JP2017502934A5 - - Google Patents
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- Publication number
- JP2017502934A5 JP2017502934A5 JP2016536150A JP2016536150A JP2017502934A5 JP 2017502934 A5 JP2017502934 A5 JP 2017502934A5 JP 2016536150 A JP2016536150 A JP 2016536150A JP 2016536150 A JP2016536150 A JP 2016536150A JP 2017502934 A5 JP2017502934 A5 JP 2017502934A5
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbyl
- heterohydrocarbylene
- hydrocarbylene
- optionally
- independently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 104
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 77
- 229910052739 hydrogen Inorganic materials 0.000 claims description 27
- 239000001257 hydrogen Substances 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
- 239000003446 ligand Substances 0.000 claims description 26
- 125000001624 naphthyl group Chemical group 0.000 claims description 17
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 17
- 150000001336 alkenes Chemical class 0.000 claims description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- 125000006658 (C1-C15) hydrocarbyl group Chemical group 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- 239000012634 fragment Substances 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 150000007527 lewis bases Chemical class 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 239000003426 co-catalyst Substances 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 5
- 239000002685 polymerization catalyst Substances 0.000 claims 3
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims 1
- 125000001145 hydrido group Chemical group *[H] 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 5
- 0 C*(CC*1C)C1=*C[C@]([C@@]1C)*(C)=C(C)*1N=C Chemical compound C*(CC*1C)C1=*C[C@]([C@@]1C)*(C)=C(C)*1N=C 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- FGRBYDKOBBBPOI-UHFFFAOYSA-N 10,10-dioxo-2-[4-(N-phenylanilino)phenyl]thioxanthen-9-one Chemical compound O=C1c2ccccc2S(=O)(=O)c2ccc(cc12)-c1ccc(cc1)N(c1ccccc1)c1ccccc1 FGRBYDKOBBBPOI-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361918309P | 2013-12-19 | 2013-12-19 | |
| US61/918,309 | 2013-12-19 | ||
| PCT/US2014/064931 WO2015094513A1 (en) | 2013-12-19 | 2014-11-11 | Metal-ligand complex, olefin polymerization catalyst derived therefrom, and olefin polymerization method utilizing the catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017502934A JP2017502934A (ja) | 2017-01-26 |
| JP2017502934A5 true JP2017502934A5 (enExample) | 2019-02-21 |
| JP6549578B2 JP6549578B2 (ja) | 2019-07-24 |
Family
ID=52016133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016536150A Active JP6549578B2 (ja) | 2013-12-19 | 2014-11-11 | 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9862734B2 (enExample) |
| EP (1) | EP3083048B1 (enExample) |
| JP (1) | JP6549578B2 (enExample) |
| KR (1) | KR102322501B1 (enExample) |
| CN (1) | CN105813742B (enExample) |
| BR (1) | BR112016012971B1 (enExample) |
| ES (1) | ES2869308T3 (enExample) |
| WO (1) | WO2015094513A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3037503A1 (en) * | 2018-04-26 | 2019-10-26 | Nova Chemicals Corporation | Phosphinimine amido-ether complexes |
| CN111171189B (zh) * | 2020-01-06 | 2022-11-08 | 万华化学集团股份有限公司 | 一种耐高温催化剂体系及其应用 |
| CN115970757B (zh) * | 2022-08-18 | 2024-07-09 | 四川大学 | 一种非茂稀土金属碳氢官能团化反应催化剂及其制备方法和应用 |
| WO2026006402A1 (en) * | 2024-06-28 | 2026-01-02 | Dow Global Technologies Llc | Heteroleptic complexes bearing 2-amino-thiazole ligands |
| WO2026006102A1 (en) * | 2024-06-28 | 2026-01-02 | Dow Global Technologies Llc | Group iv heteroleptic complexes bearing 2‑amino‑imidazole ligands for olefin polymerization |
| CN122036785A (zh) * | 2026-04-17 | 2026-05-15 | 东华大学 | 一种含有咪唑啉（烷）-2-亚胺基的ivb金属配合物、催化剂体系以及用其制备聚合物的方法 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US7163907B1 (en) | 1987-01-30 | 2007-01-16 | Exxonmobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5341807A (en) | 1992-06-30 | 1994-08-30 | American Cardiac Ablation Co., Inc. | Ablation catheter positioning system |
| US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
| US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| ATE194629T1 (de) | 1996-03-27 | 2000-07-15 | Dow Chemical Co | Hochlösliches aktivierungsmittel für olefinpolymerisationskatalysator |
| EP0889910B1 (en) | 1996-03-27 | 2003-03-19 | Dow Global Technologies Inc. | Solution polymerization process with dispersed catalyst activator |
| CZ42399A3 (cs) | 1996-08-08 | 1999-07-14 | The Dow Chemical Company | Kovové komplexy obsahující 3-heteroatom-substituovaný cyklopentadienyl, katalytický systém obsahující tento kovový komplex, způsob polymerace, cyklopentadienylový ligand a použití tohoto ligandu |
| US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
| AU726123B2 (en) | 1996-12-19 | 2000-11-02 | Dow Chemical Company, The | 3-aryl substituted indenyl containing metal complexes and polymerization process |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
| CA2243775C (en) | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
| CA2393793C (en) | 1999-12-10 | 2009-09-29 | Jerzy Klosin | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| ATE277092T1 (de) * | 2001-03-05 | 2004-10-15 | Stichting Dutch Polymer Inst | Katalysatorbestandteil für olefinpolymerisation und katalysatorsystem und polymerisationsverfahren unter verwendung eines solchen katalysatorsystems |
| WO2005014674A2 (en) | 2003-08-04 | 2005-02-17 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
| EP1506974A1 (en) | 2003-08-04 | 2005-02-16 | DSM IP Assets B.V. | Process for the preparation of a metalloorganic compound comprising at least one imine ligand |
| US20080051537A1 (en) * | 2004-08-09 | 2008-02-28 | Carnahan Edmund M | Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers |
| US20120095158A1 (en) | 2009-07-01 | 2012-04-19 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| EP2319874A1 (en) * | 2009-11-06 | 2011-05-11 | DSM IP Assets B.V. | Catalyst component for the polymerization of olefins having a guanidinate ligand |
| US8202954B2 (en) | 2010-02-19 | 2012-06-19 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| WO2011156921A2 (en) * | 2010-06-14 | 2011-12-22 | Gino Georges Lavoie | Catalyst ligands, catalytic ligand complexes and polymerization processes using same |
| JP2013155371A (ja) * | 2012-01-06 | 2013-08-15 | Japan Polyethylene Corp | オレフィン系重合体の製造方法 |
| ES2620287T3 (es) * | 2012-06-04 | 2017-06-28 | Sasol Olefins & Surfactants Gmbh | Complejos de guanidinato y su uso como catalizadores de polimerización de transferencia de cadenas |
| WO2014139861A1 (en) | 2013-03-11 | 2014-09-18 | Universität Bayreuth | Complexes for the catalytic oligomerization of olefins |
-
2014
- 2014-11-11 BR BR112016012971-7A patent/BR112016012971B1/pt active IP Right Grant
- 2014-11-11 ES ES14809547T patent/ES2869308T3/es active Active
- 2014-11-11 CN CN201480066726.3A patent/CN105813742B/zh active Active
- 2014-11-11 KR KR1020167017771A patent/KR102322501B1/ko active Active
- 2014-11-11 WO PCT/US2014/064931 patent/WO2015094513A1/en not_active Ceased
- 2014-11-11 EP EP14809547.4A patent/EP3083048B1/en active Active
- 2014-11-11 US US15/032,150 patent/US9862734B2/en active Active
- 2014-11-11 JP JP2016536150A patent/JP6549578B2/ja active Active
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