JP3598274B2 - 有機色素配合光触媒被膜用コーティング液 - Google Patents
有機色素配合光触媒被膜用コーティング液 Download PDFInfo
- Publication number
- JP3598274B2 JP3598274B2 JP2000586462A JP2000586462A JP3598274B2 JP 3598274 B2 JP3598274 B2 JP 3598274B2 JP 2000586462 A JP2000586462 A JP 2000586462A JP 2000586462 A JP2000586462 A JP 2000586462A JP 3598274 B2 JP3598274 B2 JP 3598274B2
- Authority
- JP
- Japan
- Prior art keywords
- organic dye
- film
- coating
- photocatalytic
- coating solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000576 coating method Methods 0.000 title claims description 178
- 239000011248 coating agent Substances 0.000 title claims description 153
- 230000001699 photocatalysis Effects 0.000 title claims description 119
- 239000000975 dye Substances 0.000 claims description 148
- 239000011941 photocatalyst Substances 0.000 claims description 64
- 239000011230 binding agent Substances 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 50
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 17
- 230000015572 biosynthetic process Effects 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 14
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 11
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 125000003367 polycyclic group Chemical group 0.000 claims description 10
- 150000004696 coordination complex Chemical class 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 238000004040 coloring Methods 0.000 claims description 8
- 239000007888 film coating Substances 0.000 claims description 8
- 238000009501 film coating Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000012860 organic pigment Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003906 humectant Substances 0.000 claims description 4
- 239000004566 building material Substances 0.000 claims description 3
- 238000004042 decolorization Methods 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 2
- 230000002085 persistent effect Effects 0.000 claims 1
- 239000010408 film Substances 0.000 description 106
- 239000000243 solution Substances 0.000 description 62
- 239000010410 layer Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000000987 azo dye Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- -1 tiles Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010893 electron trap Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000978 natural dye Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002367 SrTiO Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000009430 construction management Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 230000001443 photoexcitation Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0219—Coating the coating containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34729898 | 1998-12-07 | ||
| PCT/JP1999/006825 WO2000033977A1 (fr) | 1998-12-07 | 1999-12-06 | Liquide d'enduit comprenant un colorant organique pour film d'enduit contenant un photocatalyseur |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004093788A Division JP2004249288A (ja) | 1998-12-07 | 2004-03-26 | 有機色素配合光触媒被膜用コーティング液 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP3598274B2 true JP3598274B2 (ja) | 2004-12-08 |
Family
ID=18389273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000586462A Expired - Fee Related JP3598274B2 (ja) | 1998-12-07 | 1999-12-06 | 有機色素配合光触媒被膜用コーティング液 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1052027B1 (ko) |
| JP (1) | JP3598274B2 (ko) |
| KR (1) | KR100642796B1 (ko) |
| CA (1) | CA2320191C (ko) |
| DE (1) | DE69935203T2 (ko) |
| TW (1) | TWI252128B (ko) |
| WO (1) | WO2000033977A1 (ko) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008259951A (ja) * | 2007-04-11 | 2008-10-30 | Toto Ltd | 塗膜の補修方法および補修塗料 |
| JP2012505072A (ja) * | 2008-10-09 | 2012-03-01 | アルジョ ウイグギンス フイネ パペルス リミテッド | 改良されたコーティング方法 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4578623B2 (ja) * | 2000-06-02 | 2010-11-10 | 日本曹達株式会社 | 光触媒担持構造体用塗布液 |
| JP2002126633A (ja) * | 2000-10-27 | 2002-05-08 | Fujita Corp | 建物外壁表面への超親水性薄膜の形成方法 |
| US7060643B2 (en) | 2000-12-28 | 2006-06-13 | Showa Denko Kabushiki Kaisha | Photo-functional powder and applications thereof |
| CN100447188C (zh) * | 2000-12-28 | 2008-12-31 | 昭和电工株式会社 | 高活性光催化剂 |
| WO2002053285A1 (fr) * | 2000-12-28 | 2002-07-11 | Showa Denko K.K. | Poudre a fonction optique et son utilisation |
| US6887816B2 (en) | 2000-12-28 | 2005-05-03 | Showa Denko K.K. | Photocatalyst |
| JP4681777B2 (ja) * | 2001-09-05 | 2011-05-11 | 小林クリエイト株式会社 | 光判定インジケータ |
| EP2316568A1 (en) * | 2001-12-21 | 2011-05-04 | Showa Denko K.K. | Photocatlyst particles comprising a condensed phosphate |
| JP2005199155A (ja) * | 2004-01-14 | 2005-07-28 | Hakko Kirokushi Kougyo Kk | 光触媒構造 |
| JP4518567B2 (ja) * | 2007-03-09 | 2010-08-04 | Ｔｏｔｏ株式会社 | 塗布液 |
| FR2998814B1 (fr) * | 2012-11-30 | 2015-05-08 | Eurecat Sa | Procede de preparation de catalyseurs metalliques supportes |
| JP6720615B2 (ja) * | 2015-03-31 | 2020-07-08 | Toto株式会社 | 光触媒コーティング組成物 |
| US11253842B1 (en) | 2021-04-02 | 2022-02-22 | TiCoat, Inc. | Titanium dioxide containing peroxo titanium complex and methods of manufacturing and application of the same |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3623865A (en) * | 1967-03-16 | 1971-11-30 | Itek Corp | Processes for producing photographic images utilizing leucophthalocyanines and photosensitive materials and products related thereto |
| AU523480B2 (en) * | 1977-08-04 | 1982-07-29 | Ppg Industries, Inc | Amide. acrylate compounds for use in radiation-curable coat img compositions |
| CA1287829C (en) * | 1986-10-02 | 1991-08-20 | Cooper H. Langford | Composite photocatalyst for refractory waste degradation |
| AU4166896A (en) * | 1994-12-02 | 1996-06-19 | Cape Cod Research, Inc. | Zinc oxide photoactive material |
| JPH10277368A (ja) * | 1997-04-04 | 1998-10-20 | Nof Corp | 環境浄化組成物、環境浄化材料および製造方法 |
| JPH10277401A (ja) * | 1997-04-08 | 1998-10-20 | Nof Corp | 環境浄化組成物、環境浄化材料および製造方法 |
| JPH10287846A (ja) * | 1997-04-11 | 1998-10-27 | Matsushita Electric Works Ltd | 機能性無機塗料、それを用いた塗装品およびそれらの用途 |
| JPH10296185A (ja) * | 1997-04-23 | 1998-11-10 | Matsushita Electric Works Ltd | 低温硬化無機塗装方法 |
| JP3518251B2 (ja) * | 1997-05-20 | 2004-04-12 | 株式会社日立製作所 | 酸化物光触媒薄膜、及びそれを備えた物品 |
| US6066435A (en) * | 1997-06-02 | 2000-05-23 | Ciba Specialty Chemicals Corp. | Liquid photosensitive composition |
| DE69841947D1 (de) * | 1997-08-08 | 2010-11-25 | Dainippon Printing Co Ltd | Verfahren zur Herstellung einer Linse |
| JPH11256351A (ja) * | 1998-03-12 | 1999-09-21 | Nisshin Steel Co Ltd | 光触媒性に優れる金属板の製造方法 |
-
1999
- 1999-12-06 KR KR1020007008496A patent/KR100642796B1/ko not_active IP Right Cessation
- 1999-12-06 WO PCT/JP1999/006825 patent/WO2000033977A1/ja active IP Right Grant
- 1999-12-06 JP JP2000586462A patent/JP3598274B2/ja not_active Expired - Fee Related
- 1999-12-06 DE DE69935203T patent/DE69935203T2/de not_active Expired - Fee Related
- 1999-12-06 EP EP99957417A patent/EP1052027B1/en not_active Expired - Lifetime
- 1999-12-06 CA CA002320191A patent/CA2320191C/en not_active Expired - Fee Related
- 1999-12-07 TW TW088121376A patent/TWI252128B/zh not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008259951A (ja) * | 2007-04-11 | 2008-10-30 | Toto Ltd | 塗膜の補修方法および補修塗料 |
| JP2012505072A (ja) * | 2008-10-09 | 2012-03-01 | アルジョ ウイグギンス フイネ パペルス リミテッド | 改良されたコーティング方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2320191A1 (en) | 2000-06-15 |
| TWI252128B (en) | 2006-04-01 |
| DE69935203T2 (de) | 2007-10-25 |
| CA2320191C (en) | 2008-07-22 |
| EP1052027A4 (en) | 2004-07-14 |
| KR100642796B1 (ko) | 2006-11-10 |
| KR20010040625A (ko) | 2001-05-15 |
| DE69935203D1 (de) | 2007-04-05 |
| EP1052027B1 (en) | 2007-02-21 |
| WO2000033977A1 (fr) | 2000-06-15 |
| EP1052027A1 (en) | 2000-11-15 |
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