CA3018778A1 - Process for producing epoxidized polymers - Google Patents

Process for producing epoxidized polymers Download PDF

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Publication number
CA3018778A1
CA3018778A1 CA3018778A CA3018778A CA3018778A1 CA 3018778 A1 CA3018778 A1 CA 3018778A1 CA 3018778 A CA3018778 A CA 3018778A CA 3018778 A CA3018778 A CA 3018778A CA 3018778 A1 CA3018778 A1 CA 3018778A1
Authority
CA
Canada
Prior art keywords
polymer
solvent
epoxidation
epoxidized
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CA3018778A
Other languages
English (en)
French (fr)
Inventor
Nicolas SAUTY
Howard Colvin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Cooper Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cooper Tire and Rubber Co filed Critical Cooper Tire and Rubber Co
Publication of CA3018778A1 publication Critical patent/CA3018778A1/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/08—Epoxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/04—Oxidation
    • C08C19/06—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
CA3018778A 2016-04-05 2017-04-04 Process for producing epoxidized polymers Pending CA3018778A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662318387P 2016-04-05 2016-04-05
US62/318,387 2016-04-05
PCT/US2017/025857 WO2017176686A1 (en) 2016-04-05 2017-04-04 Process for producing epoxidized polymers

Publications (1)

Publication Number Publication Date
CA3018778A1 true CA3018778A1 (en) 2017-10-12

Family

ID=60000667

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3018778A Pending CA3018778A1 (en) 2016-04-05 2017-04-04 Process for producing epoxidized polymers

Country Status (8)

Country Link
US (1) US10836841B2 (enExample)
EP (1) EP3440116A4 (enExample)
JP (2) JP2019513866A (enExample)
KR (1) KR20180123585A (enExample)
CN (1) CN108884185A (enExample)
CA (1) CA3018778A1 (enExample)
MX (1) MX2018012259A (enExample)
WO (1) WO2017176686A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020132236A1 (en) 2018-12-21 2020-06-25 Bridgestone Corporation Processes for increasing the molecular weight of guayule natural rubber
KR102394623B1 (ko) * 2020-09-01 2022-05-06 김진국 에폭시화 고무의 제조방법
US20230382007A1 (en) * 2020-10-16 2023-11-30 Arizona Board Of Regents On Behalf Of The University Of Arizona Particleboards including modified guayule resins/soy protein resin blends and associated methods for forming same
CN113072652B (zh) * 2021-04-25 2022-06-28 岭南师范学院 一种定量环氧化天然橡胶及其制备方法
CN116135887A (zh) * 2021-11-17 2023-05-19 北京化工大学 一种环氧化橡胶的制备方法、环氧化橡胶及应用
CN116162205B (zh) * 2021-11-25 2025-09-16 北京化工大学 一种环氧化溶聚丁苯橡胶及其制备方法和应用
CN116162296A (zh) * 2021-11-25 2023-05-26 北京化工大学 一种高性能绿色轮胎的胎面材料及其制备方法和应用

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3305515A (en) 1964-05-06 1967-02-21 Exxon Research Engineering Co Solvent for polybutadiene rubber
US4219627A (en) 1977-03-09 1980-08-26 The Firestone Tire & Rubber Company Process for the preparation of block copolymers
US5747598A (en) 1990-01-16 1998-05-05 Mobil Oil Corporation Epoxidized solid elastomeric copolymers
US5034470A (en) * 1990-09-04 1991-07-23 The Goodyear Tire & Rubber Company Process for the preparation of epoxidized synthetic cis-1,4-polyisoprene
US5399626A (en) 1991-04-29 1995-03-21 Shell Oil Company Viscous conjugated diene block copolymers
US5310819A (en) 1992-01-23 1994-05-10 The United States Of America As Represented By The Secretary Of The Navy Surface epoxidation of elastomers
EP0624601B1 (en) 1993-05-13 1997-08-06 Kao Corporation Process for producing raw rubber
CN1475510A (zh) * 1995-12-14 2004-02-18 大赛璐化学工业株式会社 环氧化有机类聚合物的制造方法
JP3722238B2 (ja) * 1995-12-14 2005-11-30 ダイセル化学工業株式会社 エポキシ化有機系重合体の製造方法
US5789512A (en) 1996-12-23 1998-08-04 Sartomer Company Method for the epoxidation of unsaturated polymers
US6242536B1 (en) 1997-12-11 2001-06-05 Bridgestone Corporation Process for preparation of block copolymers in mixed alkane/cycloalkane solvents
US6455655B1 (en) 2000-09-28 2002-09-24 The Goodyear Tire & Rubber Company Emulsion styrene-butadiene rubber
CN1113906C (zh) * 2000-10-29 2003-07-09 青岛化工学院 环氧化反式－1,4－聚异戊二烯的合成方法
CN1259346C (zh) 2000-11-13 2006-06-14 大赛璐化学工业株式会社 环氧化热塑性聚合物
US6903165B2 (en) * 2001-05-14 2005-06-07 Daicel Chemical Industries, Ltd. Process for producing epoxidized diene polymer
US6716925B2 (en) 2001-11-02 2004-04-06 The Goodyear Tire & Rubber Company Tire with a component made of a rubber composition comprised of a rubber having pendant hydroxyl groups and a rubber containing a nitrile moiety
US8519057B2 (en) * 2007-06-01 2013-08-27 Exxonmobil Chemical Patents Inc. Impact modification and functionalization of copolymers of olefins and dienes
JP5654409B2 (ja) * 2011-04-22 2015-01-14 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
TWI426090B (zh) * 2011-05-31 2014-02-11 Tsrc Corp 製造環氧化聚合物的方法
US9193806B2 (en) * 2012-01-23 2015-11-24 Sumitomo Rubber Industries, Ltd. Method for producing an epoxidized natural rubber, rubber composition for tires, and pneumatic tire
JP5603363B2 (ja) 2012-03-08 2014-10-08 住友ゴム工業株式会社 エポキシ化天然ゴムの製造方法、タイヤ用ゴム組成物及び空気入りタイヤ
CN103130990B (zh) * 2012-10-03 2015-02-18 大连理工大学 星形梳状聚乳酸及其制备方法
KR20150074001A (ko) * 2012-10-26 2015-07-01 다우 글로벌 테크놀로지스 엘엘씨 신규 에폭시드 화합물인 1,3-디옥시라닐시클로펜탄 유도체
CN103570848B (zh) * 2013-10-24 2016-01-20 沈阳化工大学 环氧化天然杜仲胶的合成方法
FR3017393B1 (fr) * 2014-02-07 2016-02-12 Michelin & Cie Bande de roulement pour pneumatique a base de polyisoprene epoxyde
CN103910816B (zh) * 2014-04-12 2016-06-15 青岛科技大学 一种改进的环氧化反式异戊橡胶制备方法

Also Published As

Publication number Publication date
WO2017176686A1 (en) 2017-10-12
EP3440116A4 (en) 2019-12-18
US20190127495A1 (en) 2019-05-02
EP3440116A1 (en) 2019-02-13
JP2022068188A (ja) 2022-05-09
KR20180123585A (ko) 2018-11-16
JP2019513866A (ja) 2019-05-30
US10836841B2 (en) 2020-11-17
MX2018012259A (es) 2019-02-07
CN108884185A (zh) 2018-11-23

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