CA3009702C - Polymerization initiating system and method to produce highly reactive olefin functional polymers - Google Patents

Polymerization initiating system and method to produce highly reactive olefin functional polymers Download PDF

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Publication number
CA3009702C
CA3009702C CA3009702A CA3009702A CA3009702C CA 3009702 C CA3009702 C CA 3009702C CA 3009702 A CA3009702 A CA 3009702A CA 3009702 A CA3009702 A CA 3009702A CA 3009702 C CA3009702 C CA 3009702C
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Prior art keywords
feedstock
isobutene
group
amount
lewis acid
Prior art date
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CA3009702A
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English (en)
French (fr)
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CA3009702A1 (en
Inventor
Philip Dimitrov
Richard J. Severt
Thomas Skourlis
Jeremy WEBER
Jacob Emert
Rudolf Faust
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Infineum International Ltd
University of Massachusetts Amherst
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Infineum International Ltd
University of Massachusetts Amherst
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Publication of CA3009702A1 publication Critical patent/CA3009702A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
CA3009702A 2017-06-28 2018-06-26 Polymerization initiating system and method to produce highly reactive olefin functional polymers Active CA3009702C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/635,460 US10167352B1 (en) 2017-06-28 2017-06-28 Polymerization initiating system and method to produce highly reactive olefin functional polymers
US15/635,460 2017-06-28

Publications (2)

Publication Number Publication Date
CA3009702A1 CA3009702A1 (en) 2018-12-28
CA3009702C true CA3009702C (en) 2024-01-09

Family

ID=62909347

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3009702A Active CA3009702C (en) 2017-06-28 2018-06-26 Polymerization initiating system and method to produce highly reactive olefin functional polymers

Country Status (8)

Country Link
US (1) US10167352B1 (https=)
EP (1) EP3421509B1 (https=)
JP (1) JP7078953B2 (https=)
KR (1) KR102333045B1 (https=)
CN (1) CN109134719B (https=)
CA (1) CA3009702C (https=)
ES (1) ES2897629T3 (https=)
SG (1) SG10201805524WA (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102203006B1 (ko) * 2019-04-24 2021-01-13 대림산업 주식회사 고반응성 폴리부텐의 제조 방법
US10829573B1 (en) * 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
CN111171197B (zh) * 2020-02-11 2022-08-02 北京石油化工学院 一种利用双官能团引发剂制备高活性聚异丁烯的方法及应用

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Also Published As

Publication number Publication date
US20190002607A1 (en) 2019-01-03
KR20190001943A (ko) 2019-01-07
CA3009702A1 (en) 2018-12-28
EP3421509A1 (en) 2019-01-02
SG10201805524WA (en) 2019-01-30
JP2019007003A (ja) 2019-01-17
CN109134719A (zh) 2019-01-04
US10167352B1 (en) 2019-01-01
JP7078953B2 (ja) 2022-06-01
EP3421509B1 (en) 2021-09-22
ES2897629T3 (es) 2022-03-02
KR102333045B1 (ko) 2021-11-29
CN109134719B (zh) 2020-11-24

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