JP3818669B2 - 電解電池 - Google Patents
電解電池 Download PDFInfo
- Publication number
- JP3818669B2 JP3818669B2 JP52460197A JP52460197A JP3818669B2 JP 3818669 B2 JP3818669 B2 JP 3818669B2 JP 52460197 A JP52460197 A JP 52460197A JP 52460197 A JP52460197 A JP 52460197A JP 3818669 B2 JP3818669 B2 JP 3818669B2
- Authority
- JP
- Japan
- Prior art keywords
- battery
- borohydride
- electrode
- cathode
- catholyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 claims description 40
- 230000005611 electricity Effects 0.000 claims description 37
- -1 amine organic base Chemical class 0.000 claims description 32
- 229910052760 oxygen Inorganic materials 0.000 claims description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 30
- 239000012528 membrane Substances 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 25
- 230000029058 respiratory gaseous exchange Effects 0.000 claims description 21
- 239000007800 oxidant agent Substances 0.000 claims description 20
- 230000001590 oxidative effect Effects 0.000 claims description 20
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 13
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 238000003860 storage Methods 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 10
- 229910052753 mercury Inorganic materials 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical group 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 4
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
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- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 4
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 4
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052714 tellurium Inorganic materials 0.000 claims description 4
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 4
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 4
- 239000008365 aqueous carrier Substances 0.000 claims description 3
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims description 3
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
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- 229910001152 Bi alloy Inorganic materials 0.000 claims description 2
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- 229910000807 Ga alloy Inorganic materials 0.000 claims description 2
- 229910000846 In alloy Inorganic materials 0.000 claims description 2
- 229910000978 Pb alloy Inorganic materials 0.000 claims description 2
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 2
- 229910001007 Tl alloy Inorganic materials 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000004891 communication Methods 0.000 claims description 2
- 239000003014 ion exchange membrane Substances 0.000 claims description 2
- 238000010405 reoxidation reaction Methods 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229910020366 ClO 4 Inorganic materials 0.000 claims 1
- 239000003570 air Substances 0.000 claims 1
- 150000001639 boron compounds Chemical class 0.000 claims 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 claims 1
- 150000002366 halogen compounds Chemical class 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 73
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 47
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- 229910052739 hydrogen Inorganic materials 0.000 description 43
- 239000007788 liquid Substances 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 229910001868 water Inorganic materials 0.000 description 20
- 239000000446 fuel Substances 0.000 description 15
- 239000000376 reactant Substances 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 230000032258 transport Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 9
- 230000006870 function Effects 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 8
- 239000011572 manganese Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000013461 design Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000012279 sodium borohydride Substances 0.000 description 7
- 229910000033 sodium borohydride Inorganic materials 0.000 description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 229910052796 boron Inorganic materials 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910010277 boron hydride Inorganic materials 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
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- 229910000085 borane Inorganic materials 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
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- 239000000758 substrate Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- 239000003637 basic solution Substances 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 3
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- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
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- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
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- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
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- 229910015900 BF3 Inorganic materials 0.000 description 1
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- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
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Images
Classifications
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- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
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- B60—VEHICLES IN GENERAL
- B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
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- B60L50/50—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells
- B60L50/60—Electric propulsion with power supplied within the vehicle using propulsion power supplied by batteries or fuel cells using power supplied by batteries
- B60L50/64—Constructional details of batteries specially adapted for electric vehicles
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
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- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
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- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- H01M6/00—Primary cells; Manufacture thereof
- H01M6/42—Grouping of primary cells into batteries
- H01M6/46—Grouping of primary cells into batteries of flat cells
- H01M6/48—Grouping of primary cells into batteries of flat cells with bipolar electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Power Engineering (AREA)
- Transportation (AREA)
- General Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Hybrid Cells (AREA)
- Cell Separators (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Secondary Cells (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/579,781 US5804329A (en) | 1995-12-28 | 1995-12-28 | Electroconversion cell |
| US08/579,781 | 1995-12-28 | ||
| PCT/US1996/020851 WO1997024774A1 (en) | 1995-12-28 | 1996-12-27 | Electroconversion cell |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000502832A JP2000502832A (ja) | 2000-03-07 |
| JP2000502832A5 JP2000502832A5 (OSRAM) | 2004-11-04 |
| JP3818669B2 true JP3818669B2 (ja) | 2006-09-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52460197A Expired - Fee Related JP3818669B2 (ja) | 1995-12-28 | 1996-12-27 | 電解電池 |
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| Country | Link |
|---|---|
| US (2) | US5804329A (OSRAM) |
| EP (1) | EP0882310A4 (OSRAM) |
| JP (1) | JP3818669B2 (OSRAM) |
| CN (1) | CN1142608C (OSRAM) |
| AU (1) | AU728827B2 (OSRAM) |
| CA (1) | CA2241862C (OSRAM) |
| IL (1) | IL125126A (OSRAM) |
| NO (1) | NO982990L (OSRAM) |
| RU (1) | RU2186442C2 (OSRAM) |
| TW (1) | TW360990B (OSRAM) |
| WO (1) | WO1997024774A1 (OSRAM) |
| ZA (1) | ZA9610870B (OSRAM) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104122074A (zh) * | 2014-07-08 | 2014-10-29 | 国家电网公司 | 一种光纤光通量测试装置与方法 |
| CN104122074B (zh) * | 2014-07-08 | 2016-11-30 | 国家电网公司 | 一种光纤光通量测试方法 |
Families Citing this family (179)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5804329A (en) | 1995-12-28 | 1998-09-08 | National Patent Development Corporation | Electroconversion cell |
| US6468694B1 (en) * | 1997-03-27 | 2002-10-22 | Millennium Cell, Inc. | High energy density boride batteries |
| DK1051766T3 (da) * | 1998-01-28 | 2001-12-03 | Squirrel Holdings Ltd | Redox strømningsbatterisystem og cellestak |
| JP3455709B2 (ja) | 1999-04-06 | 2003-10-14 | 株式会社大和化成研究所 | めっき方法とそれに用いるめっき液前駆体 |
| US6534033B1 (en) * | 2000-01-07 | 2003-03-18 | Millennium Cell, Inc. | System for hydrogen generation |
| WO2001074710A1 (en) * | 2000-03-30 | 2001-10-11 | Manhattan Scientifics, Inc. | Portable chemical hydrogen hydride system |
| US6544679B1 (en) | 2000-04-19 | 2003-04-08 | Millennium Cell, Inc. | Electrochemical cell and assembly for same |
| US6250078B1 (en) | 2000-04-27 | 2001-06-26 | Millennium Cell, L.L.P. | Engine cycle and fuels for same |
| US20020015869A1 (en) * | 2000-08-03 | 2002-02-07 | Seijirau Suda | Liquid fuel cell |
| JP2002093413A (ja) * | 2000-09-12 | 2002-03-29 | Toshiba Battery Co Ltd | 電 池 |
| US6554877B2 (en) * | 2001-01-03 | 2003-04-29 | More Energy Ltd. | Liquid fuel compositions for electrochemical fuel cells |
| US6773470B2 (en) | 2001-01-03 | 2004-08-10 | More Energy Ltd. | Suspensions for use as fuel for electrochemical fuel cells |
| AU2007200035B2 (en) * | 2001-01-03 | 2009-01-29 | More Energy Ltd. | Liquid fuel compositions for electrochemical fuel cells |
| US7429368B2 (en) * | 2001-02-08 | 2008-09-30 | Yu Zhou | Process for synthesizing metal borohydrides |
| JP2003072059A (ja) * | 2001-06-21 | 2003-03-12 | Ricoh Co Ltd | インクジェット記録装置及び複写機 |
| US6932847B2 (en) * | 2001-07-06 | 2005-08-23 | Millennium Cell, Inc. | Portable hydrogen generator |
| US6946104B2 (en) * | 2001-07-09 | 2005-09-20 | Hydrogenics Corporation | Chemical hydride hydrogen generation system and an energy system incorporating the same |
| US7316718B2 (en) | 2001-07-11 | 2008-01-08 | Millennium Cell, Inc. | Differential pressure-driven borohydride based generator |
| US7445860B2 (en) * | 2001-08-28 | 2008-11-04 | Honeywell International Inc. | Electrical power generator |
| US7001681B2 (en) * | 2001-08-28 | 2006-02-21 | Honeywell International Inc. | Water vapor transport power generator |
| JP2003080240A (ja) * | 2001-09-17 | 2003-03-18 | Get:Kk | 溶存水素豊富水の製造方法 |
| US20030134161A1 (en) * | 2001-09-20 | 2003-07-17 | Gore Makarand P. | Protective container with preventative agent therein |
| US6737184B2 (en) | 2001-11-09 | 2004-05-18 | Hydrogenics Corporation | Chemical hydride hydrogen generation system and an energy system incorporating the same |
| US6727012B2 (en) | 2001-11-09 | 2004-04-27 | Hydrogenics Corporation | Method and apparatus for generating hydrogen inside of a fuel cell |
| US7045230B2 (en) | 2001-11-09 | 2006-05-16 | Hydrogenics Corporation | Chemical hydride hydrogen generation system and fuel cell stack incorporating a common heat transfer circuit |
| CN1319850C (zh) * | 2001-11-13 | 2007-06-06 | 蒙哥马利化学品有限责任公司 | 产生氢的含水燃料和提供能量的方法 |
| US6758981B2 (en) * | 2001-12-21 | 2004-07-06 | Hydrogenics Corporation | Method and apparatus for by-product removal in a hydrogen generation system |
| US6746496B1 (en) | 2002-01-15 | 2004-06-08 | Sandia Corporation | Compact solid source of hydrogen gas |
| US6982128B2 (en) * | 2002-01-28 | 2006-01-03 | Hewlett-Packard Development Company, L.P. | Co-catalyst proton exchange membrane fuel cell utilizing borohydride fuels |
| GB0203508D0 (en) * | 2002-02-14 | 2002-04-03 | Fuel Technology Ltd Rapid re-energising of electric power storage systems | |
| US7282073B2 (en) * | 2002-04-02 | 2007-10-16 | Millennium Cell, Inc. | Method and system for generating hydrogen by dispensing solid and liquid fuel components |
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-
1996
- 1996-09-19 TW TW085111465A patent/TW360990B/zh active
- 1996-12-23 ZA ZA9610870A patent/ZA9610870B/xx unknown
- 1996-12-27 JP JP52460197A patent/JP3818669B2/ja not_active Expired - Fee Related
- 1996-12-27 AU AU14320/97A patent/AU728827B2/en not_active Ceased
- 1996-12-27 EP EP96944546A patent/EP0882310A4/en not_active Withdrawn
- 1996-12-27 RU RU98114096/09A patent/RU2186442C2/ru not_active IP Right Cessation
- 1996-12-27 IL IL12512696A patent/IL125126A/xx not_active IP Right Cessation
- 1996-12-27 WO PCT/US1996/020851 patent/WO1997024774A1/en not_active Ceased
- 1996-12-27 CA CA002241862A patent/CA2241862C/en not_active Expired - Fee Related
- 1996-12-27 CN CNB961800194A patent/CN1142608C/zh not_active Expired - Fee Related
-
1997
- 1997-06-27 US US08/883,859 patent/US6497973B1/en not_active Expired - Fee Related
-
1998
- 1998-06-26 NO NO982990A patent/NO982990L/no not_active Application Discontinuation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104122074A (zh) * | 2014-07-08 | 2014-10-29 | 国家电网公司 | 一种光纤光通量测试装置与方法 |
| CN104122074B (zh) * | 2014-07-08 | 2016-11-30 | 国家电网公司 | 一种光纤光通量测试方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0882310A1 (en) | 1998-12-09 |
| CA2241862C (en) | 2003-09-23 |
| NO982990D0 (no) | 1998-06-26 |
| IL125126A0 (en) | 1999-01-26 |
| WO1997024774A1 (en) | 1997-07-10 |
| US6497973B1 (en) | 2002-12-24 |
| CN1209219A (zh) | 1999-02-24 |
| AU728827B2 (en) | 2001-01-18 |
| AU1432097A (en) | 1997-07-28 |
| NO982990L (no) | 1998-08-27 |
| JP2000502832A (ja) | 2000-03-07 |
| ZA9610870B (en) | 1998-03-11 |
| EP0882310A4 (en) | 2005-09-14 |
| CN1142608C (zh) | 2004-03-17 |
| RU2186442C2 (ru) | 2002-07-27 |
| CA2241862A1 (en) | 1997-07-10 |
| IL125126A (en) | 2003-01-12 |
| TW360990B (en) | 1999-06-11 |
| US5804329A (en) | 1998-09-08 |
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