KR100664657B1 - 하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 - Google Patents
하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 Download PDFInfo
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- KR100664657B1 KR100664657B1 KR1020060092387A KR20060092387A KR100664657B1 KR 100664657 B1 KR100664657 B1 KR 100664657B1 KR 1020060092387 A KR1020060092387 A KR 1020060092387A KR 20060092387 A KR20060092387 A KR 20060092387A KR 100664657 B1 KR100664657 B1 KR 100664657B1
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- catalyst
- ligand
- rhodium
- hydroformylation
- catalyst system
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
혼합옥텐 전환율 (%) | 증류생성물의 조성(%) | C9 생성물 수율(%) | C9 생성물 선택도(%) | 증류생성물중 촉매잔사 (ppm) | |||
노닐 알데히드 | 노닐알콜 | 고비점 부산물 | |||||
실시예 1 | 87.9 | 81.8 | 5.9 | 0.1 | 87.7 | 99.8 | 0.057 |
실시예 2 | 91.2 | 84.2 | 6.8 | 0.1 | 91.0 | 99.8 | 0.061 |
실시예 3 | 90.2 | 82.9 | 6.9 | 0.4 | 89.8 | 99.6 | 0.006 |
비교예 1 | 91.3 | 78.6 | 12.4 | 0.3 | 91.0 | 99.7 | 0.115 |
비교예 2 | 88.7 | 76.8 | 10.1 | 1.8 | 86.9 | 97.9 | 0.129 |
Claims (7)
- 로듐 촉매, 인계 화합물 및 ⅥB족 전이금속을 포함하는 무기아민으로 이루어지는 하이드로포르밀레이션 반응 촉매계.
- 제2항에 있어서,상기 인계 화합물은, 로듐 금속에 대하여 10 몰배 내지 100 몰배인 것을 특징으로 하는 촉매계.
- 제1항에 있어서,상기 무기아민은, 로듐 금속에 대하여 3 몰배 내지 10 몰배인 것을 특징으로 하는 촉매계.
- 제1항 내지 3항 중의 어느 한 항에 있어서,상기 무기아민이, 암모늄 디크로메이트, 암모늄 크로메이트, 암모늄 몰리브데이트, 암모늄 디몰리브데이트, 암모늄 헵타몰리브데이트, 암모늄 포스포 몰리브데이트, 암모늄 텅스테이트, 암모늄 메타텅스테이트로 이루어진 그룹에서 선택되는 것을 특징으로 하는 촉매계.
- 혼합올레핀을 수소 및 일산화탄소와 반응시켜 탄소수가 하나 더 많은 알데히 드를 제조하는 방법에 있어서, 로듐 촉매, 인계 화합물 및 ⅥB족 전이금속을 포함하는 무기아민으로 이루어지는 촉매계를 사용하는 것을 특징으로 하는 알데히드의 제조 방법.
- 제5항에 있어서,상기 혼합 올레핀이, C6~C12 올레핀을 주성분으로 하는 것임을 특징으로 하는 알데히드의 제조 방법.
- 제5항 또는 제6항에 있어서,상기 촉매를, 혼합올레핀에 대하여 로듐 금속량으로 5ppm 내지 200ppm이 되도록 사용하는 것을 특징으로 하는 알데히드의 제조 방법.
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KR1020060092387A KR100664657B1 (ko) | 2006-09-22 | 2006-09-22 | 하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 |
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KR1020060092387A KR100664657B1 (ko) | 2006-09-22 | 2006-09-22 | 하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 |
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KR1020000030312A Division KR100676299B1 (ko) | 2000-06-02 | 2000-06-02 | 하이드로포르밀레이션 반응 촉매용 배위자, 이를 함유하는촉매계 및 이를 이용한 하이드로포르밀레이션 방법 |
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KR20060118369A KR20060118369A (ko) | 2006-11-23 |
KR100664657B1 true KR100664657B1 (ko) | 2007-01-04 |
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Families Citing this family (4)
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RU2541537C2 (ru) | 2009-03-31 | 2015-02-20 | Дау Текнолоджи Инвестментс Ллс | Способ гидроформилирования с помощью двойного открыто-концевого бисфосфитного лиганда |
CN103153462B (zh) | 2010-10-05 | 2016-06-01 | 陶氏技术投资有限责任公司 | 加氢甲酰基化方法 |
CN114920643A (zh) * | 2022-04-27 | 2022-08-19 | 华东师范大学 | 一种醋酸烯丙酯制备4-乙酰氧基丁醛的方法 |
CN115007180A (zh) * | 2022-06-21 | 2022-09-06 | 烟台大学 | 一种用于烯烃氢甲酰化反应的高分散铑催化剂、其制备方法以及用途 |
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