JP2020534402A - フルオロポリマー分散体、フルオロポリマー分散体を製造するための方法、触媒インク及びポリマー電解質膜 - Google Patents

フルオロポリマー分散体、フルオロポリマー分散体を製造するための方法、触媒インク及びポリマー電解質膜 Download PDF

Info

Publication number
JP2020534402A
JP2020534402A JP2020515200A JP2020515200A JP2020534402A JP 2020534402 A JP2020534402 A JP 2020534402A JP 2020515200 A JP2020515200 A JP 2020515200A JP 2020515200 A JP2020515200 A JP 2020515200A JP 2020534402 A JP2020534402 A JP 2020534402A
Authority
JP
Japan
Prior art keywords
copolymer
present disclosure
formula
fluoropolymer dispersion
fluoropolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2020515200A
Other languages
English (en)
Japanese (ja)
Other versions
JP2020534402A5 (enExample
Inventor
チェン,リサ ピー.
ピー. チェン,リサ
ディー. ダルケ,グレッグ
ディー. ダルケ,グレッグ
ドゥチェスン,デニス
ハムロック,スティーブン ジェイ.
ジェイ. ハムロック,スティーブン
ヒンツァー,クラウス
エー. ヒルシュベルグ,マルクス
エー. ヒルシュベルグ,マルクス
タラー,アーネ
ツェー. ジップリース,ティルマン
ツェー. ジップリース,ティルマン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of JP2020534402A publication Critical patent/JP2020534402A/ja
Publication of JP2020534402A5 publication Critical patent/JP2020534402A5/ja
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/184Monomers containing fluorine with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene
    • C08F214/262Tetrafluoroethene with fluorinated vinyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/10Aqueous solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/12Hydrolysis
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36Sulfonation; Sulfation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/44Preparation of metal salts or ammonium salts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/05Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18Homopolymers or copolymers of tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/22Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14Monomers containing only one unsaturated aliphatic radical
    • C08F216/1416Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466Monomers containing sulfur
    • C08F216/1475Monomers containing sulfur and oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/50Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Wood Science & Technology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Battery Electrode And Active Subsutance (AREA)
JP2020515200A 2017-09-14 2018-09-14 フルオロポリマー分散体、フルオロポリマー分散体を製造するための方法、触媒インク及びポリマー電解質膜 Pending JP2020534402A (ja)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201762558655P 2017-09-14 2017-09-14
US201762558671P 2017-09-14 2017-09-14
US62/558,655 2017-09-14
US62/558,671 2017-09-14
US201862730648P 2018-09-13 2018-09-13
US62/730,648 2018-09-13
PCT/US2018/051096 WO2019055793A1 (en) 2017-09-14 2018-09-14 FLUOROPOLYMER DISPERSION, METHOD FOR PRODUCING FLUOROPOLYMER DISPERSION, CATALYTIC INK, AND POLYMER ELECTROLYTE MEMBRANE

Publications (2)

Publication Number Publication Date
JP2020534402A true JP2020534402A (ja) 2020-11-26
JP2020534402A5 JP2020534402A5 (enExample) 2021-10-28

Family

ID=63722797

Family Applications (3)

Application Number Title Priority Date Filing Date
JP2020515200A Pending JP2020534402A (ja) 2017-09-14 2018-09-14 フルオロポリマー分散体、フルオロポリマー分散体を製造するための方法、触媒インク及びポリマー電解質膜
JP2020515159A Pending JP2020534400A (ja) 2017-09-14 2018-09-14 スルホニルペンダント基を有するフッ素化コポリマー、並びにそれを含む組成物及び物品
JP2020515123A Pending JP2020534398A (ja) 2017-09-14 2018-09-14 フッ素化コポリマー並びにこれを含む組成物及び物品

Family Applications After (2)

Application Number Title Priority Date Filing Date
JP2020515159A Pending JP2020534400A (ja) 2017-09-14 2018-09-14 スルホニルペンダント基を有するフッ素化コポリマー、並びにそれを含む組成物及び物品
JP2020515123A Pending JP2020534398A (ja) 2017-09-14 2018-09-14 フッ素化コポリマー並びにこれを含む組成物及び物品

Country Status (6)

Country Link
US (3) US11377510B2 (enExample)
EP (3) EP3681917A1 (enExample)
JP (3) JP2020534402A (enExample)
KR (3) KR20200052896A (enExample)
CN (3) CN111094439B (enExample)
WO (3) WO2019055791A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023519957A (ja) * 2020-03-30 2023-05-15 スリーエム イノベイティブ プロパティズ カンパニー イオン性ビス(スルホニル)イミド部分及びペルフルオロエーテル末端基を有するペンダント基を含むフルオロポリマー

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9474282B2 (en) 2013-12-13 2016-10-25 Tony John Hall Acid-solubilized copper-ammonium complexes and copper-zinc-ammonium complexes, compositions, preparations, methods, and uses
WO2019055791A1 (en) * 2017-09-14 2019-03-21 3M Innovative Properties Company FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND COMPOSITIONS AND ARTICLES COMPRISING SAID FLUORINATED COPOLYMER
WO2020183306A1 (en) * 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
KR20220119048A (ko) * 2019-12-20 2022-08-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 공중합체 및 이를 포함하는 조성물 및 물품
US11746169B2 (en) 2020-07-06 2023-09-05 Asahi Kasei Kabushiki Kaisha Polymer composition and ion-exchange membrane
WO2022118215A1 (en) 2020-12-02 2022-06-09 3M Innovative Properties Company White polytetrafluoroethylene powders
EP4019580A1 (en) 2020-12-28 2022-06-29 3M Innovative Properties Company Reduction of fluorinated acid in fluoropolymers
US20240347751A1 (en) * 2021-07-28 2024-10-17 3M Innovative Properties Company Making an Electrochemical Membrane from Low T(alpha) Fluorinated Ionomer Salts
CN113937303B (zh) * 2021-10-14 2023-07-21 中汽创智科技有限公司 一种催化层电极组合物及包含其的催化层电极、膜电极
CN116265492B (zh) * 2021-12-17 2024-05-14 济南大学 一类氢键增强型全氟共轭阳离子树脂及其合成方法以及阴离子交换膜和膜电极
US20250167273A1 (en) * 2022-06-03 2025-05-22 Celadyne Technologies, Inc. Composite polyelectrolyte-ceramic membranes
CN115132961A (zh) * 2022-06-27 2022-09-30 蜂巢能源科技(无锡)有限公司 一种钠离子电池正极极片及其制备方法和应用
WO2024189366A1 (en) 2023-03-16 2024-09-19 Johnson Matthey Hydrogen Technologies Limited Reinforced ion-conducting membrane
GB2641268A (en) 2024-05-23 2025-11-26 Johnson Matthey Hydrogen Technologies Ltd Water electrolyser membrane

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11329062A (ja) * 1998-05-13 1999-11-30 Daikin Ind Ltd 燃料電池に使用するのに適した固体高分子電解質用材料
JP2002212246A (ja) * 2000-02-15 2002-07-31 Asahi Glass Co Ltd ブロックポリマー、重合体の製造方法及びブロックポリマーを含む液状組成物
JP2002216804A (ja) * 2000-02-15 2002-08-02 Asahi Glass Co Ltd 固体高分子型燃料電池
JP2014529636A (ja) * 2011-08-04 2014-11-13 スリーエム イノベイティブプロパティズカンパニー 低当量重量ポリマー
JP2015537107A (ja) * 2012-12-04 2015-12-24 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化ポリマー
JP2016006173A (ja) * 2014-05-28 2016-01-14 ダイキン工業株式会社 高酸素透過性アイオノマー
WO2017053563A1 (en) * 2015-09-23 2017-03-30 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups

Family Cites Families (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3718627A (en) 1968-11-26 1973-02-27 Du Pont Cf{11 {32 cfcf{11 cf{11 so{11 {11 f and derivatives and polymers thereof
GB1286859A (en) 1968-11-26 1972-08-23 Du Pont Solutions of fluorinated polymers
SE7712836L (sv) 1976-12-02 1978-06-03 Du Pont Polyfluoroallyloxiforeningar
US4267364A (en) 1977-04-20 1981-05-12 E. I. Dupont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
US4349650A (en) 1979-03-14 1982-09-14 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4292449A (en) 1979-03-14 1981-09-29 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4273729A (en) 1979-03-14 1981-06-16 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4275225A (en) 1979-03-14 1981-06-23 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4273728A (en) 1979-03-14 1981-06-16 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4433082A (en) 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
US4423197A (en) 1981-12-01 1983-12-27 Minnesota Mining And Manufacturing Company Cyclic perfluoroaliphatic-disulfonic acid anhydrides and sulfonamide derivatives thereof
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US5093409A (en) 1988-05-27 1992-03-03 E. I. Du Pont De Nemours And Company Process for the stabilization of fluoropolymers
JPH027384A (ja) 1988-06-27 1990-01-11 Toshiba Corp 調理器
IT1230718B (it) 1989-02-13 1991-10-29 Ausimont Srl Fluorurazione diretta di fluoro b sultoni ai corrispondenti fluorossi fluorosulfonil fluorocomposti.
US5089200A (en) 1989-10-06 1992-02-18 E. I. Dupont De Nemours And Company Process for melt extrusion of polymers
US5010130A (en) 1990-05-15 1991-04-23 E. I. Du Pont De Nemours And Company High melt viscosity fluoropolymer process aid
US5182342A (en) 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
DE4233824A1 (de) 1992-10-08 1994-04-14 Hoechst Ag Verfahren zur Aufarbeitung wäßriger Dispersionen von Fluorthermoplasten
US5285002A (en) 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
DE4402694A1 (de) 1993-06-02 1995-08-03 Hoechst Ag Verfahren zur Rückgewinnung von fluorierten Carbonsäuren
US6133389A (en) 1995-02-06 2000-10-17 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene-hexafluoropropylene copolymers
US5780552A (en) 1996-09-13 1998-07-14 E. I. Du Pont De Nemours And Company Fluoropolymers having core/shell structure with functional units in the shell
US5912280A (en) 1996-12-27 1999-06-15 E. I. Du Pont De Nemours And Company Ink jet inks containing emulsion-polymer additives to improve water-fastness
DE69835366T2 (de) * 1997-03-31 2007-07-19 Daikin Industries, Ltd. Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
JPH1167274A (ja) 1997-08-22 1999-03-09 Daikin Ind Ltd リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤
US6388139B1 (en) 1997-11-05 2002-05-14 E. I. Du Pont De Nemours And Company Production of perfluoro (alkyl vinyl) ethers
DE19824614A1 (de) 1998-06-02 1999-12-09 Dyneon Gmbh Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern
US6294627B1 (en) 1998-08-31 2001-09-25 Dyneon Llc Low temperature fluorocarbon elastomers
MY135964A (en) 1998-10-26 2008-07-31 Du Pont Ionomers and polymers for electrochemical uses
IT1303779B1 (it) 1998-11-23 2001-02-23 Ausimont Spa Preparazione di soluzioni di polimeri fluorurati solfonici.
JP2000188111A (ja) 1998-12-22 2000-07-04 Asahi Glass Co Ltd 固体高分子電解質型燃料電池
US6429258B1 (en) 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
DE19933696A1 (de) 1999-07-17 2001-01-18 Dyneon Gmbh Verfahren zur Rückgewinnung fluorierter Emulgatoren aus wässrigen Phasen
US6255536B1 (en) 1999-12-22 2001-07-03 Dyneon Llc Fluorine containing vinyl ethers
EP1126537B1 (en) * 2000-02-15 2010-12-15 Asahi Glass Company Ltd. Block polymer, process for producing a polymer, and polymer electrolyte fuel cell
WO2001060876A1 (en) 2000-02-16 2001-08-23 Daikin Industries, Ltd. Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation
US6794550B2 (en) 2000-04-14 2004-09-21 3M Innovative Properties Company Method of making an aqueous dispersion of fluoropolymers
KR100337889B1 (ko) 2000-06-22 2002-05-24 김순택 리튬 2차전지
DE60135080D1 (de) 2000-12-26 2008-09-11 Asahi Glass Co Ltd Festpolymer-Elektrolyt Material, flüssige Zusammensetzung, Festpolymer Brennstoffzelle und Fluorpolymer
US20020160272A1 (en) 2001-02-23 2002-10-31 Kabushiki Kaisha Toyota Chuo Process for producing a modified electrolyte and the modified electrolyte
US6743508B2 (en) 2002-01-17 2004-06-01 Daikin America, Inc. Fep pellet
US20040107869A1 (en) 2002-12-10 2004-06-10 3M Innovative Properties Company Catalyst ink
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7589234B2 (en) 2003-07-02 2009-09-15 Daikin Industries, Ltd. Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer
WO2005007707A1 (ja) 2003-07-16 2005-01-27 Daikin Industries, Ltd. 含フッ素重合体の製造方法、含フッ素重合体水性分散液、2−アシルオキシカルボン酸誘導体及び界面活性剤
US20050037265A1 (en) 2003-08-14 2005-02-17 Asahi Glass Company, Limited Polymer electrolyte fuel cell, electrolyte material therefore and method for its production
EP2452955B1 (en) 2003-09-10 2016-12-14 Asahi Kasei Kabushiki Kaisha Stabilized fluoropolymer and method for producing same
CN100404566C (zh) 2003-10-22 2008-07-23 大金工业株式会社 四氟乙烯聚合物水性分散液、其制造方法、四氟乙烯聚合物粉末以及四氟乙烯聚合物成型体
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7265162B2 (en) 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
EP1561729A1 (en) 2004-02-05 2005-08-10 3M Innovative Properties Company Removal of fluorinated surfactants from waste water
US7304101B2 (en) 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
JP2006036986A (ja) 2004-07-28 2006-02-09 Asahi Glass Co Ltd 含フッ素ポリマーラテックス、その製造方法および含フッ素ポリマー
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
JP2006232704A (ja) 2005-02-23 2006-09-07 Asahi Glass Co Ltd 新規なフルオロスルホニル基含有化合物
JP5061446B2 (ja) 2005-03-04 2012-10-31 旭硝子株式会社 含フッ素エラストマーラテックス、その製造方法、含フッ素エラストマーおよび含フッ素ゴム成形品
US7214740B2 (en) 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US7795332B2 (en) 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
US8367267B2 (en) 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US20070142513A1 (en) 2005-12-21 2007-06-21 Daikin Industries, Ltd. Surfactant, method of producing a fluoropolymer, fluoropolymer aqueous dispersion
ITMI20052509A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
EP1985636B1 (en) 2006-02-03 2019-07-17 Daikin Industries, Ltd. Method for producing -so3h group-containing fluoropolymer
EP1914251A1 (en) 2006-10-17 2008-04-23 Solvay Solexis S.p.A. Process for stabilizing fluoropolymer having ion exchange groups
US7456314B2 (en) * 2006-12-21 2008-11-25 E.I. Du Pont De Nemours And Company Partially fluorinated ionic compounds
US7575534B2 (en) 2006-12-22 2009-08-18 Torvec, Inc. Transmission with resistance torque control
GB0714361D0 (en) 2007-07-24 2007-09-05 3M Innovative Properties Co Cation conductive membranes comprising polysulfonic acid polymers and metal salts having an F-containing anion
CN101821301B (zh) * 2007-10-12 2012-06-27 3M创新有限公司 制备纯净含氟聚合物的方法
GB0801194D0 (en) 2008-01-23 2008-02-27 3M Innovative Properties Co Processing aid compositions comprising fluoropolymers having long-chain branches
JP5217708B2 (ja) 2008-07-09 2013-06-19 旭硝子株式会社 ポリマー、その製造方法、固体高分子形燃料電池用電解質膜および膜電極接合体
US8436053B2 (en) 2008-12-23 2013-05-07 E.I. Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8058376B2 (en) * 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ
JP5540681B2 (ja) 2009-07-14 2014-07-02 株式会社豊田中央研究所 改質電解質及びその製造方法、並びに、改質剤
CN103228708B (zh) 2010-11-26 2015-09-02 索尔维特殊聚合物意大利有限公司 (全)氟化的离子交换聚合物的液体组合物
EP2656425B1 (en) 2010-12-20 2014-12-10 E.I. Du Pont De Nemours And Company Ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
JP2014500392A (ja) 2010-12-20 2014-01-09 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー アイオノマー及びイオン伝導性組成物
WO2012088176A1 (en) 2010-12-20 2012-06-28 E. I. Du Pont De Nemours And Company High molecular weight ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
JP5862372B2 (ja) 2012-03-02 2016-02-16 旭硝子株式会社 ポリマーの製造方法、固体高分子形燃料電池用電解質膜の製造方法および膜電極接合体の製造方法
EP2882705B1 (en) 2012-08-10 2018-02-21 Solvay Specialty Polymers Italy S.p.A. Allyl-bearing fluorinated ionomers
US20150303517A1 (en) 2012-11-08 2015-10-22 Sumitomo Chemical Company, Limited Sodium secondary battery
US20140255703A1 (en) 2013-03-05 2014-09-11 E I Du Pont De Nemours And Company Adhesion of Fluoropolymer to Metal
WO2016130900A1 (en) 2015-02-12 2016-08-18 3M Innovative Properties Company Tetrafluoroethylene/hexafluoropropylene copolymers having pendant sulfonyl groups
GB201505311D0 (en) 2015-03-27 2015-05-13 Johnson Matthey Fuel Cells Ltd Process
CN108779209A (zh) 2016-03-07 2018-11-09 3M创新有限公司 具有磺酰侧基的氟化共聚物和制备离聚物的方法
WO2019055791A1 (en) 2017-09-14 2019-03-21 3M Innovative Properties Company FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND COMPOSITIONS AND ARTICLES COMPRISING SAID FLUORINATED COPOLYMER

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11329062A (ja) * 1998-05-13 1999-11-30 Daikin Ind Ltd 燃料電池に使用するのに適した固体高分子電解質用材料
US7455934B1 (en) * 1998-05-13 2008-11-25 Daikin Industries, Ltd. Fluorocopolymer material with sulfonic acid functional groups as a solid polyelectrolyte for use in fuel cells
JP2002212246A (ja) * 2000-02-15 2002-07-31 Asahi Glass Co Ltd ブロックポリマー、重合体の製造方法及びブロックポリマーを含む液状組成物
JP2002216804A (ja) * 2000-02-15 2002-08-02 Asahi Glass Co Ltd 固体高分子型燃料電池
JP2014529636A (ja) * 2011-08-04 2014-11-13 スリーエム イノベイティブプロパティズカンパニー 低当量重量ポリマー
JP2015537107A (ja) * 2012-12-04 2015-12-24 スリーエム イノベイティブ プロパティズ カンパニー 高フッ素化ポリマー
JP2016006173A (ja) * 2014-05-28 2016-01-14 ダイキン工業株式会社 高酸素透過性アイオノマー
WO2017053563A1 (en) * 2015-09-23 2017-03-30 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023519957A (ja) * 2020-03-30 2023-05-15 スリーエム イノベイティブ プロパティズ カンパニー イオン性ビス(スルホニル)イミド部分及びペルフルオロエーテル末端基を有するペンダント基を含むフルオロポリマー
JP7734684B2 (ja) 2020-03-30 2025-09-05 スリーエム イノベイティブ プロパティズ カンパニー イオン性ビス(スルホニル)イミド部分及びペルフルオロエーテル末端基を有するペンダント基を含むフルオロポリマー
US12489130B2 (en) 2020-03-30 2025-12-02 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group

Also Published As

Publication number Publication date
KR20200054213A (ko) 2020-05-19
US11492431B2 (en) 2022-11-08
US20200303755A1 (en) 2020-09-24
US20200277420A1 (en) 2020-09-03
EP3681948A1 (en) 2020-07-22
EP3681948A4 (en) 2021-07-14
US20200199259A1 (en) 2020-06-25
US11377510B2 (en) 2022-07-05
CN111094439A (zh) 2020-05-01
CN111133015B (zh) 2022-09-06
EP3681949A1 (en) 2020-07-22
CN111094438A (zh) 2020-05-01
KR20200052896A (ko) 2020-05-15
CN111094438B (zh) 2022-11-08
CN111133015A (zh) 2020-05-08
WO2019055793A1 (en) 2019-03-21
KR102601806B1 (ko) 2023-11-14
EP3681917A1 (en) 2020-07-22
JP2020534398A (ja) 2020-11-26
EP3681949A4 (en) 2021-07-14
KR20200052897A (ko) 2020-05-15
JP2020534400A (ja) 2020-11-26
CN111094439B (zh) 2022-11-08
WO2019055791A1 (en) 2019-03-21
WO2019055799A1 (en) 2019-03-21

Similar Documents

Publication Publication Date Title
US11492431B2 (en) Fluorinated copolymer having sulfonyl pendant groups and compositions and articles including the same
EP3353221B1 (en) Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
EP3426701B1 (en) Fluorinated copolymer having sulfonyl pendant groups and method of making an ionomer
CN114901710B (zh) 氟化共聚物以及包括其的组合物和制品
US20250239638A1 (en) Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
KR20220167297A (ko) 플루오르화 중합체 및 염 나노입자를 포함하는 복합재 및 이를 포함하는 물품

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210914

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20210914

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20221003

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20221004

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20221011

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20221226

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20230302

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20230331

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20230627

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20231027