JP2015126230A - 電磁波遮蔽フィルムの製造方法及びこれから製造された電磁波遮蔽フィルムmethodformanufacturingelectromagneticinterferenceshieldingfilmandelectromagneticinterferenceshieldingfilmmanufacturedthereof - Google Patents
電磁波遮蔽フィルムの製造方法及びこれから製造された電磁波遮蔽フィルムmethodformanufacturingelectromagneticinterferenceshieldingfilmandelectromagneticinterferenceshieldingfilmmanufacturedthereof Download PDFInfo
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- JP2015126230A JP2015126230A JP2014265459A JP2014265459A JP2015126230A JP 2015126230 A JP2015126230 A JP 2015126230A JP 2014265459 A JP2014265459 A JP 2014265459A JP 2014265459 A JP2014265459 A JP 2014265459A JP 2015126230 A JP2015126230 A JP 2015126230A
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- Prior art keywords
- electromagnetic wave
- wave shielding
- shielding film
- metal pattern
- conductive adhesive
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- 238000000034 method Methods 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 86
- 239000002184 metal Substances 0.000 claims abstract description 86
- 239000010410 layer Substances 0.000 claims abstract description 84
- 239000012790 adhesive layer Substances 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 15
- 238000009413 insulation Methods 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims description 35
- 239000000853 adhesive Substances 0.000 claims description 31
- 230000001070 adhesive effect Effects 0.000 claims description 31
- -1 phosphorus compound Chemical class 0.000 claims description 29
- 239000000945 filler Substances 0.000 claims description 20
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 18
- 229910052709 silver Inorganic materials 0.000 claims description 18
- 239000004332 silver Substances 0.000 claims description 18
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- 239000011342 resin composition Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 12
- 238000007645 offset printing Methods 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 239000003063 flame retardant Substances 0.000 claims description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000011231 conductive filler Substances 0.000 claims description 6
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 6
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical group OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
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- 239000001099 ammonium carbonate Substances 0.000 claims description 5
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- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical group [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 238000005299 abrasion Methods 0.000 claims description 4
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 4
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 125000000524 functional group Chemical class 0.000 claims description 4
- 238000007646 gravure printing Methods 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
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- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical group O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical group [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical group [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 150000007942 carboxylates Chemical class 0.000 claims description 3
- IBAHLNWTOIHLKE-UHFFFAOYSA-N cyano cyanate Chemical group N#COC#N IBAHLNWTOIHLKE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical group 0.000 claims description 3
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Chemical group SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 3
- 238000007641 inkjet printing Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Chemical group 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229920000642 polymer Chemical class 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Chemical group 0.000 claims description 3
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims description 3
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 3
- 229940007718 zinc hydroxide Drugs 0.000 claims description 3
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 239000012798 spherical particle Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000000059 patterning Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 96
- 230000008569 process Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000010944 silver (metal) Substances 0.000 description 8
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- 239000002904 solvent Substances 0.000 description 6
- 238000004544 sputter deposition Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- 238000007740 vapor deposition Methods 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
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- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- JWZZKOKVBUJMES-UHFFFAOYSA-N (+-)-Isoprenaline Chemical compound CC(C)NCC(O)C1=CC=C(O)C(O)=C1 JWZZKOKVBUJMES-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
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- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- UDXBSNUCGGXUNH-UHFFFAOYSA-N 2-cyanoethylazanium;2-cyanoethyl carbonate Chemical compound [NH3+]CCC#N.[O-]C(=O)OCCC#N UDXBSNUCGGXUNH-UHFFFAOYSA-N 0.000 description 1
- XEXHIBLRARSXCL-UHFFFAOYSA-N 2-cyanoethylazanium;hydrogen carbonate Chemical compound OC([O-])=O.[NH3+]CCC#N XEXHIBLRARSXCL-UHFFFAOYSA-N 0.000 description 1
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 1
- OZDFMZUKOBBNHM-UHFFFAOYSA-N 2-ethylhexyl carbamate Chemical compound CCCCC(CC)COC(N)=O OZDFMZUKOBBNHM-UHFFFAOYSA-N 0.000 description 1
- WRJRTLNJQQNHLC-UHFFFAOYSA-N 2-ethylhexylazanium;2-ethylhexyl carbonate Chemical compound CCCCC(CC)C[NH3+].CCCCC(CC)COC([O-])=O WRJRTLNJQQNHLC-UHFFFAOYSA-N 0.000 description 1
- LFTWYPLGYKQPMV-UHFFFAOYSA-N 2-ethylhexylazanium;hydrogen carbonate Chemical compound OC([O-])=O.CCCCC(CC)C[NH3+] LFTWYPLGYKQPMV-UHFFFAOYSA-N 0.000 description 1
- NNHMJLWANZZIRG-UHFFFAOYSA-N 2-methoxyethanamine 2-methoxyethyl carbamate Chemical compound COCCN.COCCOC(N)=O NNHMJLWANZZIRG-UHFFFAOYSA-N 0.000 description 1
- HTBCQGGKQJBADY-UHFFFAOYSA-N 2-methoxyethylazanium;2-methoxyethyl carbonate Chemical compound COCC[NH3+].COCCOC([O-])=O HTBCQGGKQJBADY-UHFFFAOYSA-N 0.000 description 1
- IUPKRHGZXTZBKD-UHFFFAOYSA-N 2-methylpropan-1-amine 2-methylpropyl carbamate Chemical compound CC(C)CN.CC(C)COC(N)=O IUPKRHGZXTZBKD-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- IGDXYWDETCLQJX-UHFFFAOYSA-N 3-triethoxysilylpropan-1-amine 3-triethoxysilylpropyl carbamate Chemical compound CCO[Si](OCC)(OCC)CCCN.CCO[Si](OCC)(OCC)CCCOC(N)=O IGDXYWDETCLQJX-UHFFFAOYSA-N 0.000 description 1
- SKRSRJOKBARNAS-UHFFFAOYSA-N 3-triethoxysilylpropylazanium;3-triethoxysilylpropyl carbonate Chemical compound CCO[Si](OCC)(OCC)CCC[NH3+].CCO[Si](OCC)(OCC)CCCOC([O-])=O SKRSRJOKBARNAS-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- UFGRWTLTISXGJP-UHFFFAOYSA-N C(OCC(C)C)([O-])=O.[NH4+] Chemical compound C(OCC(C)C)([O-])=O.[NH4+] UFGRWTLTISXGJP-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 208000032365 Electromagnetic interference Diseases 0.000 description 1
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- HWVVYUPLWARZKN-UHFFFAOYSA-N N-butylbutan-1-amine dibutyl carbonate Chemical compound CCCCNCCCC.CCCCOC(=O)OCCCC HWVVYUPLWARZKN-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- KOOADCGQJDGAGA-UHFFFAOYSA-N [amino(dimethyl)silyl]methane Chemical class C[Si](C)(C)N KOOADCGQJDGAGA-UHFFFAOYSA-N 0.000 description 1
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- 239000002313 adhesive film Substances 0.000 description 1
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- 125000003277 amino group Chemical group 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
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- GHFDYTIELHTMGV-UHFFFAOYSA-N benzyl carbamate;phenylmethanamine Chemical compound NCC1=CC=CC=C1.NC(=O)OCC1=CC=CC=C1 GHFDYTIELHTMGV-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- QJLWYBRKZCYIEK-UHFFFAOYSA-N benzylazanium;benzyl carbonate Chemical compound [NH3+]CC1=CC=CC=C1.[O-]C(=O)OCC1=CC=CC=C1 QJLWYBRKZCYIEK-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- DDWQBJYWGXHLCN-UHFFFAOYSA-N butan-1-amine;butylcarbamic acid Chemical compound CCCC[NH3+].CCCCNC([O-])=O DDWQBJYWGXHLCN-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SCJNFWUKTOYSRT-UHFFFAOYSA-N butylazanium;butyl carbonate Chemical compound CCCC[NH3+].CCCCOC([O-])=O SCJNFWUKTOYSRT-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 125000004802 cyanophenyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FNPQBMYFLGSBBI-UHFFFAOYSA-N decyl(methyl)azanium;n-decyl-n-methylcarbamate Chemical compound CCCCCCCCCC[NH2+]C.CCCCCCCCCCN(C)C([O-])=O FNPQBMYFLGSBBI-UHFFFAOYSA-N 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
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- JKZDDFARANSOQU-UHFFFAOYSA-N diazanium;morpholine;carbonate Chemical compound [NH4+].[NH4+].[O-]C([O-])=O.C1COCCN1.C1COCCN1 JKZDDFARANSOQU-UHFFFAOYSA-N 0.000 description 1
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- HSFZJWNDRZGOKZ-UHFFFAOYSA-N dioctadecyl carbonate N-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCCCCOC(=O)OCCCCCCCCCCCCCCCCCC HSFZJWNDRZGOKZ-UHFFFAOYSA-N 0.000 description 1
- WVDBSYPGKQYWSS-UHFFFAOYSA-N dioctadecylazanium;hydrogen carbonate Chemical compound OC([O-])=O.CCCCCCCCCCCCCCCCCC[NH2+]CCCCCCCCCCCCCCCCCC WVDBSYPGKQYWSS-UHFFFAOYSA-N 0.000 description 1
- AYGOKHJRGBNMGQ-UHFFFAOYSA-N dioctadecylazanium;n,n-dioctadecylcarbamate Chemical compound CCCCCCCCCCCCCCCCCC[NH2+]CCCCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCCCCN(C([O-])=O)CCCCCCCCCCCCCCCCCC AYGOKHJRGBNMGQ-UHFFFAOYSA-N 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- WAAUVORLARCBAF-UHFFFAOYSA-N ethylazanium;ethyl carbonate Chemical compound CC[NH3+].CCOC([O-])=O WAAUVORLARCBAF-UHFFFAOYSA-N 0.000 description 1
- GPUHGQYNYJIMDZ-UHFFFAOYSA-N ethylazanium;n-ethylcarbamate Chemical compound CC[NH3+].CCNC([O-])=O GPUHGQYNYJIMDZ-UHFFFAOYSA-N 0.000 description 1
- 239000010946 fine silver Substances 0.000 description 1
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- RGEULEMUWRTZMP-UHFFFAOYSA-N hydrogen carbonate;2-methoxyethylazanium Chemical compound OC([O-])=O.COCC[NH3+] RGEULEMUWRTZMP-UHFFFAOYSA-N 0.000 description 1
- YCADFRFBAHDVOS-UHFFFAOYSA-N hydrogen carbonate;propan-2-ylazanium Chemical compound CC(C)[NH3+].OC([O-])=O YCADFRFBAHDVOS-UHFFFAOYSA-N 0.000 description 1
- NZYYSSZGIPELSX-UHFFFAOYSA-N hydrogen carbonate;pyridin-1-ium Chemical compound OC(O)=O.C1=CC=NC=C1 NZYYSSZGIPELSX-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- NPHYYTMURMCAQE-UHFFFAOYSA-N morpholin-4-ium;n-morpholin-4-ylcarbamate Chemical compound C1COCC[NH2+]1.[O-]C(=O)NN1CCOCC1 NPHYYTMURMCAQE-UHFFFAOYSA-N 0.000 description 1
- IKVDMBQGHZVMRN-UHFFFAOYSA-N n-methyldecan-1-amine Chemical compound CCCCCCCCCCNC IKVDMBQGHZVMRN-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BTDGNUHTDOIMKX-UHFFFAOYSA-N octadecan-1-amine octadecyl carbamate Chemical compound CCCCCCCCCCCCCCCCCCN.CCCCCCCCCCCCCCCCCCOC(N)=O BTDGNUHTDOIMKX-UHFFFAOYSA-N 0.000 description 1
- XKFXSYSPQZRVOY-UHFFFAOYSA-N octadecylazanium;octadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCCC[NH3+].CCCCCCCCCCCCCCCCCCOC([O-])=O XKFXSYSPQZRVOY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- AHIHJODVQGBOND-UHFFFAOYSA-M propan-2-yl carbonate Chemical compound CC(C)OC([O-])=O AHIHJODVQGBOND-UHFFFAOYSA-M 0.000 description 1
- MPXHWRXXJUKENG-UHFFFAOYSA-N propan-2-ylazanium;n-propan-2-ylcarbamate Chemical compound CC(C)[NH3+].CC(C)NC([O-])=O MPXHWRXXJUKENG-UHFFFAOYSA-N 0.000 description 1
- TZRORHHMAGATLL-UHFFFAOYSA-N propan-2-ylazanium;propan-2-yl carbonate Chemical compound CC(C)[NH3+].CC(C)OC([O-])=O TZRORHHMAGATLL-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
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- 238000007764 slot die coating Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- XKXIQBVKMABYQJ-UHFFFAOYSA-M tert-butyl carbonate Chemical compound CC(C)(C)OC([O-])=O XKXIQBVKMABYQJ-UHFFFAOYSA-M 0.000 description 1
- YSEKXGQQTHQQMK-UHFFFAOYSA-N tert-butylazanium;hydrogen carbonate Chemical compound OC([O-])=O.CC(C)(C)[NH3+] YSEKXGQQTHQQMK-UHFFFAOYSA-N 0.000 description 1
- XBXCNNQPRYLIDE-UHFFFAOYSA-N tert-butylcarbamic acid Chemical compound CC(C)(C)NC(O)=O XBXCNNQPRYLIDE-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- ZFNFNJYRZOQPJF-UHFFFAOYSA-N trimethoxy(sulfanyl)silane Chemical compound CO[Si](S)(OC)OC ZFNFNJYRZOQPJF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/002—Casings with localised screening
- H05K9/0022—Casings with localised screening of components mounted on printed circuit boards [PCB]
- H05K9/0024—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields
- H05K9/0031—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields combining different shielding materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0213—Electrical arrangements not otherwise provided for
- H05K1/0216—Reduction of cross-talk, noise or electromagnetic interference
- H05K1/0218—Reduction of cross-talk, noise or electromagnetic interference by printed shielding conductors, ground planes or power plane
- H05K1/0219—Printed shielding conductors for shielding around or between signal conductors, e.g. coplanar or coaxial printed shielding conductors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
- H05K9/0086—Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising a single discontinuous metallic layer on an electrically insulating supporting structure, e.g. metal grid, perforated metal foil, film, aggregated flakes, sintering
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/07—Electric details
- H05K2201/0707—Shielding
- H05K2201/0715—Shielding provided by an outer layer of PCB
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Laminated Bodies (AREA)
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| JP2017038742A Pending JP2017143275A (ja) | 2013-12-26 | 2017-03-01 | 電磁波遮蔽フィルムの製造方法及びこれから製造された電磁波遮蔽フィルム |
| JP2020144609A Pending JP2021002664A (ja) | 2013-12-26 | 2020-08-28 | 電磁波遮蔽フィルムの製造方法 |
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| JP2020144609A Pending JP2021002664A (ja) | 2013-12-26 | 2020-08-28 | 電磁波遮蔽フィルムの製造方法 |
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| JP (3) | JP2015126230A (https=) |
| KR (1) | KR20150075912A (https=) |
| CN (2) | CN104754861A (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2017026211A1 (ja) * | 2015-08-11 | 2017-02-16 | コニカミノルタ株式会社 | 機能性シート |
| JP2017143275A (ja) * | 2013-12-26 | 2017-08-17 | インクテック カンパニー, リミテッドInktec Co., Ltd. | 電磁波遮蔽フィルムの製造方法及びこれから製造された電磁波遮蔽フィルム |
| KR20180066508A (ko) * | 2016-12-09 | 2018-06-19 | 공주대학교 산학협력단 | 전자파 차폐용 블록필름 |
| WO2020194109A1 (en) * | 2019-03-22 | 2020-10-01 | 3M Innovative Properties Company | Electronic assembly, electronic apparatus including the same and method for fabricating electronic assembly |
| CN112831290A (zh) * | 2020-12-25 | 2021-05-25 | 领胜城科技(江苏)有限公司 | 一种可挠电磁屏蔽胶带的制备方法 |
| CN120769434A (zh) * | 2025-06-13 | 2025-10-10 | 广州源康精密电子股份有限公司 | 一种rfpc及其制作方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102119594B1 (ko) * | 2017-03-06 | 2020-06-05 | 주식회사 아모그린텍 | 파워 릴레이 어셈블리 |
| CN107511302A (zh) * | 2017-08-16 | 2017-12-26 | 苏州城邦达力材料科技有限公司 | 屏蔽膜的加工系统及方法 |
| US12490387B2 (en) * | 2019-02-18 | 2025-12-02 | Jabil Inc. | Adhesive circuit patterning process |
| KR102236577B1 (ko) * | 2019-02-20 | 2021-04-06 | 주식회사 코모텍 | 인라인형 멀티 코팅장치 |
| CN112210321A (zh) * | 2019-07-12 | 2021-01-12 | 臻鼎科技股份有限公司 | 导电粘着剂以及使用其的电磁波屏蔽膜和电路板 |
| JP6690773B1 (ja) * | 2019-12-18 | 2020-04-28 | 東洋インキScホールディングス株式会社 | 電磁波シールドシート、および電磁波シールド性配線回路基板 |
| CN111050466A (zh) * | 2019-12-31 | 2020-04-21 | 安捷利(番禺)电子实业有限公司 | 插入损耗低且剥离强度大的pcb及其制作方法 |
| CN113133291A (zh) * | 2019-12-31 | 2021-07-16 | 广州宏庆电子有限公司 | 一种电磁屏蔽覆盖膜及其制备方法 |
| CN111246719A (zh) * | 2020-02-26 | 2020-06-05 | 东莞市华卓电子科技有限公司 | 一种5g电磁膜的生产方法 |
| DE102020128367B4 (de) | 2020-10-28 | 2025-10-30 | Te Connectivity Germany Gmbh | Anordnung mit einem aus mindestens drei aufeinanderliegenden Blechlagen zusammengefügten Blechstapel, elektrischer Kontakt umfassend diese Anordnung und Verfahren zum Durchsetzfügen eines Blechstapels |
| KR102572146B1 (ko) * | 2021-08-03 | 2023-08-30 | 주식회사 볼트크리에이션 | 전자파 차폐 시트 및 그 제조방법 |
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| JPH05235495A (ja) * | 1992-02-21 | 1993-09-10 | Sumitomo Electric Ind Ltd | シールド付フレキシブルプリント配線板 |
| JP2009289840A (ja) * | 2008-05-28 | 2009-12-10 | Toyo Ink Mfg Co Ltd | 電磁波シールド性接着フィルム |
| JP2013168643A (ja) * | 2012-01-17 | 2013-08-29 | Toyo Ink Sc Holdings Co Ltd | 電磁波シールドシートおよび電磁波シールド層付き配線板の製造方法 |
| JP2013538439A (ja) * | 2010-06-23 | 2013-10-10 | インクテック カンパニー リミテッド | 電磁波シールドフィルムの製造方法及びこれにより製造された電磁波シールドフィルム |
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| JPS62124896U (https=) * | 1986-01-28 | 1987-08-08 | ||
| JPS62145399U (https=) * | 1986-03-06 | 1987-09-12 | ||
| JPH06152178A (ja) * | 1992-11-13 | 1994-05-31 | Kansai Paint Co Ltd | 電波反射防止体および電波反射防止方法 |
| JP2000036685A (ja) * | 1998-05-15 | 2000-02-02 | Nippon Paint Co Ltd | 電磁波吸収材 |
| US20070275237A1 (en) * | 2006-05-24 | 2007-11-29 | Syh-Tau Yeh | Electromagnetic shielding tape |
| US8426749B2 (en) * | 2007-05-09 | 2013-04-23 | Fujifilm Corporation | Electromagnetic shielding film and optical filter |
| JP2009126115A (ja) * | 2007-11-27 | 2009-06-11 | Furukawa Electric Co Ltd:The | 積層板及びこれを用いた製品 |
| JP2011171522A (ja) * | 2010-02-19 | 2011-09-01 | Toyo Ink Sc Holdings Co Ltd | 硬化性電磁波シールド性接着性フィルムおよびその製造方法 |
| KR101361533B1 (ko) * | 2012-04-12 | 2014-02-13 | 한화엘앤씨 주식회사 | 전자기파 차폐 필름 제조방법 |
| CN203015375U (zh) * | 2012-12-20 | 2013-06-19 | 深圳科诺桥科技有限公司 | 印刷电路板及高填充性电磁屏蔽膜 |
| KR20150075912A (ko) * | 2013-12-26 | 2015-07-06 | 주식회사 잉크테크 | 전자파 차폐필름의 제조방법 및 이로부터 제조된 전자파 차폐필름 |
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2013
- 2013-12-26 KR KR1020130164330A patent/KR20150075912A/ko not_active Ceased
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2014
- 2014-12-25 CN CN201410828123.4A patent/CN104754861A/zh active Pending
- 2014-12-25 CN CN201910445962.0A patent/CN110177450A/zh active Pending
- 2014-12-26 JP JP2014265459A patent/JP2015126230A/ja active Pending
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| JP2021002664A (ja) * | 2013-12-26 | 2021-01-07 | インクテック カンパニー, リミテッドInktec Co., Ltd. | 電磁波遮蔽フィルムの製造方法 |
| JP2017143275A (ja) * | 2013-12-26 | 2017-08-17 | インクテック カンパニー, リミテッドInktec Co., Ltd. | 電磁波遮蔽フィルムの製造方法及びこれから製造された電磁波遮蔽フィルム |
| JPWO2017026211A1 (ja) * | 2015-08-11 | 2018-06-07 | コニカミノルタ株式会社 | 機能性シート |
| WO2017026211A1 (ja) * | 2015-08-11 | 2017-02-16 | コニカミノルタ株式会社 | 機能性シート |
| KR20180066508A (ko) * | 2016-12-09 | 2018-06-19 | 공주대학교 산학협력단 | 전자파 차폐용 블록필름 |
| US10985111B2 (en) | 2019-03-22 | 2021-04-20 | 3M Innovative Properties Company | Electronic assembly, electronic apparatus including the same and method for fabricating electronic assembly |
| WO2020194109A1 (en) * | 2019-03-22 | 2020-10-01 | 3M Innovative Properties Company | Electronic assembly, electronic apparatus including the same and method for fabricating electronic assembly |
| JP2022526888A (ja) * | 2019-03-22 | 2022-05-27 | スリーエム イノベイティブ プロパティズ カンパニー | 電子アセンブリ、電子アセンブリを含む電子装置、及び電子アセンブリの製造方法 |
| US11355453B2 (en) | 2019-03-22 | 2022-06-07 | 3M Innovative Properties Company | Electronic assembly, electronic apparatus including the same and method for fabricating electronic assembly |
| US12068258B2 (en) | 2019-03-22 | 2024-08-20 | 3M Innovative Properties Company | Method for fabricating electronic assembly including a magnetic field shielding film |
| CN112831290A (zh) * | 2020-12-25 | 2021-05-25 | 领胜城科技(江苏)有限公司 | 一种可挠电磁屏蔽胶带的制备方法 |
| CN112831290B (zh) * | 2020-12-25 | 2022-12-06 | 领胜城科技(江苏)有限公司 | 一种可挠电磁屏蔽胶带的制备方法 |
| CN120769434A (zh) * | 2025-06-13 | 2025-10-10 | 广州源康精密电子股份有限公司 | 一种rfpc及其制作方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20150075912A (ko) | 2015-07-06 |
| CN110177450A (zh) | 2019-08-27 |
| JP2017143275A (ja) | 2017-08-17 |
| JP2021002664A (ja) | 2021-01-07 |
| CN104754861A (zh) | 2015-07-01 |
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