JP2019007003A5 - - Google Patents
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- Publication number
- JP2019007003A5 JP2019007003A5 JP2018120424A JP2018120424A JP2019007003A5 JP 2019007003 A5 JP2019007003 A5 JP 2019007003A5 JP 2018120424 A JP2018120424 A JP 2018120424A JP 2018120424 A JP2018120424 A JP 2018120424A JP 2019007003 A5 JP2019007003 A5 JP 2019007003A5
- Authority
- JP
- Japan
- Prior art keywords
- isobutene
- feed
- lewis acid
- hydrocarbyl
- hydrocarbyl groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 15
- 239000002879 Lewis base Substances 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 7
- 150000007527 lewis bases Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000011968 lewis acid catalyst Substances 0.000 claims description 4
- 229920001083 polybutene Polymers 0.000 claims description 4
- 239000002841 Lewis acid Substances 0.000 claims description 3
- 150000007517 lewis acids Chemical group 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000000746 allylic group Chemical group 0.000 claims description 2
- 125000001743 benzylic group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- -1 saturated C 4 hydrocarbons Chemical class 0.000 description 2
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/635,460 US10167352B1 (en) | 2017-06-28 | 2017-06-28 | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US15/635,460 | 2017-06-28 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019007003A JP2019007003A (ja) | 2019-01-17 |
| JP2019007003A5 true JP2019007003A5 (https=) | 2021-07-26 |
| JP7078953B2 JP7078953B2 (ja) | 2022-06-01 |
Family
ID=62909347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018120424A Active JP7078953B2 (ja) | 2017-06-28 | 2018-06-26 | 高反応性オレフィン機能性ポリマーを作製するための重合開始系および方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10167352B1 (https=) |
| EP (1) | EP3421509B1 (https=) |
| JP (1) | JP7078953B2 (https=) |
| KR (1) | KR102333045B1 (https=) |
| CN (1) | CN109134719B (https=) |
| CA (1) | CA3009702C (https=) |
| ES (1) | ES2897629T3 (https=) |
| SG (1) | SG10201805524WA (https=) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102203006B1 (ko) * | 2019-04-24 | 2021-01-13 | 대림산업 주식회사 | 고반응성 폴리부텐의 제조 방법 |
| US10829573B1 (en) * | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
| CN111171197B (zh) * | 2020-02-11 | 2022-08-02 | 北京石油化工学院 | 一种利用双官能团引发剂制备高活性聚异丁烯的方法及应用 |
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| EP0920909A1 (en) | 1994-03-31 | 1999-06-09 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
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| DE19734176A1 (de) | 1997-08-07 | 1999-02-11 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
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| RU2555400C2 (ru) * | 2010-02-17 | 2015-07-10 | Басф Се | Способ получения высокореакционноспособных гомополимеров или сополимеров изобутена |
| US8349977B2 (en) | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| CN102050901B (zh) * | 2010-11-23 | 2012-07-25 | 中国石油天然气股份有限公司吉林石化分公司 | 三氟化硼引发体系中分子量聚异丁烯的制备方法 |
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| JP6099648B2 (ja) | 2011-08-11 | 2017-03-22 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高反応性イソブテンホモポリマーまたはイソブテンコポリマーの製造法 |
| US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9156924B2 (en) | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9771554B2 (en) | 2013-07-16 | 2017-09-26 | Brown University | Device and method for engineering living tissues |
| US9631038B2 (en) * | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| KR101658545B1 (ko) * | 2014-08-22 | 2016-09-21 | 대림산업 주식회사 | 폴리부텐의 제조방법 |
| US9771442B2 (en) * | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
-
2017
- 2017-06-28 US US15/635,460 patent/US10167352B1/en active Active
-
2018
- 2018-06-26 EP EP18179951.1A patent/EP3421509B1/en active Active
- 2018-06-26 CA CA3009702A patent/CA3009702C/en active Active
- 2018-06-26 ES ES18179951T patent/ES2897629T3/es active Active
- 2018-06-26 JP JP2018120424A patent/JP7078953B2/ja active Active
- 2018-06-27 KR KR1020180074167A patent/KR102333045B1/ko active Active
- 2018-06-27 SG SG10201805524WA patent/SG10201805524WA/en unknown
- 2018-06-28 CN CN201810687672.2A patent/CN109134719B/zh active Active
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