ES2168681T3 - Indenilo 3-(aril sustituido) que contiene complejos metalicos y procedimiento de polimerizacion. - Google Patents

Indenilo 3-(aril sustituido) que contiene complejos metalicos y procedimiento de polimerizacion.

Info

Publication number
ES2168681T3
ES2168681T3 ES97946326T ES97946326T ES2168681T3 ES 2168681 T3 ES2168681 T3 ES 2168681T3 ES 97946326 T ES97946326 T ES 97946326T ES 97946326 T ES97946326 T ES 97946326T ES 2168681 T3 ES2168681 T3 ES 2168681T3
Authority
ES
Spain
Prior art keywords
replaced
aril
indenyl
containing metallic
polymerization procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97946326T
Other languages
English (en)
Inventor
Peter N Nickias
Jasson T Patton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2168681T3 publication Critical patent/ES2168681T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

LA INVENCION SE REFIERE A COMPLEJOS DE METALES DEL GRUPO 4, DE GEOMETRIA CONSTREÑIDA, QUE COMPRENDEN COMO LIGANDO UN INDENILO SUSTITUIDO POR 3 - ARILO Y A DERIVADOS DE LOS MISMOS. SE DESCRIBE TAMBIEN SU UTILIZACION COMO CATALIZADORES DE POLIMERIZACION DE OLEFINAS, ESPECIALMENTE PARA PREPARAR INTERPOLIMEROS QUE COMPRENDEN ETILENO Y UN MONOMERO MONOVINILICO AROMATICO.
ES97946326T 1996-12-19 1997-10-17 Indenilo 3-(aril sustituido) que contiene complejos metalicos y procedimiento de polimerizacion. Expired - Lifetime ES2168681T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US3481996P 1996-12-19 1996-12-19

Publications (1)

Publication Number Publication Date
ES2168681T3 true ES2168681T3 (es) 2002-06-16

Family

ID=21878814

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97946326T Expired - Lifetime ES2168681T3 (es) 1996-12-19 1997-10-17 Indenilo 3-(aril sustituido) que contiene complejos metalicos y procedimiento de polimerizacion.

Country Status (19)

Country Link
US (2) US5866704A (es)
EP (1) EP0946574B1 (es)
JP (1) JP2001506260A (es)
KR (1) KR20000049229A (es)
CN (1) CN1094129C (es)
AR (1) AR010798A1 (es)
AT (1) ATE213250T1 (es)
AU (1) AU726123B2 (es)
BR (1) BR9712535A (es)
CA (1) CA2265515A1 (es)
DE (1) DE69710491T2 (es)
ES (1) ES2168681T3 (es)
ID (1) ID21507A (es)
MY (1) MY115258A (es)
NO (1) NO991816L (es)
RU (1) RU2186073C2 (es)
TR (1) TR199900841T2 (es)
TW (1) TW397845B (es)
WO (1) WO1998027102A1 (es)

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US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US6218557B1 (en) * 1996-11-22 2001-04-17 Boulder Scientific Company Synthesis of titanocenes
DE19720171A1 (de) * 1997-05-14 1998-11-19 Bayer Ag Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen
US6630215B1 (en) * 1998-03-09 2003-10-07 Denki Kagaku Kogyo Kabushiki Kaisha Medical Device
US6015916A (en) * 1999-02-02 2000-01-18 Boulder Scientific Company Constrained geometry metallocene catalyst complexes
EP1102778B1 (en) * 1999-06-04 2003-04-02 Basell Polyolefine GmbH Process for the preparation of titanium complexes
WO2002018459A1 (en) * 2000-08-29 2002-03-07 Chevron Phillips Chemical Company Lp Process for the production of copolymers or terpolymers with functionalized pendant groups
WO2002068529A2 (en) * 2001-02-27 2002-09-06 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
WO2002092610A1 (en) * 2001-05-14 2002-11-21 Dow Global Technologies Inc. 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process
US6946531B2 (en) * 2001-05-14 2005-09-20 Dow Global Technologies Inc. Low molecular weight ethylene interpolymers and polymerization process
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
CA2477776C (en) * 2002-03-14 2011-11-15 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US7737205B2 (en) 2003-07-28 2010-06-15 Dow Global Technologies Inc Thermoplastic vulcanizates and process to prepare them
WO2005092503A1 (en) * 2004-03-16 2005-10-06 Union Carbide Chemicals & Plastics Technology Corporation Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
MXPA06010485A (es) 2004-03-17 2006-12-19 Dow Global Technologies Inc Composicion catalizadora que comprende agente de enlace para la formacion de copolimeros de etileno.
RU2381240C2 (ru) 2004-03-17 2010-02-10 Дау Глобал Текнолоджиз Инк. Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена
WO2005090426A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US20050217153A1 (en) * 2004-04-05 2005-10-06 Ward John W Ii Hanging greeting card with gift/care package container
ATE504349T1 (de) 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
JP4734878B2 (ja) 2004-09-28 2011-07-27 旭硝子株式会社 ガス吸収装置およびガス吸収方法、重合体の製造方法
BRPI0609835A2 (pt) 2005-03-17 2010-05-04 Dow Global Technologies Inc copolìmero, processo para preparar um copolìmero em multiblocos, copolìmero em multiblocos, derivado funcionalizado, mistura polimérica homogênea, e polìmero
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
KR101263966B1 (ko) * 2005-03-17 2013-05-13 다우 글로벌 테크놀로지스 엘엘씨 레지오-불규칙 멀티-블록 공중합체 형성을 위한 이동제를포함하는 촉매 조성물
JP5230426B2 (ja) * 2005-09-15 2013-07-10 ダウ グローバル テクノロジーズ エルエルシー 多中心シャトリング剤（ｍｕｌｔｉ−ｃｅｎｔｅｒｅｄｓｈｕｔｔｌｉｎｇａｇｅｎｔ）によるポリマー構造および分子量分布の制御
US7858707B2 (en) * 2005-09-15 2010-12-28 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
US7981517B2 (en) 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
KR101621703B1 (ko) 2009-07-29 2016-05-17 다우 글로벌 테크놀로지스 엘엘씨 다작용성 쇄 셔틀링제
US20110054122A1 (en) * 2009-08-31 2011-03-03 Jerzy Klosin Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
US8729201B2 (en) 2010-02-19 2014-05-20 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor
EP2536735B1 (en) 2010-02-19 2018-08-01 Dow Global Technologies LLC Metal-ligand complexes and catalysts
WO2012103080A1 (en) 2011-01-26 2012-08-02 Dow Global Technologies Llc Process for making a polyolefin-polysiloxane block copolymer
WO2012155022A1 (en) 2011-05-12 2012-11-15 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
JP5600219B2 (ja) 2011-10-24 2014-10-01 三菱化学株式会社 熱可塑性エラストマー組成物及びその製造方法
EP2880097B1 (en) * 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
JP6549578B2 (ja) 2013-12-19 2019-07-24 ダウ グローバル テクノロジーズ エルエルシー 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法
BR112018005199B1 (pt) 2015-09-30 2020-12-15 Dow Global Technologies Llc Processo para a preparação de uma composição, composição e processo para polimerização de pelo menos um monômero polimerizável por adição para formar uma composição de polímero
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
JP7029448B2 (ja) 2016-09-30 2022-03-03 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用な封鎖されたマルチまたはデュアルヘッド組成物、およびそれを調製するプロセス
CN109963888A (zh) 2016-09-30 2019-07-02 陶氏环球技术有限责任公司 用于制备适用于链梭移的多头或双头组合物的方法
TW201840572A (zh) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 適用於鏈梭移之多頭或雙頭組合物及其製備方法
SG11201908414YA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
JP7028885B2 (ja) 2017-03-15 2022-03-02 ダウ グローバル テクノロジーズ エルエルシー マルチブロックコポリマー形成用触媒系
BR112019019129A2 (pt) 2017-03-15 2020-04-14 Dow Global Technologies Llc sistema catalisador para formação de copolímero de múltiplos blocos
JP7179750B2 (ja) 2017-03-15 2022-11-29 ダウ グローバル テクノロジーズ エルエルシー マルチブロックコポリマー形成用触媒系
JP7101185B2 (ja) 2017-03-15 2022-07-14 ダウ グローバル テクノロジーズ エルエルシー マルチブロックコポリマー形成用触媒系
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Also Published As

Publication number Publication date
CN1233253A (zh) 1999-10-27
TR199900841T2 (xx) 1999-06-21
BR9712535A (pt) 1999-10-19
JP2001506260A (ja) 2001-05-15
KR20000049229A (ko) 2000-07-25
MY115258A (en) 2003-04-30
TW397845B (en) 2000-07-11
NO991816D0 (no) 1999-04-16
CA2265515A1 (en) 1998-06-25
CN1094129C (zh) 2002-11-13
DE69710491T2 (de) 2002-10-02
ID21507A (id) 1999-06-17
EP0946574B1 (en) 2002-02-13
WO1998027102A1 (en) 1998-06-25
ATE213250T1 (de) 2002-02-15
NO991816L (no) 1999-04-16
DE69710491D1 (de) 2002-03-21
US5959047A (en) 1999-09-28
AU726123B2 (en) 2000-11-02
EP0946574A1 (en) 1999-10-06
US5866704A (en) 1999-02-02
AU5152198A (en) 1998-07-15
RU2186073C2 (ru) 2002-07-27
AR010798A1 (es) 2000-07-12

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