JP4279687B2 - レトロクロミックビーズの製造方法およびそのキット - Google Patents
レトロクロミックビーズの製造方法およびそのキット Download PDFInfo
- Publication number
- JP4279687B2 JP4279687B2 JP2003584780A JP2003584780A JP4279687B2 JP 4279687 B2 JP4279687 B2 JP 4279687B2 JP 2003584780 A JP2003584780 A JP 2003584780A JP 2003584780 A JP2003584780 A JP 2003584780A JP 4279687 B2 JP4279687 B2 JP 4279687B2
- Authority
- JP
- Japan
- Prior art keywords
- beads
- retrochromic
- essentially
- retroreflective
- optical interference
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011324 bead Substances 0.000 title claims abstract description 198
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 25
- 230000003287 optical effect Effects 0.000 claims description 56
- 238000000034 method Methods 0.000 claims description 37
- 238000000151 deposition Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 4
- 239000011521 glass Substances 0.000 description 49
- 239000002243 precursor Substances 0.000 description 30
- 239000000463 material Substances 0.000 description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 25
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 23
- 229910044991 metal oxide Inorganic materials 0.000 description 22
- 150000004706 metal oxides Chemical class 0.000 description 22
- 239000000203 mixture Substances 0.000 description 22
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 238000000576 coating method Methods 0.000 description 16
- 238000001228 spectrum Methods 0.000 description 16
- 239000012159 carrier gas Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 13
- 239000000377 silicon dioxide Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000008021 deposition Effects 0.000 description 11
- 229910010413 TiO 2 Inorganic materials 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000012071 phase Substances 0.000 description 8
- 238000002791 soaking Methods 0.000 description 8
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000005286 illumination Methods 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000001066 destructive effect Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000000543 intermediate Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000003301 hydrolyzing effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- -1 metalloid cations Chemical class 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000001429 visible spectrum Methods 0.000 description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 229910003902 SiCl 4 Inorganic materials 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000012705 liquid precursor Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 239000012713 reactive precursor Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000003889 Paeonia suffruticosa Nutrition 0.000 description 1
- 240000005001 Paeonia suffruticosa Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000007244 Zea mays Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 239000012702 metal oxide precursor Substances 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- XCGYUJZMCCFSRP-UHFFFAOYSA-N oxamniquine Chemical compound OCC1=C([N+]([O-])=O)C=C2NC(CNC(C)C)CCC2=C1 XCGYUJZMCCFSRP-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000010944 pre-mature reactiony Methods 0.000 description 1
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Elements Other Than Lenses (AREA)
- Decoration Of Textiles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/122,527 US6978896B2 (en) | 2002-04-11 | 2002-04-11 | Method of making retrochromic beads and kit thereof |
| PCT/US2003/003907 WO2003087895A1 (en) | 2002-04-11 | 2003-02-11 | Method of making retrochromic beads and kit thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005522729A JP2005522729A (ja) | 2005-07-28 |
| JP2005522729A5 JP2005522729A5 (enExample) | 2006-03-30 |
| JP4279687B2 true JP4279687B2 (ja) | 2009-06-17 |
Family
ID=28790562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003584780A Expired - Fee Related JP4279687B2 (ja) | 2002-04-11 | 2003-02-11 | レトロクロミックビーズの製造方法およびそのキット |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6978896B2 (enExample) |
| EP (1) | EP1495349B1 (enExample) |
| JP (1) | JP4279687B2 (enExample) |
| CN (1) | CN1299133C (enExample) |
| AT (1) | ATE394690T1 (enExample) |
| AU (1) | AU2003210940A1 (enExample) |
| DE (1) | DE60320775D1 (enExample) |
| WO (1) | WO2003087895A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2235266A1 (en) * | 2007-12-21 | 2010-10-06 | 3M Innovative Properties Company | Retroreflective pavement markings |
| JP2011509421A (ja) * | 2007-12-21 | 2011-03-24 | スリーエム イノベイティブ プロパティズ カンパニー | 衣類、繊維及びフィラメント形態の再帰反射物品 |
| EP2242656A2 (en) * | 2007-12-21 | 2010-10-27 | 3M Innovative Properties Company | Retroreflective security articles |
| EP2238486A1 (en) * | 2007-12-21 | 2010-10-13 | 3M Innovative Properties Company | Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers |
| ES2764964T3 (es) | 2008-04-30 | 2020-06-05 | Nanosys Inc | Superficies resistentes al ensuciamiento para esferas reflectivas |
| US8622555B2 (en) | 2010-08-31 | 2014-01-07 | 3M Innovative Properties Company | Security article having a switching feature |
| FR3003247B1 (fr) * | 2013-03-14 | 2015-10-02 | Colas Sa | Billes de verre a couche(s) de surface pour le marquage routier, marquage routier et son procede de realisation |
| FR3003248B1 (fr) * | 2013-03-14 | 2015-10-02 | Colas Sa | Billes de verre a couche(s) de surface a proprietes de retro-reflexion, procede de realisation |
| US11009632B2 (en) * | 2017-01-25 | 2021-05-18 | Face International Corporation | Methods for making compositions of materials for forming coatings and layered structures including elements for scattering and passing selectively tunable wavelengths of electromagnetic energy |
| US10482361B2 (en) | 2015-07-05 | 2019-11-19 | Thewhollysee Ltd. | Optical identification and characterization system and tags |
| WO2019021130A1 (en) | 2017-07-28 | 2019-01-31 | 3M Innovative Properties Company | NANOCRYSTALLINE CERAMIC OXIDE BALLS |
| CN111564110B (zh) * | 2020-05-29 | 2022-07-12 | 上海中航光电子有限公司 | 一种显示面板和显示装置 |
Family Cites Families (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2326634A (en) | 1941-12-26 | 1943-08-10 | Minnesota Mining & Mfg | Reflex light reflector |
| US2407680A (en) | 1945-03-02 | 1946-09-17 | Minnesota Mining & Mfg | Reflex light reflector |
| US2713286A (en) | 1949-10-22 | 1955-07-19 | Minnesota Mining & Mfg | Reflex light reflectors and glass bead elements thereof |
| US2963378A (en) | 1955-04-25 | 1960-12-06 | Minnesota Mining & Mfg | Ass beads hemispherically reflectorled with metallic coating and compositions thereof |
| US3025764A (en) | 1956-10-04 | 1962-03-20 | Minnesota Mining & Mfg | Retroreflective elements and structures |
| NL257502A (enExample) | 1959-11-02 | |||
| US3154872A (en) | 1963-02-13 | 1964-11-03 | Minnesota Mining & Mfg | Tamper-proof markings for reflecting structures |
| US3758192A (en) | 1970-08-20 | 1973-09-11 | Minnesota Mining & Mfg | Reflex-reflective structures including fabric and transfer foils |
| US3700478A (en) | 1970-11-09 | 1972-10-24 | Minnesota Mining & Mfg | Microspheres having an antireflection coating and their use |
| US3700305A (en) | 1970-12-14 | 1972-10-24 | Minnesota Mining & Mfg | Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres |
| NL7300593A (enExample) | 1972-01-15 | 1973-07-17 | ||
| US3858977A (en) | 1972-01-18 | 1975-01-07 | Canadian Patents Dev | Optical interference authenticating means |
| US3767291A (en) | 1972-03-31 | 1973-10-23 | Minnesota Mining & Mfg | Retroviewer |
| US3832038A (en) | 1972-08-09 | 1974-08-27 | Minnesota Mining & Mfg | Hand retroviewer |
| US3801183A (en) | 1973-06-01 | 1974-04-02 | Minnesota Mining & Mfg | Retro-reflective film |
| US4022318A (en) * | 1975-11-03 | 1977-05-10 | Morris Goodman | Jewelry kit with decorative yarn or beads |
| US4099838A (en) | 1976-06-07 | 1978-07-11 | Minnesota Mining And Manufacturing Company | Reflective sheet material |
| US4102562A (en) | 1976-06-14 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US4082426A (en) | 1976-11-26 | 1978-04-04 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting with retroreflective markings |
| US4367920A (en) | 1979-10-01 | 1983-01-11 | Minnesota Mining And Manufacturing Company | Retroflective sheeting |
| US4630891A (en) | 1984-09-14 | 1986-12-23 | Minnesota Mining And Manufacturing Company | Tamper resistant security film |
| US4564556A (en) | 1984-09-24 | 1986-01-14 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous ceramic particulate |
| JPS61166501A (ja) | 1985-01-18 | 1986-07-28 | Yoshio Morita | 水溶液反応による二酸化チタン光学薄膜の形成方法 |
| US4688894A (en) | 1985-05-13 | 1987-08-25 | Minnesota Mining And Manufacturing Company | Transparent retroreflective sheets containing directional images and method for forming the same |
| CA1308845C (en) | 1986-01-13 | 1992-10-13 | Roger W. Lange | Pavement markings containing transparent non-vitreous ceramic microspheres |
| US4896943A (en) | 1987-05-13 | 1990-01-30 | Minnesota Mining And Manufacturing Company | Encapsulated-lens retroreflective sheeting having improved cover film |
| JP2546853B2 (ja) | 1987-09-03 | 1996-10-23 | オーツタイヤ株式会社 | 装飾性ビーズコートシートおよびその製造方法 |
| US4988555A (en) | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Patterned pavement marking |
| US5227221A (en) | 1988-06-09 | 1993-07-13 | Minnesota Mining And Manufacturing Company | Patterned skid preventative sheet |
| US4988541A (en) | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Process for making retroreflector sheet |
| JPH0299988A (ja) | 1988-10-06 | 1990-04-11 | Ichikoh Ind Ltd | 虹彩発光するマーク類の形成方法 |
| US4957335A (en) | 1989-05-26 | 1990-09-18 | Minnesota Mining And Manufacturing Company | Microsphere-based retroreflective articles with enhanced retroreflective brightness |
| DK257390A (da) | 1990-10-25 | 1992-04-26 | Reflex Promotion | Transfer til dekorering af overflader med billeder, der er ekstremt holdbare, og specielt billeder omfattende lysreflekterende og farvede omraader i vilkaarlig kombination, samt fremgangsmaade til fremstilling deraf |
| US5229882A (en) | 1990-05-16 | 1993-07-20 | Reflexite Corporation | Colored retroreflective sheeting and method of making same |
| US5254390B1 (en) | 1990-11-15 | 1999-05-18 | Minnesota Mining & Mfg | Plano-convex base sheet for retroreflective articles |
| US5169707A (en) | 1991-05-08 | 1992-12-08 | Minnesota Mining And Manufacturing Company | Retroreflective security laminates with dual level verification |
| JP2513976B2 (ja) | 1991-12-13 | 1996-07-10 | エイ・ティ・アンド・ティ・コーポレーション | 複数の球状部品の被覆方法 |
| US5344705A (en) | 1993-05-05 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
| US5814367A (en) | 1993-08-13 | 1998-09-29 | General Atomics | Broadband infrared and signature control materials and methods of producing the same |
| US5344024A (en) * | 1993-09-28 | 1994-09-06 | Cohu Gary D | Case for storing, organizing and sorting small articles |
| WO1995031739A1 (en) * | 1994-05-12 | 1995-11-23 | Minnesota Mining And Manufacturing Company | Retroreflective article and method of making same |
| US5673148A (en) | 1994-06-23 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Encapsulated retroreflective elements and method for making same |
| US5516227A (en) | 1994-07-07 | 1996-05-14 | Iit Research Institute | Spherodized fluorescent beads for improved roadway pavement marker visibility |
| EP0795137B1 (en) * | 1994-11-29 | 1998-08-26 | Minnesota Mining And Manufacturing Company | Transparent decorative article having an etched appearing/prismatic image thereon |
| US5624731A (en) | 1995-03-10 | 1997-04-29 | Desjardins; Alexander | Multi-color, multi-image retroflective goniochromatic display |
| US5477219A (en) | 1995-03-30 | 1995-12-19 | Minnesota Mining And Manufacturing Company | Composite electronic article surveillance, identification, and security marker assembly and system |
| WO1997001776A1 (en) | 1995-06-29 | 1997-01-16 | Minnesota Mining & Mfg | Rainbow sheeting having distinct color changes and/or hidden images |
| US5620775A (en) | 1995-11-03 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same |
| JP3686167B2 (ja) | 1996-06-10 | 2005-08-24 | 日鉄鉱業株式会社 | 多層膜被覆粉体 |
| TW338078B (en) | 1996-07-08 | 1998-08-11 | Scapa Group Plc | Membrane felt for use in yankee machine |
| JPH10170710A (ja) | 1996-12-12 | 1998-06-26 | Minnesota Mining & Mfg Co <3M> | 光再帰性反射シート |
| TW417023B (en) | 1997-09-30 | 2001-01-01 | Shiseido Corp | Color light retroreflective material and retroreflective hologram reproduction using such retroreflective material |
| US6010770A (en) * | 1997-10-21 | 2000-01-04 | Advanced Deposition Technologies, Inc. | Patterned retroreflective film and methods to produce |
| GB9816617D0 (en) | 1997-10-28 | 1998-09-30 | Melba Prod | Safety assemblies |
| JPH11175007A (ja) | 1997-11-21 | 1999-07-02 | Minnesota Mining & Mfg Co <3M> | 自発光可能な再帰性反射シートおよびその製造方法 |
| US6045894A (en) | 1998-01-13 | 2000-04-04 | 3M Innovative Properties Company | Clear to colored security film |
| US6157486A (en) | 1998-01-13 | 2000-12-05 | 3M Innovative Properties Company | Retroreflective dichroic reflector |
| CN1173835C (zh) | 1998-04-29 | 2004-11-03 | 3M创新有限公司 | 具有压纹表面的喷墨打印接受片 |
| DE69925086T2 (de) | 1998-10-30 | 2006-02-02 | Avery Dennison Corp., Pasadena | Retroreflektierende Folie mit einem Bild zur Echtheitsprüfung und Verfahren zu ihrer Herstellung |
| JP2000321414A (ja) | 1999-04-28 | 2000-11-24 | Three M Innovative Properties Co | 光再帰性反射シート |
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| US6571955B1 (en) * | 2000-06-27 | 2003-06-03 | Terri Rossman | Bead holder |
| US6500526B1 (en) | 2000-09-28 | 2002-12-31 | Avery Dennison Corporation | Retroreflective sheeting containing a validation image and methods of making the same |
-
2002
- 2002-04-11 US US10/122,527 patent/US6978896B2/en not_active Expired - Lifetime
-
2003
- 2003-02-11 AT AT03746531T patent/ATE394690T1/de not_active IP Right Cessation
- 2003-02-11 CN CNB038109689A patent/CN1299133C/zh not_active Expired - Fee Related
- 2003-02-11 AU AU2003210940A patent/AU2003210940A1/en not_active Abandoned
- 2003-02-11 WO PCT/US2003/003907 patent/WO2003087895A1/en not_active Ceased
- 2003-02-11 EP EP03746531A patent/EP1495349B1/en not_active Expired - Lifetime
- 2003-02-11 DE DE60320775T patent/DE60320775D1/de not_active Expired - Lifetime
- 2003-02-11 JP JP2003584780A patent/JP4279687B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1495349A1 (en) | 2005-01-12 |
| JP2005522729A (ja) | 2005-07-28 |
| WO2003087895A1 (en) | 2003-10-23 |
| ATE394690T1 (de) | 2008-05-15 |
| AU2003210940A1 (en) | 2003-10-27 |
| CN1299133C (zh) | 2007-02-07 |
| US6978896B2 (en) | 2005-12-27 |
| DE60320775D1 (de) | 2008-06-19 |
| US20030194490A1 (en) | 2003-10-16 |
| CN1653363A (zh) | 2005-08-10 |
| EP1495349B1 (en) | 2008-05-07 |
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