JP2013533597A - 燃料電池を動作させるための水素添加ポリシランによる水素生成 - Google Patents
燃料電池を動作させるための水素添加ポリシランによる水素生成 Download PDFInfo
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 137
- 239000001257 hydrogen Substances 0.000 title claims abstract description 123
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 123
- 239000000446 fuel Substances 0.000 title claims abstract description 118
- 229920000548 poly(silane) polymer Polymers 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 129
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 52
- 238000003860 storage Methods 0.000 claims description 26
- 239000000376 reactant Substances 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 11
- 238000012432 intermediate storage Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 8
- 239000002918 waste heat Substances 0.000 claims description 8
- 239000000443 aerosol Substances 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 5
- 239000008188 pellet Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 11
- 230000007062 hydrolysis Effects 0.000 abstract description 9
- 239000012528 membrane Substances 0.000 abstract description 4
- 239000000969 carrier Substances 0.000 abstract description 3
- 239000003792 electrolyte Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 20
- 239000007864 aqueous solution Substances 0.000 description 18
- 238000005259 measurement Methods 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000002585 base Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 150000002431 hydrogen Chemical class 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- 239000003513 alkali Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000003637 basic solution Substances 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002407 reforming Methods 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- PXUPMNQUMKZKRK-UHFFFAOYSA-N bis(disilanylsilylsilylsilylsilylsilyl)silane Chemical compound [SiH3][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH2][SiH3] PXUPMNQUMKZKRK-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
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- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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Abstract
【選択図】図2
Description
本出願は、参照によりその内容が本明細書に援用されている、2010年7月23日に出願された独国特許出願第10 2010 032 075.7号の優先権を主張するものである。
SiH2+2NaOH+H2O→Na2SiO3+3H2
2H2+O2→2H2O
Claims (15)
- 航空機(300)における燃料電池のための水素を生成するための燃料電池供給デバイス(100)であって、
水素添加ポリシラン(126)またはその混合物を水と反応させるために設計される反応室(120)と、
少なくとも1つの反応物を前記反応室(120)に給送するための給送デバイス(112)と、
前記反応によって形成される水素を燃料電池(150)に導くための吐出デバイス(122、123、124)と
を有する燃料電池供給デバイス(100)。 - 水素添加ポリシラン(126)またはその混合物が、
粉末
粒状物
ビーズ
立方体
ペレット
多孔片
からなるグループから選択される固体構造で存在する、請求項1に記載の燃料電池供給デバイス。 - 前記反応室が塩基性媒体、好ましくはアルカリ性媒体を提供するために設計される、請求項1または請求項2に記載の燃料電池供給デバイス。
- 前記反応室(120)が金属触媒を有する、請求項1から請求項3のうちいずれか1項に記載の燃料電池供給デバイス。
- 供給デバイス(200)が、前記反応(121)によって解放される熱を利用する廃熱復熱装置(129)を有する、請求項1から請求項4のうちいずれか1項に記載の燃料電池供給デバイス。
- 前記給送デバイス(112)に水を供給するための水貯蔵タンク(110)
をさらに備える、請求項1から請求項5のうちいずれか1項に記載の燃料電池供給デバイス。 - 給送デバイス(154)が、復水のため、および水貯蔵タンク(110)に水を給送するために設計され、前記水が前記燃料電池(150)内の反応の水として形成される、請求項1から請求項6のうちいずれか1項に記載の燃料電池供給デバイス。
- 前記吐出デバイス(122、123、124、145)が、入口弁(123)および出口弁(143)を備えた、製造された前記水素を中間貯蔵するための圧力容器(140)を有する、請求項1から請求項7のうちいずれか1項に記載の燃料電池供給デバイス。
- 前記吐出デバイス(122、123、124)が、製造された前記水素の品質および/または量を測定するために設計される水素測定デバイス(130)を有する、請求項1から請求項8のうちいずれか1項に記載の燃料電池供給デバイス。
- 製造される前記水素の前記吐出デバイス(122、123、124)が残留蒸気および/またはエアロゾルのための分離デバイス(122)を有する、請求項1から請求項9のうちいずれか1項に記載の燃料電池供給デバイス。
- 制御デバイス(160)
をさらに備え、前記制御デバイス(160)が、製造される前記水素の量を添加される前記水の量によって制御する、請求項1から請求項10のうちいずれか1項に記載の燃料電池供給デバイス。 - 航空機(300)における燃料電池(150)に水素供給のための、
請求項1から請求項11のうちいずれか1項に記載の燃料電池供給デバイスの使用方法。 - 航空機のための非常システムとしての、
請求項1から請求項12のうちいずれか1項に記載の燃料電池供給デバイスの使用方法。 - 請求項1から請求項11のうちいずれか1項に記載の燃料電池供給デバイスを備えた航空機(300)。
- 航空機(300)における燃料電池(150)のための水素製造方法であって、
少なくとも1つの第1および第2の反応物を反応室(120)に給送する処理ステップであって、前記第1の反応物が水素添加ポリシラン(126)またはその混合物を有し、前記第2の反応物が水である処理ステップと、
前記第1の反応物(126)を前記反応室(120)で前記第2の反応物と反応させる処理ステップと、
前記反応によって形成される水素を前記航空機の燃料電池(150)へ導く処理ステップと
を有する水素製造方法。
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DE102010032075A DE102010032075A1 (de) | 2010-07-23 | 2010-07-23 | Wasserstofferzeugung mittels hydrierten Polysilanen zum Betrieb von Brennstoffzellen |
DE102010032075.7 | 2010-07-23 | ||
PCT/EP2011/062466 WO2012010639A1 (de) | 2010-07-23 | 2011-07-20 | Wasserstofferzeugung mittels hydrierten polysilanen zum betrieb von brennstoffzellen |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010032075A1 (de) | 2010-07-23 | 2012-01-26 | Eads Deutschland Gmbh | Wasserstofferzeugung mittels hydrierten Polysilanen zum Betrieb von Brennstoffzellen |
US20130320136A1 (en) * | 2012-05-31 | 2013-12-05 | General Electric Company | System and method for providing electrical power |
FR2999342B1 (fr) * | 2012-12-10 | 2015-05-01 | Snecma | Systeme de production d'electricite embarque avec pile a combustible |
EP2746548B1 (en) * | 2012-12-21 | 2017-03-15 | Inergy Automotive Systems Research (Société Anonyme) | Method and system for purifying the exhaust gases of a combustion engine. |
Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05194748A (ja) * | 1992-01-21 | 1993-08-03 | Shin Etsu Chem Co Ltd | 両末端ヒドロキシポリシラン及びその製造方法 |
JPH06172711A (ja) * | 1992-12-02 | 1994-06-21 | Japan Synthetic Rubber Co Ltd | コーティング用組成物 |
JP2000009685A (ja) * | 1998-06-19 | 2000-01-14 | Ngk Spark Plug Co Ltd | 水素ガスセンサ、燃料電池システム、及び水素ガス濃度測定方法 |
JP2001053355A (ja) * | 1999-08-06 | 2001-02-23 | Sharp Corp | 光電変換素子、その製造方法及び太陽電池 |
JP2001083347A (ja) * | 1999-09-16 | 2001-03-30 | Toshiba Corp | 三次元構造体およびその製造方法 |
JP2001220445A (ja) * | 2000-02-07 | 2001-08-14 | Hitachi Chem Co Ltd | ポリシランの製造方法 |
JP2002042843A (ja) * | 2000-07-24 | 2002-02-08 | Yamaha Motor Co Ltd | 燃料電池システム及び自動二輪車 |
JP2003137502A (ja) * | 2001-10-24 | 2003-05-14 | Toyota Motor Corp | 水素発生装置 |
JP2004206950A (ja) * | 2002-12-24 | 2004-07-22 | Nissan Motor Co Ltd | 燃料電池システム |
WO2007019172A2 (en) * | 2005-08-03 | 2007-02-15 | The University Of Alabama | Silanes as a source of hydrogen |
JP2007077190A (ja) * | 2005-09-12 | 2007-03-29 | Osaka Gas Co Ltd | 高屈折率ポリシラン |
JP2007115543A (ja) * | 2005-10-20 | 2007-05-10 | Toyota Motor Corp | 燃料電池のオフガス燃焼装置、燃料電池システム、オフガス燃焼部のパージ方法 |
JP2008532253A (ja) * | 2005-03-07 | 2008-08-14 | エアバス・ドイチュラント・ゲーエムベーハー | 燃料電池緊急システム |
JP2008189490A (ja) * | 2007-02-02 | 2008-08-21 | Commertechs:Kk | 水素供給装置 |
JP2008243565A (ja) * | 2007-03-27 | 2008-10-09 | Fis Inc | 燃料電池用ガス測定方法、燃料電池用ガス測定装置及び燃料電池システム |
JP2008273758A (ja) * | 2007-04-26 | 2008-11-13 | Hitachi Maxell Ltd | 水素発生材料組成物および水素発生装置 |
JP2009001460A (ja) * | 2007-06-21 | 2009-01-08 | Hitachi Maxell Ltd | 水素発生装置、およびそれを備えた燃料電池システム |
WO2009023535A2 (en) * | 2007-08-10 | 2009-02-19 | Hydrogen Solutions International | Devices and methods for improved generation of hydrogen |
JP2009046331A (ja) * | 2007-08-16 | 2009-03-05 | Seiko Instruments Inc | 水素発生装置及び燃料電池システム |
JP2009509835A (ja) * | 2005-09-29 | 2009-03-12 | エアバス・ドイチュラント・ゲーエムベーハー | 航空機システムにエネルギーを供給するエネルギー供給システム |
JP2009099491A (ja) * | 2007-10-19 | 2009-05-07 | Sharp Corp | 燃料電池システムおよび電子機器 |
JP2009526242A (ja) * | 2006-02-13 | 2009-07-16 | オルナトスキー オルガ | 元素分析によって実施される遺伝子発現アッセイ |
JP2009536604A (ja) * | 2006-05-08 | 2009-10-15 | カリフォルニア・インスティチュート・オブ・テクノロジー | 水素を貯蔵及び発生させるための方法及びシステム |
JP2009298607A (ja) * | 2008-06-10 | 2009-12-24 | Hitachi Maxell Ltd | 水素製造方法および水素製造装置、ならびに燃料電池システム |
JP2009545842A (ja) * | 2006-08-03 | 2009-12-24 | アールイーヴィー・リニューアブル・エナジー・ベンチャーズ・インコーポレイテッド | シラン又はポリシランを用いて燃料電池に水素を供給するための方法 |
JP2010516025A (ja) * | 2007-01-12 | 2010-05-13 | エアバス・オペレーションズ・ゲーエムベーハー | 燃料電池システムの燃料供給装置、燃料電池システムおよび燃料供給装置監視方法 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57108402A (en) * | 1980-12-25 | 1982-07-06 | Mitsui Eng & Shipbuild Co Ltd | Equipment for recovering heat of exhaust gas of internal combustion engine |
DE19821952C2 (de) * | 1998-05-15 | 2000-07-27 | Dbb Fuel Cell Engines Gmbh | Energieversorgungseinheit an Bord eines Luftfahrzeugs |
US6568633B2 (en) * | 2000-08-24 | 2003-05-27 | James P. Dunn | Fuel cell powered electric aircraft |
JP4457475B2 (ja) * | 2000-08-28 | 2010-04-28 | 株式会社島津製作所 | 航空機用燃料供給システム |
DE10059625A1 (de) | 2000-09-18 | 2002-05-16 | Peter Plichta | Verfahren zur Herstellung von Höheren Silanen im Hinblick auf ihre Verwendung als Treibstoffe |
JP2003059519A (ja) * | 2001-08-09 | 2003-02-28 | Mitsubishi Heavy Ind Ltd | 燃料電池システム及びコジェネレーションシステム |
CN1403578A (zh) * | 2001-09-06 | 2003-03-19 | 中国科学院大连化学物理研究所 | 一种由多菌株联合液态发酵制备氢气的方法 |
US7124790B2 (en) * | 2004-06-28 | 2006-10-24 | General Electric Company | System and method for storing and discharging hydrogen |
JP4829494B2 (ja) * | 2004-11-24 | 2011-12-07 | 本田技研工業株式会社 | 燃料電池システム |
DE102005051583A1 (de) | 2005-10-27 | 2007-05-03 | Airbus Deutschland Gmbh | Brennstoffzellensystem für die Versorgung von Luftfahrzeugen |
DE102005053694B3 (de) * | 2005-11-10 | 2007-01-04 | Airbus Deutschland Gmbh | Brennstoffzellensystem zum Löschen von Bränden |
DE102006030798B4 (de) | 2006-06-30 | 2009-04-02 | Christoph Mennel | Verwendung von Silanen als chemische Wasserstoffspeicher und silanbetriebenes Brennstoffzellensystem |
DE102006034885A1 (de) * | 2006-07-25 | 2008-08-07 | Daimlerchrysler Ag | Wasserstoff- und Energiegewinnung durch thermische Umsetzung von Silanen |
DE102006043929B4 (de) | 2006-09-14 | 2016-10-06 | Spawnt Private S.À.R.L. | Verfahren zur Herstellung von festen Polysilanmischungen |
US8205482B2 (en) * | 2006-12-28 | 2012-06-26 | Mikuni Corporation | Hydrogen sensor with detection film comprised of rare earth metal particles dispersed in a ceramic |
CN101186275A (zh) * | 2007-12-03 | 2008-05-28 | 天津海蓝德能源技术发展有限公司 | 移动式制氢储氢一体化装置及其供氢方法 |
JP5481801B2 (ja) * | 2008-04-22 | 2014-04-23 | 日産自動車株式会社 | 燃料電池システム、燃料電池システムに用いるプログラム、及び情報記録媒体。 |
DE102010032075A1 (de) | 2010-07-23 | 2012-01-26 | Eads Deutschland Gmbh | Wasserstofferzeugung mittels hydrierten Polysilanen zum Betrieb von Brennstoffzellen |
-
2010
- 2010-07-23 DE DE102010032075A patent/DE102010032075A1/de not_active Withdrawn
-
2011
- 2011-07-20 KR KR1020137004594A patent/KR101943114B1/ko active IP Right Grant
- 2011-07-20 JP JP2013521072A patent/JP2013533597A/ja active Pending
- 2011-07-20 EP EP11741424.3A patent/EP2596541B1/de not_active Not-in-force
- 2011-07-20 WO PCT/EP2011/062466 patent/WO2012010639A1/de active Application Filing
- 2011-07-20 US US13/811,521 patent/US20130266505A1/en not_active Abandoned
- 2011-07-20 CN CN201180035876.4A patent/CN103270634B/zh not_active Expired - Fee Related
-
2016
- 2016-04-28 JP JP2016090404A patent/JP2016189330A/ja active Pending
Patent Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05194748A (ja) * | 1992-01-21 | 1993-08-03 | Shin Etsu Chem Co Ltd | 両末端ヒドロキシポリシラン及びその製造方法 |
JPH06172711A (ja) * | 1992-12-02 | 1994-06-21 | Japan Synthetic Rubber Co Ltd | コーティング用組成物 |
JP2000009685A (ja) * | 1998-06-19 | 2000-01-14 | Ngk Spark Plug Co Ltd | 水素ガスセンサ、燃料電池システム、及び水素ガス濃度測定方法 |
JP2001053355A (ja) * | 1999-08-06 | 2001-02-23 | Sharp Corp | 光電変換素子、その製造方法及び太陽電池 |
JP2001083347A (ja) * | 1999-09-16 | 2001-03-30 | Toshiba Corp | 三次元構造体およびその製造方法 |
JP2001220445A (ja) * | 2000-02-07 | 2001-08-14 | Hitachi Chem Co Ltd | ポリシランの製造方法 |
JP2002042843A (ja) * | 2000-07-24 | 2002-02-08 | Yamaha Motor Co Ltd | 燃料電池システム及び自動二輪車 |
JP2003137502A (ja) * | 2001-10-24 | 2003-05-14 | Toyota Motor Corp | 水素発生装置 |
JP2004206950A (ja) * | 2002-12-24 | 2004-07-22 | Nissan Motor Co Ltd | 燃料電池システム |
JP2008532253A (ja) * | 2005-03-07 | 2008-08-14 | エアバス・ドイチュラント・ゲーエムベーハー | 燃料電池緊急システム |
WO2007019172A2 (en) * | 2005-08-03 | 2007-02-15 | The University Of Alabama | Silanes as a source of hydrogen |
JP2007077190A (ja) * | 2005-09-12 | 2007-03-29 | Osaka Gas Co Ltd | 高屈折率ポリシラン |
JP2009509835A (ja) * | 2005-09-29 | 2009-03-12 | エアバス・ドイチュラント・ゲーエムベーハー | 航空機システムにエネルギーを供給するエネルギー供給システム |
JP2007115543A (ja) * | 2005-10-20 | 2007-05-10 | Toyota Motor Corp | 燃料電池のオフガス燃焼装置、燃料電池システム、オフガス燃焼部のパージ方法 |
JP2009526242A (ja) * | 2006-02-13 | 2009-07-16 | オルナトスキー オルガ | 元素分析によって実施される遺伝子発現アッセイ |
JP2009536604A (ja) * | 2006-05-08 | 2009-10-15 | カリフォルニア・インスティチュート・オブ・テクノロジー | 水素を貯蔵及び発生させるための方法及びシステム |
JP2009545842A (ja) * | 2006-08-03 | 2009-12-24 | アールイーヴィー・リニューアブル・エナジー・ベンチャーズ・インコーポレイテッド | シラン又はポリシランを用いて燃料電池に水素を供給するための方法 |
JP2010516025A (ja) * | 2007-01-12 | 2010-05-13 | エアバス・オペレーションズ・ゲーエムベーハー | 燃料電池システムの燃料供給装置、燃料電池システムおよび燃料供給装置監視方法 |
JP2008189490A (ja) * | 2007-02-02 | 2008-08-21 | Commertechs:Kk | 水素供給装置 |
JP2008243565A (ja) * | 2007-03-27 | 2008-10-09 | Fis Inc | 燃料電池用ガス測定方法、燃料電池用ガス測定装置及び燃料電池システム |
JP2008273758A (ja) * | 2007-04-26 | 2008-11-13 | Hitachi Maxell Ltd | 水素発生材料組成物および水素発生装置 |
JP2009001460A (ja) * | 2007-06-21 | 2009-01-08 | Hitachi Maxell Ltd | 水素発生装置、およびそれを備えた燃料電池システム |
WO2009023535A2 (en) * | 2007-08-10 | 2009-02-19 | Hydrogen Solutions International | Devices and methods for improved generation of hydrogen |
JP2009046331A (ja) * | 2007-08-16 | 2009-03-05 | Seiko Instruments Inc | 水素発生装置及び燃料電池システム |
JP2009099491A (ja) * | 2007-10-19 | 2009-05-07 | Sharp Corp | 燃料電池システムおよび電子機器 |
JP2009298607A (ja) * | 2008-06-10 | 2009-12-24 | Hitachi Maxell Ltd | 水素製造方法および水素製造装置、ならびに燃料電池システム |
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CN103270634A (zh) | 2013-08-28 |
DE102010032075A1 (de) | 2012-01-26 |
DE102010032075A8 (de) | 2013-05-08 |
EP2596541B1 (de) | 2015-02-25 |
WO2012010639A1 (de) | 2012-01-26 |
KR20140035864A (ko) | 2014-03-24 |
US20130266505A1 (en) | 2013-10-10 |
EP2596541A1 (de) | 2013-05-29 |
JP2016189330A (ja) | 2016-11-04 |
CN103270634B (zh) | 2016-11-16 |
KR101943114B1 (ko) | 2019-01-28 |
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