CN105813742B - 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法 - Google Patents

金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法 Download PDF

Info

Publication number
CN105813742B
CN105813742B CN201480066726.3A CN201480066726A CN105813742B CN 105813742 B CN105813742 B CN 105813742B CN 201480066726 A CN201480066726 A CN 201480066726A CN 105813742 B CN105813742 B CN 105813742B
Authority
CN
China
Prior art keywords
hydrocarbyl
metal
solution
group
nmr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480066726.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN105813742A (zh
Inventor
J·克洛西
P·P·方丹
R·菲格罗阿
D·M·皮尔森
T·D·塞内卡尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of CN105813742A publication Critical patent/CN105813742A/zh
Application granted granted Critical
Publication of CN105813742B publication Critical patent/CN105813742B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64041—Monoanionic ligand
    • C08F4/64044—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64068—Dianionic ligand
    • C08F4/64072—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201480066726.3A 2013-12-19 2014-11-11 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法 Active CN105813742B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361918309P 2013-12-19 2013-12-19
US61/918309 2013-12-19
PCT/US2014/064931 WO2015094513A1 (en) 2013-12-19 2014-11-11 Metal-ligand complex, olefin polymerization catalyst derived therefrom, and olefin polymerization method utilizing the catalyst

Publications (2)

Publication Number Publication Date
CN105813742A CN105813742A (zh) 2016-07-27
CN105813742B true CN105813742B (zh) 2020-05-15

Family

ID=52016133

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480066726.3A Active CN105813742B (zh) 2013-12-19 2014-11-11 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法

Country Status (8)

Country Link
US (1) US9862734B2 (enExample)
EP (1) EP3083048B1 (enExample)
JP (1) JP6549578B2 (enExample)
KR (1) KR102322501B1 (enExample)
CN (1) CN105813742B (enExample)
BR (1) BR112016012971B1 (enExample)
ES (1) ES2869308T3 (enExample)
WO (1) WO2015094513A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3037503A1 (en) * 2018-04-26 2019-10-26 Nova Chemicals Corporation Phosphinimine amido-ether complexes
CN111171189B (zh) * 2020-01-06 2022-11-08 万华化学集团股份有限公司 一种耐高温催化剂体系及其应用
CN115970757B (zh) * 2022-08-18 2024-07-09 四川大学 一种非茂稀土金属碳氢官能团化反应催化剂及其制备方法和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101001885A (zh) * 2004-08-09 2007-07-18 陶氏环球技术公司 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7163907B1 (en) 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5341807A (en) 1992-06-30 1994-08-30 American Cardiac Ablation Co., Inc. Ablation catheter positioning system
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
JP2000517349A (ja) 1996-03-27 2000-12-26 ザ ダウ ケミカル カンパニー 分散した触媒活性剤による溶液重合法
RU2178422C2 (ru) 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
DE69730718T2 (de) 1996-08-08 2005-09-22 Dow Global Technologies, Inc., Midland Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
CA2265515A1 (en) 1996-12-19 1998-06-25 Dow Global Technologies Inc. 3-aryl substituted indenyl containing metal complexes and polymerization process
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
CA2243775C (en) 1998-07-21 2007-06-12 Nova Chemicals Ltd. Phosphinimine/heteroatom catalyst component
CA2646567A1 (en) 1999-12-10 2001-06-14 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2002070569A1 (en) 2001-03-05 2002-09-12 Stichting Dutch Polymer Institute Olefin polymerization catalyst component and catalyst system and polymerization process using such a catalyst system
US7547751B2 (en) 2003-08-04 2009-06-16 Dsm Ip Assets B.V. Process for the preparation of a polyolefin
EP1506974A1 (en) 2003-08-04 2005-02-16 DSM IP Assets B.V. Process for the preparation of a metalloorganic compound comprising at least one imine ligand
SG177446A1 (en) 2009-07-01 2012-02-28 Dow Global Technologies Llc Ethylenic polymer and its use
EP2319874A1 (en) * 2009-11-06 2011-05-11 DSM IP Assets B.V. Catalyst component for the polymerization of olefins having a guanidinate ligand
US8202954B2 (en) 2010-02-19 2012-06-19 Dow Global Technologies Llc Metal-ligand complexes and catalysts
WO2011156921A2 (en) * 2010-06-14 2011-12-22 Gino Georges Lavoie Catalyst ligands, catalytic ligand complexes and polymerization processes using same
JP2013155371A (ja) * 2012-01-06 2013-08-15 Japan Polyethylene Corp オレフィン系重合体の製造方法
EP2671639B1 (en) * 2012-06-04 2017-01-11 Sasol Performance Chemicals GmbH Guanidinate complexes and their use as chain transfer polymerization catalysts
WO2014139861A1 (en) * 2013-03-11 2014-09-18 Universität Bayreuth Complexes for the catalytic oligomerization of olefins

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101001885A (zh) * 2004-08-09 2007-07-18 陶氏环球技术公司 用于制备聚合物的负载型双(羟基芳基芳氧基)催化剂

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Imidazolin-2-iminato titanium complexes: synthesis, structure and use in ethylene polymerization catalysis;Matthias Tamm等;《Dalton Transactions》;20051028;第459–467页 *
Mono(imidazolin-2-iminato) Titanium Complexes for Ethylene Polymerization at LowAmounts of Methylaluminoxane;Dana Shoken等;《J.Am.Chem.Soc.》;20130815(第135期);第12592-12595页 *

Also Published As

Publication number Publication date
CN105813742A (zh) 2016-07-27
BR112016012971B1 (pt) 2021-06-08
ES2869308T3 (es) 2021-10-25
WO2015094513A1 (en) 2015-06-25
JP2017502934A (ja) 2017-01-26
US9862734B2 (en) 2018-01-09
BR112016012971A2 (pt) 2017-08-08
EP3083048A1 (en) 2016-10-26
US20160311837A1 (en) 2016-10-27
KR20160100994A (ko) 2016-08-24
KR102322501B1 (ko) 2021-11-05
JP6549578B2 (ja) 2019-07-24
EP3083048B1 (en) 2021-04-07

Similar Documents

Publication Publication Date Title
JP5837514B2 (ja) 金属−配位子錯体及び触媒
CN102105480B (zh) 吡啶基二氨基过渡金属络合物、其制备和用途
CN108779204B (zh) 烯烃聚合催化剂体系和其使用方法
CN102958957B (zh) 产生高分子量聚乙烯的方法
CN102958959B (zh) 产生高分子量聚乙烯的方法
JP6336870B2 (ja) ビフェノール化合物及びそれを用いるオレフィン重合用触媒並びにオレフィン重合体の製造方法
CN102958956B (zh) 产生高分子量聚乙烯的方法
JP7627660B2 (ja) 連鎖移動能を有するビアリールヒドロキシチオフェンｉｖ族遷移金属重合
KR101989208B1 (ko) 저분자량 에틸렌- 및 α-올레핀-계 물질의 제조 방법
KR102577967B1 (ko) 올레핀 중합을 위한 바이아릴 페녹시 4족 전이 금속 촉매
KR20130079313A (ko) 에틸렌의 선택적 중합 방법 및 그를 위한 촉매
JP2013531111A (ja) 高分子量ポリエチレンの繊維及び膜、それらの製造及び使用
CN102958958A (zh) 产生高分子量聚乙烯的方法
JP7304880B2 (ja) 二核オレフィン重合活性化剤
JP7627274B2 (ja) グループｉｉｉ及びランタニドビス－フェニル－フェノキシ金属－配位子錯体
CN105813742B (zh) 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法
JP2023512637A (ja) 第ｉｉｉ族及びランタニドビス－フェニル－フェノキシ金属－配位子錯体及び連鎖移動剤を含む重合プロセス
US8907031B2 (en) Imino carbene compounds and derivatives, and catalyst compositions made therefrom
WO2014021494A1 (ko) 전이 금속 화합물을 포함하는 전이 금속 촉매 조성물 및 상기 촉매 조성물을 이용한 폴리 올레핀의 제조 방법
CN108779205A (zh) 烯烃聚合催化剂
JP7728252B2 (ja) オレフィン重合のための遷移金属触媒
CN113784995B (zh) 单齿、双齿和四齿胍iv族过渡金属烯烃共聚催化剂
CN111108132A (zh) 用于改进溶解度的在金属上具有亚甲基三烷基硅配体的双-苯基-苯氧基聚烯烃催化剂

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant