JP2018527304A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2018527304A5 JP2018527304A5 JP2017567370A JP2017567370A JP2018527304A5 JP 2018527304 A5 JP2018527304 A5 JP 2018527304A5 JP 2017567370 A JP2017567370 A JP 2017567370A JP 2017567370 A JP2017567370 A JP 2017567370A JP 2018527304 A5 JP2018527304 A5 JP 2018527304A5
- Authority
- JP
- Japan
- Prior art keywords
- silica catalyst
- catalyst
- mfi
- butene
- mesoporous silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 114
- 239000003054 catalyst Substances 0.000 claims description 81
- 239000000377 silicon dioxide Substances 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 28
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 14
- 239000003607 modifier Substances 0.000 claims description 12
- 238000005649 metathesis reaction Methods 0.000 claims description 11
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 10
- 229910044991 metal oxide Inorganic materials 0.000 claims description 10
- 150000004706 metal oxides Chemical class 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 238000005336 cracking Methods 0.000 claims description 8
- 230000009977 dual effect Effects 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052680 mordenite Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical group O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- LMHUKLLZJMVJQZ-UHFFFAOYSA-N but-1-ene;prop-1-ene Chemical group CC=C.CCC=C LMHUKLLZJMVJQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000005686 cross metathesis reaction Methods 0.000 claims description 2
- 238000006317 isomerization reaction Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 2
- -1 C 5 olefins Chemical class 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562188178P | 2015-07-02 | 2015-07-02 | |
| US62/188,178 | 2015-07-02 | ||
| PCT/US2016/038967 WO2017003812A1 (en) | 2015-07-02 | 2016-06-23 | Dual catalyst system for propylene production |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018527304A JP2018527304A (ja) | 2018-09-20 |
| JP2018527304A5 true JP2018527304A5 (enExample) | 2018-11-29 |
| JP6671399B2 JP6671399B2 (ja) | 2020-03-25 |
Family
ID=56345262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017567370A Active JP6671399B2 (ja) | 2015-07-02 | 2016-06-23 | プロピレン生成のための二元触媒系 |
Country Status (6)
| Country | Link |
|---|---|
| US (4) | US9884794B2 (enExample) |
| EP (2) | EP3317239B1 (enExample) |
| JP (1) | JP6671399B2 (enExample) |
| KR (3) | KR102178406B1 (enExample) |
| CN (2) | CN108137438A (enExample) |
| WO (1) | WO2017003812A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108137438A (zh) | 2015-07-02 | 2018-06-08 | 沙特阿拉伯石油公司 | 用于丙烯生产的双重催化剂体系 |
| EP3317237B1 (en) | 2015-07-02 | 2024-09-25 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317014B1 (en) | 2015-07-02 | 2022-03-02 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
| WO2017003817A1 (en) * | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| US10934231B2 (en) * | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
| US10329225B2 (en) * | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
| US10550048B2 (en) | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
| FR3068967B1 (fr) * | 2017-07-13 | 2019-06-28 | IFP Energies Nouvelles | Methode et procede pour convertir l'ethylene present dans l'effluent de tete d'un fcc de maniere a augmenter la production de propylene |
| US11369950B2 (en) * | 2018-02-21 | 2022-06-28 | Saudi Arabian Oil Company | Multi-functional composite catalyst materials and methods of synthesizing the catalyst materials |
| US11242299B2 (en) | 2018-10-10 | 2022-02-08 | Saudi Arabian Oil Company | Catalyst systems that include metal oxide co-catalysts for the production of propylene |
| US10961171B2 (en) | 2018-10-10 | 2021-03-30 | Saudi Arabian Oil Company | Catalysts systems that include metal co-catalysts for the production of propylene |
| CN111085207A (zh) * | 2018-10-24 | 2020-05-01 | 中国石油化工股份有限公司 | 载体为球形三介孔复合材料的非贵金属系低碳烷烃脱氢催化剂及其制法和应用 |
| US10975004B2 (en) | 2019-01-03 | 2021-04-13 | Saudi Arabian Oil Company | Integrated process for production of ethylene from propylene |
| CN113646081B (zh) * | 2019-03-18 | 2024-01-09 | 埃克森美孚科技工程公司 | 中孔催化剂化合物及其用途 |
| CN112387302B (zh) * | 2019-08-13 | 2023-05-30 | 中国石油化工股份有限公司 | 催化裂化助剂及其制备方法和应用及烃油催化裂化的方法 |
| US11185850B2 (en) * | 2019-12-02 | 2021-11-30 | Saudi Arabian Oil Company | Dual functional composite catalyst for olefin metathesis and cracking |
| US11311869B2 (en) | 2019-12-03 | 2022-04-26 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11517892B2 (en) | 2019-12-03 | 2022-12-06 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
| CN113304786B (zh) * | 2020-02-27 | 2023-05-30 | 中国石油化工股份有限公司 | 含有二氯二甲基硅烷改性全硅介孔材料的催化裂化助剂及其制备方法和应用 |
| US11572516B2 (en) | 2020-03-26 | 2023-02-07 | Saudi Arabian Oil Company | Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins |
| WO2021216576A1 (en) | 2020-04-22 | 2021-10-28 | Lyondell Chemical Technology, L.P. | On-purpose propylene production from butenes |
| CN116075493A (zh) | 2020-09-15 | 2023-05-05 | 利安德化学技术有限公司 | 用于将萃余液丁烯转化为丙烯的方法 |
| US11679378B2 (en) | 2021-02-25 | 2023-06-20 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11845705B2 (en) | 2021-08-17 | 2023-12-19 | Saudi Arabian Oil Company | Processes integrating hydrocarbon cracking with metathesis for producing propene |
| KR20230145993A (ko) * | 2022-04-07 | 2023-10-18 | 피티티 글로벌 케미칼 피씨엘 | 경질 올레핀을 제조하기 위한 촉매 및 상기 촉매를 사용함으로써 경질 올레핀을 제조하는 방법 |
| USD1040950S1 (en) * | 2022-11-07 | 2024-09-03 | Wolf Fitness, LLC | Barbell jack |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442821A (en) | 1966-09-29 | 1969-05-06 | Universal Oil Prod Co | Manufacture of spheroidal silica-alumina particles |
| US3546313A (en) | 1967-04-03 | 1970-12-08 | Phillips Petroleum Co | Conversion of olefins |
| NL135562C (enExample) | 1967-04-03 | |||
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| GB1489300A (en) | 1974-08-26 | 1977-10-19 | Agency Ind Science Techn | Process for the selective disproportionation reaction of olefins |
| US4071471A (en) | 1974-12-23 | 1978-01-31 | Phillips Petroleum Company | Catalysts for conversion of olefins |
| DE3775059D1 (de) | 1983-03-10 | 1992-01-16 | Dow Chemical Co | Verfahren zur disproportionierung von alkenen. |
| US4609769A (en) * | 1984-02-15 | 1986-09-02 | Phillips Petroleum Company | Olefin conversion |
| US4575575A (en) | 1984-04-05 | 1986-03-11 | Phillips Petroleum Company | Catalysts and process for olefin conversion |
| US5191131A (en) | 1988-12-05 | 1993-03-02 | Research Association For Utilization Of Light Oil | Process for preparation of lower aliphatic hydrocarbons |
| US5026936A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
| US5026935A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of ethylene from higher hydrocarbons |
| FR2733986B1 (fr) | 1995-05-11 | 1997-06-13 | Inst Francais Du Petrole | Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene |
| DE19746040A1 (de) | 1997-10-17 | 1999-04-22 | Basf Ag | Verfahren zur Herstellung von Propen |
| EP0921181A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of propylene |
| EP0920911A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of catalysts for olefin conversion |
| US6586649B1 (en) | 1998-09-04 | 2003-07-01 | Sasol Technology (Proprietary) Limited | Production of propylene |
| KR20020010149A (ko) | 1999-05-20 | 2002-02-02 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 다공성 무기 산화물의 금속 함유 거대 구조체, 그의제조방법 및 용도 |
| DE19932060A1 (de) | 1999-07-12 | 2001-01-18 | Basf Ag | Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen |
| DE10013253A1 (de) | 2000-03-17 | 2001-09-20 | Basf Ag | Verfahren zur flexiblen Herstellung von Propen und Hexen |
| US7566799B2 (en) * | 2001-10-01 | 2009-07-28 | Basf Aktiengesellschaft | Process for the preparation of alkylaryl compounds and sulfonates thereof |
| US6777582B2 (en) | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
| CN100402148C (zh) | 2002-08-16 | 2008-07-16 | Sasol技术股份有限公司 | 复分解催化剂及方法 |
| DE10319439A1 (de) | 2003-04-30 | 2004-11-18 | Basf Ag | Aktivierte Metathesekatalysatoren |
| US7214841B2 (en) | 2003-07-15 | 2007-05-08 | Abb Lummus Global Inc. | Processing C4 olefin streams for the maximum production of propylene |
| ITMI20040855A1 (it) | 2004-04-29 | 2004-07-29 | Polimeri Europa Spa | Catalizzatore di renio supportato su allimuna modificata e suo impiego nella reazione di metatesi delle olefine |
| TWI371440B (en) | 2004-07-16 | 2012-09-01 | Asahi Kasei Chemicals Corp | Method of producing ethylene and propylene |
| DE102005009596A1 (de) | 2005-02-28 | 2006-08-31 | Basf Ag | Verfahren zur Metathese umfassend die Reinigung der Ausgangsstoffe |
| RU2367644C2 (ru) | 2005-03-03 | 2009-09-20 | Мицуи Кемикалз, Инк. | Способ получения олефинов |
| US7692057B2 (en) | 2005-08-15 | 2010-04-06 | China Petroleum & Chemical Corporation | Process for producing lower olefins by using multiple reaction zones |
| WO2007117221A1 (en) | 2006-04-11 | 2007-10-18 | Agency For Science, Technology And Research | Catalysts for ring closing metathesis |
| WO2007141277A1 (de) | 2006-06-06 | 2007-12-13 | Basf Se | Herstellung reaktiver, im wesentlichen halogenfreier polyisobutene aus isobuten-armen c4-kohlenwasserstoff-gemischen |
| WO2008071640A2 (en) | 2006-12-12 | 2008-06-19 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst |
| MY146409A (en) * | 2007-04-27 | 2012-08-15 | Mitsui Chemicals Inc | Process for producing olefins |
| CN101531558B (zh) | 2008-03-13 | 2013-04-24 | 中国石油化工股份有限公司 | 一种制取丙烯和芳烃的催化转化方法 |
| US20090240010A1 (en) | 2008-03-20 | 2009-09-24 | Mcdaniel Max P | Alumina-silica activator-supports for metallocene catalyst compositions |
| CA2733890C (en) * | 2008-08-12 | 2013-10-01 | Lummus Technology Inc. | Integrated propylene production |
| CN102131752A (zh) | 2008-08-28 | 2011-07-20 | 三井化学株式会社 | 烯烃制造方法 |
| EP2331488B1 (en) | 2008-09-04 | 2025-02-26 | Lummus Technology Inc. | Olefin isomerization and metathesis catalyst |
| US8119849B2 (en) | 2008-12-29 | 2012-02-21 | Lyondell Chemical Technology, L.P. | Propylene production |
| US8586813B2 (en) | 2009-07-21 | 2013-11-19 | Lummus Technology Inc. | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
| US8324440B2 (en) | 2010-02-05 | 2012-12-04 | Uop Llc | Support properties of silica supported catalysts and their use in olefin metathesis |
| US8895795B2 (en) | 2010-02-05 | 2014-11-25 | Uop Llc | Acid washed silica supported catalysts and their use in olefin metathesis |
| CA2791219C (en) | 2010-03-15 | 2015-11-24 | Total Research & Technology Feluy | Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis |
| US8722950B2 (en) | 2010-04-26 | 2014-05-13 | Saudi Basic Industries Corporation | Process for producing propylene and aromatics from butenes by metathesis and aromatization |
| US9079159B2 (en) | 2011-04-14 | 2015-07-14 | Uop Llc | Olefin metathesis process using a treated tungsten oxide catalyst |
| US20120289617A1 (en) | 2011-05-10 | 2012-11-15 | Saudi Arabian Oil Company | Hybrid Catalyst for Olefin Metathesis |
| KR101279691B1 (ko) * | 2011-11-29 | 2013-06-28 | 롯데케미칼 주식회사 | 미세 및 중형기공성 ｚｓｍ-5 촉매, 이의 제조방법 및 그 촉매를 이용한 탄화수소 혼합물의 촉매 접촉분해를 통한 경질 올레핀 제조방법 |
| KR101262549B1 (ko) * | 2011-09-29 | 2013-05-09 | 롯데케미칼 주식회사 | 중형기공성 ｚｓｍ-5 촉매 제조방법 및 그 촉매를 이용한 경질 올레핀 제조방법 |
| US20130085311A1 (en) | 2011-09-29 | 2013-04-04 | Honam Petrochemical Corporation | Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst |
| US8575406B2 (en) | 2011-12-22 | 2013-11-05 | Celanese International Corporation | Catalysts having promoter metals and process for producing ethanol |
| EP2862629A1 (en) | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyst and process for olefin metathesis reaction |
| CN105764875B (zh) | 2013-11-20 | 2018-05-22 | 鲁姆斯科技公司 | 烯烃转化方法 |
| CN104370676B (zh) | 2014-11-11 | 2016-06-08 | 中国石油天然气集团公司 | 一种以碳四烯烃为原料生产丙烯副产乙烯的方法 |
| WO2017003817A1 (en) | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| CN108137438A (zh) | 2015-07-02 | 2018-06-08 | 沙特阿拉伯石油公司 | 用于丙烯生产的双重催化剂体系 |
| EP3317237B1 (en) | 2015-07-02 | 2024-09-25 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317014B1 (en) | 2015-07-02 | 2022-03-02 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
-
2016
- 2016-06-23 CN CN201680039097.4A patent/CN108137438A/zh active Pending
- 2016-06-23 CN CN201811179717.1A patent/CN109364983A/zh active Pending
- 2016-06-23 EP EP16734842.4A patent/EP3317239B1/en active Active
- 2016-06-23 KR KR1020197005618A patent/KR102178406B1/ko active Active
- 2016-06-23 EP EP19163840.2A patent/EP3536679B1/en active Active
- 2016-06-23 US US15/190,981 patent/US9884794B2/en active Active
- 2016-06-23 KR KR1020187003238A patent/KR101921891B1/ko active Active
- 2016-06-23 KR KR1020187033411A patent/KR101955183B1/ko active Active
- 2016-06-23 JP JP2017567370A patent/JP6671399B2/ja active Active
- 2016-06-23 WO PCT/US2016/038967 patent/WO2017003812A1/en not_active Ceased
-
2017
- 2017-01-04 US US15/398,196 patent/US10052618B2/en active Active
-
2018
- 2018-01-02 US US15/859,794 patent/US10532347B2/en active Active
- 2018-07-19 US US16/039,983 patent/US10583423B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2018527304A5 (enExample) | ||
| JP6671399B2 (ja) | プロピレン生成のための二元触媒系 | |
| JP2018521053A5 (enExample) | ||
| JP2020505370A5 (enExample) | ||
| Rahimi et al. | Catalytic cracking of hydrocarbons over modified ZSM-5 zeolites to produce light olefins: A review | |
| Ghorbanpour et al. | Epitaxial growth of ZSM-5@ Silicalite-1: A core–shell zeolite designed with passivated surface acidity | |
| CN110267932B (zh) | 用于自复分解连同受控异构化和裂化的多级催化剂系统 | |
| WO2011097127A3 (en) | Acid washed silica supported catalysts and their use in olefin metathesis | |
| JP2018521053A (ja) | プロピレンを生成するためのシステム及び方法 | |
| WO2012039838A3 (en) | System and method for the production of liquid fuels | |
| MY148877A (en) | Integrated propylene production | |
| MY151943A (en) | Process for producing alkenes from oxygenates by using supported heteropolyacid catalysts | |
| SG10201407378RA (en) | Process for the preparation of a lower olefin product | |
| JP2020505371A (ja) | プロピレン製造のための２元触媒プロセスおよび系 | |
| EA201892824A1 (ru) | Кобальтосодержащая каталитическая композиция | |
| Zhai et al. | Construction of HZSM-5 with a mesoporous structure and suitable acidity: Application in catalytic syngas conversion to light aromatics over Na–FeMn/HZSM-5 zeolite | |
| MY190048A (en) | Method and device for manufacturing propene and c4 hydrocarbon | |
| EA201990391A1 (ru) | Твердые фосфорнокислые катализаторы | |
| WO2014123243A1 (ja) | オレフィン低重合方法およびそれに用いる触媒 | |
| WO2012092014A3 (en) | Olefin metathesis process and catalyst containing tungsten fluorine bonds | |
| JP2009544647A5 (enExample) | ||
| MX2023004844A (es) | Metodo para producir una fraccion de producto de craqueo que comprende propileno, olefinas de cuatro carbonos (c4) o ambos. | |
| MY185577A (en) | Catalysts and methods for producing propylene from ethylene and butene | |
| CN105272800B (zh) | 丁烯-2异构化为丁烯-1的方法 | |
| CN105524650B (zh) | 石脑油催化裂解产丙烯的方法 |