JP2014502302A - 低ｐｉ及び改善された低温流れを有する官能性ジエンエラストマー、及びそれを含有するゴム組成物 - Google Patents
低ｐｉ及び改善された低温流れを有する官能性ジエンエラストマー、及びそれを含有するゴム組成物 Download PDFInfo
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- JP2014502302A JP2014502302A JP2013540334A JP2013540334A JP2014502302A JP 2014502302 A JP2014502302 A JP 2014502302A JP 2013540334 A JP2013540334 A JP 2013540334A JP 2013540334 A JP2013540334 A JP 2013540334A JP 2014502302 A JP2014502302 A JP 2014502302A
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- Prior art keywords
- elastomer
- diene elastomer
- star
- functionalized
- diene
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 67
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- 238000007306 functionalization reaction Methods 0.000 claims abstract description 21
- 238000009826 distribution Methods 0.000 claims abstract description 15
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- 239000003795 chemical substances by application Substances 0.000 claims description 13
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- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
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- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 description 2
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- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920006216 polyvinyl aromatic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000006235 reinforcing carbon black Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- GPNLWUFFWOYKLP-UHFFFAOYSA-N s-(1,3-benzothiazol-2-yl)thiohydroxylamine Chemical compound C1=CC=C2SC(SN)=NC2=C1 GPNLWUFFWOYKLP-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- 239000012936 vulcanization activator Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/26—Incorporating metal atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1059641 | 2010-11-23 | ||
| FR1059641A FR2967679B1 (fr) | 2010-11-23 | 2010-11-23 | Elastomere dienique a ip faible fonctionnel a fluage a froid ameliore et composition de caoutchouc le contenant |
| PCT/EP2011/070742 WO2012069506A1 (fr) | 2010-11-23 | 2011-11-23 | Elastomère diénique à ip faible fonctionnel à fluage à froid amélioré et composition de caoutchouc le contenant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014502302A true JP2014502302A (ja) | 2014-01-30 |
| JP2014502302A5 JP2014502302A5 (https=) | 2015-01-15 |
Family
ID=43825378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013540334A Pending JP2014502302A (ja) | 2010-11-23 | 2011-11-23 | 低ｐｉ及び改善された低温流れを有する官能性ジエンエラストマー、及びそれを含有するゴム組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9624359B2 (https=) |
| EP (1) | EP2643406B1 (https=) |
| JP (1) | JP2014502302A (https=) |
| KR (1) | KR101911687B1 (https=) |
| CN (1) | CN103221475B (https=) |
| ES (1) | ES2539730T3 (https=) |
| FR (1) | FR2967679B1 (https=) |
| HU (1) | HUE026301T2 (https=) |
| PL (1) | PL2643406T3 (https=) |
| WO (1) | WO2012069506A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014503617A (ja) * | 2010-11-23 | 2014-02-13 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 特定のジエンエラストマーと特定の比表面積を有するカーボンブラックとを含む組成物 |
| JP2014105238A (ja) * | 2012-11-26 | 2014-06-09 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP2017521547A (ja) * | 2014-07-03 | 2017-08-03 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 鎖末端にシラノール官能基を有するｐｉが低いジエンエラストマー及びそれを含有する組成物 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3014872B1 (fr) * | 2013-12-18 | 2017-03-10 | Michelin & Cie | Elastomere dienique modifie et composition de caoutchouc le contenant |
| FR3038313B1 (fr) * | 2015-07-02 | 2017-07-21 | Michelin & Cie | Elastomere dienique modifie a ip reduit et composition de caoutchouc le contenant |
| FR3038315B1 (fr) * | 2015-07-02 | 2017-07-21 | Michelin & Cie | Elastomere dienique modifie a ip reduit et composition le contenant |
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| JPS6114214A (ja) * | 1984-06-29 | 1986-01-22 | Asahi Chem Ind Co Ltd | 加硫ゴム用ゴム状重合体組成物 |
| JPS6289704A (ja) * | 1985-10-15 | 1987-04-24 | Asahi Chem Ind Co Ltd | 改良されたゴム状重合体の製造方法 |
| JPS6469645A (en) * | 1987-09-09 | 1989-03-15 | Japan Synthetic Rubber Co Ltd | Rubberlike butadiene copolymer composition |
| JPH0625472A (ja) * | 1992-06-02 | 1994-02-01 | Bridgestone Corp | タイヤ踏み面組成物 |
| JPH07109384A (ja) * | 1993-10-12 | 1995-04-25 | Sumitomo Rubber Ind Ltd | ベーストレッド用ゴム組成物およびそれを用いてなるタイヤ |
| JPH09110942A (ja) * | 1995-10-16 | 1997-04-28 | Bridgestone Corp | 重合体の製造方法 |
| JP2005263893A (ja) * | 2004-03-17 | 2005-09-29 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物およびそれを用いて得られたランフラットタイヤ |
| JP2007077317A (ja) * | 2005-09-15 | 2007-03-29 | Bridgestone Corp | ゴム組成物およびそれを用いたタイヤ |
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| JPS58189203A (ja) | 1982-04-30 | 1983-11-04 | Nippon Zeon Co Ltd | ゴム組成物 |
| JPH0662808B2 (ja) | 1985-03-29 | 1994-08-17 | 日本ゼオン株式会社 | 防振ゴム |
| JPH0713158B2 (ja) | 1987-01-14 | 1995-02-15 | 株式会社ブリヂストン | タイヤ |
| DE69501999T2 (de) | 1994-10-28 | 1998-09-10 | Bridgestone Corp | Kautschukmischung für Laufflächen |
| WO1996030419A1 (en) | 1995-03-30 | 1996-10-03 | Nippon Zeon Co., Ltd. | Styrene-isoprene-butadiene copolymer rubber and process for the production thereof |
| FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
| BR9708412A (pt) | 1996-04-01 | 2000-10-24 | Cabot Corp | Aparelho, método e compostos de elastÈmero novos |
| CN100473684C (zh) | 1997-09-30 | 2009-04-01 | 卡伯特公司 | 弹性体复合共混料及其制备方法 |
| DE69822278T2 (de) | 1997-12-16 | 2004-08-12 | Jsr Corp. | Kautschuk aus einem konjugierten Diolefin -Copolymer und dessen Zusammensetzungen |
| CA2261481A1 (en) * | 1998-03-09 | 1999-09-09 | Thierry Florent Edme Materne | Rubber composition containing silica having first and second aggregates each containing different particle sizes |
| CA2377195A1 (fr) | 2000-04-25 | 2001-11-01 | Michelin Recherche Et Technique S.A. | Copolymeres a blocs pour des compositions de caoutchouc utilisables pour des pneumatiques |
| FR2808459B1 (fr) * | 2000-05-02 | 2003-01-10 | Rena Sa | Filtre exterieur a un bac, notamment a un aquarium |
| EP1311600A2 (fr) | 2000-07-31 | 2003-05-21 | Société de Technologie Michelin | Bande de roulement pour pneumatique |
| CA2425330A1 (fr) | 2000-10-13 | 2002-04-18 | Jean-Claude Tardivat | Composition de caoutchouc comportant a titre d'agent de couplage un organosilane polyfonctionnel |
| ES2256317T3 (es) | 2000-10-13 | 2006-07-16 | Societe De Technologie Michelin | Organosilano polifuncional utilizable como agente de acoplamiento y su procedimiento de obtencion. |
| FR2823215B1 (fr) | 2001-04-10 | 2005-04-08 | Michelin Soc Tech | Pneumatique et bande de roulement de pneumatique comportant a titre d'agent de couplage un tetrasulfure de bis-alkoxysilane |
| JP4536375B2 (ja) | 2001-06-28 | 2010-09-01 | ソシエテ ド テクノロジー ミシュラン | 極めて低い比表面積のシリカで強化されたタイヤトレッド |
| WO2003002648A1 (fr) | 2001-06-28 | 2003-01-09 | Societe De Technologie Michelin | Bande de roulement pour pneumatique renforcee d'une silice a basse surface specifique |
| SE519792C2 (sv) | 2001-08-17 | 2003-04-08 | Volvo Lastvagnar Ab | Metod för estimering av massan hos ett fordon vilket framförs på en väg med en varierande lutning samt metod för estimering av lutningen av den väg där ett fordon framförs |
| EP1448647A2 (fr) | 2001-10-31 | 2004-08-25 | Société de Technologie Michelin | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique |
| US20060041071A1 (en) * | 2004-08-19 | 2006-02-23 | Sandstrom Paul H | Pneumatic tire having a rubber component containing polyethylene terpolymer |
| FR2880354B1 (fr) | 2004-12-31 | 2007-03-02 | Michelin Soc Tech | Composition elastomerique renforcee d'une charge de polyvinylaromatique fonctionnalise |
| FR2880349B1 (fr) | 2004-12-31 | 2009-03-06 | Michelin Soc Tech | Nanoparticules de polyvinylaromatique fonctionnalise |
| FR2886304B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un systeme de couplage organosilicique |
| FR2886305B1 (fr) | 2005-05-26 | 2007-08-10 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosilicique et un agent de recouvrement de charge inorganique |
| FR2886306B1 (fr) | 2005-05-26 | 2007-07-06 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de couplage organosiloxane |
| US7629409B2 (en) * | 2006-09-21 | 2009-12-08 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| FR2923831B1 (fr) | 2007-11-15 | 2010-04-09 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant un agent de recouvrement hydroxysilane |
-
2010
- 2010-11-23 FR FR1059641A patent/FR2967679B1/fr not_active Expired - Fee Related
-
2011
- 2011-11-23 EP EP11785442.2A patent/EP2643406B1/fr not_active Not-in-force
- 2011-11-23 CN CN201180055467.0A patent/CN103221475B/zh active Active
- 2011-11-23 ES ES11785442.2T patent/ES2539730T3/es active Active
- 2011-11-23 HU HUE11785442A patent/HUE026301T2/en unknown
- 2011-11-23 US US13/989,103 patent/US9624359B2/en not_active Expired - Fee Related
- 2011-11-23 WO PCT/EP2011/070742 patent/WO2012069506A1/fr not_active Ceased
- 2011-11-23 KR KR1020137016303A patent/KR101911687B1/ko not_active Expired - Fee Related
- 2011-11-23 JP JP2013540334A patent/JP2014502302A/ja active Pending
- 2011-11-23 PL PL11785442T patent/PL2643406T3/pl unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS6114214A (ja) * | 1984-06-29 | 1986-01-22 | Asahi Chem Ind Co Ltd | 加硫ゴム用ゴム状重合体組成物 |
| JPS6289704A (ja) * | 1985-10-15 | 1987-04-24 | Asahi Chem Ind Co Ltd | 改良されたゴム状重合体の製造方法 |
| JPS6469645A (en) * | 1987-09-09 | 1989-03-15 | Japan Synthetic Rubber Co Ltd | Rubberlike butadiene copolymer composition |
| JPH0625472A (ja) * | 1992-06-02 | 1994-02-01 | Bridgestone Corp | タイヤ踏み面組成物 |
| JPH07109384A (ja) * | 1993-10-12 | 1995-04-25 | Sumitomo Rubber Ind Ltd | ベーストレッド用ゴム組成物およびそれを用いてなるタイヤ |
| JPH09110942A (ja) * | 1995-10-16 | 1997-04-28 | Bridgestone Corp | 重合体の製造方法 |
| JP2005263893A (ja) * | 2004-03-17 | 2005-09-29 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物およびそれを用いて得られたランフラットタイヤ |
| JP2007077317A (ja) * | 2005-09-15 | 2007-03-29 | Bridgestone Corp | ゴム組成物およびそれを用いたタイヤ |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014503617A (ja) * | 2010-11-23 | 2014-02-13 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 特定のジエンエラストマーと特定の比表面積を有するカーボンブラックとを含む組成物 |
| JP2014105238A (ja) * | 2012-11-26 | 2014-06-09 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP2017521547A (ja) * | 2014-07-03 | 2017-08-03 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 鎖末端にシラノール官能基を有するｐｉが低いジエンエラストマー及びそれを含有する組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130132491A (ko) | 2013-12-04 |
| PL2643406T3 (pl) | 2015-08-31 |
| WO2012069506A1 (fr) | 2012-05-31 |
| HUE026301T2 (en) | 2016-06-28 |
| EP2643406A1 (fr) | 2013-10-02 |
| FR2967679B1 (fr) | 2012-12-21 |
| KR101911687B1 (ko) | 2018-10-25 |
| CN103221475A (zh) | 2013-07-24 |
| US20130289163A1 (en) | 2013-10-31 |
| ES2539730T3 (es) | 2015-07-03 |
| FR2967679A1 (fr) | 2012-05-25 |
| CN103221475B (zh) | 2016-01-20 |
| US9624359B2 (en) | 2017-04-18 |
| EP2643406B1 (fr) | 2015-03-18 |
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