JP2016509086A - 硬化性シリコーン組成物、導電性シリコーン接着剤、これらの製造及び使用方法、並びにこれらを含有する電気装置 - Google Patents
硬化性シリコーン組成物、導電性シリコーン接着剤、これらの製造及び使用方法、並びにこれらを含有する電気装置 Download PDFInfo
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- JP2016509086A JP2016509086A JP2015549503A JP2015549503A JP2016509086A JP 2016509086 A JP2016509086 A JP 2016509086A JP 2015549503 A JP2015549503 A JP 2015549503A JP 2015549503 A JP2015549503 A JP 2015549503A JP 2016509086 A JP2016509086 A JP 2016509086A
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- silicone composition
- curable silicone
- curable
- silver
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- 238000001374 small-angle light scattering Methods 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- CAAPVQVUCVXKKS-UHFFFAOYSA-N triethyl(2-methylbut-3-yn-2-yloxy)silane Chemical compound CC[Si](CC)(CC)OC(C)(C)C#C CAAPVQVUCVXKKS-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 description 1
- ASEGJSMHCHEQSA-UHFFFAOYSA-N trimethoxy(undec-10-enyl)silane Chemical compound CO[Si](OC)(OC)CCCCCCCCCC=C ASEGJSMHCHEQSA-UHFFFAOYSA-N 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- VEDJZFSRVVQBIL-UHFFFAOYSA-N trisilane Chemical compound [SiH3][SiH2][SiH3] VEDJZFSRVVQBIL-UHFFFAOYSA-N 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
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Abstract
Description
Claims (15)
- 硬化性オルガノシロキサン組成物と、銀と、少なくとも1つの銀以外の導電性金属と、を含む硬化性シリコーン組成物であって、前記硬化性シリコーン組成物が、50から60重量パーセント未満の全銀濃度及びTI試験方法に従って測定された3〜10に調節可能なチクソ性指数を特徴とし、一方、前記硬化性シリコーン組成物中の導電性金属の全濃度を72重量パーセント以上に増加させずに、体積抵抗率試験方法に従って測定された0.001オームセンチメートル未満の体積抵抗率を有する導電性シリコーン接着剤への硬化性を保つ、硬化性シリコーン組成物。
- 硬化性シリコーン組成物の重量に基づき、4.0〜20重量パーセントの濃度の炭化水素溶媒であって、100〜360摂氏度の沸点を特徴とする炭化水素溶媒と、
硬化性シリコーン組成物の重量に基づき、10〜40重量パーセントの濃度の硬化性オルガノシロキサン組成物と、
銀粒子、銀コーティングされたコア粒子、及びカーボンナノチューブの組み合わせから本質的になる導電性充填材であって、全て硬化性シリコーン組成物の重量に基づき、銀の全濃度が50から60重量パーセント未満であり、カーボンナノチューブが0を超え5.0重量パーセントまでの濃度である、導電性充填材と、の成分のブレンドを含む硬化性シリコーン組成物であって、
前記硬化性シリコーン組成物の全成分の全濃度が100.0重量パーセントであり、
前記硬化性シリコーン組成物が、TI試験方法に従って測定された少なくとも3のチクソ性指数(η1/η10)を特徴とし、
前記硬化性シリコーン組成物が、体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、硬化性シリコーン組成物。 - 前記炭化水素溶媒が、150摂氏度を超える初留点及び300摂氏度未満の終留点を有し、前記炭化水素溶媒が、前記硬化性シリコーン組成物の重量に基づき、5〜15重量パーセントの濃度である、
前記硬化性オルガノシロキサン組成物が、少なくとも1つのジオルガノシロキサン化合物と、触媒と、接着促進剤と、を含み、前記少なくとも1つのジオルガノシロキサン化合物が、分子当たり平均して少なくとも1つの反応性部分を有し、各反応性部分が、独立して、アルケニル部分、Si−H部分、Si−OH部分、Si−OR部分であり、式中、Rは、(C1〜C10)ヒドロカルビル、−C(O)(C1〜C10)ヒドロカルビル、又は−N=CR1R2であり、R1及びR2はそれぞれ独立して、(C1〜C10)ヒドロカルビルであり、又は、R1及びR2を合わせて(C2〜C10)ヒドロカルビレンを形成し、前記少なくとも1つのジオルガノシロキサン化合物が、前記硬化性オルガノシロキサン組成物の少なくとも50重量パーセントである、
全て前記硬化性シリコーン組成物の重量に基づき、銀粒子の濃度が42〜55重量パーセントであり、銀コーティングされたコア粒子の濃度が15〜25重量パーセントであり、銀の全濃度が50.5〜59.4重量パーセントである、
前記銀コーティングされたコア粒子中の銀の濃度が、前記銀コーティングされたコア粒子の重量に基づき、2〜58重量パーセントである、
カーボンナノチューブの濃度が、前記硬化性シリコーン組成物の重量に基づき、0.1〜2.9重量パーセントである、
前記硬化性シリコーン組成物が、TI試験方法に従って測定された3〜10のチクソ性指数(η1/η10)を特徴とする、並びに、
前記硬化性シリコーン組成物が、前記体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、によって限定することを特徴とする、請求項2に記載の硬化性シリコーン組成物。 - 前記炭化水素溶媒がアルカン混合物である、
前記硬化性オルガノシロキサン組成物が、少なくとも1つのジオルガノシロキサン化合物と、少なくとも1つのオルガノハイドロジェンシリコン化合物と、ヒドロシリル化触媒と、エポキシ官能性接着促進剤と、を含み、前記少なくとも1つのジオルガノシロキサン化合物が、分子当たり平均して少なくとも1つのアルケニル部分を有し、前記オルガノハイドロジェンシリコン化合物が、分子当たり平均して少なくとも1つのSi−H部分を有し、前記少なくとも1つのジオルガノシロキサン化合物が前記硬化性オルガノシロキサン組成物の60〜80重量%である、
全て前記硬化性シリコーン組成物の重量に基づき、銀粒子の濃度が45〜55重量パーセントであり、銀コーティングされたコア粒子の濃度が16〜22重量パーセントであり、銀の全濃度が50.7〜59.4重量パーセントである、
前記銀コーティングされたコア粒子中の銀の濃度が、前記銀コーティングされたコア粒子の重量に基づき、10〜45重量パーセントである、
前記カーボンナノチューブが、シングルウォールカーボンナノチューブ、マルチウォールカーボンナノチューブ、誘導体化カーボンナノチューブ、又はシングルウォールカーボンナノチューブ、マルチウォールカーボンナノチューブ、及び誘導体化カーボンナノチューブのうち任意の2つ以上の組み合わせであり、カーボンナノチューブの濃度が、前記硬化性シリコーン組成物の重量に基づき、0.4〜2.5重量パーセントである、並びに、
前記硬化性シリコーン組成物が、体積抵抗率試験方法に従って測定された0.00090オームセンチメートル未満の体積抵抗率を特徴とする、によって限定することを特徴とする、請求項2又は3に記載の硬化性シリコーン組成物。 - 前記アルカン混合物が、少なくとも2つの(C9〜C12)イソアルカン、少なくとも2つの(C12〜C16)イソアルカン、又は、少なくとも2つの(C16〜C22)イソアルカンを含む、イソアルカン混合物であり、前記炭化水素溶媒が、前記硬化性シリコーン組成物の重量に基づき、5〜14重量パーセントの濃度である、
前記硬化性オルガノシロキサン組成物がヒドロシリル硬化性であり、前記少なくとも1つのジオルガノシロキサン化合物と、前記少なくとも1つのトリメチルシロキシ末端ジメチルオルガノハイドロジェンシリコン化合物と、マイクロカプセル化ヒドロシリル化触媒と、ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤と、を含み;前記ジオルガノシロキサンのアルケニルがビニルであり、前記少なくとも1つのジオルガノシロキサン化合物が、分子当たり平均して少なくとも1.1個のビニル部分を有し、前記少なくとも1つのトリメチルシロキシ末端ジメチルオルガノハイドロジェンシリコン化合物が、分子当たり平均して少なくとも1.1個のSi−H部分を有し、又は、前記少なくとも1つのジオルガノシロキサン化合物が、分子当たり平均して少なくとも1.1個のビニル部分を有し、前記少なくとも1つのオルガノハイドロジェンシリコン化合物が、分子当たり平均して少なくとも1.1個のSi−H部分を有し;ビニル部分を有する前記少なくとも1つのジオルガノシロキサン化合物が、前記硬化性オルガノシロキサン組成物の70〜78重量%であり;前記少なくとも1つのオルガノハイドロジェンシリコン化合物が1〜5重量パーセントであり、前記マイクロカプセル化ヒドロシリル化触媒が10〜15重量パーセントであり、前記ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤が0.1〜10重量パーセントであり、前記オルガノハイドロジェンシリコン化合物、前記マイクロカプセル化ヒドロシリル化触媒、及び前記ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤を合わせて、前記硬化性オルガノシロキサン組成物の20〜30重量%である、
全て前記硬化性シリコーン組成物の重量に基づき、銀粒子の濃度が48〜52重量パーセントであり、銀コーティングされたコア粒子の濃度が16〜20重量パーセントであり、銀の全濃度が54〜59.0重量パーセントである、
前記銀コーティングされたコア粒子中の銀の濃度が、前記銀コーティングされたコア粒子の重量に基づき、12〜43重量パーセントである、
前記銀コーティングされたコア粒子において、前記コアが、アルミニウム;石英ガラス;炭素;セラミックス;銅;鉄;リチウム;モリブデン;ニッケル;有機ポリマー;パラジウム;白金;シリカ;スズ;タングステン;亜鉛;又は、アルミニウム、銅、鉄、リチウム、モリブデン、ニッケル、パラジウム、白金、スズ、タングステン、及び亜鉛のうち任意の2つ以上の合金;又は、アルミニウム;石英ガラス;炭素;セラミックス;銅;鉄;リチウム;モリブデン;ニッケル;有機ポリマー;パラジウム;白金;シリカ;スズ;タングステン;亜鉛;及び前記合金のうち任意の2つ以上の物理的ブレンドである、
前記カーボンナノチューブの濃度が、前記硬化性シリコーン組成物の重量に基づき、0.6〜2.3重量パーセントである、並びに、
前記硬化性シリコーン組成物が、前記体積抵抗率試験方法に従って測定された0.00080オームセンチメートル未満の体積抵抗率を特徴とする、によって限定することを特徴とする、請求項2〜4のいずれか一項に記載の硬化性シリコーン組成物。 - 少なくとも3つの(C12〜C16)イソアルカンを含むイソアルカン混合物であって、210摂氏度を超える初留点及び270摂氏度未満の終留点を有し、前記炭化水素溶媒が、硬化性シリコーン組成物の重量に基づき、6〜11重量パーセントの濃度である、イソアルカン混合物と、
ヒドロシリル硬化性ポリジメチルシロキサン組成物であって、分子当たり平均して少なくとも1つのビニル部分を有する少なくとも1つのビニル官能性ポリジメチルシロキサン化合物と、分子当たり平均して少なくとも1.1個のSi−H部分を有する少なくとも1つのトリメチルシロキシ末端ジメチルメチルハイドロジェンシリコン化合物と、マイクロカプセル化白金ヒドロシリル化触媒と、ビス(α,ω−グリシドキシアルキル−D3〜D6アルキル,ハイドロジェンシクロシロキサン)と、ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤と、を含み;前記ビニル官能性ポリジメチルシロキサン化合物が前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の70〜78重量パーセントであり、前記トリメチルシロキシ末端ジメチルメチルハイドロジェンシリコン化合物が前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の1〜5重量パーセントであり、前記マイクロカプセル化ヒドロシリル化触媒が前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の10〜15重量パーセントであり、前記ビス(α,ω−グリシドキシアルキル−D3〜D6アルキル,ハイドロジェンシクロシロキサン)が前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の0〜7重量パーセントであり、前記ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤が前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の1〜10重量パーセントであり;前記トリメチルシロキシ末端ジメチルメチルハイドロジェンシリコン化合物、前記マイクロカプセル化ヒドロシリル化触媒、前記ビス(α,ω−グリシドキシアルキル−D3〜D6アルキル,ハイドロジェンシクロシロキサン)、及び前記ビス(α,ω−グリシドキシアルキル)−ジアルキル/(アルキル,アルケニル)シロキサン接着促進剤を合わせて前記ヒドロシリル硬化性ポリジメチルシロキサン組成物の20〜30重量%である、ヒドロシリル硬化性ポリジメチルシロキサン組成物と、
銀粒子、銀コーティングされたニッケル粒子、及びマルチウォールカーボンナノチューブの組み合わせから本質的になる導電性充填材であって、前記銀粒子が銀フレークであり、全て硬化性シリコーン組成物の重量に基づき、銀フレークの濃度が40〜51重量パーセントであり、銀コーティングされたニッケル粒子の濃度が17〜32重量パーセントであり、銀の全濃度が54.0〜59.0重量パーセントであり;前記銀コーティングされたニッケル粒子中の銀の濃度が、前記銀コーティングされたニッケル粒子の重量に基づき、28〜42重量パーセントであり;前記マルチウォールカーボンナノチューブが硬化性シリコーン組成物の重量に基づき、0.3〜2.2重量パーセントの濃度である、導電性充填材と、の成分のブレンドを含む硬化性シリコーン組成物であって、
前記硬化性シリコーン組成物が、TI試験方法に従って測定された3〜7のチクソ性指数(η1/η10)を特徴とし、
前記硬化性シリコーン組成物が、体積抵抗率試験方法に従って測定された0.00070オームセンチメートル未満の体積抵抗率を特徴とする、硬化性シリコーン組成物。 - 非導電性粒子を更に含む、請求項1〜6のいずれか一項に記載の硬化性シリコーン組成物。
- 前記硬化性シリコーン組成物が、銀粒子、銀コーティングされたコア粒子、及びカーボンナノチューブ以外の導電性充填材を欠く、請求項1〜7のいずれか一項に記載の硬化性シリコーン組成物。
- 請求項1〜8のいずれか一項に記載の硬化性シリコーン組成物の硬化生成物である導電性シリコーン接着剤であって、体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、導電性シリコーン接着剤。
- 剥離抵抗性試験方法に従って石英ガラス基材で測定するとき、少なくとも0.3ニュートンの接着強度を特徴とする、請求項9に記載の導電性シリコーン接着剤。
- 対向面を有する第1電気部品及び第2電気部品と、前記第1電気部品及び第2電気部品の間に、前記対向面と動作可能に接触するよう接着して配置された請求項9又は10に記載の導電性シリコーン接着剤と、を備える電気装置であって、前記第1電気部品及び第2電気部品が、前記導電性シリコーン接着剤を介して互いに電気作動的に連通するように配置され、前記導電性シリコーン接着剤が、体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、電気装置。
- 表面を有する第1電気部品及び第2電気部品と、導電性シリコーン接着剤と、を備える、電気装置の製造方法であって、前記方法が、請求項1〜8のいずれか一項に記載の硬化性シリコーン組成物を、前記第1電気部品及び第2電気部品の一方の又は両方の面に堆積させる工程と、前記第1電気部品及び第2電気部品を、これらの表面が互いに向かい合うように方向付け、前記第1電気部品及び第2電気部品の間に、前記対向面と物理的に接触して配置される、前記硬化性シリコーン組成物を含むプレアセンブリを得る工程と、前記第1電気部品及び第2電気部品の対向面の間の前記硬化性シリコーン組成物を硬化して、前記第1電気部品及び第2電気部品が、前記導電性シリコーン接着剤を介して互いに電気作動的に連通するように配置されるように、前記第1電気部品及び第2電気部品と、前記第1電気部品及び第2電気部品の間に、前記対向面と動作可能に接触するよう接着して配置された導電性シリコーン接着剤と、を備える電気装置を得る工程と、を含み、前記導電性シリコーン接着剤が、体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、方法。
- 前記方法が、第1及び第2電気装置を、記載したように、異なる堆積条件又は硬化条件下で製造する工程を含み、前記第1電気装置の製造方法が、第1堆積条件及び第1硬化条件を使用し、かつ、レオロジー及び/又は導電率を調節する前の硬化性シリコーン組成物を使用し、前記第2電気装置の製造方法が、第2堆積条件及び第2硬化条件を使用し、かつ、前記第2堆積条件及び/又は第2硬化条件下で使用するためにレオロジーが調節された、導電率が調節された、又はレオロジー及び導電率が調節された後の前記硬化性シリコーン組成物を使用し、前記第1堆積条件若しくは第2堆積条件が互いに異なり、前記第1硬化条件及び第2硬化条件が同じである若しくは互いに異なる、又はその両方であり、それぞれの導電性シリコーン接着剤が、体積抵抗率試験方法に従って測定された0.0010オームセンチメートル未満の体積抵抗率を特徴とする、請求項12に記載の方法。
- 前記レオロジーが、レオロジー調節前後のチクソ性指数(η1/η10)値がそれぞれ3〜10であり、互いに少なくとも0.3異なるように、導電性コアの全濃度を上げずに調節される、請求項13に記載の方法。
- 第1硬化性シリコーン組成物の第1バッチの前記堆積及び/又は前記硬化が第1製造条件下で行われ、第2硬化性シリコーン組成物の前記堆積及び/又は前記硬化が第2製造条件で行われ、前記第1製造条件及び第2製造条件が、前記第1硬化性シリコーン組成物及び第2硬化性シリコーン組成物の温度、前記第1硬化性シリコーン組成物及び第2硬化性シリコーン組成物の流速、前記第1硬化性シリコーン組成物及び第2硬化性シリコーン組成物の硬化時間、それぞれ前記第1硬化性シリコーン組成物及び第2硬化性シリコーン組成物と接触するときの基材の向き、並びに、第1基材及び第2基材の表面の化学組成又は構造のうち、少なくとも1つにおいて互いに異なる、請求項13又は14に記載の製造方法。
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CN104854176B (zh) | 2017-06-06 |
CN104854176A (zh) | 2015-08-19 |
US9441086B2 (en) | 2016-09-13 |
US20150315437A1 (en) | 2015-11-05 |
KR20150096674A (ko) | 2015-08-25 |
JP6355646B2 (ja) | 2018-07-11 |
EP2935429A1 (en) | 2015-10-28 |
WO2014099639A1 (en) | 2014-06-26 |
EP2935429B1 (en) | 2018-11-07 |
KR102132587B1 (ko) | 2020-07-10 |
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