JP2018521053A5 - - Google Patents
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- Publication number
- JP2018521053A5 JP2018521053A5 JP2017567371A JP2017567371A JP2018521053A5 JP 2018521053 A5 JP2018521053 A5 JP 2018521053A5 JP 2017567371 A JP2017567371 A JP 2017567371A JP 2017567371 A JP2017567371 A JP 2017567371A JP 2018521053 A5 JP2018521053 A5 JP 2018521053A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction product
- metathesis
- catalyst
- stream
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 96
- 239000003054 catalyst Substances 0.000 claims description 85
- 238000005649 metathesis reaction Methods 0.000 claims description 73
- 239000007795 chemical reaction product Substances 0.000 claims description 69
- 238000000034 method Methods 0.000 claims description 65
- 239000000377 silicon dioxide Substances 0.000 claims description 48
- 238000000354 decomposition reaction Methods 0.000 claims description 39
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 38
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 38
- 239000011148 porous material Substances 0.000 claims description 26
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 16
- 150000004706 metal oxides Chemical class 0.000 claims description 15
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 229910044991 metal oxide Inorganic materials 0.000 claims description 13
- 238000005336 cracking Methods 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 11
- 229910052680 mordenite Inorganic materials 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 4
- 229920000428 triblock copolymer Polymers 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052702 rhenium Inorganic materials 0.000 claims description 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000463 Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) Polymers 0.000 claims description 2
- 229910052755 nonmetal Inorganic materials 0.000 claims description 2
- 239000003607 modifier Substances 0.000 description 4
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 4
- 229910001930 tungsten oxide Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical group O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562188052P | 2015-07-02 | 2015-07-02 | |
| US62/188,052 | 2015-07-02 | ||
| PCT/US2016/039012 WO2017003817A1 (en) | 2015-07-02 | 2016-06-23 | Systems and methods for producing propylene |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018521053A JP2018521053A (ja) | 2018-08-02 |
| JP2018521053A5 true JP2018521053A5 (enExample) | 2019-07-25 |
| JP6704941B2 JP6704941B2 (ja) | 2020-06-03 |
Family
ID=56409168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017567371A Active JP6704941B2 (ja) | 2015-07-02 | 2016-06-23 | プロピレンを生成するためのシステム及び方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10059645B2 (enExample) |
| EP (1) | EP3317236B1 (enExample) |
| JP (1) | JP6704941B2 (enExample) |
| KR (1) | KR102063095B1 (enExample) |
| CN (1) | CN107709276B (enExample) |
| SA (1) | SA517390635B1 (enExample) |
| SG (1) | SG10201913486WA (enExample) |
| WO (1) | WO2017003817A1 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108137438A (zh) | 2015-07-02 | 2018-06-08 | 沙特阿拉伯石油公司 | 用于丙烯生产的双重催化剂体系 |
| WO2017003817A1 (en) | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317237B1 (en) | 2015-07-02 | 2024-09-25 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| US10550048B2 (en) | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
| US10329225B2 (en) | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
| US10934231B2 (en) * | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
| US20180212791A1 (en) * | 2017-01-25 | 2018-07-26 | Sears Brands, L.L.C. | Contextual application interactions with connected devices |
| US11369950B2 (en) * | 2018-02-21 | 2022-06-28 | Saudi Arabian Oil Company | Multi-functional composite catalyst materials and methods of synthesizing the catalyst materials |
| US10961171B2 (en) | 2018-10-10 | 2021-03-30 | Saudi Arabian Oil Company | Catalysts systems that include metal co-catalysts for the production of propylene |
| US11242299B2 (en) | 2018-10-10 | 2022-02-08 | Saudi Arabian Oil Company | Catalyst systems that include metal oxide co-catalysts for the production of propylene |
| US10975004B2 (en) | 2019-01-03 | 2021-04-13 | Saudi Arabian Oil Company | Integrated process for production of ethylene from propylene |
| US11117108B2 (en) * | 2019-09-13 | 2021-09-14 | Kellogg Brown & Root Llc | Use of a fuel oil wash to remove catalyst from a fluidized-bed propane dehydrogenation reactor effluent |
| US11185850B2 (en) * | 2019-12-02 | 2021-11-30 | Saudi Arabian Oil Company | Dual functional composite catalyst for olefin metathesis and cracking |
| US11517892B2 (en) | 2019-12-03 | 2022-12-06 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11311869B2 (en) | 2019-12-03 | 2022-04-26 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
| US11236031B2 (en) | 2020-02-12 | 2022-02-01 | Saudi Arabian Oil Company | Integrated process for the production of isononanol and gasoline and diesel blending components |
| US11572516B2 (en) | 2020-03-26 | 2023-02-07 | Saudi Arabian Oil Company | Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins |
| US11679378B2 (en) | 2021-02-25 | 2023-06-20 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11542447B2 (en) | 2021-03-09 | 2023-01-03 | Saudi Arabian Oil Company | Integrated process for the production of isononanol and stable / lubricating gasoline and diesel blending components |
| US11845705B2 (en) | 2021-08-17 | 2023-12-19 | Saudi Arabian Oil Company | Processes integrating hydrocarbon cracking with metathesis for producing propene |
| EP4626852A1 (en) * | 2022-11-29 | 2025-10-08 | SABIC Global Technologies B.V. | Multi-reactor systems and methods for propylene production |
Family Cites Families (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3546313A (en) | 1967-04-03 | 1970-12-08 | Phillips Petroleum Co | Conversion of olefins |
| NL135562C (enExample) | 1967-04-03 | |||
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| GB1489300A (en) | 1974-08-26 | 1977-10-19 | Agency Ind Science Techn | Process for the selective disproportionation reaction of olefins |
| US4071471A (en) | 1974-12-23 | 1978-01-31 | Phillips Petroleum Company | Catalysts for conversion of olefins |
| DE3775059D1 (de) | 1983-03-10 | 1992-01-16 | Dow Chemical Co | Verfahren zur disproportionierung von alkenen. |
| US4609769A (en) | 1984-02-15 | 1986-09-02 | Phillips Petroleum Company | Olefin conversion |
| US4575575A (en) | 1984-04-05 | 1986-03-11 | Phillips Petroleum Company | Catalysts and process for olefin conversion |
| US5026936A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
| US5026935A (en) * | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of ethylene from higher hydrocarbons |
| FR2733986B1 (fr) * | 1995-05-11 | 1997-06-13 | Inst Francais Du Petrole | Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene |
| DE19746040A1 (de) | 1997-10-17 | 1999-04-22 | Basf Ag | Verfahren zur Herstellung von Propen |
| EP0921181A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of propylene |
| US6586649B1 (en) | 1998-09-04 | 2003-07-01 | Sasol Technology (Proprietary) Limited | Production of propylene |
| KR20020010149A (ko) * | 1999-05-20 | 2002-02-02 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 다공성 무기 산화물의 금속 함유 거대 구조체, 그의제조방법 및 용도 |
| DE19932060A1 (de) | 1999-07-12 | 2001-01-18 | Basf Ag | Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen |
| DE10013253A1 (de) | 2000-03-17 | 2001-09-20 | Basf Ag | Verfahren zur flexiblen Herstellung von Propen und Hexen |
| US20050124839A1 (en) * | 2001-06-13 | 2005-06-09 | Gartside Robert J. | Catalyst and process for the metathesis of ethylene and butene to produce propylene |
| US7566799B2 (en) | 2001-10-01 | 2009-07-28 | Basf Aktiengesellschaft | Process for the preparation of alkylaryl compounds and sulfonates thereof |
| US6777582B2 (en) * | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
| CN100402148C (zh) | 2002-08-16 | 2008-07-16 | Sasol技术股份有限公司 | 复分解催化剂及方法 |
| DE10319439A1 (de) | 2003-04-30 | 2004-11-18 | Basf Ag | Aktivierte Metathesekatalysatoren |
| US7214841B2 (en) * | 2003-07-15 | 2007-05-08 | Abb Lummus Global Inc. | Processing C4 olefin streams for the maximum production of propylene |
| ITMI20040855A1 (it) | 2004-04-29 | 2004-07-29 | Polimeri Europa Spa | Catalizzatore di renio supportato su allimuna modificata e suo impiego nella reazione di metatesi delle olefine |
| TWI371440B (en) | 2004-07-16 | 2012-09-01 | Asahi Kasei Chemicals Corp | Method of producing ethylene and propylene |
| DE102005009596A1 (de) | 2005-02-28 | 2006-08-31 | Basf Ag | Verfahren zur Metathese umfassend die Reinigung der Ausgangsstoffe |
| US7692057B2 (en) * | 2005-08-15 | 2010-04-06 | China Petroleum & Chemical Corporation | Process for producing lower olefins by using multiple reaction zones |
| WO2007117221A1 (en) | 2006-04-11 | 2007-10-18 | Agency For Science, Technology And Research | Catalysts for ring closing metathesis |
| WO2007141277A1 (de) | 2006-06-06 | 2007-12-13 | Basf Se | Herstellung reaktiver, im wesentlichen halogenfreier polyisobutene aus isobuten-armen c4-kohlenwasserstoff-gemischen |
| MY146409A (en) * | 2007-04-27 | 2012-08-15 | Mitsui Chemicals Inc | Process for producing olefins |
| CN101531558B (zh) | 2008-03-13 | 2013-04-24 | 中国石油化工股份有限公司 | 一种制取丙烯和芳烃的催化转化方法 |
| US20090240010A1 (en) | 2008-03-20 | 2009-09-24 | Mcdaniel Max P | Alumina-silica activator-supports for metallocene catalyst compositions |
| JP2010013366A (ja) * | 2008-07-01 | 2010-01-21 | Sumitomo Chemical Co Ltd | プロピレンの製造方法 |
| CA2733890C (en) * | 2008-08-12 | 2013-10-01 | Lummus Technology Inc. | Integrated propylene production |
| CN102131752A (zh) | 2008-08-28 | 2011-07-20 | 三井化学株式会社 | 烯烃制造方法 |
| EP2331488B1 (en) | 2008-09-04 | 2025-02-26 | Lummus Technology Inc. | Olefin isomerization and metathesis catalyst |
| US8119849B2 (en) | 2008-12-29 | 2012-02-21 | Lyondell Chemical Technology, L.P. | Propylene production |
| US8586813B2 (en) | 2009-07-21 | 2013-11-19 | Lummus Technology Inc. | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
| US8324440B2 (en) | 2010-02-05 | 2012-12-04 | Uop Llc | Support properties of silica supported catalysts and their use in olefin metathesis |
| US8895795B2 (en) | 2010-02-05 | 2014-11-25 | Uop Llc | Acid washed silica supported catalysts and their use in olefin metathesis |
| US8722950B2 (en) | 2010-04-26 | 2014-05-13 | Saudi Basic Industries Corporation | Process for producing propylene and aromatics from butenes by metathesis and aromatization |
| US9079159B2 (en) | 2011-04-14 | 2015-07-14 | Uop Llc | Olefin metathesis process using a treated tungsten oxide catalyst |
| US20120289617A1 (en) | 2011-05-10 | 2012-11-15 | Saudi Arabian Oil Company | Hybrid Catalyst for Olefin Metathesis |
| KR101262549B1 (ko) * | 2011-09-29 | 2013-05-09 | 롯데케미칼 주식회사 | 중형기공성 ｚｓｍ-5 촉매 제조방법 및 그 촉매를 이용한 경질 올레핀 제조방법 |
| KR101279691B1 (ko) * | 2011-11-29 | 2013-06-28 | 롯데케미칼 주식회사 | 미세 및 중형기공성 ｚｓｍ-5 촉매, 이의 제조방법 및 그 촉매를 이용한 탄화수소 혼합물의 촉매 접촉분해를 통한 경질 올레핀 제조방법 |
| US20130085311A1 (en) * | 2011-09-29 | 2013-04-04 | Honam Petrochemical Corporation | Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst |
| EP2862629A1 (en) | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyst and process for olefin metathesis reaction |
| CN105764875B (zh) | 2013-11-20 | 2018-05-22 | 鲁姆斯科技公司 | 烯烃转化方法 |
| CN104370676B (zh) | 2014-11-11 | 2016-06-08 | 中国石油天然气集团公司 | 一种以碳四烯烃为原料生产丙烯副产乙烯的方法 |
| CN108137438A (zh) | 2015-07-02 | 2018-06-08 | 沙特阿拉伯石油公司 | 用于丙烯生产的双重催化剂体系 |
| WO2017003817A1 (en) | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317237B1 (en) * | 2015-07-02 | 2024-09-25 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317014B1 (en) * | 2015-07-02 | 2022-03-02 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
-
2016
- 2016-06-23 WO PCT/US2016/039012 patent/WO2017003817A1/en not_active Ceased
- 2016-06-23 JP JP2017567371A patent/JP6704941B2/ja active Active
- 2016-06-23 US US15/190,964 patent/US10059645B2/en active Active
- 2016-06-23 KR KR1020187003251A patent/KR102063095B1/ko active Active
- 2016-06-23 SG SG10201913486WA patent/SG10201913486WA/en unknown
- 2016-06-23 EP EP16738271.2A patent/EP3317236B1/en active Active
- 2016-06-23 CN CN201680038822.6A patent/CN107709276B/zh active Active
-
2017
- 2017-12-28 SA SA517390635A patent/SA517390635B1/ar unknown
-
2018
- 2018-07-24 US US16/043,924 patent/US10214466B2/en active Active
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