JP2021053585A - 界面活性剤組成物、樹脂水分散体の製造方法、塗料及び粘着剤 - Google Patents
界面活性剤組成物、樹脂水分散体の製造方法、塗料及び粘着剤 Download PDFInfo
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- JP2021053585A JP2021053585A JP2019179665A JP2019179665A JP2021053585A JP 2021053585 A JP2021053585 A JP 2021053585A JP 2019179665 A JP2019179665 A JP 2019179665A JP 2019179665 A JP2019179665 A JP 2019179665A JP 2021053585 A JP2021053585 A JP 2021053585A
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
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- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
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Abstract
Description
項1
下記一般式(1)
で表される化合物C1、及び、
下記一般式(2)
本発明の界面活性剤組成物は、下記一般式(1)で表される化合物C1、及び、下記一般式(2)で表される化合物C2を含む。
化合物C1は、式(1)で表されるように、分子内に重合性部位(炭素−炭素二重結合部位)を有し、かつ、長鎖アルキレンを有するオキシアルキレン部位(A1O)と、短鎖アルキレンを有するオキシアルキレン部位(A2O)とを有する界面活性剤である。化合物C1は、1個のオキシアルキレン部位(A1O)と、n個のオキシアルキレン部位(A2O)とを分子内に有する。化合物C1において、重合性部位とオキシアルキレン部位(A1O)とはエーテル結合を介して結合している。
化合物C2は、式(2)で表されるように、分子内に重合性部位(炭素−炭素二重結合部位)を有し、かつ、長鎖アルキレンを有するオキシアルキレン部位(A1O)と、短鎖アルキレンを有するオキシアルキレン部位(A2O)とを有する界面活性剤である。化合物C1と化合物C2との違いは、オキシアルキレン部位(A1O)の数である。具体的に、化合物C1は、オキシアルキレン部位(A1O)が1個であるのに対し、化合物C2は、オキシアルキレン部位(A1O)が2個である
界面活性剤組成物において、前記化合物C1及び前記化合物C2の含有割合は、化合物C1及び化合物C2のモル比C1/C2が99/1〜84/16である限り、特に限定されない。前記モル比C1/C2が99/1を上回ると、界面活性剤組成物を使用して得られた樹脂水分散体から形成される樹脂フィルムは、耐水性及び耐水粘着力に劣る。前記モル比C1/C2が84/16を下回ると重合安定性及び耐水粘着力が低下し、所望の樹脂水分散体を得ることが難しくなる。
界面活性剤組成物の調製方法は特に限定されない。例えば、化合物C1及び化合物C2と、必要に応じて添加される添加剤とを所定の割合で混合することで、界面活性剤組成物を調製することができる。特に、本発明では、以下に説明するように、化合物C1及び化合物C2を一つの反応工程内で得る製造方法を採用することができる。以下、この製造方法を「製造方法P」と表記する。
界面活性剤組成物は、例えば、重合性化合物の乳化重合用の界面活性剤として使用することができこれにより、樹脂水分散体を得ることができる。例えば、樹脂水分散体は、界面活性剤組成物の存在下、重合性化合物の重合反応を行う工程により製造することができる。
<アリルアルコールのα−オレフィンエポキシド付加物>
撹拌機、温度計、還流管、窒素導入管を備えた反応容器に、アリルアルコール76g(1.3モル)と水酸化カリウム8.4g(0.15モル)とを仕込み、窒素雰囲気下、80℃に保持した。この反応容器に、α−オレフィンエポキシド(炭素数12と炭素数14の混合物;平均炭素数13)0.85モルを滴下して加え、5時間反応を行なった。その後、減圧して残存するアリルアルコールを留去してから、水洗及び乾燥を行い、アリルアルコールのα−オレフィンエポキシド付加物a−1を得た。このα−オレフィンエポキシド付加物a−1は、後掲の表1に示すように、1付加物(α−オレフィンエポキシドが一つ付加)と2付加物(α−オレフィンエポキシドが二つ付加)の混合物であった。
<界面活性剤組成物>
得られたアリルアルコールのα−オレフィンエポキシド付加物a−1をオートクレーブに移し、水酸化カリウム触媒の存在下、圧力1.5kg/cm3、温度130℃の条件にて、a−1に対し20モルのエチレンオキシドを反応させた。その後、適宜精製することにより、a−1に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−1とした。
α−オレフィンエポキシドの使用量を1モルに変更したこと以外は、実施例1−1と同様の方法でアリルアルコールのα−オレフィンエポキシド付加物a−2を得た。次いで、α−オレフィンエポキシド付加物a−1をα−オレフィンエポキシド付加物a−2に変更したこと以外は、実施例1−1と同様の方法で、α−オレフィンエポキシド付加物a−2に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−2とした。
α−オレフィンエポキシドの使用量を1.05モルに変更したこと以外は、実施例1−1と同様の方法でアリルアルコールのα−オレフィンエポキシド付加物a−3を得た。次いで、α−オレフィンエポキシド付加物a−1をα−オレフィンエポキシド付加物a−3に変更したこと以外は、実施例1−1と同様の方法で、α−オレフィンエポキシド付加物a−3に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−3とした。
α−オレフィンエポキシドの使用量を1.15モルに変更したこと以外は、実施例1−1と同様の方法でアリルアルコールのα−オレフィンエポキシド付加物a−4を得た。次いで、α−オレフィンエポキシド付加物a−1をα−オレフィンエポキシド付加物a−4に変更したこと以外は、実施例1−1と同様の方法で、α−オレフィンエポキシド付加物a−4に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−4とした。
α−オレフィンエポキシドの使用量を0.7モルに変更したこと以外は、実施例1−1と同様の方法でアリルアルコールのα−オレフィンエポキシド付加物a−5を得た。次いで、α−オレフィンエポキシド付加物a−1をα−オレフィンエポキシド付加物a−5に変更したこと以外は、実施例1−1と同様の方法で、α−オレフィンエポキシド付加物a−5に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−5とした。
α−オレフィンエポキシドの使用量を1.3モルに変更したこと以外は、実施例1−1と同様の方法でアリルアルコールのα−オレフィンエポキシド付加物a−6を得た。次いで、α−オレフィンエポキシド付加物a−1をα−オレフィンエポキシド付加物a−6に変更したこと以外は、実施例1−1と同様の方法で、α−オレフィンエポキシド付加物a−6に対してエチレンオキシドが20モル付加された化合物C1及び化合物C2の混合物を得た。この混合物を界面活性剤S−6とした。
・測定装置:Agilent 7820A
・カラム;Agilent DB−1
・注入量:1.0μL(スプリット比50:1)
・注入口温度:300℃
・昇温条件:初期温度40℃×1分保持、その後、10℃/分の速度で80℃まで昇温し、次いで、15℃/分の速度で300℃まで昇温
・キャリアガス:ヘリウム(25mL/分)
・検出器:水素炎イオン化型検出器(FID)
撹拌機、温度計、窒素導入管、原料仕込み用導入管、及び減圧用排気管を備えた温度調節機付きのオートクレーブに、スチレン化フェノール(モノ体/ジ体/トリ体=15/55/30質量比)318g(1.0モル)、触媒として水酸化カリウム5.0gを仕込んだ。次いで、オートクレーブ内の雰囲気を窒素で置換し、減圧条件下で温度100℃まで昇温した後、エチレンオキサイド66g(1.5モル)を逐次導入しながら圧力0.15MPa、温度120℃の条件にて反応させた。この後、温度100℃でアリルグリシジルエーテル171g(1.5モル)をオートクレーブに導入して5時間攪拌継続して反応させた。次いで、圧力0.15MPa、温度130℃の条件下でエチレンオキサイド880g(20モル)を逐次導入して反応させることで界面活性剤S−7を得た。
メタクリル酸メチルを123.75g、アクリル酸ブチルを123.75g、アクリル酸を2.5g、界面活性剤S−1を15.0gおよびイオン交換水を107g配合して、ホモミキサーで混合し、混合モノマー乳濁液を調製した。これとは別に、撹拌機、還流冷却器、温度計、窒素導入管及び滴下漏斗を備えた反応器に、イオン交換水128g、炭酸水素ナトリウム0.25gを混合した。ここに、上記混合モノマー乳濁液のうち37gを添加し、80℃に昇温し、15分間撹拌した。続いて、過硫酸アンモニウム0.5gとイオン交換水20gとの混合物(水溶液)を添加して15分間混合した後、3時間かけて、残りの混合モノマー乳濁液を滴下した。さらに、2時間混合した後、冷却し、アンモニア水を用いてpH8に調整することにより、樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−2に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−3に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−4に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
メタクリル酸メチルをアクリル酸2−エチルヘキシルに変更したこと以外は、実施例2−2と同様の方法で樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−5に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−6に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
界面活性剤S−1を界面活性剤S−7に変更したこと以外は、実施例2−1と同様の方法で樹脂水分散体を得た。
(重合安定性)
重合直後の樹脂水分散体をポリエステルメッシュ(200メッシュ)に通し、乳化重合中に生成した凝集物をろ別した。ろ過残渣を水洗した後、105℃で2時間乾燥し、その質量から樹脂水分散体の固形分に対する質量%を求め、以下の基準に基づいて評価した。◎:ろ過残渣は0.5質量%未満であり、重合安定性は極めて良好であった。
〇:ろ過残渣は0.5質量%以上1.0質量%未満であり、重合安定性は良好であった。
×:ろ過残渣は1.0質量%以上であり、重合安定性は悪かった。
自動接触角計「DropMaster500」(協和界面科学株式会社製)を用いて、ポリプロピレン板(PP標準試験板、日本テストパネル株式会社)上の樹脂水分散体(10μL)の60秒後の接触角を測定した。
樹脂水分散体を乾燥時の膜厚が120μmになるようにガラス板に塗布し、60℃で60分間乾燥後、20℃、65%RHの雰囲気下で48時間乾燥させた。得られた樹脂フィルムを25℃の純水に浸漬し、16ポイントの印刷文字の上にガラス板を置き、樹脂フィルムを通して文字を透かして見たときに、その文字が見えなくなるまでの日数を調査し、下記の基準で評価した。
◎:15日以上であり、耐水白化性が極めて優れていた。
〇:5日以上15日未満であり、耐水白化性が優れていた。
×:5日未満であり、耐水白化性が悪かった。
ただし、実施例2−5に限っては、下記の基準で評価した。
◎:24時間以上であり、耐水白化性が極めて優れていた。
〇:6時間以上24時間未満であり、耐水白化性が優れていた。
×:6時間未満であり、耐水白化性が悪かった。
25mm幅に切ったポリエチレンテレフタレートフィルム上に樹脂水分散体を52μmの厚さに塗工し、熱風循環式乾燥器にて105℃で20分間乾燥させて粘着シートを作製した。これをステンレス板に2kgのローラーを2往復させて貼り合わせ、20℃の水に24時間浸漬させた。その後、水から試験片を取り出し、引張速度30mm/分、測定温度20℃の条件で180度剥離テストを行い、粘着力(N/25mm)を測定した。その結果を、以下の基準に基づいて評価した。
◎:5.0N/25mm以上であり、耐水粘着力が極めて優れていた。
〇:1.0N/25mm以上5.0N/25mm未満であり、耐水粘着力が優れていた。
×:1.0N/25mm未満であり、耐水粘着力が悪かった。
Claims (4)
- 請求項1に記載の界面活性剤組成物の存在下、重合性化合物の重合反応を行う工程を具備する、樹脂水分散体の製造方法。
- 請求項2に記載の製造方法で製造された樹脂水分散体を含む、塗料。
- 請求項2に記載の製造方法で製造された樹脂水分散体を含む、粘着剤。
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TW109131655A TW202115153A (zh) | 2019-09-30 | 2020-09-15 | 界面活性劑組成物、樹脂水分散體的製造方法、塗料及黏著劑 |
EP20871505.2A EP4039360A4 (en) | 2019-09-30 | 2020-09-23 | SURFACTANT COMPOSITION, METHOD FOR PRODUCING AQUEOUS RESIN DISPERSION, PAINT AND ADHESIVE |
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CN202080062041.7A CN114341200B (zh) | 2019-09-30 | 2020-09-23 | 表面活性剂组合物、树脂水分散体的制造方法、涂料及粘合剂 |
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