JP2016506023A - 有機電子素子用基板 - Google Patents
有機電子素子用基板 Download PDFInfo
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- JP2016506023A JP2016506023A JP2015544005A JP2015544005A JP2016506023A JP 2016506023 A JP2016506023 A JP 2016506023A JP 2015544005 A JP2015544005 A JP 2015544005A JP 2015544005 A JP2015544005 A JP 2015544005A JP 2016506023 A JP2016506023 A JP 2016506023A
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- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
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- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 1
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- 229910052718 tin Inorganic materials 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
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- 238000001771 vacuum deposition Methods 0.000 description 1
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Abstract
Description
15μm ≦ n×d ≦ 200μm
<有機電子素子用基板の製造>
キャリア基板でガラスを使用して有機電子素子用基板と有機電子素子を製造した。まず、下記化学式Aの化合物(3,3'−sulfonyldianiline)及び下記化学式Bの化合物(3,3',4,4'−bipheynyltetracarboxylic dianhydride)を使用して公知のポリアミド酸(poly(amic acid))の合成方式で合成したポリアミド酸を含むコーティング液として、分子量(Mw)が、約5万程度であるコーティング液を、前記キャリア基板上に最終高分子層の厚さが約30μmになるようにコーティングした後にイミド化反応(imidization)を実行し、633nmの波長の光に対する屈折率が、約1.7〜1.8程度である基材層を形成した。
公知のスパッタリング方式で、前記第2高分子基材層上にITO(Indium Tin Oxide)を含む正孔注入性電極層を形成した。続いて、公知の素材及び方式を使用して、正孔注入層、正孔輸送層、発光層、電子輸送層、電子注入層及び電子注入性電極層を形成した。その後、ガラス缶で前記構造を封止して、有機電子装置を製作した。
光散乱層用コーティング液の製造時に散乱粒子を使用しないで、HM−150を利用してJIS K 7105方式で測定したヘイズが1%未満の層を形成したこと以外は、実施例1と同一な方式で有機電子素子用基板及び有機電子装置を製造した。
101:第1高分子基材層
102:光学機能性層
103:高屈折層
104:第1バリア層
105:第2バリア層
1021:マトリックス物質
1022:散乱性領域
1023:凹凸構造の光散乱層
401:第1電極層
402:有機層
403:第2電極層
404:缶形態の封止構造
501:フィルム形態の封止構造
502:第2基板
Claims (20)
- 第1高分子基材層と、
前記第1高分子基材層上に形成されている光学機能性層と、
前記光学機能性層上に形成されている高屈折層と、
前記第1高分子基材層または前記高屈折層の一面または両面に形成されており、633nmの波長の光に対する屈折率が1.45以上であるバリア層と、を含む有機電子素子用基板。 - 前記第1高分子基材層は、下記数式1を満足する請求項1に記載の有機電子素子用基板。
[数式1]
15μm ≦ n×d ≦ 200μm
数式1で、nは、前記第1高分子基材層の633nmの波長の光に対する屈折率であり、dは、前記第1高分子基材層の厚さである。 - 前記第1高分子基材層は、ポリアミド酸、ポリイミド、ポリエチレンナフタレート、ポリエーテルエーテルケトン、ポリカーボネート、ポリエチレンテレフタレート、ポリエーテルスルフィド、ポリスルホンアクリル樹脂、ポリスチレンまたはエポキシ樹脂を含む請求項1または2に記載の有機電子素子用基板。
- 前記バリア層は、TiO、TiO2、Ti3O3、Al2O3、MgO、SiO、SiO2、GeO、NiO、CaO、BaO、Fe2O3、Y2O3、ZrO2、Nb2O3及びCeOからなる群より選択される1種以上を含む請求項1から3のいずれか1項に記載の有機電子素子用基板。
- 前記光学機能性層は、ヘイズが10%〜50%である請求項1から4のいずれか1項に記載の有機電子素子用基板。
- 前記光学機能性層は、光散乱層である請求項1から5のいずれか1項に記載の有機電子素子用基板。
- 前記光散乱層は、マトリックス物質及び前記マトリックス物質とは屈折率が異なる散乱性粒子を含む請求項6に記載の有機電子素子用基板。
- 前記光散乱層は、凹凸構造を有する層である請求項6または7に記載の有機電子素子用基板。
- 前記高屈折層は、633nmの波長の光に対する屈折率が1.6〜2.0である請求項1から8のいずれか1項に記載の有機電子素子用基板。
- 前記高屈折層は、平坦層である請求項1から9のいずれか1項に記載の有機電子素子用基板。
- 前記平坦層は、ポリアミド酸、ポリイミド、ポリシロキサンまたはエポキシ樹脂を含む請求項10に記載の有機電子素子用基板。
- 前記平坦層は、633nmの波長の光に対する屈折率が1.8以上であり、平均粒径が50nm以下である粒子をさらに含む請求項11に記載の有機電子素子用基板。
- 前記高屈折層は、第2高分子基材層である請求項1から12のいずれか1項に記載の有機電子素子用基板。
- キャリア基板をさらに含み、前記第1高分子基材層の光学機能性層とは反対側面が前記キャリア基板と接触している請求項1から13のいずれか1項に記載の有機電子素子用基板。
- キャリア基板に第1高分子基材層を形成し、前記基材層上に光学機能性層を形成し、前記光学機能性層上に高屈折層を形成する過程を含み、
前記第1高分子基材層または前記高屈折層の一面または両面に、633nmの波長の光に対する屈折率が1.45以上であるバリア層をさらに形成する有機電子素子用基板の製造方法。 - 前記第1高分子基材層は、前記キャリア基板上に高分子フィルムをラミネートするか高分子を含むコーティング液をコーティングして形成する請求項15に記載の有機電子素子用基板の製造方法。
- 請求項1から14のいずれか1項に記載の有機電子素子用基板と、
前記有機電子素子用基板上に形成されている第1電極と、
前記第1電極上に形成されている機能性有機層と、
前記機能性有機層上に形成されている第2電極と、を含む有機電子装置。 - 請求項15または16に記載の方法によって製造された有機電子素子用基板上に、第1電極、機能性有機層及び第2電極を順次形成する有機電子装置の製造方法。
- 請求項17に記載の有機電子装置を含むディスプレイ用光源。
- 請求項17に記載の有機電子装置を含む照明器機。
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JP2020136145A (ja) * | 2019-02-22 | 2020-08-31 | キヤノン株式会社 | 有機el素子及び発光装置 |
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EP2927984A4 (en) | 2016-09-21 |
KR20140070492A (ko) | 2014-06-10 |
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CN104823298B (zh) | 2017-03-08 |
WO2014084701A1 (ko) | 2014-06-05 |
US9768398B2 (en) | 2017-09-19 |
KR101587330B1 (ko) | 2016-02-02 |
EP2927984B1 (en) | 2019-08-07 |
CN104823298A (zh) | 2015-08-05 |
US20150303389A1 (en) | 2015-10-22 |
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TWI523294B (zh) | 2016-02-21 |
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