JP2016522844A5 - - Google Patents
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- Publication number
- JP2016522844A5 JP2016522844A5 JP2016508290A JP2016508290A JP2016522844A5 JP 2016522844 A5 JP2016522844 A5 JP 2016522844A5 JP 2016508290 A JP2016508290 A JP 2016508290A JP 2016508290 A JP2016508290 A JP 2016508290A JP 2016522844 A5 JP2016522844 A5 JP 2016522844A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- hydrogen
- formula
- halide
- transition metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910052739 hydrogen Inorganic materials 0.000 claims 19
- 239000001257 hydrogen Substances 0.000 claims 19
- 239000010936 titanium Substances 0.000 claims 16
- 239000003054 catalyst Substances 0.000 claims 14
- 150000002431 hydrogen Chemical class 0.000 claims 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 12
- 238000000034 method Methods 0.000 claims 11
- 229910052723 transition metal Inorganic materials 0.000 claims 11
- 150000003624 transition metals Chemical class 0.000 claims 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 10
- 125000000217 alkyl group Chemical group 0.000 claims 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 9
- 150000004820 halides Chemical class 0.000 claims 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 9
- 239000007788 liquid Substances 0.000 claims 8
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical class OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 claims 8
- -1 alkali metal salt Chemical class 0.000 claims 7
- 239000003446 ligand Substances 0.000 claims 7
- 229910052719 titanium Inorganic materials 0.000 claims 7
- 239000004215 Carbon black (E152) Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- 229930195733 hydrocarbon Natural products 0.000 claims 6
- 150000002430 hydrocarbons Chemical class 0.000 claims 6
- 239000011572 manganese Substances 0.000 claims 6
- 239000010955 niobium Substances 0.000 claims 6
- 239000002243 precursor Substances 0.000 claims 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 5
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 5
- 150000001336 alkenes Chemical class 0.000 claims 5
- 125000003545 alkoxy group Chemical group 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 5
- 125000004104 aryloxy group Chemical group 0.000 claims 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 5
- 229910052736 halogen Inorganic materials 0.000 claims 5
- 150000002367 halogens Chemical class 0.000 claims 5
- 125000001072 heteroaryl group Chemical group 0.000 claims 5
- 150000002466 imines Chemical class 0.000 claims 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims 4
- 239000011707 mineral Substances 0.000 claims 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- 229910052783 alkali metal Inorganic materials 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229910052735 hafnium Inorganic materials 0.000 claims 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 3
- 229910052748 manganese Inorganic materials 0.000 claims 3
- 229910052758 niobium Inorganic materials 0.000 claims 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 3
- 229910052702 rhenium Inorganic materials 0.000 claims 3
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 3
- 235000015096 spirit Nutrition 0.000 claims 3
- 229910052715 tantalum Inorganic materials 0.000 claims 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 3
- 229910052721 tungsten Inorganic materials 0.000 claims 3
- 239000010937 tungsten Substances 0.000 claims 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 claims 2
- 239000002262 Schiff base Substances 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 2
- 238000005468 ion implantation Methods 0.000 claims 2
- ZCSHNCUQKCANBX-UHFFFAOYSA-N lithium diisopropylamide Chemical compound [Li+].CC(C)[N-]C(C)C ZCSHNCUQKCANBX-UHFFFAOYSA-N 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 2
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 claims 1
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 claims 1
- RRIQVLZDOZPJTH-UHFFFAOYSA-N 3,5-di-tert-butyl-2-hydroxybenzaldehyde Chemical compound CC(C)(C)C1=CC(C=O)=C(O)C(C(C)(C)C)=C1 RRIQVLZDOZPJTH-UHFFFAOYSA-N 0.000 claims 1
- ROILLNJICXGZQQ-UHFFFAOYSA-N 3-tert-butyl-2-hydroxybenzaldehyde Chemical compound CC(C)(C)C1=CC=CC(C=O)=C1O ROILLNJICXGZQQ-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 150000004984 aromatic diamines Chemical class 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- YGGXZTQSGNFKPJ-UHFFFAOYSA-N methyl 2-naphthalen-1-ylacetate Chemical compound C1=CC=C2C(CC(=O)OC)=CC=CC2=C1 YGGXZTQSGNFKPJ-UHFFFAOYSA-N 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 239000012041 precatalyst Substances 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 239000012312 sodium hydride Substances 0.000 claims 1
- 229910000104 sodium hydride Inorganic materials 0.000 claims 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN1440/MUM/2013 | 2013-04-17 | ||
| PCT/IN2014/000234 WO2014170913A2 (en) | 2013-04-17 | 2014-04-15 | A novel transition metal based pro-catalyst and a process for its preparation |
| IN1440MU2013 IN2013MU01440A (cg-RX-API-DMAC10.html) | 2013-04-17 | 2014-04-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016522844A JP2016522844A (ja) | 2016-08-04 |
| JP2016522844A5 true JP2016522844A5 (cg-RX-API-DMAC10.html) | 2017-06-01 |
| JP6306150B2 JP6306150B2 (ja) | 2018-04-04 |
Family
ID=51731930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016508290A Active JP6306150B2 (ja) | 2013-04-17 | 2014-04-15 | 遷移金属を応用した画期的前駆触媒およびその調製プロセス |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9611345B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP2986622B2 (cg-RX-API-DMAC10.html) |
| JP (1) | JP6306150B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR102038180B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN105229018B (cg-RX-API-DMAC10.html) |
| BR (1) | BR112015026360A2 (cg-RX-API-DMAC10.html) |
| IN (1) | IN2013MU01440A (cg-RX-API-DMAC10.html) |
| SA (1) | SA515370008B1 (cg-RX-API-DMAC10.html) |
| WO (1) | WO2014170913A2 (cg-RX-API-DMAC10.html) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105263972A (zh) | 2013-05-26 | 2016-01-20 | 瑞来斯实业有限公司 | 高强度聚乙烯产品及其制备方法 |
| CN104437647A (zh) * | 2014-12-01 | 2015-03-25 | 昆明学院 | 一种制备功能材料的方法 |
| US10030121B2 (en) * | 2015-04-01 | 2018-07-24 | Reliance Industries Limited | Catalyst composition and process for obtaining a colored olefin polymer |
| WO2017130103A1 (en) * | 2016-01-25 | 2017-08-03 | Reliance Industries Limited | Process for preparing a transition metal-schiff base imine ligand complex |
| CN108456233B (zh) * | 2017-02-20 | 2019-12-24 | 中国石油化工股份有限公司 | 一种双席夫碱类铁配合物及其应用和一种制备共轭二烯烃聚合物的方法 |
| CN107298727B (zh) * | 2017-06-28 | 2019-07-26 | 青岛科技大学 | 一种双水杨醛亚胺-蒽双金属钛催化剂的制备与应用 |
| CN107899614B (zh) * | 2017-11-20 | 2020-05-26 | 常州大学 | 一种双核占吨桥连胺基-吡啶镍催化剂及其制备方法和应用 |
| CN111116408B (zh) * | 2018-10-31 | 2022-12-13 | 中国石油化工股份有限公司 | 胺基亚胺配体、胺基亚胺配合物及其应用 |
| CN110013877B (zh) * | 2019-03-01 | 2020-03-10 | 东北石油大学 | 一种席夫碱配体共价接枝碳纳米管负载后过渡金属烯烃聚合催化剂及其制备方法 |
| CA3122825C (en) * | 2020-06-23 | 2024-03-19 | Indian Oil Corporation Limited | Process for producing ultrahigh molecular weight polymer in powder form |
| CN112538098B (zh) * | 2020-12-08 | 2021-11-26 | 中山大学 | 一种α-磺酸-β-二亚胺镍配合物、制备方法及其在催化烯烃聚合中的应用 |
| CN112851712A (zh) * | 2020-12-29 | 2021-05-28 | 晨茵科创(天津)有限公司 | 一种三齿[ono]钨配位化合物及其光学应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0521099T3 (da) * | 1990-03-21 | 1998-09-07 | Res Corp Technologies Inc | Chirale katalysatorer og epoxidationsreaktioner katalyseret derved |
| US5637739A (en) | 1990-03-21 | 1997-06-10 | Research Corporation Technologies, Inc. | Chiral catalysts and catalytic epoxidation catalyzed thereby |
| TWI246520B (en) * | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
| US6545108B1 (en) * | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
| CN1251842A (zh) * | 1999-11-11 | 2000-05-03 | 中国石油化工集团公司 | 非茂类钛金属聚烯烃催化剂的制备及应用 |
| CN1138791C (zh) * | 2000-03-28 | 2004-02-18 | 中国石油化工股份有限公司 | 非茂类锆金属化合物及其制备与在烯烃聚合中的应用 |
| JP2003268030A (ja) * | 2002-03-18 | 2003-09-25 | Mitsui Chemicals Inc | オレフィン重合用触媒およびオレフィンの重合方法 |
| KR100843598B1 (ko) * | 2005-11-28 | 2008-07-03 | 주식회사 엘지화학 | 새로운 이핵 전이금속 화합물, 상기 화합물을 포함하는촉매 조성물, 올레핀 중합체 제조 방법, 상기 방법으로제조된 올레핀 중합체 |
| CN101089006B (zh) | 2006-06-12 | 2011-08-10 | 华东理工大学 | 芳基桥联的水杨醛二亚胺类双核化合物及制备方法和应用 |
| CN101280031B (zh) | 2007-04-06 | 2010-05-19 | 中国石油化工股份有限公司 | 用于制备双峰或宽分布聚乙烯的催化剂体系及其应用 |
| JP5490372B2 (ja) * | 2007-04-26 | 2014-05-14 | 三洋化成工業株式会社 | 結晶性ポリオキシアルキレンポリオールの製造方法およびこれを原料とした樹脂 |
| EP2014445A1 (en) * | 2007-07-09 | 2009-01-14 | Teijin Aramid B.V. | Polyethylene film with high tensile strength and high tensile energy to break |
| EP2313736B1 (en) * | 2008-07-17 | 2019-01-23 | Teijin Aramid B.V. | Ballistic resistant articles comprising elongate bodies |
| WO2010139720A1 (en) | 2009-06-04 | 2010-12-09 | Teijin Aramid B.V. | Process for manufacturing ultra-high molecular weight polyethylene catalyst |
| CN101659628B (zh) | 2009-09-09 | 2012-09-12 | 重庆大学 | 一种钛金属配合物、制备方法及用途 |
| HUE034931T2 (en) | 2011-08-05 | 2018-03-28 | Total Res & Technology Feluy | Catalysts for the production of ultra high molecular weight polyethylene (UHMWPE) |
| WO2013034582A1 (en) | 2011-09-05 | 2013-03-14 | Stichting Dutch Polymer Institute | Process for the melt extrusion of ultra high molecular weight polyethylene |
| EP2766402A2 (en) * | 2011-10-10 | 2014-08-20 | Reliance Industries Limited | A process for synthesis of ethylene polymers |
| EP2812362B1 (en) | 2012-02-08 | 2017-08-09 | Reliance Industries Limited | Immobilization of single site catalyst on inorganic oxide support for preparation of uhmwpe |
| WO2014045303A2 (en) | 2012-09-10 | 2014-03-27 | Reliance Industries Limited | Disentangled ultra high molecular weight polyethylene graft co-polymers and a process for preparation thereof |
| CN102936301B (zh) | 2012-11-07 | 2015-04-22 | 复旦大学 | 三齿席夫碱钛基烯烃聚合催化剂及其制备方法和应用 |
| EP2907829B1 (en) | 2014-02-13 | 2020-08-19 | Borealis AG | Disentangled high or ultrahigh molecular weight polyethylene prepared with Ziegler-Natta catalyst |
-
2014
- 2014-04-15 US US14/785,306 patent/US9611345B2/en active Active
- 2014-04-15 KR KR1020157031814A patent/KR102038180B1/ko not_active Expired - Fee Related
- 2014-04-15 JP JP2016508290A patent/JP6306150B2/ja active Active
- 2014-04-15 IN IN1440MU2013 patent/IN2013MU01440A/en unknown
- 2014-04-15 WO PCT/IN2014/000234 patent/WO2014170913A2/en not_active Ceased
- 2014-04-15 CN CN201480021747.3A patent/CN105229018B/zh active Active
- 2014-04-15 EP EP14784688.5A patent/EP2986622B2/en active Active
- 2014-04-15 BR BR112015026360A patent/BR112015026360A2/pt active Search and Examination
-
2015
- 2015-10-15 SA SA515370008A patent/SA515370008B1/ar unknown
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