JP2017502934A - 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法 - Google Patents
金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法 Download PDFInfo
- Publication number
- JP2017502934A JP2017502934A JP2016536150A JP2016536150A JP2017502934A JP 2017502934 A JP2017502934 A JP 2017502934A JP 2016536150 A JP2016536150 A JP 2016536150A JP 2016536150 A JP2016536150 A JP 2016536150A JP 2017502934 A JP2017502934 A JP 2017502934A
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbyl
- hydrocarbylene
- taken together
- optionally taken
- heterohydrocarbylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003446 ligand Substances 0.000 title claims abstract description 69
- 239000003054 catalyst Substances 0.000 title claims abstract description 48
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 37
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims description 27
- 238000006116 polymerization reaction Methods 0.000 title abstract description 21
- 239000002685 polymerization catalyst Substances 0.000 title description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 119
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 95
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 62
- 229910052757 nitrogen Inorganic materials 0.000 claims description 61
- 229920000098 polyolefin Polymers 0.000 claims description 26
- 230000004913 activation Effects 0.000 claims description 24
- 239000001257 hydrogen Substances 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 20
- 239000005977 Ethylene Substances 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 13
- 125000001624 naphthyl group Chemical group 0.000 claims description 13
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 13
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 230000007935 neutral effect Effects 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 125000006658 (C1-C15) hydrocarbyl group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 4
- 239000012634 fragment Substances 0.000 claims description 4
- 150000007527 lewis bases Chemical class 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 230000001143 conditioned effect Effects 0.000 claims 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 258
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 216
- 239000000243 solution Substances 0.000 description 182
- UHOVQNZJYSORNB-MZWXYZOWSA-N benzene-d6 Chemical compound [2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1[2H] UHOVQNZJYSORNB-MZWXYZOWSA-N 0.000 description 82
- 239000007787 solid Substances 0.000 description 80
- -1 hydrocarbon radical Chemical class 0.000 description 77
- 238000006243 chemical reaction Methods 0.000 description 51
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 239000000463 material Substances 0.000 description 48
- 230000015572 biosynthetic process Effects 0.000 description 46
- 239000003921 oil Substances 0.000 description 46
- 235000019198 oils Nutrition 0.000 description 46
- 239000000047 product Substances 0.000 description 46
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 44
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 41
- 238000003786 synthesis reaction Methods 0.000 description 41
- 239000000203 mixture Substances 0.000 description 27
- 238000003756 stirring Methods 0.000 description 25
- 239000003039 volatile agent Substances 0.000 description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 24
- 125000003118 aryl group Chemical group 0.000 description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 238000002390 rotary evaporation Methods 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 235000019439 ethyl acetate Nutrition 0.000 description 18
- 238000010992 reflux Methods 0.000 description 17
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 239000013078 crystal Substances 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 125000002947 alkylene group Chemical group 0.000 description 14
- ATDGTVJJHBUTRL-UHFFFAOYSA-N cyanogen bromide Chemical compound BrC#N ATDGTVJJHBUTRL-UHFFFAOYSA-N 0.000 description 14
- 239000000725 suspension Substances 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 125000004474 heteroalkylene group Chemical group 0.000 description 13
- 238000003818 flash chromatography Methods 0.000 description 12
- 125000000592 heterocycloalkyl group Chemical group 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 239000004711 α-olefin Substances 0.000 description 12
- 238000007792 addition Methods 0.000 description 11
- 239000008346 aqueous phase Substances 0.000 description 11
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 10
- 239000000741 silica gel Substances 0.000 description 10
- 229910002027 silica gel Inorganic materials 0.000 description 10
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 9
- 239000012267 brine Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 239000012299 nitrogen atmosphere Substances 0.000 description 9
- 239000012044 organic layer Substances 0.000 description 9
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 9
- 0 CC1*[C@@](C)C(*)C(C)C1 Chemical compound CC1*[C@@](C)C(*)C(C)C1 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 125000000753 cycloalkyl group Chemical group 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000012074 organic phase Substances 0.000 description 8
- CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 description 8
- MFRIHAYPQRLWNB-UHFFFAOYSA-N sodium tert-butoxide Chemical compound [Na+].CC(C)(C)[O-] MFRIHAYPQRLWNB-UHFFFAOYSA-N 0.000 description 8
- 229910052735 hafnium Inorganic materials 0.000 description 7
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 238000002330 electrospray ionisation mass spectrometry Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 125000001072 heteroaryl group Chemical group 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 5
- 239000002841 Lewis acid Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000007517 lewis acids Chemical class 0.000 description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 125000006653 (C1-C20) heteroaryl group Chemical group 0.000 description 4
- 125000006651 (C3-C20) cycloalkyl group Chemical group 0.000 description 4
- CZXPCBGOKOOGDN-UHFFFAOYSA-N 1-(2,4,6-trimethylphenyl)ethane-1,2-diamine Chemical compound CC1=CC(C)=C(C(N)CN)C(C)=C1 CZXPCBGOKOOGDN-UHFFFAOYSA-N 0.000 description 4
- JTMASTRJQWXJND-UHFFFAOYSA-N 1-(2-methoxyphenyl)-4,5-dihydroimidazol-2-amine Chemical compound COC1=CC=CC=C1N1C(N)=NCC1 JTMASTRJQWXJND-UHFFFAOYSA-N 0.000 description 4
- ZXLLRIHDLIMTFO-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]-3-(2-methoxyphenyl)imidazolidin-2-imine Chemical compound COC1=C(C=CC=C1)N1CCN(C1=N)C1=C(C=CC=C1C(C)C)C(C)C ZXLLRIHDLIMTFO-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 125000004404 heteroalkyl group Chemical group 0.000 description 4
- 231100000518 lethal Toxicity 0.000 description 4
- 230000001665 lethal effect Effects 0.000 description 4
- 125000002950 monocyclic group Chemical group 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 231100000925 very toxic Toxicity 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 3
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 description 3
- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 description 3
- HEVQKTSFRAXZIU-UHFFFAOYSA-N 1-(2-chloroethyl)-3-(2,4,6-trimethylphenyl)urea Chemical compound CC1=CC(C)=C(NC(=O)NCCCl)C(C)=C1 HEVQKTSFRAXZIU-UHFFFAOYSA-N 0.000 description 3
- YNSZTSXGISXCSA-UHFFFAOYSA-N 1-(2-phenoxyphenyl)-3-(2,4,6-trimethylphenyl)imidazolidin-2-imine Chemical compound CC1=CC(C)=C(N2CCN(C2=N)C2=C(OC3=CC=CC=C3)C=CC=C2)C(C)=C1 YNSZTSXGISXCSA-UHFFFAOYSA-N 0.000 description 3
- VFSODTOUXYOMAM-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]ethane-1,2-diamine Chemical compound CC(C)C1=CC=CC(C(C)C)=C1C(N)CN VFSODTOUXYOMAM-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical class B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 3
- 150000001639 boron compounds Chemical class 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000012312 sodium hydride Substances 0.000 description 3
- 229910000104 sodium hydride Inorganic materials 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 description 2
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- KLWNVJQJSRCDKW-UHFFFAOYSA-N 1-(2,4,6-trimethylphenyl)imidazolidin-2-one Chemical compound CC1=CC(C)=C(N2CCNC2=O)C(C)=C1 KLWNVJQJSRCDKW-UHFFFAOYSA-N 0.000 description 2
- PYCDOXYHGGXYBQ-UHFFFAOYSA-N 1-(2-chloroethyl)-3-[2,6-di(propan-2-yl)phenyl]urea Chemical compound CC(C)C1=CC=CC(C(C)C)=C1NC(=O)NCCCl PYCDOXYHGGXYBQ-UHFFFAOYSA-N 0.000 description 2
- SJMHPTOVPSFUIJ-UHFFFAOYSA-N 1-(2-ethylphenyl)-N'-(2,4,6-trimethylphenyl)ethane-1,2-diamine Chemical compound C(C)C1=C(C=CC=C1)C(CNC1=C(C=C(C=C1C)C)C)N SJMHPTOVPSFUIJ-UHFFFAOYSA-N 0.000 description 2
- IRUYVWVQTXESNX-UHFFFAOYSA-N 1-(2-phenoxyphenyl)-3-(2,4,6-trimethylphenyl)imidazolidin-2-one Chemical compound CC1=CC(C)=C(N2CCN(C2=O)C2=C(OC3=CC=CC=C3)C=CC=C2)C(C)=C1 IRUYVWVQTXESNX-UHFFFAOYSA-N 0.000 description 2
- NMASHUDAXHLLHE-UHFFFAOYSA-N 1-(2-phenoxyphenyl)-3-(2,4,6-trimethylphenyl)imidazolidine-2-thione Chemical compound CC1=CC(C)=C(N2CCN(C2=S)C2=C(OC3=CC=CC=C3)C=CC=C2)C(C)=C1 NMASHUDAXHLLHE-UHFFFAOYSA-N 0.000 description 2
- LKGPFNSICFUYCU-UHFFFAOYSA-N 1-(2-phenoxyphenyl)-4,5-dihydroimidazol-2-amine Chemical compound O(C1=CC=CC=C1)C1=C(C=CC=C1)N1C(NCC1)=N LKGPFNSICFUYCU-UHFFFAOYSA-N 0.000 description 2
- YGMCQWFBYDRTNT-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]-3-(2-methoxyphenyl)imidazolidin-2-one Chemical compound COC1=C(C=CC=C1)N1CCN(C1=O)C1=C(C=CC=C1C(C)C)C(C)C YGMCQWFBYDRTNT-UHFFFAOYSA-N 0.000 description 2
- XTYBLGRDJLZEGF-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]-3-(2-methoxyphenyl)imidazolidine-2-thione Chemical compound COC1=C(C=CC=C1)N1CCN(C1=S)C1=C(C=CC=C1C(C)C)C(C)C XTYBLGRDJLZEGF-UHFFFAOYSA-N 0.000 description 2
- WAICIWDWFAEYKZ-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]-3-[2-[3-[2-[3-[2,6-di(propan-2-yl)phenyl]-2-iminoimidazolidin-1-yl]-4-methylphenoxy]propoxy]-5-methylphenyl]imidazolidin-2-imine Chemical compound C(CCOC1=C(C=C(C=C1)C)N1C(N(CC1)C1=C(C=CC=C1C(C)C)C(C)C)=N)OC1=C(C=C(C=C1)C)N1C(N(CC1)C1=C(C=CC=C1C(C)C)C(C)C)=N WAICIWDWFAEYKZ-UHFFFAOYSA-N 0.000 description 2
- JPZHJPFBOLMODX-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]imidazolidin-2-one Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N1C(=O)NCC1 JPZHJPFBOLMODX-UHFFFAOYSA-N 0.000 description 2
- MCFWHGVKLLORMK-UHFFFAOYSA-N 1-[2-(methoxymethyl)phenyl]-3-(2,4,6-trimethylphenyl)imidazolidin-2-imine Chemical compound COCC1=C(C=CC=C1)N1CCN(C1=N)C1=C(C)C=C(C)C=C1C MCFWHGVKLLORMK-UHFFFAOYSA-N 0.000 description 2
- HVRUGFJYCAFAAN-UHFFFAOYSA-N 1-bromo-2-ethylbenzene Chemical compound CCC1=CC=CC=C1Br HVRUGFJYCAFAAN-UHFFFAOYSA-N 0.000 description 2
- BCMYXYHEMGPZJN-UHFFFAOYSA-N 1-chloro-2-isocyanatoethane Chemical compound ClCCN=C=O BCMYXYHEMGPZJN-UHFFFAOYSA-N 0.000 description 2
- AOZLGVLVAJRLPS-UHFFFAOYSA-N 1-iodo-2-phenoxybenzene Chemical compound IC1=CC=CC=C1OC1=CC=CC=C1 AOZLGVLVAJRLPS-UHFFFAOYSA-N 0.000 description 2
- KWVPRPSXBZNOHS-UHFFFAOYSA-N 2,4,6-Trimethylaniline Chemical compound CC1=CC(C)=C(N)C(C)=C1 KWVPRPSXBZNOHS-UHFFFAOYSA-N 0.000 description 2
- WKBALTUBRZPIPZ-UHFFFAOYSA-N 2,6-di(propan-2-yl)aniline Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N WKBALTUBRZPIPZ-UHFFFAOYSA-N 0.000 description 2
- WJAXXWSZNSFVNG-UHFFFAOYSA-N 2-bromoethanamine;hydron;bromide Chemical compound [Br-].[NH3+]CCBr WJAXXWSZNSFVNG-UHFFFAOYSA-N 0.000 description 2
- VZLJZJJAFDMHRZ-UHFFFAOYSA-M 2-chloro-1-(2-phenoxyphenyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-3-ium chloride Chemical compound [Cl-].ClC=1N(CC[N+]1C1=C(C=C(C=C1C)C)C)C1=C(C=CC=C1)OC1=CC=CC=C1 VZLJZJJAFDMHRZ-UHFFFAOYSA-M 0.000 description 2
- FAJKTTUFVUFDMY-UHFFFAOYSA-M 2-chloro-1-[2,6-di(propan-2-yl)phenyl]-3-(2-methoxyphenyl)-4,5-dihydroimidazol-1-ium chloride Chemical compound [Cl-].ClC=1N(CC[N+]1C1=C(C=CC=C1C(C)C)C(C)C)C1=C(C=CC=C1)OC FAJKTTUFVUFDMY-UHFFFAOYSA-M 0.000 description 2
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 2
- DISXFZWKRTZTRI-UHFFFAOYSA-N 4,5-dihydro-1h-imidazol-2-amine Chemical compound NC1=NCCN1 DISXFZWKRTZTRI-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- WPXXAMKOYWIVMN-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)COC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)COC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 WPXXAMKOYWIVMN-UHFFFAOYSA-N 0.000 description 2
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910007950 ZrBN Inorganic materials 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000001548 androgenic effect Effects 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 125000002619 bicyclic group Chemical group 0.000 description 2
- 239000012455 biphasic mixture Substances 0.000 description 2
- 229910000085 borane Inorganic materials 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 description 2
- 125000002993 cycloalkylene group Chemical group 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910021482 group 13 metal Inorganic materials 0.000 description 2
- KNLGRGALOHHVOL-UHFFFAOYSA-N hafnium(4+);methanidylbenzene Chemical compound [Hf+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 KNLGRGALOHHVOL-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- KVKFRMCSXWQSNT-UHFFFAOYSA-N n,n'-dimethylethane-1,2-diamine Chemical compound CNCCNC KVKFRMCSXWQSNT-UHFFFAOYSA-N 0.000 description 2
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 1
- 125000006573 (C1-C10) heteroaryl group Chemical group 0.000 description 1
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 1
- 125000006735 (C1-C20) heteroalkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 description 1
- 125000006747 (C2-C10) heterocycloalkyl group Chemical group 0.000 description 1
- 125000003626 1,2,4-triazol-1-yl group Chemical group [*]N1N=C([H])N=C1[H] 0.000 description 1
- 125000004509 1,3,4-oxadiazol-2-yl group Chemical group O1C(=NN=C1)* 0.000 description 1
- 125000004521 1,3,4-thiadiazol-2-yl group Chemical group S1C(=NN=C1)* 0.000 description 1
- RUKVGXGTVPPWDD-UHFFFAOYSA-N 1,3-bis(2,4,6-trimethylphenyl)imidazolidine Chemical compound CC1=CC(C)=CC(C)=C1N1CN(C=2C(=CC(C)=CC=2C)C)CC1 RUKVGXGTVPPWDD-UHFFFAOYSA-N 0.000 description 1
- AHTWWLZQUGEXPP-UHFFFAOYSA-N 1-(2-ethylphenyl)-3-(2,4,6-trimethylphenyl)imidazolidin-2-imine Chemical compound CCC1=C(C=CC=C1)N1CCN(C1=N)C1=C(C)C=C(C)C=C1C AHTWWLZQUGEXPP-UHFFFAOYSA-N 0.000 description 1
- YDESLDQJZQBBOW-UHFFFAOYSA-N 1-(2-methoxyphenyl)-3-(2,4,6-trimethylphenyl)imidazolidin-2-imine Chemical compound COC1=C(C=CC=C1)N1CCN(C1=N)C1=C(C)C=C(C)C=C1C YDESLDQJZQBBOW-UHFFFAOYSA-N 0.000 description 1
- OEESCZRPWUIKIF-UHFFFAOYSA-N 1-[2,6-di(propan-2-yl)phenyl]-4,5-dihydroimidazol-2-amine Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N1CCNC1=N OEESCZRPWUIKIF-UHFFFAOYSA-N 0.000 description 1
- IKERUQRMKXJZDC-UHFFFAOYSA-N 1-[2-(methoxymethyl)phenyl]ethane-1,2-diamine Chemical compound COCC1=CC=CC=C1C(N)CN IKERUQRMKXJZDC-UHFFFAOYSA-N 0.000 description 1
- 125000004173 1-benzimidazolyl group Chemical group [H]C1=NC2=C([H])C([H])=C([H])C([H])=C2N1* 0.000 description 1
- QFAZLCRHLRJNAW-UHFFFAOYSA-N 1-bromo-2-(methoxymethyl)benzene Chemical compound COCC1=CC=CC=C1Br QFAZLCRHLRJNAW-UHFFFAOYSA-N 0.000 description 1
- QGRPVMLBTFGQDQ-UHFFFAOYSA-N 1-chloro-2-methoxybenzene Chemical compound COC1=CC=CC=C1Cl QGRPVMLBTFGQDQ-UHFFFAOYSA-N 0.000 description 1
- 125000004214 1-pyrrolidinyl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001462 1-pyrrolyl group Chemical group [*]N1C([H])=C([H])C([H])=C1[H] 0.000 description 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- NMXLXQGHBSPIDR-UHFFFAOYSA-N 2-(2-methylpropyl)oxaluminane Chemical compound CC(C)C[Al]1CCCCO1 NMXLXQGHBSPIDR-UHFFFAOYSA-N 0.000 description 1
- KCSKXVNXNAWIFA-UHFFFAOYSA-N 2-bromo-1-[3-(2-bromo-4-methylphenoxy)propoxy]-4-methylbenzene Chemical compound BrC1=C(OCCCOC2=C(C=C(C=C2)C)Br)C=CC(=C1)C KCSKXVNXNAWIFA-UHFFFAOYSA-N 0.000 description 1
- 125000004204 2-methoxyphenyl group Chemical group [H]C1=C([H])C(*)=C(OC([H])([H])[H])C([H])=C1[H] 0.000 description 1
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- YNGIDJIETOTNDN-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=CC=C1)CC)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=CC=C1)CC)(CC1=CC=CC=C1)CC1=CC=CC=C1 YNGIDJIETOTNDN-UHFFFAOYSA-N 0.000 description 1
- OEXCOPFZLFRXLR-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 OEXCOPFZLFRXLR-UHFFFAOYSA-N 0.000 description 1
- WBYNYBYVOFTBDB-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 WBYNYBYVOFTBDB-UHFFFAOYSA-N 0.000 description 1
- ZBNZVRNCZFUGEG-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 ZBNZVRNCZFUGEG-UHFFFAOYSA-N 0.000 description 1
- SGTQUACRKCZIPL-UHFFFAOYSA-N C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Hf](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)CC1=CC=CC=C1 SGTQUACRKCZIPL-UHFFFAOYSA-N 0.000 description 1
- LSXPGPJMJNCZHQ-UHFFFAOYSA-N C(C1=CC=CC=C1)[Ti](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Ti](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 LSXPGPJMJNCZHQ-UHFFFAOYSA-N 0.000 description 1
- CRZZDAVEJYAOPU-UHFFFAOYSA-N C(C1=CC=CC=C1)[Ti](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Ti](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 CRZZDAVEJYAOPU-UHFFFAOYSA-N 0.000 description 1
- YYWRMKBCVSFSRE-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 YYWRMKBCVSFSRE-UHFFFAOYSA-N 0.000 description 1
- GDYUYMRUNQFLHP-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=CC=C1)CC)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=C(C=C1C)C)C)C1=C(C=CC=C1)CC)(CC1=CC=CC=C1)CC1=CC=CC=C1 GDYUYMRUNQFLHP-UHFFFAOYSA-N 0.000 description 1
- FUZHTTZWMLXQBR-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)COC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)COC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 FUZHTTZWMLXQBR-UHFFFAOYSA-N 0.000 description 1
- NWNKBRPJRLNAJG-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 NWNKBRPJRLNAJG-UHFFFAOYSA-N 0.000 description 1
- SAJYFXGYBHJLLG-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 SAJYFXGYBHJLLG-UHFFFAOYSA-N 0.000 description 1
- JUGDDZLNQZYTRU-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 Chemical compound C(C1=CC=CC=C1)[Zr](N=C1N(CCN1C1=C(C=CC=C1)OC1=CC=CC=C1)C1=C(C=C(C=C1C)C)C)(CC1=CC=CC=C1)CC1=CC=CC=C1 JUGDDZLNQZYTRU-UHFFFAOYSA-N 0.000 description 1
- YFDVSERUSDANOF-UHFFFAOYSA-N C1(CCCCC1)N(C(CC1=CC=CC=C1)=NC1CCCCC1)[Zr] Chemical compound C1(CCCCC1)N(C(CC1=CC=CC=C1)=NC1CCCCC1)[Zr] YFDVSERUSDANOF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XYHKQHLXXLEHCK-UHFFFAOYSA-N Cc(cc1C)cc(C)c1NCCNc1ccccc1OC Chemical compound Cc(cc1C)cc(C)c1NCCNc1ccccc1OC XYHKQHLXXLEHCK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 229910000799 K alloy Inorganic materials 0.000 description 1
- RDJFPFXXFMVDKE-UHFFFAOYSA-N N'-(2-methoxyphenyl)-1-(2,4,6-trimethylphenyl)ethane-1,2-diamine Chemical compound C1(=C(C(=CC(=C1)C)C)C(CNC1=C(C=CC=C1)OC)N)C RDJFPFXXFMVDKE-UHFFFAOYSA-N 0.000 description 1
- BNNDCLKMQVXVRX-UHFFFAOYSA-N N'-[2-(methoxymethyl)phenyl]-1-(2,4,6-trimethylphenyl)ethane-1,2-diamine Chemical compound C1(=C(C(=CC(=C1)C)C)C(CNC1=C(C=CC=C1)COC)N)C BNNDCLKMQVXVRX-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 229910000528 Na alloy Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- CBAFVKIHYRRACC-UHFFFAOYSA-N [Hf+4].C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1 Chemical compound [Hf+4].C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1.C(C1=CC=CC=C1)C=1C(=C(C=CC1)C(C(=NC1CCCCC1)[N-]C1CCCCC1)N=C1N(CCN1C1=C(C=CC=C1)OC)C1=C(C=CC=C1C(C)C)C(C)C)CC1=CC=CC=C1 CBAFVKIHYRRACC-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910000573 alkali metal alloy Inorganic materials 0.000 description 1
- 229910000941 alkaline earth metal alloy Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000004791 alkyl magnesium halides Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- WZMUUWMLOCZETI-UHFFFAOYSA-N azane;borane Chemical compound B.N WZMUUWMLOCZETI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 238000006758 bulk electrolysis reaction Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000005517 carbenium group Chemical group 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical class 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- WDVGNXKCFBOKDF-UHFFFAOYSA-N dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane Chemical compound COC1=CC=C(OC)C(C=2C(=CC(=CC=2C(C)C)C(C)C)C(C)C)=C1P(C1CCCCC1)C1CCCCC1 WDVGNXKCFBOKDF-UHFFFAOYSA-N 0.000 description 1
- IWMMXPNBCHCFCY-UHFFFAOYSA-M dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;palladium(2+);2-phenylethanamine;chloride Chemical compound [Pd+]Cl.NCCC1=CC=CC=[C-]1.COC1=CC=C(OC)C(C=2C(=CC(=CC=2C(C)C)C(C)C)C(C)C)=C1P(C1CCCCC1)C1CCCCC1 IWMMXPNBCHCFCY-UHFFFAOYSA-M 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 125000004639 dihydroindenyl group Chemical group C1(CCC2=CC=CC=C12)* 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000003037 imidazol-2-yl group Chemical group [H]N1C([*])=NC([H])=C1[H] 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 125000003427 indacenyl group Chemical group 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 125000000593 indol-1-yl group Chemical group [H]C1=C([H])C([H])=C2N([*])C([H])=C([H])C2=C1[H] 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000004501 isothiazol-5-yl group Chemical group S1N=CC=C1* 0.000 description 1
- 125000000842 isoxazolyl group Chemical group 0.000 description 1
- CFHGBZLNZZVTAY-UHFFFAOYSA-N lawesson's reagent Chemical compound C1=CC(OC)=CC=C1P1(=S)SP(=S)(C=2C=CC(OC)=CC=2)S1 CFHGBZLNZZVTAY-UHFFFAOYSA-N 0.000 description 1
- 238000004895 liquid chromatography mass spectrometry Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- AXTNYCDVWRSOCU-UHFFFAOYSA-N n'-tert-butyl-n-ethylmethanediimine Chemical compound CCN=C=NC(C)(C)C AXTNYCDVWRSOCU-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 125000003145 oxazol-4-yl group Chemical group O1C=NC(=C1)* 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000012041 precatalyst Substances 0.000 description 1
- OLBCVFGFOZPWHH-UHFFFAOYSA-N propofol Chemical compound CC(C)C1=CC=CC(C(C)C)=C1O OLBCVFGFOZPWHH-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 125000004307 pyrazin-2-yl group Chemical group [H]C1=C([H])N=C(*)C([H])=N1 0.000 description 1
- 125000004353 pyrazol-1-yl group Chemical group [H]C1=NN(*)C([H])=C1[H] 0.000 description 1
- 125000000246 pyrimidin-2-yl group Chemical group [H]C1=NC(*)=NC([H])=C1[H] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical class [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- QLUMLEDLZDMGDW-UHFFFAOYSA-N sodium;1h-naphthalen-1-ide Chemical compound [Na+].[C-]1=CC=CC2=CC=CC=C21 QLUMLEDLZDMGDW-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000001712 tetrahydronaphthyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 description 1
- 125000004523 tetrazol-1-yl group Chemical group N1(N=NN=C1)* 0.000 description 1
- 125000004299 tetrazol-5-yl group Chemical group [H]N1N=NC(*)=N1 0.000 description 1
- 125000000437 thiazol-2-yl group Chemical group [H]C1=C([H])N=C(*)S1 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ANEFWEBMQHRDLH-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl) borate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OB(OC=1C(=C(F)C(F)=C(F)C=1F)F)OC1=C(F)C(F)=C(F)C(F)=C1F ANEFWEBMQHRDLH-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64006—Bidentate ligand
- C08F4/64041—Monoanionic ligand
- C08F4/64044—NN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/64006—Bidentate ligand
- C08F4/64068—Dianionic ligand
- C08F4/64072—NN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (17)
- 式(I)の金属−配位子錯体であって、
Jが、(RK)(RL)(RX)P=N−、(RK)(RL)C=N−、(RK)((RL)(RX)N)C=N−、(RK)(RL)B−O−、RKO−、RKS−、RKS(O)−、(RK)(RL)N−、(RKN=C(RL)−N(RX))−、(RK)(RL)NO−、RKC(O)O−、RKC(O)NH−、及び(RK)(RL)P−から選択されるモノアニオン性部分であり、式中、各RK、RL、及びRXが独立して、水素、(C1−C40))ヒドロカルビル−、((C1−C15)ヒドロカルビル)3Si、((C1−C15)ヒドロカルビル)2N−、または(C1−C40)ヘテロヒドロカルビル−であり、
Lが、各発生で独立して、ハロゲン、水素、((C1−C40)ヒドロカルビル)C(O)N(H)−、((C1−C40)ヒドロカルビル)C(O)N(H)(C1−C20)ヒドロカルビル−、((C1−C40)ヒドロカルビル)C(O)O−、(C1−C40)ヒドロカルビル−、(C1−C40)ヘテロヒドロカルビル−、RK(RL)N−、RLO−、RLS−、またはRK(RL)P−であり、式中、RK及びRLの各々が独立して、上に定義される通りであり、Lの各発生が、Mに結合するモノアニオン性部分であり、
Mが、元素周期表の第3、4、5、及び6族のうちのいずれか1つの金属であり、前記金属が+2、+3、+4、+5、または+6の形式上の酸化状態にあり、
R1、R2、R3、及びR4が、各発生で独立して、水素、(C1−C40)ヒドロカルビル−、((C1−C40)ヒドロカルビル)O−、((C1−C40)ヒドロカルビル)S−、((C1−C40)ヒドロカルビル)3Si−、または(C1−C40)ヘテロヒドロカルビル−であり、
Xが、RXN(RK)(RL)、RX=N(RK)、RKO(RL)、RKS(RL)、及びRXP(RK)(RL)から選択される中性ルイス塩基性基であり、式中、RK、RL、及びRXの各々が独立して、上に定義される通りであり、
pが、0、1、2、または3であり、qが、0または1であるが、但し、p及びqの合計が少なくとも1であることを条件とし、
rが、2または3であり、
Lの2つの発生が、任意に一緒になって、(C2−C40)ヒドロカルビレンもしくは(C1−C40)ヘテロヒドロカルビレン、または(RD)2C=C(RD)−C(RD)=C(RD)2を形成し、式中、各RDが独立して、H、非置換(C1−C6)アルキル、フェニル、またはナフチルであり、
JならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
Xの1つの発生ならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C1−C40)ヘテロヒドロカルビレンを形成し、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
X及びJが、任意に一緒になって、モノアニオン性二座部分X−Jを形成するが、但し、X−JがMに結合して以下の構造を有する断片を形成する場合、
前記上述の(C1−C40)ヒドロカルビル、(C1−C40)ヘテロヒドロカルビル、(C2−C40)ヒドロカルビレン、及び(C1−C40)ヘテロヒドロカルビレンの各々が独立して、同一または異なり、かつ非置換であるか、またはハロゲン、非置換(C1−C18)ヒドロカルビル、F3C−、FCH2O−、F2HCO−、F3CO−、オキソ、R3Si−、RO−、RS−、RS(O)−、RS(O)2−、R2P−、R2N−、R2C=N−、NC−、RC(O)O−、ROC(O)−、RC(O)N(R)−、及びR2NC(O)−から選択される1つ以上の置換基RSで置換され、各Rが独立して、非置換(C1−C18)ヒドロカルビルである、前記金属−配位子錯体。 - Mが、Ti、Zr、またはHfである、請求項1に記載の前記金属−配位子錯体。
- 式(II)を有し、
L、M、R1、R2、R3、及びR4が、請求項1に定義される通りであり、
R5、R6、及びR7が各々独立して、水素、(C1−C40)ヒドロカルビル−、((C1−C40)ヒドロカルビル)O−、((C1−C40)ヒドロカルビル)S−、((C1−C40)ヒドロカルビル)3Si−、または(C1−C40)ヘテロヒドロカルビル−であり、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちのいずれか1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R5、R6、及びR7のうちの1つが、任意に、R1、R2、R3、R4、及びLのうちの1つと一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
前記Lの2つの発生が、任意に一緒になって、(C2−C40)ヒドロカルビレンもしくは(C1−C40)ヘテロヒドロカルビレン、または(RD)2C=C(RD)−C(RD)=C(RD)2を形成し、式中、各RDが独立して、H、非置換(C1−C6)アルキル、フェニル、またはナフチルである、請求項1〜3のいずれか一項に記載の前記金属−配位子錯体。 - 式(III)を有し、
L、M、p、R1、R2、R3、R4、及びXが、請求項1に定義される通りであり、
J1が、NまたはPであり、
R8及びR9が各々独立して、水素、(C1−C40)ヒドロカルビル−、((C1−C40)ヒドロカルビル)O−、((C1−C40)ヒドロカルビル)S−、((C1−C40)ヒドロカルビル)3Si−、または(C1−C40)ヘテロヒドロカルビル−であり、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちのいずれか1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
前記Lの2つの発生が、任意に一緒になって、(C2−C40)ヒドロカルビレンもしくは(C1−C40)ヘテロヒドロカルビレン、または(RD)2C=C(RD)−C(RD)=C(RD)2を形成し、式中、各RDが独立して、H、非置換(C1−C6)アルキル、フェニル、またはナフチルであり、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R8及びR9が、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R8及びR9が、任意に一緒になって、J1に2重結合する基を形成し、
R8及びR9のうちの1つが、任意に、R1、R2、R3、R4、及びLのうちの1つと一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R8及びR9のうちの1つが、任意に、Xに共有結合し、
XならびにR1、R2、R3、及びR4のうちのいずれか1つが、任意に一緒になって、(C1−C40)ヘテロヒドロカルビレンを形成する、請求項1〜3のいずれか一項に記載の前記金属−配位子錯体。 - 式(IV)を有し、
L、M、p、R1、R2、R3、R4、及びXが、請求項1に定義される通りであり、
J2が、OまたはSであり、
R10が、(C1−C40)ヒドロカルビル−、((C1−C40)ヒドロカルビル)3Si−、または(C1−C40)ヘテロヒドロカルビル−であり、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちのいずれか1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
XならびにR1、R2、R3、及びR4のうちのいずれか1つが、任意に一緒になって、(C1−C40)ヘテロヒドロカルビレンを形成し、
R10が、任意に、R1、R2、R3、R4、及びLのうちの1つと一緒になって、(C1−C40)ヘテロヒドロカルビレンを形成し、
R10が、任意に、Xに共有結合する、請求項1〜3のいずれか一項に記載の前記金属−配位子錯体。 - 式(V)を有し、
L、M、R1、R2、R3、及びR4が、式(I)に定義される通りであり、
J3が、OまたはNR12であり、
R11及びR12が各々独立して、水素、(C1−C40)ヒドロカルビル−、((C1−C40)ヒドロカルビル)O−、((C1−C40)ヒドロカルビル)S−、((C1−C40)ヒドロカルビル)3Si−、または(C1−C40)ヘテロヒドロカルビル−であり、
R11及びR12が、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R11及びR12のうちの1つが、任意に、R1、R2、R3、R4、及びLのうちの1つと一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
Lの2つの発生が、任意に一緒になって、(C2−C40)ヒドロカルビレンもしくは(C1−C40)ヘテロヒドロカルビレン、または(RD)2C=C(RD)−C(RD)=C(RD)2を形成し、式中、各RDが独立して、H、非置換(C1−C6)アルキル、フェニル、またはナフチルであり、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成する、請求項1〜3のいずれか一項に記載の前記金属−配位子錯体。 - 式(VI)を有し、
L、M、R1、R2、R3、R4、及びXが、式(I)に定義される通りであり、
Lの2つの発生が、任意に一緒になって、(C2−C40)ヒドロカルビレンもしくは(C1−C40)ヘテロヒドロカルビレン、または(RD)2C=C(RD)−C(RD)=C(RD)2を形成し、式中、各RDが独立して、H、非置換(C1−C6)アルキル、フェニル、またはナフチルであり、
Lの1つの発生ならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成し、
XならびにR1、R2、R3、及びR4のうちの1つが、任意に一緒になって、(C1−C40)ヘテロヒドロカルビレンを形成し、
R1、R2、R3、及びR4のうちのいずれか2つが、任意に一緒になって、(C2−C40)ヒドロカルビレンまたは(C1−C40)ヘテロヒドロカルビレンを形成する、請求項1〜3のいずれか一項に記載の前記金属−配位子錯体。 - 請求項1〜14のいずれか一項に記載の1つ以上の金属−配位子錯体と、1つ以上の活性化助触媒とを含む、またはそれらの反応生成物を含む触媒であって、前記1つ以上の金属−配位子錯体の総モル数と前記1つ以上の活性化助触媒の総モル数との比率が、1:10,000〜100:1である、前記触媒。
- ポリオレフィンを調製するためのプロセスであって、少なくとも1つの重合可能なオレフィンと請求項15に記載の前記触媒とを、前記少なくとも1つの重合可能なオレフィンのうちの少なくとも一部を重合するのに十分な条件下で接触させ、それによりポリオレフィンを生成することを含む、前記プロセス。
- 前記少なくとも1つの重合可能なオレフィンが、エチレン及びオクテンを含む、請求項16に記載の前記プロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361918309P | 2013-12-19 | 2013-12-19 | |
US61/918,309 | 2013-12-19 | ||
PCT/US2014/064931 WO2015094513A1 (en) | 2013-12-19 | 2014-11-11 | Metal-ligand complex, olefin polymerization catalyst derived therefrom, and olefin polymerization method utilizing the catalyst |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2017502934A true JP2017502934A (ja) | 2017-01-26 |
JP2017502934A5 JP2017502934A5 (ja) | 2019-02-21 |
JP6549578B2 JP6549578B2 (ja) | 2019-07-24 |
Family
ID=52016133
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016536150A Active JP6549578B2 (ja) | 2013-12-19 | 2014-11-11 | 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9862734B2 (ja) |
EP (1) | EP3083048B1 (ja) |
JP (1) | JP6549578B2 (ja) |
KR (1) | KR102322501B1 (ja) |
CN (1) | CN105813742B (ja) |
BR (1) | BR112016012971B1 (ja) |
ES (1) | ES2869308T3 (ja) |
WO (1) | WO2015094513A1 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA3037503A1 (en) * | 2018-04-26 | 2019-10-26 | Nova Chemicals Corporation | Phosphinimine amido-ether complexes |
CN111171189B (zh) * | 2020-01-06 | 2022-11-08 | 万华化学集团股份有限公司 | 一种耐高温催化剂体系及其应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004527608A (ja) * | 2001-03-05 | 2004-09-09 | スティヒティング ダッチ ポリマー インスティテュート | オレフィン重合触媒成分及び触媒システム、並びにそのような触媒システムを用いた重合プロセス |
WO2011156921A2 (en) * | 2010-06-14 | 2011-12-22 | Gino Georges Lavoie | Catalyst ligands, catalytic ligand complexes and polymerization processes using same |
JP2013510214A (ja) * | 2009-11-06 | 2013-03-21 | ランクセス・エラストマーズ・ベー・フェー | グアニジナト配位子を有するオレフィンの重合用の触媒成分 |
JP2013520418A (ja) * | 2010-02-19 | 2013-06-06 | ダウ グローバル テクノロジーズ エルエルシー | 金属−配位子錯体及び触媒 |
JP2013155371A (ja) * | 2012-01-06 | 2013-08-15 | Japan Polyethylene Corp | オレフィン系重合体の製造方法 |
WO2013182290A1 (en) * | 2012-06-04 | 2013-12-12 | Sasol Olefins & Surfactants Gmbh | Amidinate and guanidinate complexes, their use as chain transfer polymerization catalysts and long chain alcohols obtained by such process |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US7163907B1 (en) | 1987-01-30 | 2007-01-16 | Exxonmobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5296433A (en) | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
US5341807A (en) | 1992-06-30 | 1994-08-30 | American Cardiac Ablation Co., Inc. | Ablation catheter positioning system |
US5372682A (en) | 1993-06-24 | 1994-12-13 | The Dow Chemical Company | Electrochemical preparation of addition polymerization catalysts |
US5625087A (en) | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
EP0889910B1 (en) | 1996-03-27 | 2003-03-19 | Dow Global Technologies Inc. | Solution polymerization process with dispersed catalyst activator |
AU2214997A (en) | 1996-03-27 | 1997-10-17 | Dow Chemical Company, The | Highly soluble olefin polymerization catalyst activator |
BR9711124A (pt) | 1996-08-08 | 1999-09-28 | Dow Chemical Co | Complexo de metal, sistema de catalisador para polimerização de olefina, processo para a polimerização de olefinas, processo de polemerização em solução a alta temperatura, produto de poliolefina e ligante contendo ciclopentadienila |
US5783512A (en) | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
ES2168681T3 (es) | 1996-12-19 | 2002-06-16 | Dow Chemical Co | Indenilo 3-(aril sustituido) que contiene complejos metalicos y procedimiento de polimerizacion. |
US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
CA2243775C (en) | 1998-07-21 | 2007-06-12 | Nova Chemicals Ltd. | Phosphinimine/heteroatom catalyst component |
CN1409729A (zh) | 1999-12-10 | 2003-04-09 | 陶氏环球技术公司 | 取代的第4族金属配合物,催化剂和烯烃聚合方法 |
EP1506974A1 (en) | 2003-08-04 | 2005-02-16 | DSM IP Assets B.V. | Process for the preparation of a metalloorganic compound comprising at least one imine ligand |
US7547751B2 (en) | 2003-08-04 | 2009-06-16 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
WO2006020624A1 (en) * | 2004-08-09 | 2006-02-23 | Dow Global Technologies Inc. | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
BRPI1010092B1 (pt) | 2009-07-01 | 2022-05-03 | Dow Global Technologies Llc | Polímero de etileno e comonômero de a-olefina c3-c8, composição e artigo fabricado |
WO2014139861A1 (en) * | 2013-03-11 | 2014-09-18 | Universität Bayreuth | Complexes for the catalytic oligomerization of olefins |
-
2014
- 2014-11-11 US US15/032,150 patent/US9862734B2/en active Active
- 2014-11-11 JP JP2016536150A patent/JP6549578B2/ja active Active
- 2014-11-11 BR BR112016012971-7A patent/BR112016012971B1/pt active IP Right Grant
- 2014-11-11 ES ES14809547T patent/ES2869308T3/es active Active
- 2014-11-11 WO PCT/US2014/064931 patent/WO2015094513A1/en active Application Filing
- 2014-11-11 EP EP14809547.4A patent/EP3083048B1/en active Active
- 2014-11-11 KR KR1020167017771A patent/KR102322501B1/ko active IP Right Grant
- 2014-11-11 CN CN201480066726.3A patent/CN105813742B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004527608A (ja) * | 2001-03-05 | 2004-09-09 | スティヒティング ダッチ ポリマー インスティテュート | オレフィン重合触媒成分及び触媒システム、並びにそのような触媒システムを用いた重合プロセス |
JP2013510214A (ja) * | 2009-11-06 | 2013-03-21 | ランクセス・エラストマーズ・ベー・フェー | グアニジナト配位子を有するオレフィンの重合用の触媒成分 |
JP2013520418A (ja) * | 2010-02-19 | 2013-06-06 | ダウ グローバル テクノロジーズ エルエルシー | 金属−配位子錯体及び触媒 |
WO2011156921A2 (en) * | 2010-06-14 | 2011-12-22 | Gino Georges Lavoie | Catalyst ligands, catalytic ligand complexes and polymerization processes using same |
JP2013155371A (ja) * | 2012-01-06 | 2013-08-15 | Japan Polyethylene Corp | オレフィン系重合体の製造方法 |
WO2013182290A1 (en) * | 2012-06-04 | 2013-12-12 | Sasol Olefins & Surfactants Gmbh | Amidinate and guanidinate complexes, their use as chain transfer polymerization catalysts and long chain alcohols obtained by such process |
Non-Patent Citations (1)
Title |
---|
ISABELLE HAAS, CHRISTIAN HUBNER, WINFRIED P. KRETSCHMER, AND RHETT KEMPE: "A Highly Efficient Titanium Catalyst for the Synthesis of Ultrahigh-Molecular-Weight Polyethylene (U", CHEMISTRY - A EUROPEAN JOURNAL, vol. 19, JPN6018028447, 28 May 2013 (2013-05-28), pages 9132 - 9136, ISSN: 0003843947 * |
Also Published As
Publication number | Publication date |
---|---|
CN105813742B (zh) | 2020-05-15 |
BR112016012971A2 (pt) | 2017-08-08 |
BR112016012971B1 (pt) | 2021-06-08 |
WO2015094513A1 (en) | 2015-06-25 |
US9862734B2 (en) | 2018-01-09 |
JP6549578B2 (ja) | 2019-07-24 |
CN105813742A (zh) | 2016-07-27 |
ES2869308T3 (es) | 2021-10-25 |
EP3083048B1 (en) | 2021-04-07 |
EP3083048A1 (en) | 2016-10-26 |
KR20160100994A (ko) | 2016-08-24 |
US20160311837A1 (en) | 2016-10-27 |
KR102322501B1 (ko) | 2021-11-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101827023B1 (ko) | 금속-리간드 착체 및 촉매 | |
US7973116B2 (en) | Pyridyldiamido transition metal complexes, production and use thereof | |
RU2434854C2 (ru) | Способ получения асимметричных бис(имино)соединений | |
JP4481820B2 (ja) | 非共有結合的な相互作用を利用したポリオレフィン触媒成分 | |
JP4808625B2 (ja) | ジイミン配位子、金属化合物、オレフィン重合法 | |
JP6549578B2 (ja) | 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法 | |
US7105672B2 (en) | Cyclometallated catalysts | |
JP2001261731A (ja) | 二座ジイミノニッケルおよびパラジウム錯体およびこれから得られた重合触媒 | |
KR101654432B1 (ko) | 1-헥센 및 1-옥텐의 제조방법 | |
US8907031B2 (en) | Imino carbene compounds and derivatives, and catalyst compositions made therefrom | |
KR101594682B1 (ko) | 촉매 조성물 및 알파-올레핀의 제조 방법 | |
EP3947479A1 (en) | Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators | |
JP2023547335A (ja) | 6-アミノ-n-アリールアザインドール配位子を有するオレフィン重合触媒 | |
JP2023500591A (ja) | オレフィン重合のための遷移金属触媒 | |
KR20240004523A (ko) | 촉매 | |
KR20200042950A (ko) | 올레핀의 중합 | |
US20010044511A1 (en) | Polymerization of olefins |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20171027 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180712 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180731 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20181030 |
|
A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20190109 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190528 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190627 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6549578 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
S802 | Written request for registration of partial abandonment of right |
Free format text: JAPANESE INTERMEDIATE CODE: R311802 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |