JP2019510850A - 酵素を含む粒子 - Google Patents
酵素を含む粒子 Download PDFInfo
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- JP2019510850A JP2019510850A JP2018545902A JP2018545902A JP2019510850A JP 2019510850 A JP2019510850 A JP 2019510850A JP 2018545902 A JP2018545902 A JP 2018545902A JP 2018545902 A JP2018545902 A JP 2018545902A JP 2019510850 A JP2019510850 A JP 2019510850A
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- 235000015229 magnesium lactate Nutrition 0.000 description 1
- 229960004658 magnesium lactate Drugs 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229960002366 magnesium silicate Drugs 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 229940095060 magnesium tartrate Drugs 0.000 description 1
- ZSMRTTMJRRECKC-RJNTXXOISA-L magnesium;(2e,4e)-hexa-2,4-dienoate Chemical compound [Mg+2].C\C=C\C=C\C([O-])=O.C\C=C\C=C\C([O-])=O ZSMRTTMJRRECKC-RJNTXXOISA-L 0.000 description 1
- AIOKQVJVNPDJKA-ZZMNMWMASA-L magnesium;(2r)-2-[(1s)-1,2-dihydroxyethyl]-4-hydroxy-5-oxo-2h-furan-3-olate Chemical compound [Mg+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] AIOKQVJVNPDJKA-ZZMNMWMASA-L 0.000 description 1
- MUZDLCBWNVUYIR-ZVGUSBNCSA-L magnesium;(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Mg+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O MUZDLCBWNVUYIR-ZVGUSBNCSA-L 0.000 description 1
- QQFLQYOOQVLGTQ-UHFFFAOYSA-L magnesium;dihydrogen phosphate Chemical compound [Mg+2].OP(O)([O-])=O.OP(O)([O-])=O QQFLQYOOQVLGTQ-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- BDRTVPCFKSUHCJ-UHFFFAOYSA-N molecular hydrogen;potassium Chemical compound [K].[H][H] BDRTVPCFKSUHCJ-UHFFFAOYSA-N 0.000 description 1
- 229910000401 monomagnesium phosphate Inorganic materials 0.000 description 1
- 235000019785 monomagnesium phosphate Nutrition 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002773 nucleotide Substances 0.000 description 1
- 125000003729 nucleotide group Chemical group 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 235000019275 potassium ascorbate Nutrition 0.000 description 1
- 229940017794 potassium ascorbate Drugs 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 description 1
- 235000011085 potassium lactate Nutrition 0.000 description 1
- 239000001521 potassium lactate Substances 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 1
- 229940074439 potassium sodium tartrate Drugs 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 229940116317 potato starch Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229960002668 sodium chloride Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000011006 sodium potassium tartrate Nutrition 0.000 description 1
- 229940032158 sodium silicate Drugs 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229920001221 xylan Polymers 0.000 description 1
- 150000004823 xylans Chemical class 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Images
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
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- Detergent Compositions (AREA)
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Abstract
Description
複数の孔を有する分配器を提供する工程と、当該前駆材料を当該孔に通過させる工程と、当該分配器の下に移動コンベアを提供する工程と、
当該前駆材料を当該移動コンベア上に堆積させる工程と、当該前駆材料を冷却して複数の粒子を形成する工程と、を含み、当該前駆体材料は、水溶性ポリマーと、当該前駆体材料の約0.0001重量%〜約5重量%の酵素と、約0.1重量%〜約20重量%の香料とを含み、当該前駆材料は、約70℃未満の温度で提供される。
当該投入量の当該粒子を洗濯機に分注する工程と、を含み、当該粒子の各々が、約1mg〜約5グラムの質量を有する。
担体は、水溶性無機アルカリ金属塩、水溶性アルカリ土類金属塩、水溶性有機アルカリ金属塩、水溶性有機アルカリ土類金属塩、水溶性炭水化物、水溶性ケイ酸塩、水溶性尿素、及びこれらの任意の組み合わせからなる群から選択される物質であってよい、又はこれらを含んでよい。アルカリ金属塩は、例えば、リチウムの塩、ナトリウムの塩、及びカリウムの塩、並びにこれらの任意の組み合わせからなる群から選択されてよい。有用なアルカリ金属塩は、例えば、アルカリ金属フッ化物、アルカリ金属塩化物、アルカリ金属臭化物、アルカリ金属ヨウ化物、アルカリ金属硫酸塩、アルカリ金属重硫酸塩、アルカリ金属リン酸塩、アルカリ金属一水素リン酸塩、アルカリ金属二水素リン酸塩、アルカリ金属炭素塩、アルカリ金属一水素炭素塩、アルカリ金属酢酸塩、アルカリ金属クエン酸塩、アルカリ金属乳酸塩、アルカリ金属ピルビン酸塩、アルカリ金属ケイ酸塩、アルカリ金属アスコルビン酸塩、及びこれらの組み合わせからなる群から選択されてよい。
粒子中の酵素は、ケア酵素、ヌクレアーゼ、及びこれらの組み合わせから選択される、粒子の0.0001重量%〜約5重量%の酵素のレベルで提供され得る。粒子中の酵素は、ケア酵素、ヌクレアーゼ、及びこれらの組み合わせから選択される、粒子の0.001重量%〜約5重量%の酵素のレベルで提供され得る。本明細書に開示される粒子中の酵素は、アミラーゼ、リパーゼ、プロテアーゼ、セルラーゼ、キシログルカナーゼ、ペクタートリアーゼ、ペルオキシダーゼ、マンナナーゼ、クチナーゼ、P−ニトロベンジルエステラーゼ、ヌクレアーゼ、及びこれらの混合物からなる群から選択される酵素であってもよい。粒子中の酵素は、粒子の0.0001重量%〜約5重量%のレベルで提供され得る。粒子中の酵素は、粒子の0.001重量%〜約5重量%のレベルで提供され得る。これらの酵素は、洗濯工程で使用される場合、染み除去、布地再生、及び悪臭の改善のうちの1つ以上を提供することができる。酵素はヌクレアーゼであってもよく、それは、布地と関連する悪臭を低減することができる。
粒子は、染料を含んでもよい。染料としては、洗濯洗剤又は布地柔軟剤で一般的に使用される染料が挙げられ得る。布地処理組成物は、布地処理組成物の粒子の約0.1重量%未満、代替的に約0.001重量%〜約0.1重量%、代替的に約0.01重量%〜約0.02重量%、代替的にこれらの組み合わせ、及び前述のあらゆる範囲内の任意の百分率又は百分率の範囲の染料を含んでもよい。好適な染料の例としては、限定されないが、LIQUITINT PINK AM、AQUA AS CYAN 15及びVIOLET FL(Milliken Chemical)が挙げられる。使用者が異なる香りを有する粒子の区別を補助することを目的として、染料を用いることは実用的であり得る。
担体に加えて、粒子は、0.1重量%〜約20重量%の香料を更に含むことができる。香料は、非カプセル封入香料、カプセル封入香料、香料送達技術によってもたらされた香料、又は他の方法でもたらされた香料であってよい。香料は、概して、米国特許第7,186,680号の第10欄56行〜第25欄22行に記載されている。粒子は、非カプセル封入香料を含む場合もあり、香料マイクロカプセルなどの香料担体を本質的に含まない。粒子は、香料担体材料(及びそれに含まれる香料)を含み得る。香料担体材料の例は、米国特許第7,186,680号の第25欄23行〜第31欄7行に記載されている。香料担体材料の具体例としては、シクロデキストリン及びゼオライトを挙げることができる。
粒子を形成するための装置1を図1に示す。原材料は、ミキサー10に提供される。ミキサー10は、原材料の所望のレベルの混合及び/又は反応を可能にするのに十分な滞留時間にわたって、ミキサーに供給された大量の原材料を保持するのに十分な容量を有する。ミキサー10を出る材料は、前駆材料20である。前駆材料20は、溶融物であってよい。ミキサー10は、動的ミキサーであってもよい。動的ミキサーとは、ミキサーの内容物を混合するためにエネルギーが加えられるミキサーである。ミキサー10は、ミキサー10の内容物を混合する1つ以上のインペラを備えることができる。
A.複数の粒子を含む組成物であって、当該粒子が、
当該粒子の約40重量%〜約99重量%の担体と、
当該粒子の約0.0001重量%〜約5重量%の酵素と、
約0.1重量%〜約20重量%の香料と、を含み、
当該複数の粒子が、約1mg〜約5000gの平均粒子質量を有し、
当該複数の粒子が、約30mg未満の質量の標準偏差を有する、組成物。
B.当該担体が、水溶性ポリマーである、段落Aに記載の組成物。
C.当該粒子が、当該粒子の45重量%超〜約99重量%の当該担体を含む、段落A又はBに記載の組成物。
D.当該粒子の各々が、約5mg〜約200mgの質量を有する、段落A〜Cのいずれか1つに記載の組成物。
E.当該担体及び当該酵素が、互いと実質的に均一に混合される、段落A〜Dのいずれか1つに記載の組成物。
F.当該酵素が、酵素微粒子である、段落A〜Eのいずれか1つに記載の組成物。
G.当該粒子が、当該粒子の約0.5重量%〜3重量%未満の当該酵素を含む、段落A〜Fのいずれか1つに記載の組成物。
H.当該担体が、ポリエチレングリコールであり、当該ポリエチレングリコールが、約2000〜約13000の重量平均分子量を有する、段落A〜Gのいずれか1つに記載の組成物。
I.当該粒子が、約0.1重量%〜約10重量%のカプセル封入香料を含む、段落A〜Hのいずれか1つに記載の組成物。
J.当該担体が、スクロース、スクロースベントナイト、水溶性有機アルカリ金属塩、水溶性無機アルカリ土類金属塩、水溶性有機アルカリ土類金属塩、水溶性炭水化物、水溶性ケイ酸塩、水溶性尿素、デンプン、粘土、水不溶性ケイ酸塩、クエン酸カルボキシメチルセルロース、脂肪酸、脂肪族アルコール、水素化獣脂のグリセリルジエステル、グリセロール、ポリエチレングリコール、及びこれらの組み合わせからなる群から選択される、段落A〜Iのいずれか1つに記載の組成物。
K.当該複数の粒子が、約10mg未満の質量を有する粒子を実質的に含まない、段落A〜Jのいずれか1つに記載の組成物。
L.粒子を形成するためのプロセスであって、
前駆材料を提供する工程と、
複数の孔を有する分配器を提供する工程と、
当該前駆材料を当該孔に通過させる工程と、
当該分配器の下に移動コンベアを提供する工程と、
当該前駆材料を当該移動コンベア上に堆積させる工程と、
当該前駆材料を冷却して、複数の粒子を形成する工程と、を含み、
当該前駆体材料は、水溶性ポリマーと、当該前駆材料の約0.0001重量%〜約5重量%の酵素と、約0.1重量%〜約20重量%の香料と、を含み、
当該前駆材料が、約70℃未満の温度で提供される、プロセス。
M.当該前駆材料が、ポリエチレングリコールであり、当該ポリエチレングリコールが、約2000〜約13000の重量平均分子量を有する、段落Lに記載のプロセス。
N.洗濯物を処理するためのプロセスであって、
当該粒子の約40重量%〜約99重量%の担体と、
当該粒子の約0.0001重量%〜約5重量%の酵素と、
約0.1重量%〜約20重量%の香料と、を含む粒子を提供する工程と、
ある投入量の当該粒子を投入カップ内に配置する工程と、
当該投入量の当該粒子を洗濯機に分注する工程と、を含み、
当該粒子の各々が、約1mg〜約5グラムの質量を有する、プロセス。
O.当該担体が、水溶性ポリマーである、段落Nに記載のプロセス。
P.当該担体が、ポリエチレングリコールであり、当該ポリエチレングリコールが、約2000〜約13000の重量平均分子量を有する、段落N又はOに記載のプロセス。
Q.当該複数の粒子が、約5mg〜約200mgの平均粒子質量を有し、
当該複数の粒子が、約30mg未満の質量の標準偏差を有する、段落N〜Pのいずれか1つに記載のプロセス。
Claims (15)
- 複数の粒子(90)を含む組成物であって、前記粒子が、
前記粒子の40重量%〜99重量%の担体と、
前記粒子の0.0001重量%〜5重量%の酵素と、
0.1重量%〜20重量%の香料と、を含み、
前記複数の粒子が、1mg〜5000gの平均粒子質量を有し、
前記複数の粒子が、30mg未満の質量の標準偏差を有する、組成物。 - 前記担体が、水溶性ポリマーである、請求項1に記載の組成物。
- 前記粒子が、前記粒子の45重量%超〜99重量%の前記担体を含む、請求項1又は2に記載の組成物。
- 前記粒子の各々が、5mg〜200mgの質量を有する、請求項1〜3のいずれか一項に記載の組成物。
- 前記担体及び前記酵素が、互いと実質的に均一に混合される、請求項1〜4のいずれか一項に記載の組成物。
- 前記酵素が、酵素微粒子である、請求項1〜5のいずれか一項に記載の組成物。
- 前記粒子が、前記粒子の0.5重量%〜3重量%未満の前記酵素を含む、請求項1〜6のいずれか一項に記載の組成物。
- 前記担体が、ポリエチレングリコールであり、前記ポリエチレングリコールが、2000〜13000の重量平均分子量を有する、請求項1〜7のいずれか一項に記載の組成物。
- 前記粒子が、0.1重量%〜10重量%のカプセル封入香料を含む、請求項1〜8のいずれか一項に記載の組成物。
- 前記担体が、スクロース、スクロースベントナイト、水溶性有機アルカリ金属塩、水溶性無機アルカリ土類金属塩、水溶性有機アルカリ土類金属塩、水溶性炭水化物、水溶性ケイ酸塩、水溶性尿素、デンプン、粘土、水不溶性ケイ酸塩、クエン酸カルボキシメチルセルロース、脂肪酸、脂肪族アルコール、水素化獣脂のグリセリルジエステル、グリセロール、ポリエチレングリコール、及びこれらの組み合わせからなる群から選択される、請求項1〜7及び9のいずれか一項に記載の組成物。
- 前記複数の粒子が、10mg未満の質量を有する粒子を実質的に含まない、請求項1〜10のいずれか一項に記載の組成物。
- 請求項1〜11のいずれか一項に記載の粒子を形成するためのプロセスであって、
前駆材料(2)を提供する工程と、
複数の孔(60)を有する分配器(30)を提供する工程と、
前記前駆材料を前記孔に通過させる工程と、
前記分配器の下に移動コンベア(80)を提供する工程と、
前記前駆材料を前記移動コンベア上に堆積させる工程と、
前記前駆材料を冷却して、前記粒子を形成する工程と、を含み、
前記前駆体材料が、水溶性ポリマーと、前記前駆体材料の0.0001重量%〜5重量%の酵素と、0.1重量%〜20重量%の香料と、を含み、
前記前駆材料が、70℃未満の温度で提供される、プロセス。 - 前記前駆材料が、ポリエチレングリコールを含み、前記ポリエチレングリコールが、2000〜13000の重量平均分子量を有する、請求項12に記載のプロセス。
- 請求項1〜11のいずれか一項に記載の粒子を用いて洗濯物を処理するためのプロセスであって、
ある投入量の前記粒子を投入カップ内に配置する工程と、
前記投入量の前記粒子を洗濯機に分注する工程と、を含み、
前記粒子の各々が、1mg〜5グラムの質量を有する、プロセス。 - 前記担体が、ポリエチレングリコールであり、前記ポリエチレングリコールが、2000〜13000の重量平均分子量を有する、段落N又はOに記載のプロセス。
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JP2008050411A (ja) * | 2006-08-22 | 2008-03-06 | Diversey Ip Internatl Bv | 衣料用粒状洗浄剤組成物およびその製法、並びにその使用方法 |
JP2013509508A (ja) * | 2009-11-05 | 2013-03-14 | ザ プロクター アンド ギャンブル カンパニー | 洗濯物香り添加剤 |
JP2019513166A (ja) * | 2016-03-08 | 2019-05-23 | ザ プロクター アンド ギャンブル カンパニー | 酵素を含む粒子 |
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JP2020183542A (ja) | 2020-11-12 |
EP3426759A1 (en) | 2019-01-16 |
US10538720B2 (en) | 2020-01-21 |
WO2017156098A1 (en) | 2017-09-14 |
CN108603147A (zh) | 2018-09-28 |
US20170260481A1 (en) | 2017-09-14 |
JP6828048B2 (ja) | 2021-02-17 |
EP3426759B1 (en) | 2023-07-26 |
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