JP2016507864A5 - - Google Patents
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- JP2016507864A5 JP2016507864A5 JP2015549753A JP2015549753A JP2016507864A5 JP 2016507864 A5 JP2016507864 A5 JP 2016507864A5 JP 2015549753 A JP2015549753 A JP 2015549753A JP 2015549753 A JP2015549753 A JP 2015549753A JP 2016507864 A5 JP2016507864 A5 JP 2016507864A5
- Authority
- JP
- Japan
- Prior art keywords
- ions
- mol
- molar ratio
- cathode
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010406 cathode material Substances 0.000 claims description 17
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 239000011263 electroactive material Substances 0.000 claims description 4
- 239000002114 nanocomposite Substances 0.000 claims description 4
- 239000010450 olivine Substances 0.000 claims description 4
- 229910052609 olivine Inorganic materials 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000008151 electrolyte solution Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910003002 lithium salt Inorganic materials 0.000 claims description 3
- 159000000002 lithium salts Chemical group 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 description 38
- 239000002019 doping agent Substances 0.000 description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 21
- 239000011572 manganese Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 229910021645 metal ion Inorganic materials 0.000 description 11
- 229910052742 iron Inorganic materials 0.000 description 10
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
- -1 iron ions Chemical class 0.000 description 9
- 229910001416 lithium ion Inorganic materials 0.000 description 9
- 229910001437 manganese ion Inorganic materials 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 239000002243 precursor Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000012692 Fe precursor Substances 0.000 description 1
- PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- DVATZODUVBMYHN-UHFFFAOYSA-K lithium;iron(2+);manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[Fe+2].[O-]P([O-])([O-])=O DVATZODUVBMYHN-UHFFFAOYSA-K 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910000319 transition metal phosphate Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261740575P | 2012-12-21 | 2012-12-21 | |
| US61/740,575 | 2012-12-21 | ||
| USPCT/US13/29597 | 2013-03-07 | ||
| PCT/US2013/029597 WO2014098937A1 (en) | 2012-12-21 | 2013-03-07 | Lmfp cathode materials with improved electrochemical performance |
| PCT/US2013/076780 WO2014100529A1 (en) | 2012-12-21 | 2013-12-20 | Lmfp cathode materials with improved electrochemical performance |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016507864A JP2016507864A (ja) | 2016-03-10 |
| JP2016507864A5 true JP2016507864A5 (enExample) | 2018-12-13 |
| JP6531041B2 JP6531041B2 (ja) | 2019-06-12 |
Family
ID=47901426
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015549351A Active JP6326065B2 (ja) | 2012-12-21 | 2013-03-07 | 改善された電気化学性能を有するｌｍｆｐカソード材料 |
| JP2015549753A Active JP6531041B2 (ja) | 2012-12-21 | 2013-12-20 | 改善された電気化学性能を有するｌｍｆｐカソード材料 |
| JP2017245891A Withdrawn JP2018060811A (ja) | 2012-12-21 | 2017-12-22 | 改善された電気化学性能を有するｌｍｆｐカソード材料 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015549351A Active JP6326065B2 (ja) | 2012-12-21 | 2013-03-07 | 改善された電気化学性能を有するｌｍｆｐカソード材料 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017245891A Withdrawn JP2018060811A (ja) | 2012-12-21 | 2017-12-22 | 改善された電気化学性能を有するｌｍｆｐカソード材料 |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US9793538B2 (enExample) |
| EP (2) | EP2936590B8 (enExample) |
| JP (3) | JP6326065B2 (enExample) |
| KR (2) | KR101993030B1 (enExample) |
| CN (2) | CN104885268B (enExample) |
| CA (2) | CA2894494A1 (enExample) |
| ES (2) | ES2927465T3 (enExample) |
| HU (1) | HUE063202T2 (enExample) |
| PL (1) | PL2936592T3 (enExample) |
| TW (1) | TWI556498B (enExample) |
| WO (2) | WO2014098937A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2927465T3 (es) | 2012-12-21 | 2022-11-07 | Jiangsu Hengtron Nanotech Co Ltd | Materiales cátodos LMFP con rendimiento electroquímico mejorado |
| US10147945B2 (en) * | 2013-03-08 | 2018-12-04 | Umicore | Olivine composition with improved cell performance |
| JP6239095B2 (ja) * | 2013-05-08 | 2017-11-29 | 台湾立凱電能科技股▲ふん▼有限公司 | 電池複合材料及びその前駆体の製造方法 |
| EP3180812B1 (en) * | 2014-08-13 | 2019-02-27 | Umicore | Olivine composition with improved cell performance |
| JP6341512B2 (ja) * | 2014-12-15 | 2018-06-13 | 株式会社三井Ｅ＆Ｓホールディングス | リチウムイオン二次電池用電極材料の製造方法 |
| EP3244473B1 (en) * | 2015-01-08 | 2024-06-26 | Advanced Lithium Electrochemistry Co., Ltd. | Method for preparing battery composite material and precursor thereof |
| MY186936A (en) * | 2016-04-06 | 2021-08-26 | Ube Corp | Biomass solid fuel |
| CN107359342B (zh) * | 2017-07-27 | 2019-12-24 | 泓辰电池材料有限公司 | 磷酸锂锰铁系颗粒及磷酸锂锰铁系粉体 |
| US20220069292A1 (en) | 2019-01-07 | 2022-03-03 | A123 Systems, LLC | Abuse-tolerant lithium ion battery cathode blends with symbiotic power performance benefits |
| KR20210116586A (ko) * | 2019-01-23 | 2021-09-27 | 무사시 에너지 솔루션즈 가부시키가이샤 | 전극 제조 시스템 및 전극 제조 방법 |
| CN110416525B (zh) * | 2019-08-08 | 2022-09-27 | 上海华谊（集团）公司 | 具有核壳结构的含磷酸锰铁锂的复合材料及其制备方法 |
| US11616232B2 (en) * | 2019-10-16 | 2023-03-28 | Hcm Co., Ltd. | Doped lithium manganese iron phosphate-based particulate, doped lithium manganese iron phosphate-based powdery material including the same, and method for preparing powdery material |
| CN111276693B (zh) * | 2020-01-22 | 2022-09-20 | 上海华谊（集团）公司 | 磷酸铁锰锂的改性方法、改性的磷酸铁锰锂及其用途 |
| JP2024505446A (ja) * | 2021-10-22 | 2024-02-06 | 寧徳時代新能源科技股▲分▼有限公司 | 正極活物質及び製造方法、正極板、二次電池、電池モジュール、電池パック並びに電力消費装置 |
| US20230387404A1 (en) * | 2022-05-25 | 2023-11-30 | Rivian Ip Holdings, Llc | Olivine-based cathode materials with improved conductivity |
| KR102746787B1 (ko) * | 2022-05-25 | 2024-12-26 | 후베이 알티 어드밴스드 머터리얼스 그룹 컴퍼니 리미티드 | 인산망간철리튬의 제조 방법 |
| CN115663144A (zh) * | 2022-11-04 | 2023-01-31 | 横店集团东磁股份有限公司 | 一种层状钠电正极材料及其制备方法和应用 |
| CN117012937A (zh) * | 2023-08-29 | 2023-11-07 | 湖北融通高科先进材料集团股份有限公司 | 一种钠离子电池正极材料的制备方法和应用 |
| CN117117177B (zh) * | 2023-10-20 | 2024-02-02 | 中创新航科技集团股份有限公司 | 一种电池 |
| KR20250109298A (ko) * | 2024-01-10 | 2025-07-17 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 양극활물질 및 이의 제조방법 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4461566B2 (ja) * | 2000-04-25 | 2010-05-12 | ソニー株式会社 | 正極活物質及び非水電解質電池 |
| CA2344903C (en) * | 2000-04-25 | 2013-03-05 | Sony Corporation | Positive electrode active material and non-aqueous electrolyte cell |
| JP4432203B2 (ja) * | 2000-04-25 | 2010-03-17 | ソニー株式会社 | 正極活物質及び非水電解質電池 |
| DE10117904B4 (de) | 2001-04-10 | 2012-11-15 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung | Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP2278643B1 (en) * | 2001-12-21 | 2018-03-28 | Massachusetts Institute of Technology (MIT) | Conductive lithium storage electrode |
| JP2004063422A (ja) * | 2002-07-31 | 2004-02-26 | Sony Corp | 正極活物質、並びに非水電解質電池 |
| EP1555711B1 (en) | 2002-10-22 | 2011-12-21 | Mitsubishi Chemical Corporation | Nonaqueous electrolytic solution and nonaqueous electrolyte secondary battery containing the same |
| US7842420B2 (en) | 2005-02-03 | 2010-11-30 | A123 Systems, Inc. | Electrode material with enhanced ionic transport properties |
| JP5344452B2 (ja) * | 2005-09-21 | 2013-11-20 | 関東電化工業株式会社 | 正極活物質及びその製造方法並びに正極活物質を含む正極を有する非水電解質電池 |
| US8377586B2 (en) * | 2005-10-05 | 2013-02-19 | California Institute Of Technology | Fluoride ion electrochemical cell |
| KR101320788B1 (ko) * | 2005-12-02 | 2013-10-23 | 에이일이삼 시스템즈 인코포레이티드 | 비정질 및 부분 비정질의 나노스케일 이온 저장 재료 |
| WO2008018633A1 (en) * | 2006-08-09 | 2008-02-14 | Kanto Denka Kogyo Co., Ltd. | Compound having olivine structure, method for producing the same, positive electrode active material using compound having olivine structure, and nonaqueous electrolyte battery |
| WO2009127901A1 (en) * | 2008-04-14 | 2009-10-22 | High Power Lithium S.A. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| EP2383820B1 (en) * | 2009-01-15 | 2014-03-26 | GS Yuasa International Ltd. | Positive electrode active material for lithium secondary battery, and lithium secondary battery |
| US9178215B2 (en) | 2009-08-25 | 2015-11-03 | A123 Systems Llc | Mixed metal olivine electrode materials for lithium ion batteries having improved specific capacity and energy density |
| CA2772255A1 (en) * | 2009-09-24 | 2011-03-31 | Valence Technology, Inc. | Manganese phosphates and related electrode active materials |
| DE102010006077B4 (de) * | 2010-01-28 | 2014-12-11 | Süd-Chemie Ip Gmbh & Co. Kg | Substituiertes Lithium-Mangan-Metallphosphat |
| JP5760524B2 (ja) | 2011-03-09 | 2015-08-12 | 株式会社Ｇｓユアサ | リチウム二次電池用正極活物質およびリチウム二次電池 |
| JP5736965B2 (ja) * | 2011-05-27 | 2015-06-17 | 日立金属株式会社 | リチウム二次電池用正極活物質とその製造方法、リチウム二次電池用正極、及びリチウム二次電池 |
| ES2927465T3 (es) * | 2012-12-21 | 2022-11-07 | Jiangsu Hengtron Nanotech Co Ltd | Materiales cátodos LMFP con rendimiento electroquímico mejorado |
| WO2017018633A1 (ko) | 2015-07-28 | 2017-02-02 | 주식회사 맥스젠테크놀로지 | 3d 시뮬레이션의 디자인 체험을 통한 모바일 기기 액세서리의 온라인 판매 시스템 및 이를 이용한 판매방법 |
| JP6414533B2 (ja) | 2015-10-16 | 2018-10-31 | 株式会社オートネットワーク技術研究所 | 多相コンバータ |
-
2013
- 2013-03-07 ES ES13710749T patent/ES2927465T3/es active Active
- 2013-03-07 CA CA2894494A patent/CA2894494A1/en not_active Abandoned
- 2013-03-07 EP EP13710749.6A patent/EP2936590B8/en active Active
- 2013-03-07 CN CN201380066816.8A patent/CN104885268B/zh active Active
- 2013-03-07 JP JP2015549351A patent/JP6326065B2/ja active Active
- 2013-03-07 WO PCT/US2013/029597 patent/WO2014098937A1/en not_active Ceased
- 2013-03-07 US US14/646,370 patent/US9793538B2/en active Active
- 2013-03-07 KR KR1020157016170A patent/KR101993030B1/ko active Active
- 2013-03-15 TW TW102109224A patent/TWI556498B/zh active
- 2013-12-20 CN CN201380065608.6A patent/CN104854739B/zh active Active
- 2013-12-20 CA CA2894545A patent/CA2894545C/en active Active
- 2013-12-20 PL PL13817834.8T patent/PL2936592T3/pl unknown
- 2013-12-20 KR KR1020157016172A patent/KR102157404B1/ko active Active
- 2013-12-20 HU HUE13817834A patent/HUE063202T2/hu unknown
- 2013-12-20 JP JP2015549753A patent/JP6531041B2/ja active Active
- 2013-12-20 US US14/646,372 patent/US9960413B2/en active Active
- 2013-12-20 ES ES13817834T patent/ES2957469T3/es active Active
- 2013-12-20 EP EP13817834.8A patent/EP2936592B1/en active Active
- 2013-12-20 WO PCT/US2013/076780 patent/WO2014100529A1/en not_active Ceased
-
2017
- 2017-10-10 US US15/729,607 patent/US10205158B2/en active Active
- 2017-12-22 JP JP2017245891A patent/JP2018060811A/ja not_active Withdrawn
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