JP2014502254A5 - - Google Patents
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- Publication number
- JP2014502254A5 JP2014502254A5 JP2013532821A JP2013532821A JP2014502254A5 JP 2014502254 A5 JP2014502254 A5 JP 2014502254A5 JP 2013532821 A JP2013532821 A JP 2013532821A JP 2013532821 A JP2013532821 A JP 2013532821A JP 2014502254 A5 JP2014502254 A5 JP 2014502254A5
- Authority
- JP
- Japan
- Prior art keywords
- ligand
- substituted
- group
- calixarene
- organic phosphine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003446 ligand Substances 0.000 claims 15
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 14
- VTJUKNSKBAOEHE-UHFFFAOYSA-N calixarene Chemical compound COC(=O)COC1=C(CC=2C(=C(CC=3C(=C(C4)C=C(C=3)C(C)(C)C)OCC(=O)OC)C=C(C=2)C(C)(C)C)OCC(=O)OC)C=C(C(C)(C)C)C=C1CC1=C(OCC(=O)OC)C4=CC(C(C)(C)C)=C1 VTJUKNSKBAOEHE-UHFFFAOYSA-N 0.000 claims 11
- 239000000203 mixture Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 10
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 7
- 150000001336 alkenes Chemical class 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 5
- 239000001257 hydrogen Substances 0.000 claims 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 229910052723 transition metal Inorganic materials 0.000 claims 4
- 150000003624 transition metals Chemical class 0.000 claims 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical group C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 3
- 238000007037 hydroformylation reaction Methods 0.000 claims 3
- 125000003368 amide group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000000732 arylene group Chemical group 0.000 claims 2
- GQPLZGRPYWLBPW-UHFFFAOYSA-N calix[4]arene Chemical group C1C(C=2)=CC=CC=2CC(C=2)=CC=CC=2CC(C=2)=CC=CC=2CC2=CC=CC1=C2 GQPLZGRPYWLBPW-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 229930194542 Keto Natural products 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 1
- 125000004104 aryloxy group Chemical group 0.000 claims 1
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38997210P | 2010-10-05 | 2010-10-05 | |
| US61/389,972 | 2010-10-05 | ||
| PCT/US2011/052500 WO2012047514A1 (en) | 2010-10-05 | 2011-09-21 | Hydroformylation process |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015097978A Division JP6077590B2 (ja) | 2010-10-05 | 2015-05-13 | ヒドロホルミル化の方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014502254A JP2014502254A (ja) | 2014-01-30 |
| JP2014502254A5 true JP2014502254A5 (cg-RX-API-DMAC7.html) | 2014-07-10 |
Family
ID=44720184
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013532821A Withdrawn JP2014502254A (ja) | 2010-10-05 | 2011-09-21 | ヒドロホルミル化の方法 |
| JP2015097978A Active JP6077590B2 (ja) | 2010-10-05 | 2015-05-13 | ヒドロホルミル化の方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015097978A Active JP6077590B2 (ja) | 2010-10-05 | 2015-05-13 | ヒドロホルミル化の方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8741173B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2624953B1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP2014502254A (cg-RX-API-DMAC7.html) |
| CN (1) | CN103153462B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012047514A1 (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA201302026B (cg-RX-API-DMAC7.html) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101411307B1 (ko) | 2012-04-12 | 2014-06-24 | 삼성메디슨 주식회사 | 초음파 진단장치 |
| CN105384772B (zh) * | 2015-12-18 | 2020-12-18 | 湖南理工学院 | 一种制备全取代杯[8]芳烃磷酸酯衍生物的方法 |
| WO2019231610A1 (en) * | 2018-05-30 | 2019-12-05 | Dow Technology Investments Llc | Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes |
| BR112020022070B1 (pt) | 2018-05-30 | 2023-09-26 | Dow Technology Investments Llc | Método para controlar um processo de hidroformilação para produzir aldeídos |
| JP2021525166A (ja) | 2018-05-30 | 2021-09-24 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | モノホスフィン、テトラホスフィン配位子の組み合わせを含む触媒組成物、およびそれを使用するヒドロホルミル化プロセス |
| US11976017B2 (en) | 2019-12-19 | 2024-05-07 | Dow Technology Investments Llc | Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms |
| JPWO2023080071A1 (cg-RX-API-DMAC7.html) * | 2021-11-02 | 2023-05-11 | ||
| CN116693573A (zh) * | 2023-06-07 | 2023-09-05 | 北京旭阳科技有限公司 | 柱芳烃双亚磷酸酯配体及其制备方法和应用 |
| CN116726996B (zh) * | 2023-06-26 | 2025-09-09 | 北京旭阳科技有限公司 | 一种用于支链不饱和脂肪腈异构化的催化剂及其制备方法和用途 |
| WO2025006020A1 (en) | 2023-06-26 | 2025-01-02 | Dow Technology Investments Llc | Methods of controlling hydroformylation processes |
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| CN100430139C (zh) | 2006-06-09 | 2008-11-05 | 中国科学院上海有机化学研究所 | 联萘酚骨架的取代双齿亚磷酰胺配体在烯烃氢甲酰化反应中的应用 |
| KR100664657B1 (ko) | 2006-09-22 | 2007-01-04 | 주식회사 엘지화학 | 하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 |
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| RU2458906C2 (ru) | 2007-03-20 | 2012-08-20 | Дау Текнолоджи Инвестментс Ллс | Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов |
| JP5400760B2 (ja) * | 2007-04-05 | 2014-01-29 | ダウ グローバル テクノロジーズ エルエルシー | ヒドロホルミル化方法用のカリックスアレーンビスホスファイト配位子 |
| KR100964099B1 (ko) | 2007-09-14 | 2010-06-16 | 주식회사 엘지화학 | 인을 포함하는 촉매 조성물 및 이를 이용한 히드로포밀화방법 |
| WO2010021863A1 (en) * | 2008-08-19 | 2010-02-25 | Dow Technology Investments Llc | Hydroformylation process using a symmetric bisphosphite ligand for improved control over product isomers |
| RU2541537C2 (ru) * | 2009-03-31 | 2015-02-20 | Дау Текнолоджи Инвестментс Ллс | Способ гидроформилирования с помощью двойного открыто-концевого бисфосфитного лиганда |
| ES2738498T3 (es) | 2010-02-19 | 2020-01-23 | Dow Global Technologies Llc | Proceso para polimerizar un monómero de olefina y catalizador para el mismo |
-
2011
- 2011-09-21 US US13/877,386 patent/US8741173B2/en active Active
- 2011-09-21 EP EP11761799.3A patent/EP2624953B1/en active Active
- 2011-09-21 JP JP2013532821A patent/JP2014502254A/ja not_active Withdrawn
- 2011-09-21 CN CN201180048078.5A patent/CN103153462B/zh active Active
- 2011-09-21 WO PCT/US2011/052500 patent/WO2012047514A1/en not_active Ceased
-
2013
- 2013-03-18 ZA ZA2013/02026A patent/ZA201302026B/en unknown
-
2015
- 2015-05-13 JP JP2015097978A patent/JP6077590B2/ja active Active
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