JP2015510489A5 - - Google Patents
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- Publication number
- JP2015510489A5 JP2015510489A5 JP2014558853A JP2014558853A JP2015510489A5 JP 2015510489 A5 JP2015510489 A5 JP 2015510489A5 JP 2014558853 A JP2014558853 A JP 2014558853A JP 2014558853 A JP2014558853 A JP 2014558853A JP 2015510489 A5 JP2015510489 A5 JP 2015510489A5
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- cmos compatible
- surface treatment
- treatment process
- carbon source
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 56
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 30
- 239000000758 substrate Substances 0.000 claims 19
- 238000004381 surface treatment Methods 0.000 claims 18
- 229910052799 carbon Inorganic materials 0.000 claims 17
- 229910021389 graphene Inorganic materials 0.000 claims 11
- 239000012159 carrier gas Substances 0.000 claims 9
- 239000007789 gas Substances 0.000 claims 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 5
- 239000000463 material Substances 0.000 claims 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 238000001069 Raman spectroscopy Methods 0.000 claims 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 3
- 239000011889 copper foil Substances 0.000 claims 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 238000001237 Raman spectrum Methods 0.000 claims 2
- 238000004140 cleaning Methods 0.000 claims 2
- 230000007547 defect Effects 0.000 claims 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims 2
- 238000005530 etching Methods 0.000 claims 2
- 239000012530 fluid Substances 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 238000003860 storage Methods 0.000 claims 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261603104P | 2012-02-24 | 2012-02-24 | |
| US61/603,104 | 2012-02-24 | ||
| US201261607337P | 2012-03-06 | 2012-03-06 | |
| US61/607,337 | 2012-03-06 | ||
| US201261677323P | 2012-07-30 | 2012-07-30 | |
| US61/677,323 | 2012-07-30 | ||
| PCT/US2013/027284 WO2013126671A1 (en) | 2012-02-24 | 2013-02-22 | Method and system for graphene formation |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017238223A Division JP6562996B2 (ja) | 2012-02-24 | 2017-12-13 | 銅材料を銅基板から除去する方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015510489A JP2015510489A (ja) | 2015-04-09 |
| JP2015510489A5 true JP2015510489A5 (enExample) | 2016-11-10 |
| JP6262156B2 JP6262156B2 (ja) | 2018-01-17 |
Family
ID=49006226
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014558853A Active JP6262156B2 (ja) | 2012-02-24 | 2013-02-22 | グラフェン形成のための方法およびシステム |
| JP2017238223A Active JP6562996B2 (ja) | 2012-02-24 | 2017-12-13 | 銅材料を銅基板から除去する方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017238223A Active JP6562996B2 (ja) | 2012-02-24 | 2017-12-13 | 銅材料を銅基板から除去する方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US9150418B2 (enExample) |
| EP (1) | EP2817261B1 (enExample) |
| JP (2) | JP6262156B2 (enExample) |
| KR (1) | KR102107382B1 (enExample) |
| CN (2) | CN106744866B (enExample) |
| SG (3) | SG10201908213VA (enExample) |
| TW (1) | TWI552954B (enExample) |
| WO (1) | WO2013126671A1 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106744866B (zh) * | 2012-02-24 | 2021-01-01 | 加州理工学院 | 用于石墨烯形成的方法和系统 |
| WO2014110446A2 (en) * | 2013-01-14 | 2014-07-17 | California Institute Of Technology | Method and system for graphene formation |
| US9242865B2 (en) | 2013-03-05 | 2016-01-26 | Lockheed Martin Corporation | Systems and methods for production of graphene by plasma-enhanced chemical vapor deposition |
| US9458020B2 (en) * | 2013-05-06 | 2016-10-04 | Centre National De La Recherche Scientifique | Process and device for forming a graphene layer |
| GB201318463D0 (en) * | 2013-08-13 | 2013-12-04 | Medical Res Council | Graphene Modification |
| WO2015149116A1 (en) * | 2014-04-04 | 2015-10-08 | Commonwealth Scientific And Industrial Research Organisation | Graphene process and product |
| US10072355B2 (en) * | 2014-04-15 | 2018-09-11 | Board Of Regents, The University Of Texas System | Methods of forming graphene single crystal domains on a low nucleation site density substrate |
| US10566104B2 (en) * | 2014-07-09 | 2020-02-18 | Daegu Gyeongbuk Institute Of Science And Technology | Metal nanowire having core-shell structure coated with graphene, and manufacturing method therefor |
| CN104211054B (zh) * | 2014-09-09 | 2016-05-18 | 中国科学院化学研究所 | 一种可控制备石墨烯的方法 |
| CN104576457A (zh) * | 2014-12-26 | 2015-04-29 | 常州二维碳素科技有限公司 | 一种对石墨烯制件进行表面处理的设备及其处理方法 |
| KR101723521B1 (ko) * | 2015-02-26 | 2017-04-05 | 주성엔지니어링(주) | 그래핀 성장 장치 |
| KR101717476B1 (ko) * | 2015-02-27 | 2017-03-27 | 주성엔지니어링(주) | 그래핀 성장 장치 |
| TWI539043B (zh) | 2015-07-21 | 2016-06-21 | 財團法人工業技術研究院 | 石墨烯花的形成方法 |
| JP6661189B2 (ja) * | 2015-10-02 | 2020-03-11 | 国立研究開発法人産業技術総合研究所 | グラフェン膜の作製方法 |
| CN105220128B (zh) * | 2015-11-16 | 2018-03-16 | 哈尔滨工业大学 | 一种锆合金表面原位垂直生长石墨烯防腐层的制备方法 |
| JP6652770B2 (ja) * | 2016-04-04 | 2020-02-26 | 株式会社不二越 | 固体高分子形燃料電池用セパレータの製造方法 |
| NO345837B1 (en) * | 2016-05-04 | 2021-08-30 | Cealtech As | Apparatus for large scale producing 3D graphene and method describing the same |
| CN106248221A (zh) * | 2016-07-19 | 2016-12-21 | 中国科学院重庆绿色智能技术研究院 | 一种基于石墨烯的非制冷红外探测器及原位制作方法 |
| US9997334B1 (en) * | 2017-02-09 | 2018-06-12 | Lyten, Inc. | Seedless particles with carbon allotropes |
| US10825586B2 (en) * | 2017-08-30 | 2020-11-03 | Ultra Conductive Copper Company, Inc. | Method and system for forming a multilayer composite structure |
| ES2717199B2 (es) * | 2017-12-19 | 2022-07-21 | Pamies Javier Biela | Planta de biogas |
| WO2020123974A1 (en) | 2018-12-14 | 2020-06-18 | Massachusetts Institute Of Technology | Fabrication of carbon-based nanostructures on metallic substrates, including aluminum-containing substrates |
| WO2020124018A1 (en) * | 2018-12-14 | 2020-06-18 | Massachusetts Institute Of Technology | Formation and/or growth of carbon-based nanostructures on copper-containing substrates, and related systems and methods |
| US12217958B2 (en) | 2019-03-04 | 2025-02-04 | Samsung Electronics Co., Ltd. | Method of pre-treating substrate and method of directly forming graphene using the same |
| CN109930133A (zh) * | 2019-03-21 | 2019-06-25 | 西南大学 | 一种用于气敏传感的石墨烯氧化锆复合材料的制备方法 |
| CN109975368A (zh) * | 2019-03-21 | 2019-07-05 | 西南大学 | 一种用于气敏传感的石墨烯氧化锡复合材料的制备方法 |
| WO2021156196A1 (en) | 2020-02-03 | 2021-08-12 | Cealtech As | Process and device for large-scale production of graphene |
| JP7561530B2 (ja) * | 2020-06-25 | 2024-10-04 | 東京エレクトロン株式会社 | 成膜方法及び成膜装置 |
| CN111847432B (zh) * | 2020-07-24 | 2023-08-29 | 北京石墨烯研究院 | 大面积多层石墨烯及其制备方法 |
| US12312679B2 (en) | 2020-12-22 | 2025-05-27 | Joz̃Stefan Institute | Method for producing N-doped carbon nanomesh |
| US11515163B2 (en) * | 2021-01-06 | 2022-11-29 | Applied Materials, Inc. | Low temperature graphene growth |
| US12300497B2 (en) * | 2021-02-11 | 2025-05-13 | Applied Materials, Inc. | Method and apparatus of low temperature plasma enhanced chemical vapor deposition of graphene |
| US20250163572A1 (en) * | 2021-11-04 | 2025-05-22 | Universite Picardie Jules Verne | Process for direct deposition of graphene or graphene oxide onto a substrate of interest |
| KR102727835B1 (ko) | 2022-10-12 | 2024-11-08 | 주식회사 케이비엘러먼트 | 질소가 도핑된 그래핀 제조 방법 |
| WO2025018599A1 (ko) * | 2023-07-14 | 2025-01-23 | 주성엔지니어링(주) | 탄소 함유막의 형성 방법 |
| WO2025018598A1 (ko) * | 2023-07-14 | 2025-01-23 | 주성엔지니어링(주) | 그래핀막의 형성 방법 |
| CN117623291B (zh) * | 2023-12-14 | 2025-10-21 | 北京石墨烯研究院 | 双层石墨烯薄膜及其制备方法 |
| CN119218986B (zh) * | 2024-11-28 | 2025-04-08 | 中国人民解放军国防科技大学 | 一种基于脉冲离子束的石墨烯单层去除方法 |
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| JPS55158275A (en) * | 1979-05-28 | 1980-12-09 | Hitachi Ltd | Corrosion preventing method for al and al alloy |
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| JPH0225571A (ja) * | 1988-07-13 | 1990-01-29 | Kawasaki Steel Corp | 硬質炭素膜合成方法 |
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| JP2000096233A (ja) * | 1998-06-20 | 2000-04-04 | Nissin Electric Co Ltd | 炭素膜及びその形成方法並びに炭素膜被覆物品及びその製造方法 |
| JP2001007117A (ja) * | 1999-06-24 | 2001-01-12 | Tokyo Electron Ltd | 処理装置及び処理方法 |
| KR101276694B1 (ko) * | 2003-02-14 | 2013-06-19 | 어플라이드 머티어리얼스, 인코포레이티드 | 수소-함유 라디칼을 이용한 자연 산화물 세정 |
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| FR2943660B1 (fr) * | 2009-03-25 | 2011-04-29 | Commissariat Energie Atomique | Procede d'elaboration de graphene |
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| US20120161098A1 (en) * | 2009-08-20 | 2012-06-28 | Nec Corporation | Substrate, manufacturing method of substrate, semiconductor element, and manufacturing method of semiconductor element |
| KR101636442B1 (ko) * | 2009-11-10 | 2016-07-21 | 삼성전자주식회사 | 촉매합금을 이용한 그라핀의 제조방법 |
| KR101279606B1 (ko) * | 2009-12-11 | 2013-07-05 | 한국전자통신연구원 | 그래핀 박막의 증착방법 |
| JP5692794B2 (ja) * | 2010-03-17 | 2015-04-01 | 独立行政法人産業技術総合研究所 | 透明導電性炭素膜の製造方法 |
| JP5660804B2 (ja) * | 2010-04-30 | 2015-01-28 | 東京エレクトロン株式会社 | カーボンナノチューブの形成方法及びカーボンナノチューブ成膜装置 |
| KR20120012271A (ko) * | 2010-07-30 | 2012-02-09 | 성균관대학교산학협력단 | 그래핀의 제조 방법, 그래핀 시트 및 이를 이용한 소자 |
| WO2012051182A2 (en) * | 2010-10-11 | 2012-04-19 | University Of Houston System | Fabrication of single-crystalline graphene arrays |
| CN102212794B (zh) * | 2011-04-13 | 2012-10-10 | 中国科学院上海微系统与信息技术研究所 | 一种基于电镀铜衬底制备大面积石墨烯薄膜的方法 |
| JP5806318B2 (ja) | 2011-08-24 | 2015-11-10 | 旭化成イーマテリアルズ株式会社 | 樹脂封止シート及び太陽電池モジュール |
| CN106744866B (zh) | 2012-02-24 | 2021-01-01 | 加州理工学院 | 用于石墨烯形成的方法和系统 |
-
2013
- 2013-02-22 CN CN201611162591.8A patent/CN106744866B/zh active Active
- 2013-02-22 EP EP13751679.5A patent/EP2817261B1/en active Active
- 2013-02-22 US US13/774,188 patent/US9150418B2/en active Active
- 2013-02-22 SG SG10201908213V patent/SG10201908213VA/en unknown
- 2013-02-22 SG SG10201607367UA patent/SG10201607367UA/en unknown
- 2013-02-22 WO PCT/US2013/027284 patent/WO2013126671A1/en not_active Ceased
- 2013-02-22 CN CN201380010837.8A patent/CN104136368B/zh active Active
- 2013-02-22 KR KR1020147025067A patent/KR102107382B1/ko active Active
- 2013-02-22 SG SG11201404775RA patent/SG11201404775RA/en unknown
- 2013-02-22 JP JP2014558853A patent/JP6262156B2/ja active Active
- 2013-02-23 TW TW102106432A patent/TWI552954B/zh active
-
2015
- 2015-08-27 US US14/838,202 patent/US20150368111A1/en not_active Abandoned
-
2016
- 2016-08-24 US US15/246,427 patent/US20170044018A1/en not_active Abandoned
-
2017
- 2017-12-13 JP JP2017238223A patent/JP6562996B2/ja active Active
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