JP2015516891A5 - - Google Patents
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- Publication number
- JP2015516891A5 JP2015516891A5 JP2014556678A JP2014556678A JP2015516891A5 JP 2015516891 A5 JP2015516891 A5 JP 2015516891A5 JP 2014556678 A JP2014556678 A JP 2014556678A JP 2014556678 A JP2014556678 A JP 2014556678A JP 2015516891 A5 JP2015516891 A5 JP 2015516891A5
- Authority
- JP
- Japan
- Prior art keywords
- block copolymer
- layer
- item
- topcoat
- layered structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 79
- 229920001400 block copolymer Polymers 0.000 claims description 31
- 239000002086 nanomaterial Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 19
- 238000000137 annealing Methods 0.000 claims description 16
- 230000003472 neutralizing effect Effects 0.000 claims description 15
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 238000005530 etching Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 229920006037 cross link polymer Polymers 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 238000004528 spin coating Methods 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000001459 lithography Methods 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 229920000052 poly(p-xylylene) Polymers 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 229920000428 triblock copolymer Polymers 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261597327P | 2012-02-10 | 2012-02-10 | |
| US61/597,327 | 2012-02-10 | ||
| PCT/US2013/025174 WO2013119832A1 (en) | 2012-02-10 | 2013-02-07 | Anhydride copolymer top coats for orientation control of thin film block copolymers |
| US13/761,918 US9157008B2 (en) | 2012-02-10 | 2013-02-07 | Anhydride copolymer top coats for orientation control of thin film block copolymers |
| US13/761,918 | 2013-02-07 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015516891A JP2015516891A (ja) | 2015-06-18 |
| JP2015516891A5 true JP2015516891A5 (enExample) | 2016-03-31 |
| JP6258227B2 JP6258227B2 (ja) | 2018-01-10 |
Family
ID=47748780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014556678A Active JP6258227B2 (ja) | 2012-02-10 | 2013-02-07 | 薄膜ブロックコポリマーの配向性の制御のための無水コポリマートップコート |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US9157008B2 (enExample) |
| JP (1) | JP6258227B2 (enExample) |
| KR (1) | KR102018932B1 (enExample) |
| CN (1) | CN104303103B (enExample) |
| SG (1) | SG11201404414SA (enExample) |
| WO (1) | WO2013119832A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8691925B2 (en) | 2011-09-23 | 2014-04-08 | Az Electronic Materials (Luxembourg) S.A.R.L. | Compositions of neutral layer for directed self assembly block copolymers and processes thereof |
| US8686109B2 (en) | 2012-03-09 | 2014-04-01 | Az Electronic Materials (Luxembourg) S.A.R.L. | Methods and materials for removing metals in block copolymers |
| JP6027912B2 (ja) * | 2013-02-22 | 2016-11-16 | 東京応化工業株式会社 | 相分離構造を含む構造体の製造方法、及びパターン形成方法、並びにトップコート材料 |
| US10457088B2 (en) | 2013-05-13 | 2019-10-29 | Ridgefield Acquisition | Template for self assembly and method of making a self assembled pattern |
| TWI658055B (zh) * | 2013-06-19 | 2019-05-01 | 德州大學董事會 | 用於薄膜嵌段共聚物之定向控制之酸酐共聚物面塗層 |
| US9093263B2 (en) | 2013-09-27 | 2015-07-28 | Az Electronic Materials (Luxembourg) S.A.R.L. | Underlayer composition for promoting self assembly and method of making and using |
| US9181449B2 (en) | 2013-12-16 | 2015-11-10 | Az Electronic Materials (Luxembourg) S.A.R.L. | Underlayer composition for promoting self assembly and method of making and using |
| TWI648320B (zh) * | 2014-01-23 | 2019-01-21 | 東京應化工業股份有限公司 | 含相分離結構之結構體之製造方法、圖型形成方法、微細圖型形成方法 |
| TWI561919B (en) | 2014-03-15 | 2016-12-11 | Univ Texas | Ordering block copolymers |
| JP6298691B2 (ja) * | 2014-04-09 | 2018-03-20 | 東京応化工業株式会社 | 相分離構造を含む構造体の製造方法及びトップコート膜の成膜方法 |
| JP6325320B2 (ja) * | 2014-04-09 | 2018-05-16 | 東京応化工業株式会社 | 相分離構造を含む構造体の製造方法及びトップコート膜の成膜方法 |
| JP2016107211A (ja) * | 2014-12-05 | 2016-06-20 | Jsr株式会社 | 自己組織化膜の形成方法、パターン形成方法及び自己組織化膜形成用組成物 |
| FR3037071B1 (fr) * | 2015-06-02 | 2019-06-21 | Arkema France | Procede de reduction de la defectivite d'un film de copolymere a blocs |
| FR3037070B1 (fr) * | 2015-06-02 | 2019-05-31 | Arkema France | Procede de controle de l'energie de surface a l'interface entre un copolymere a blocs et un autre compose |
| JP6039028B1 (ja) * | 2015-09-11 | 2016-12-07 | 株式会社東芝 | 自己組織化材料及びパターン形成方法 |
| TWI612108B (zh) * | 2015-10-31 | 2018-01-21 | Rohm And Haas Electronic Materials Llc | 嵌段共聚物及圖案處理組合物以及方法 |
| EP3500637B1 (en) | 2016-08-18 | 2022-06-22 | Merck Patent GmbH | Polymer compositions for self-assembly applications |
| TWI755344B (zh) | 2016-12-21 | 2022-02-11 | 德商馬克專利公司 | 用於嵌段共聚物之自組裝之新穎組合物及方法 |
| FR3069339B1 (fr) * | 2017-07-21 | 2021-05-14 | Arkema France | Procede de controle de l'orientation des nano-domaines d'un copolymere a blocs |
| FR3069340A1 (fr) | 2017-07-21 | 2019-01-25 | Arkema France | Procede de controle de l'orientation des nano-domaines d'un copolymere a blocs |
| FR3074180B1 (fr) | 2017-11-24 | 2021-01-01 | Arkema France | Procede de controle de la planeite d'un empilement polymerique |
| FR3074179B1 (fr) | 2017-11-24 | 2021-01-01 | Arkema France | Procede de controle de la planeite d'un empilement polymerique |
| KR102136470B1 (ko) * | 2018-12-24 | 2020-07-22 | (주)서영 | 기판과 평행방향으로 자기조립된 실린더 블록공중합체를 이용한 대면적 나노패턴 제조 방법 |
| FR3096281A1 (fr) | 2019-05-20 | 2020-11-27 | Université De Bordeaux | procédé de préparation d’un film de copolymère à blocs destiné à la création d’un masque de nanolithographie |
| FR3105786A1 (fr) * | 2019-12-31 | 2021-07-02 | Arkema France | Procédé de nanostructuration d’un substrat |
| US12072987B1 (en) * | 2020-04-10 | 2024-08-27 | Google Llc | Private counting from anonymous messages: near-optimal accuracy with vanishing communication overhead |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4278510A (en) * | 1980-03-31 | 1981-07-14 | Gulf Oil Corporation | Platable propylene polymer compositions |
| KR19990060476A (ko) * | 1997-12-31 | 1999-07-26 | 구본준 | 삼중 블록 공중합체의 박막에서 수직적 구조 형성 방법 |
| US20130052769A1 (en) * | 2000-02-04 | 2013-02-28 | Daniel Luch | Substrate structures for integrated series connected photovoltaic arrays and process of manufacture of such arrays |
| KR20090031349A (ko) * | 2006-04-28 | 2009-03-25 | 폴리셋 컴파니, 인코퍼레이티드 | 재분배층 적용을 위한 실록산 에폭시 중합체 |
| US7964107B2 (en) * | 2007-02-08 | 2011-06-21 | Micron Technology, Inc. | Methods using block copolymer self-assembly for sub-lithographic patterning |
| US7763319B2 (en) * | 2008-01-11 | 2010-07-27 | International Business Machines Corporation | Method of controlling orientation of domains in block copolymer films |
| US7989026B2 (en) | 2008-01-12 | 2011-08-02 | International Business Machines Corporation | Method of use of epoxy-containing cycloaliphatic acrylic polymers as orientation control layers for block copolymer thin films |
| US8999492B2 (en) | 2008-02-05 | 2015-04-07 | Micron Technology, Inc. | Method to produce nanometer-sized features with directed assembly of block copolymers |
| US8426313B2 (en) | 2008-03-21 | 2013-04-23 | Micron Technology, Inc. | Thermal anneal of block copolymer films with top interface constrained to wet both blocks with equal preference |
| JP2010115832A (ja) | 2008-11-12 | 2010-05-27 | Panasonic Corp | ブロックコポリマーの自己組織化促進方法及びそれを用いたブロックコポリマーの自己組織化パターン形成方法 |
| JP2011122081A (ja) * | 2009-12-11 | 2011-06-23 | Nissan Chem Ind Ltd | 熱硬化性膜形成組成物 |
| CN101734610B (zh) * | 2009-12-15 | 2012-05-23 | 江苏大学 | 一种用于微机电系统低载荷工况的多层薄膜及其制备方法 |
| US8623458B2 (en) * | 2009-12-18 | 2014-01-07 | International Business Machines Corporation | Methods of directed self-assembly, and layered structures formed therefrom |
| CN102870247A (zh) | 2010-03-18 | 2013-01-09 | 得克萨斯大学体系董事会 | 含硅嵌段共聚合物及其合成和使用方法 |
| KR101853598B1 (ko) * | 2010-03-23 | 2018-04-30 | 가부시키가이샤 아사히 러버 | 실리콘 수지제 반사 기재, 그 제조 방법, 및 그 반사 기재에 이용하는 원재료 조성물 |
| US8372928B2 (en) * | 2011-05-20 | 2013-02-12 | Massachusetts Institute Of Technology | Hard, impermeable, flexible and conformal organic coatings |
| US8956804B2 (en) | 2011-06-23 | 2015-02-17 | Asml Netherlands B.V. | Self-assemblable polymer and methods for use in lithography |
| US9314819B2 (en) * | 2012-02-10 | 2016-04-19 | Board Of Regents, The University Of Texas System | Anhydride copolymer top coats for orientation control of thin film block copolymers |
-
2013
- 2013-02-07 WO PCT/US2013/025174 patent/WO2013119832A1/en not_active Ceased
- 2013-02-07 KR KR1020147024159A patent/KR102018932B1/ko active Active
- 2013-02-07 US US13/761,918 patent/US9157008B2/en active Active
- 2013-02-07 CN CN201380011365.8A patent/CN104303103B/zh not_active Expired - Fee Related
- 2013-02-07 SG SG11201404414SA patent/SG11201404414SA/en unknown
- 2013-02-07 JP JP2014556678A patent/JP6258227B2/ja active Active
-
2015
- 2015-08-28 US US14/839,147 patent/US10139724B2/en active Active
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