese (ja)
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JPWO2009054436A1 (ja
Inventor
直樹 熊田
慎也 蔭井
祥巳 畑
健志 佐々木
康弘 越智
啓祐 宮之原
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Mitsui Kinzoku Co Ltd
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Mitsui Mining and Smelting Co Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
JP2009503345A 2007-10-23 2008-10-23 スピネル型リチウム遷移金属酸化物 Active JP4489841B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2007275500 2007-10-23
JP2007275500 2007-10-23
JP2008237043 2008-09-16
JP2008237043 2008-09-16
PCT/JP2008/069191 WO2009054436A1 (ja) 2007-10-23 2008-10-23 スピネル型リチウム遷移金属酸化物

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2009271546A Division JP4987063B2 (ja) 2007-10-23 2009-11-30 スピネル型リチウム遷移金属酸化物

Publications (2)

Publication Number Publication Date
JP4489841B2 true JP4489841B2 (ja) 2010-06-23
JPWO2009054436A1 JPWO2009054436A1 (ja) 2011-03-03

Family

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JP2009503345A Active JP4489841B2 (ja) 2007-10-23 2008-10-23 スピネル型リチウム遷移金属酸化物
JP2009271546A Active JP4987063B2 (ja) 2007-10-23 2009-11-30 スピネル型リチウム遷移金属酸化物

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Country Status (6)

Country Link
US (1) US7988880B2 (enExample)
EP (2) EP2214232B1 (enExample)
JP (2) JP4489841B2 (enExample)
KR (1) KR101012323B1 (enExample)
AT (1) ATE545162T1 (enExample)
WO (1) WO2009054436A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008029804A1 (de) 2008-06-24 2010-07-08 Süd-Chemie AG Mischoxid enthaltend einen Lithium-Mangan-Spinell und Verfahren zu dessen Herstellung
US8703341B2 (en) 2009-03-31 2014-04-22 Mitsui Mining & Smelting Co., Ltd. Positive electrode active material for lithium battery
KR101520903B1 (ko) * 2010-03-29 2015-05-18 주식회사 포스코이에스엠 리튬 이온 이차 전지용 리튬 망간 복합 산화물의 제조 방법, 그 제조 방법에 의하여 제조된 리튬 이온 이차 전지용 리튬 망간 복합 산화물, 및 이를 포함하는 리튬 이온 이차 전지
JP5575537B2 (ja) * 2010-05-10 2014-08-20 日立マクセル株式会社 非水電解質電池
KR101330613B1 (ko) * 2010-06-13 2013-11-18 삼성에스디아이 주식회사 리튬 이차전지용 양극 활물질의 제조 방법
US20110311435A1 (en) * 2010-06-21 2011-12-22 Ngk Insulators, Ltd. Method for producing spinel-type lithium manganate
US20100330429A1 (en) * 2010-06-21 2010-12-30 Ngk Insulators, Ltd. Positive electrode active material and lithium secondary battery
WO2012008480A1 (ja) * 2010-07-16 2012-01-19 三井金属鉱業株式会社 スピネル型リチウム遷移金属酸化物及びリチウム電池用正極活物質材料
KR101264333B1 (ko) * 2011-01-12 2013-05-14 삼성에스디아이 주식회사 양극활물질, 이를 채용한 양극과 리튬전지 및 그 제조방법
WO2012118117A1 (ja) 2011-03-02 2012-09-07 三井金属鉱業株式会社 スピネル型リチウムマンガン系複合酸化物
JP2013218875A (ja) 2012-04-09 2013-10-24 Sony Corp 正極活物質、正極、二次電池、電池パック、電動車両、電力貯蔵システム、電動工具および電子機器
JP2014060143A (ja) 2012-08-22 2014-04-03 Sony Corp 正極活物質、正極および電池、並びに電池パック、電子機器、電動車両、蓄電装置および電力システム
KR101529951B1 (ko) * 2012-09-25 2015-06-18 미쓰이금속광업주식회사 스피넬형 리튬망간 함유 복합 산화물
US9905851B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Cathode active material and method of preparing the same
JP6048711B2 (ja) * 2013-07-26 2016-12-21 エルジー・ケム・リミテッド 多結晶リチウムマンガン酸化物粒子、その製造方法及びこれを含む正極活物質、正極、およびリチウム二次電池
US9905850B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same
EP3065207B1 (en) * 2013-10-29 2017-08-30 LG Chem, Ltd. Manufacturing method of cathode active material, and cathode active material for lithium secondary battery manufactured thereby
CN105745174B (zh) 2013-11-22 2018-04-10 三井金属矿业株式会社 尖晶石型锂金属复合氧化物
GB2536166B (en) * 2013-12-04 2018-03-07 Mitsui Mining & Smelting Co Spinel-type lithium cobalt manganese-containing complex oxide
KR102327532B1 (ko) * 2018-11-20 2021-11-17 주식회사 엘지화학 리튬 이차전지용 양극 활물질 및 이의 제조 방법
US20240304802A1 (en) * 2020-12-25 2024-09-12 Tosoh Corporation Spinel-type lithium manganese oxide, method for producing the same and applications thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000159522A (ja) * 1998-11-19 2000-06-13 Tosoh Corp Ｍｇ含有スピネル構造リチウムマンガン複合酸化物及びその製造法並びにその用途
JP2001106528A (ja) * 1999-10-01 2001-04-17 Mitsui Mining & Smelting Co Ltd マンガン酸リチウム及びこれを用いたリチウム二次電池
JP2001180939A (ja) * 1999-12-24 2001-07-03 Mitsui Mining & Smelting Co Ltd スピネル型マンガン酸リチウムの製造方法
JP2002316823A (ja) * 2001-02-16 2002-10-31 Tosoh Corp リチウムマンガン複合酸化物とその製造方法並びにその用途
JP2004186149A (ja) * 2002-11-22 2004-07-02 Mitsui Mining & Smelting Co Ltd Ｌｉイオン二次電池用正極材料

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JPH1145710A (ja) 1997-07-25 1999-02-16 Toshiba Corp リチウムイオン二次電池
JP3670895B2 (ja) * 1999-08-04 2005-07-13 三洋電機株式会社 リチウム二次電池
JP2001223006A (ja) 2000-02-08 2001-08-17 Nissan Motor Co Ltd リチウム二次電池用正極活物質およびリチウム二次電池
JP2002000331A (ja) 2000-06-22 2002-01-08 Kaburagi Kikaku:Kk 携帯品用支持具
JP2002033101A (ja) 2000-07-14 2002-01-31 Mitsui Mining & Smelting Co Ltd リチウムーマンガン系酸化物及びこれを用いたリチウム二次電池
JP2002151070A (ja) * 2000-11-06 2002-05-24 Japan Storage Battery Co Ltd 非水電解質二次電池
EP1233001B1 (en) * 2001-02-16 2010-09-15 Tosoh Corporation Lithium-manganese complex oxide, production method thereof and use thereof
WO2004049474A1 (ja) * 2002-11-22 2004-06-10 Mitsui Mining & Smelting Co., Ltd. Liイオン二次電池用正極材料
JP2004356092A (ja) * 2003-05-02 2004-12-16 Sony Corp 電池

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000159522A (ja) * 1998-11-19 2000-06-13 Tosoh Corp Ｍｇ含有スピネル構造リチウムマンガン複合酸化物及びその製造法並びにその用途
JP2001106528A (ja) * 1999-10-01 2001-04-17 Mitsui Mining & Smelting Co Ltd マンガン酸リチウム及びこれを用いたリチウム二次電池
JP2001180939A (ja) * 1999-12-24 2001-07-03 Mitsui Mining & Smelting Co Ltd スピネル型マンガン酸リチウムの製造方法
JP2002316823A (ja) * 2001-02-16 2002-10-31 Tosoh Corp リチウムマンガン複合酸化物とその製造方法並びにその用途
JP2004186149A (ja) * 2002-11-22 2004-07-02 Mitsui Mining & Smelting Co Ltd Ｌｉイオン二次電池用正極材料

Also Published As

Publication number Publication date
WO2009054436A1 (ja) 2009-04-30
JP2010097947A (ja) 2010-04-30
ATE545162T1 (de) 2012-02-15
EP2214232B1 (en) 2012-02-08
EP2442388A1 (en) 2012-04-18
KR20100075418A (ko) 2010-07-02
US20100243952A1 (en) 2010-09-30
EP2214232A1 (en) 2010-08-04
EP2214232A4 (en) 2010-12-22
JPWO2009054436A1 (ja) 2011-03-03
US7988880B2 (en) 2011-08-02
KR101012323B1 (ko) 2011-02-08
EP2442388B1 (en) 2013-07-10
JP4987063B2 (ja) 2012-07-25

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