JP2019513866A5 - - Google Patents
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- Publication number
- JP2019513866A5 JP2019513866A5 JP2018552830A JP2018552830A JP2019513866A5 JP 2019513866 A5 JP2019513866 A5 JP 2019513866A5 JP 2018552830 A JP2018552830 A JP 2018552830A JP 2018552830 A JP2018552830 A JP 2018552830A JP 2019513866 A5 JP2019513866 A5 JP 2019513866A5
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- solvent
- epoxidation
- range
- epoxidizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 claims description 30
- 229920000642 polymer Polymers 0.000 claims description 27
- 239000002904 solvent Substances 0.000 claims description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 238000006735 epoxidation reaction Methods 0.000 claims description 8
- 239000003153 chemical reaction reagent Substances 0.000 claims description 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 150000008065 acid anhydrides Chemical class 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- LOVYCUYJRWLTSU-UHFFFAOYSA-N 2-(3,4-dichlorophenoxy)-n,n-diethylethanamine Chemical compound CCN(CC)CCOC1=CC=C(Cl)C(Cl)=C1 LOVYCUYJRWLTSU-UHFFFAOYSA-N 0.000 claims description 3
- 241001495453 Parthenium argentatum Species 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- MPRWIVBRDAXEAF-UHFFFAOYSA-N acetyloxy ethaneperoxoate Chemical compound CC(=O)OOOC(C)=O MPRWIVBRDAXEAF-UHFFFAOYSA-N 0.000 claims description 2
- 239000008346 aqueous phase Substances 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 239000002244 precipitate Substances 0.000 claims description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022012125A JP2022068188A (ja) | 2016-04-05 | 2022-01-28 | エポキシ化ポリマーの製造法 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662318387P | 2016-04-05 | 2016-04-05 | |
| US62/318,387 | 2016-04-05 | ||
| PCT/US2017/025857 WO2017176686A1 (en) | 2016-04-05 | 2017-04-04 | Process for producing epoxidized polymers |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022012125A Division JP2022068188A (ja) | 2016-04-05 | 2022-01-28 | エポキシ化ポリマーの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2019513866A JP2019513866A (ja) | 2019-05-30 |
| JP2019513866A5 true JP2019513866A5 (enExample) | 2020-07-30 |
Family
ID=60000667
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018552830A Pending JP2019513866A (ja) | 2016-04-05 | 2017-04-04 | エポキシ化ポリマーの製造法 |
| JP2022012125A Pending JP2022068188A (ja) | 2016-04-05 | 2022-01-28 | エポキシ化ポリマーの製造法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022012125A Pending JP2022068188A (ja) | 2016-04-05 | 2022-01-28 | エポキシ化ポリマーの製造法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10836841B2 (enExample) |
| EP (1) | EP3440116A4 (enExample) |
| JP (2) | JP2019513866A (enExample) |
| KR (1) | KR20180123585A (enExample) |
| CN (1) | CN108884185A (enExample) |
| CA (1) | CA3018778A1 (enExample) |
| MX (1) | MX2018012259A (enExample) |
| WO (1) | WO2017176686A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3898704A1 (en) | 2018-12-21 | 2021-10-27 | Bridgestone Corporation | Processes for increasing the molecular weight of guayule natural rubber |
| KR102394623B1 (ko) * | 2020-09-01 | 2022-05-06 | 김진국 | 에폭시화 고무의 제조방법 |
| US20230382007A1 (en) * | 2020-10-16 | 2023-11-30 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Particleboards including modified guayule resins/soy protein resin blends and associated methods for forming same |
| CN113072652B (zh) * | 2021-04-25 | 2022-06-28 | 岭南师范学院 | 一种定量环氧化天然橡胶及其制备方法 |
| CN116135887A (zh) * | 2021-11-17 | 2023-05-19 | 北京化工大学 | 一种环氧化橡胶的制备方法、环氧化橡胶及应用 |
| CN116162296A (zh) * | 2021-11-25 | 2023-05-26 | 北京化工大学 | 一种高性能绿色轮胎的胎面材料及其制备方法和应用 |
| CN116162205B (zh) * | 2021-11-25 | 2025-09-16 | 北京化工大学 | 一种环氧化溶聚丁苯橡胶及其制备方法和应用 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305515A (en) | 1964-05-06 | 1967-02-21 | Exxon Research Engineering Co | Solvent for polybutadiene rubber |
| US4219627A (en) | 1977-03-09 | 1980-08-26 | The Firestone Tire & Rubber Company | Process for the preparation of block copolymers |
| US5747598A (en) | 1990-01-16 | 1998-05-05 | Mobil Oil Corporation | Epoxidized solid elastomeric copolymers |
| US5034470A (en) * | 1990-09-04 | 1991-07-23 | The Goodyear Tire & Rubber Company | Process for the preparation of epoxidized synthetic cis-1,4-polyisoprene |
| US5399626A (en) | 1991-04-29 | 1995-03-21 | Shell Oil Company | Viscous conjugated diene block copolymers |
| US5310819A (en) | 1992-01-23 | 1994-05-10 | The United States Of America As Represented By The Secretary Of The Navy | Surface epoxidation of elastomers |
| EP0624601B1 (en) | 1993-05-13 | 1997-08-06 | Kao Corporation | Process for producing raw rubber |
| CN1475539A (zh) * | 1995-12-14 | 2004-02-18 | 大赛璐化学工业株式会社 | 底涂剂组合物 |
| JP3722238B2 (ja) * | 1995-12-14 | 2005-11-30 | ダイセル化学工業株式会社 | エポキシ化有機系重合体の製造方法 |
| US5789512A (en) | 1996-12-23 | 1998-08-04 | Sartomer Company | Method for the epoxidation of unsaturated polymers |
| US6242536B1 (en) | 1997-12-11 | 2001-06-05 | Bridgestone Corporation | Process for preparation of block copolymers in mixed alkane/cycloalkane solvents |
| US6455655B1 (en) | 2000-09-28 | 2002-09-24 | The Goodyear Tire & Rubber Company | Emulsion styrene-butadiene rubber |
| CN1113906C (zh) * | 2000-10-29 | 2003-07-09 | 青岛化工学院 | 环氧化反式-1,4-聚异戊二烯的合成方法 |
| US6903164B2 (en) | 2000-11-13 | 2005-06-07 | Daicel Chemical Industries, Ltd. | Epoxidized thermoplastic polymers and processes for their production |
| US6903165B2 (en) * | 2001-05-14 | 2005-06-07 | Daicel Chemical Industries, Ltd. | Process for producing epoxidized diene polymer |
| US6716925B2 (en) | 2001-11-02 | 2004-04-06 | The Goodyear Tire & Rubber Company | Tire with a component made of a rubber composition comprised of a rubber having pendant hydroxyl groups and a rubber containing a nitrile moiety |
| US8519057B2 (en) * | 2007-06-01 | 2013-08-27 | Exxonmobil Chemical Patents Inc. | Impact modification and functionalization of copolymers of olefins and dienes |
| JP5654409B2 (ja) * | 2011-04-22 | 2015-01-14 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| TWI426090B (zh) | 2011-05-31 | 2014-02-11 | Tsrc Corp | 製造環氧化聚合物的方法 |
| US9193806B2 (en) * | 2012-01-23 | 2015-11-24 | Sumitomo Rubber Industries, Ltd. | Method for producing an epoxidized natural rubber, rubber composition for tires, and pneumatic tire |
| JP5603363B2 (ja) | 2012-03-08 | 2014-10-08 | 住友ゴム工業株式会社 | エポキシ化天然ゴムの製造方法、タイヤ用ゴム組成物及び空気入りタイヤ |
| CN103130990B (zh) * | 2012-10-03 | 2015-02-18 | 大连理工大学 | 星形梳状聚乳酸及其制备方法 |
| WO2014066717A1 (en) * | 2012-10-26 | 2014-05-01 | Dow Global Technologies Llc | Novel epoxide compounds: 1,3-dioxiranylcyclopentane derivatives |
| CN103570848B (zh) * | 2013-10-24 | 2016-01-20 | 沈阳化工大学 | 环氧化天然杜仲胶的合成方法 |
| FR3017393B1 (fr) * | 2014-02-07 | 2016-02-12 | Michelin & Cie | Bande de roulement pour pneumatique a base de polyisoprene epoxyde |
| CN103910816B (zh) * | 2014-04-12 | 2016-06-15 | 青岛科技大学 | 一种改进的环氧化反式异戊橡胶制备方法 |
-
2017
- 2017-04-04 KR KR1020187032146A patent/KR20180123585A/ko not_active Ceased
- 2017-04-04 US US16/091,431 patent/US10836841B2/en not_active Expired - Fee Related
- 2017-04-04 JP JP2018552830A patent/JP2019513866A/ja active Pending
- 2017-04-04 WO PCT/US2017/025857 patent/WO2017176686A1/en not_active Ceased
- 2017-04-04 MX MX2018012259A patent/MX2018012259A/es unknown
- 2017-04-04 CA CA3018778A patent/CA3018778A1/en active Pending
- 2017-04-04 EP EP17779622.4A patent/EP3440116A4/en not_active Withdrawn
- 2017-04-04 CN CN201780022017.9A patent/CN108884185A/zh active Pending
-
2022
- 2022-01-28 JP JP2022012125A patent/JP2022068188A/ja active Pending
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