JP4300445B2 - 重合調節剤としての長アルキル鎖を有する２，２，６，６−テトラアルキルピペリジン−ｎ−オキシルラジカルの使用 - Google Patents

重合調節剤としての長アルキル鎖を有する２，２，６，６−テトラアルキルピペリジン−ｎ−オキシルラジカルの使用 Download PDF

Info

Publication number
JP4300445B2
JP4300445B2 JP2000555948A JP2000555948A JP4300445B2 JP 4300445 B2 JP4300445 B2 JP 4300445B2 JP 2000555948 A JP2000555948 A JP 2000555948A JP 2000555948 A JP2000555948 A JP 2000555948A JP 4300445 B2 JP4300445 B2 JP 4300445B2
Authority
JP
Japan
Prior art keywords
carbon atoms
group
polymerization
polymer
oligomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2000555948A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002518559A5 (enExample
JP2002518559A (ja
Inventor
ヴィーブケ ウンデルリッヒ
マルゴー クルー
ミハエル ロス
フランチェスコ フソ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JP2002518559A publication Critical patent/JP2002518559A/ja
Publication of JP2002518559A5 publication Critical patent/JP2002518559A5/ja
Application granted granted Critical
Publication of JP4300445B2 publication Critical patent/JP4300445B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Graft Or Block Polymers (AREA)
JP2000555948A 1998-06-25 1999-06-15 重合調節剤としての長アルキル鎖を有する２，２，６，６−テトラアルキルピペリジン−ｎ−オキシルラジカルの使用 Expired - Fee Related JP4300445B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98810585.4 1998-06-25
EP98810585 1998-06-25
PCT/EP1999/004119 WO1999067298A1 (en) 1998-06-25 1999-06-15 Use of 2,2,6,6 tetraalkylpiperidine-n-oxyl radicals having long alkyl chains as polymerization regulators

Publications (3)

Publication Number Publication Date
JP2002518559A JP2002518559A (ja) 2002-06-25
JP2002518559A5 JP2002518559A5 (enExample) 2006-08-03
JP4300445B2 true JP4300445B2 (ja) 2009-07-22

Family

ID=8236156

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000555948A Expired - Fee Related JP4300445B2 (ja) 1998-06-25 1999-06-15 重合調節剤としての長アルキル鎖を有する２，２，６，６−テトラアルキルピペリジン−ｎ−オキシルラジカルの使用

Country Status (11)

Country Link
US (1) US6569940B1 (enExample)
EP (1) EP1095066B1 (enExample)
JP (1) JP4300445B2 (enExample)
KR (1) KR100578457B1 (enExample)
AU (1) AU4772399A (enExample)
CA (1) CA2334563C (enExample)
DE (1) DE69930517T2 (enExample)
ES (1) ES2259835T3 (enExample)
MY (1) MY133149A (enExample)
TW (1) TWI246519B (enExample)
WO (1) WO1999067298A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60017790T2 (de) * 1999-12-09 2005-06-30 Ciba Specialty Chemicals Holding Inc. Verwendung von einer zusatzzusammensetzung zur erhöhung der lagerstabilität von äthylenischen ungesättigten harzen
TW541303B (en) * 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
BR0110854B1 (pt) 2000-05-19 2017-10-24 Ciba Specialty Chemicals Holdings Inc Method for reducing the polypropylene molecular weight, propylene copolymers or polypropylene mixtures, as a compound
TW574236B (en) * 2000-09-25 2004-02-01 Ciba Sc Holding Ag Process for controlled radical polymerization in aqueous dispersion
WO2004000809A1 (en) 2002-06-24 2003-12-31 Ciba Specialty Chemicals Holding Inc. Cationic alkoxyamines and their use in producing nano particles from natural or synthetic clays
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
EP1861429B1 (en) 2005-01-11 2013-03-13 Basf Se Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
EP2978786A1 (en) 2013-03-27 2016-02-03 Basf Se Block copolymers as soil release agents in laundry processes
CN108498458B (zh) * 2018-05-03 2019-10-11 大连理工大学 一种基于普鲁兰多糖的用于超声控制释放的纳米药物载体、药物载体系统及制备方法
EP4251665B1 (en) 2020-11-30 2025-01-08 Basf Se Process of producing polymer dispersions
CN117062872A (zh) 2021-03-26 2023-11-14 巴斯夫欧洲公司 作为分散剂的包含聚丙烯酸系嵌段共聚物和芳族基聚氧化烯的聚合物组合物

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4314933A (en) * 1979-02-15 1982-02-09 Ciba-Geigy Corporation Method for light stabilization of two-layer uni-lacquer coatings
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법
US5204473A (en) 1987-09-21 1993-04-20 Ciba-Geigy Corporation O-substituted N-hydroxy hindered amine stabilizers
US5412047A (en) 1994-05-13 1995-05-02 Xerox Corporation Homoacrylate polymerization processes with oxonitroxides
DE19510184A1 (de) * 1995-03-21 1996-09-26 Basf Ag 4-Acylaminopiperidin-N-oxyle
US5654434A (en) 1995-11-09 1997-08-05 Ciba-Geigy Corporation Hydrogen peroxide oxidation of 4-hydroxy-2, 2, 6, 6-tetramethylpiperidine
BR9708300A (pt) 1996-03-29 1999-08-03 Dow Chemical Co Processo de polimerização em massa por radical livre
DE19622441A1 (de) * 1996-06-05 1997-12-11 Basf Ag Verfahren zum Verdichten ethylenisch ungesättigter Monomerer
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
DE19648811A1 (de) 1996-11-27 1998-05-28 Basf Ag Verfahren zur Polymerisation vinylischer Monomerer
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
US6140396A (en) * 1997-12-19 2000-10-31 Nippon Shokubai Co., Ltd. Thermosetting resin composition and producing process thereof

Also Published As

Publication number Publication date
EP1095066B1 (en) 2006-03-22
DE69930517T2 (de) 2006-08-17
KR20010053043A (ko) 2001-06-25
US6569940B1 (en) 2003-05-27
EP1095066A1 (en) 2001-05-02
AU4772399A (en) 2000-01-10
TWI246519B (en) 2006-01-01
DE69930517D1 (de) 2006-05-11
MY133149A (en) 2007-10-31
WO1999067298A1 (en) 1999-12-29
CA2334563C (en) 2007-07-31
ES2259835T3 (es) 2006-10-16
CA2334563A1 (en) 1999-12-29
KR100578457B1 (ko) 2006-05-10
JP2002518559A (ja) 2002-06-25

Similar Documents

Publication Publication Date Title
JP4300445B2 (ja) 重合調節剤としての長アルキル鎖を有する２，２，６，６−テトラアルキルピペリジン−ｎ−オキシルラジカルの使用
KR100479628B1 (ko) 리빙 특성을 갖는 중합 방법
KR100743975B1 (ko) 2,2,6,6 디에틸-디메틸-1-알콕시-피페리딘 화합물 및이들을 포함하는 중합성 조성물
GB2335190A (en) 1-Alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
AU2007347458A1 (en) Process for transforming the end groups of polymers
MXPA05001530A (es) Alcoxiaminas que se originan de nitroxidos b-fosforilados y su uso en la polimerizacion de radical.
JP2002524589A (ja) ポリマー上へのエチレン性不飽和モノマーのグラフト化
JP2002524590A (ja) エチレン系不飽和モノマーのポリマーへのグラフト
JP4389247B2 (ja) ４−イミノ−ｎ−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用
KR20030032031A (ko) 디술피드 화합물 존재 하의 제어 라디칼중합에 의한 블록중합체의 합성 방법
KR20030051780A (ko) 안정한 자유 니트록실 라디칼의 존재하에서 염화비닐의(공)중합반응
DE60012738T2 (de) Mono- und multifunktionelle alkoxyamine zur herstellung von funktionalisierten makromeren
EP1082369A1 (en) Process to make low-molecular weight sma
US6864313B2 (en) Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
ES2246585T3 (es) Composicion y procedimiento para polimerizacion radicalica controlada utilizando compuestos iniciadores/reguladores multifuncionales.
JP2004509988A (ja) 水性分散液中の制御されたラジカル重合方法
EP0891986A1 (en) Polymerizable compositions containing alkoxyamine compounds derived from nitrogen oxide
JP4490269B2 (ja) エポキシ官能化したニトロキシルエーテルを使用する櫛型または星型コポリマーの生成方法
JP2004067680A (ja) アルコキシアミンの合成方法およびそのラジカル重合における使用
ES2258555T3 (es) Composicion y procedimiento para mejorar la polimerizacion de radical libre controlada.
JP2007091882A (ja) 樹脂の合成法

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060612

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060612

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20081113

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20081126

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090225

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20090325

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20090408

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120501

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees