JP2016523992A - フッ素化フィルム - Google Patents
フッ素化フィルム Download PDFInfo
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- JP2016523992A JP2016523992A JP2016509524A JP2016509524A JP2016523992A JP 2016523992 A JP2016523992 A JP 2016523992A JP 2016509524 A JP2016509524 A JP 2016509524A JP 2016509524 A JP2016509524 A JP 2016509524A JP 2016523992 A JP2016523992 A JP 2016523992A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1407—Greenhouses of flexible synthetic material
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/14—Greenhouses
- A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0256—Ground coverings
- A01G13/0268—Mats or sheets, e.g. nets or fabrics
- A01G13/0275—Films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/08—Homopolymers or copolymers of vinylidene chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D5/00—Roof covering by making use of flexible material, e.g. supplied in roll form
- E04D5/06—Roof covering by making use of flexible material, e.g. supplied in roll form by making use of plastics
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
- B32B2419/06—Roofs, roof membranes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Soil Sciences (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Greenhouses (AREA)
- Protection Of Plants (AREA)
- Housing For Livestock And Birds (AREA)
Abstract
Description
機械的特性、例えば−20℃から+60℃までの温度範囲での引裂強度、クリープ強度、延伸性;
光学的特性、例えば可視光の透過率、紫外線に対する耐性;
化学的耐性、特に農薬に対する耐性;
耐久性、湿熱および冷気に対する耐性;
耐熱性、内部の熱エネルギーを保ちながら温室中の赤外線を一晩反射する高い能力;
を有する必要がある。
耐火性;
曇り止め特性;
防汚性;
を示し得る。
メチルメタクリレートおよびエチルアクリレートのコポリマー製のコア、
ブチルアクリレートおよびスチレンのコポリマー製のシェル、
メチルメタクリレートおよびエチルアクリレートのコポリマー製のシェル、
からなる衝撃改良剤を挙げることができる。
メチルメタクリレートおよびエチルアクリレートのコポリマー製のコア、
ブチルアクリレートおよびスチレンのコポリマー製のシェル、
メチルメタクリレート、ブチルアクリレートおよびスチレンのコポリマー製のシェル、
メチルメタクリレートおよびエチルアクリレートのコポリマー製のシェル、
からなる衝撃改良剤も挙げられる。
押出コンパウンドは、当分野の通例に従い、温度が240℃に設定されたダイを備えた同方向回転二軸スクリュー押出機において製造される。引き続き、フィルムは、パンケーキダイ(直径50mm、ギャップ1.2mm)を有する5層式の研究室用ライン(5−layer laboratory line)でフィルムブロー成形によって製造される。引取速度は3m/分であり、ブローアップ比(BUR)は2.8である。フィルム全体の厚さは、100μmに設定される。
PE:LDPE Exxon LD165BW1、MI(190℃、2.16kg)=1。
低温引裂強度のキャラクタリゼーション:フィルムを枠に入れて、1Nの引張下に置く。この試験は、30cmの高さから、円錐形先端を有する1kgの重さのストライカーを落下させることにある。この試験は、環境調節チャンバ中で行われ、変形の延性と脆性の性質は、貫通後のフィルムに観察される破壊プロフィールから推測される。
発火源が取り除かれた後の残炎時間を計ること、
燃えたフィルムの長さおよび幅を計ること、
燃焼滴下物の存在を計ること、
にある。
Claims (15)
- ポリフッ化ビニリデン(PVDF)マトリックスと、ポリ(オルガノシロキサン)コアおよび少なくとも1つの熱可塑性シェルを有する少なくとも1種のコア−シェル衝撃改良剤を含む単層ポリマーフィルムであって、衝撃改良剤の重量基準の含有量が2.5%から40%未満である、単層ポリマーフィルム。
- 衝撃改良剤の重量基準の含有量は、5%を超え、かつ30%以下である請求項1に記載のフィルム。
- 前記PVDFマトリックスは、PVDFホモポリマーから構成されるか、またはフッ化ビニル;トリフルオロエチレン;クロロトリフルオロエチレン;1,2−ジフルオロエチレン;テトラフルオロエチレン;ヘキサフルオロプロピレン;ペルフルオロ(メチルビニル)エーテル、ペルフルオロ(エチルビニル)エーテル(PEVE)およびペルフルオロ(プロピルビニル)エーテルから選択されるペルフルオロ(アルキルビニル)エーテル;ペルフルオロ(1,3−ジオキソール)ならびにペルフルオロ(2,2−ジメチル−1,3−ジオキソール)から選択されるフッ素化コモノマーとフッ化ビニリデンの共重合によって調製されるコポリマーから構成される請求項1および2のいずれかに記載のフィルム。
- 前記ポリ(オルガノシロキサン)コアは、1個から18個の炭素、有利には1個から6個の炭素を含むアルキル基もしくはビニル基、アリール基ならびに置換された炭化水素から選択される1つ以上の基を含む請求項1から3の一項に記載のフィルム。
- 前記コアは全体的にまたは部分的に架橋されている請求項1から4の一項に記載のフィルム。
- 前記コアの平均官能化度は2から3である請求項5に記載のフィルム。
- 前記シェルは、アルキルアクリレートもしくはメタクリレート、アクリロニトリル、スチレン、ビニルスチレン、ビニルプロピオネート、マレイミド、塩化ビニル、エチレン、ブタジエン、イソプレンおよびクロロプレンから選択されるモノマーから形成されるポリマーまたはコポリマーである請求項1から6の一項に記載のフィルム。
- 前記シェルは、スチレン、アルキルスチレンもしくはメチルメタクリレートのホモポリマーであるか、または少なくとも70モル%のこれらのモノマーの1種と、残りのモノマー、別のアルキル(メタ)アクリレート、ビニルアセテートおよびアクリロニトリルから選択される少なくとも1種のコモノマーを含むコポリマーである請求項7に記載のフィルム。
- 30ミクロンから200ミクロン、好ましくは80ミクロンから150ミクロンの厚さを有する請求項1から8のいずれか一項に記載のフィルム。
- 前記衝撃改良剤中の前記コアの割合は0.05重量%から90重量%であり、好ましくは60重量%から80重量%である請求項1から9のいずれか一項に記載のフィルム。
- 艶消し剤、赤外線反射剤、乳白剤、可塑剤または真珠光沢顔料から選択される少なくとも1種の添加剤を含む請求項1から10のいずれか一項に記載のフィルム。
- 請求項1から11のいずれか一項に記載のフィルムの少なくとも1層と、少なくとも1層のPVDF層を含む多層フィルム。
- 請求項1から11の一項に記載の1層の内層と、2層のPVDFの外層からなり、前記外層が同一または異なる構造を有する請求項12に記載のフィルム。
- 農業用カバー材料、特に温室用カバーとしての、請求項1から11の一項に記載のフィルムまたは請求項12および13のいずれかに記載のフィルムの使用。
- 建造物、特に農業用建造物、例えば家畜用建造物の屋根および/またはファサードのためのフィルムの製造のための材料としての、請求項1から11の一項に記載のフィルムまたは請求項12および13のいずれかに記載のフィルムの使用。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1353672 | 2013-04-23 | ||
FR1353672A FR3004714B1 (fr) | 2013-04-23 | 2013-04-23 | Film fluore |
FR1452980A FR3004715B1 (fr) | 2013-04-23 | 2014-04-03 | Film fluore |
FR1452980 | 2014-04-03 | ||
PCT/FR2014/050965 WO2014174197A1 (fr) | 2013-04-23 | 2014-04-22 | Film fluore |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016523992A true JP2016523992A (ja) | 2016-08-12 |
JP6420316B2 JP6420316B2 (ja) | 2018-11-07 |
Family
ID=48782422
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016509524A Active JP6420316B2 (ja) | 2013-04-23 | 2014-04-22 | フッ素化フィルム |
Country Status (8)
Country | Link |
---|---|
US (1) | US20160095282A1 (ja) |
EP (1) | EP2988934B1 (ja) |
JP (1) | JP6420316B2 (ja) |
KR (1) | KR102173664B1 (ja) |
CN (1) | CN105189116A (ja) |
CA (1) | CA2909485C (ja) |
FR (2) | FR3004714B1 (ja) |
WO (1) | WO2014174197A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3268429B1 (en) * | 2015-03-11 | 2021-07-21 | Arkema, Inc. | High impact blends of vinylidene fluoride-containing polymers |
JP6712445B2 (ja) * | 2015-05-27 | 2020-06-24 | 株式会社バルカー | 熱可塑性フッ素樹脂組成物、及び架橋体の製造方法 |
JP6942692B2 (ja) * | 2016-04-08 | 2021-09-29 | デンカ株式会社 | 農業用フッ素系樹脂フィルム及び農業用被覆資材 |
JP7084869B2 (ja) * | 2016-05-25 | 2022-06-15 | デンカ株式会社 | 農業用フッ素含有積層フィルム及びそれを用いてなる農業用被覆資材 |
WO2017204191A1 (ja) * | 2016-05-25 | 2017-11-30 | デンカ株式会社 | 農業用フッ素系樹脂フィルム及び農業用被覆資材 |
CN107573621B (zh) * | 2017-09-12 | 2021-03-16 | 苏州固泰新材股份有限公司 | 一种含核壳橡胶粒子的pvdf拉伸膜 |
WO2019219789A1 (en) | 2018-05-17 | 2019-11-21 | Solvay Specialty Polymers Italy S.P.A. | Flexible vdf polymers |
EP3867055A4 (en) * | 2018-10-18 | 2022-08-10 | Trinseo Europe GmbH | LIGHT DIFFUSER FOR HORTICULTURAL LIGHTING |
CN110116508A (zh) * | 2019-04-19 | 2019-08-13 | 苏州亨利通信材料有限公司 | 用于电缆的铝塑复合带加工方法 |
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WO2006046811A1 (en) * | 2004-10-25 | 2006-05-04 | Lg Chem, Ltd. | Silicone-acrylic impact modifier having improved colorability and thermoplastic resin composition comprising the same |
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KR100838451B1 (ko) * | 2005-12-30 | 2008-06-16 | 제일모직주식회사 | 내열도가 높고, 내충격성이 우수한 난연성 폴리카보네이트수지 조성물 |
DE102007007336A1 (de) * | 2007-02-14 | 2008-08-21 | Wacker Chemie Ag | Redispergierbare Kern-Schale Polymere und ein Verfahren zu deren Herstellung |
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WO2011068081A1 (ja) * | 2009-12-02 | 2011-06-09 | ユニチカ株式会社 | ポリ乳酸系樹脂組成物、成形体およびポリ乳酸系マスターバッチペレット |
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Also Published As
Publication number | Publication date |
---|---|
CA2909485A1 (fr) | 2014-10-30 |
FR3004714B1 (fr) | 2015-12-18 |
KR20160004327A (ko) | 2016-01-12 |
CA2909485C (fr) | 2021-06-08 |
WO2014174197A1 (fr) | 2014-10-30 |
FR3004714A1 (fr) | 2014-10-24 |
US20160095282A1 (en) | 2016-04-07 |
EP2988934B1 (fr) | 2019-10-30 |
EP2988934A1 (fr) | 2016-03-02 |
FR3004715A1 (fr) | 2014-10-24 |
CN105189116A (zh) | 2015-12-23 |
JP6420316B2 (ja) | 2018-11-07 |
KR102173664B1 (ko) | 2020-11-03 |
FR3004715B1 (fr) | 2019-03-22 |
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