JP2013533261A - 毛髪の洗浄方法 - Google Patents
毛髪の洗浄方法 Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
Abstract
Description
(a)前記毛髪に組成物を適用する工程と、
(b)水性溶媒を使用して、前記組成物を溶解して泡立てる工程と、
(c)水性溶媒で前記毛髪をすすぐ工程と、を含み、
前記すすぎ工程の間に、毛髪1グラム(乾燥重量)当り、合計約100グラム〜約300グラムの水性溶媒が使用され、
前記組成物が、約3重量%〜約35重量%の、少なくとも2種の式Iの化合物の混合物を含み、
化合物のうちの少なくとも1つに関しては、R1がHである場合、R2は1、2、又は3の(C1〜C3)アルキル分枝を有し、R1がメチル又はエチルである場合、R2は0、1、又は2つの(C1〜C3)アルキル分枝を有する。
(R1)aG3-a−Si−(−OSiG2)n−O−SiG3-a(R1)aIII
式中、Gは、水素、フェニル、ヒドロキシ、又はC1〜C8のアルキル、好ましくはメチルであり、aは1〜3の値を有する整数、好ましくは1であり、bは、0、1、又は2、好ましくは1であり、nは、0〜1,999の数であり、R1は、一般式CqH2qLに一致する一価のラジカルであって、式中、qは、2〜8の値を有する整数であり、Lは、基:−N(R2)CH2−CH2−N(R2)2、−N(R2)2、−N(R2)3A-、−N(R2)CH2−CH2−NR2H2A-から選択され、式中、R2は、水素、フェニル、ベンジル、又は飽和炭化水素ラジカル、好ましくは約C1〜約C20のアルキルラジカルであり、A-は、ハロゲン化物イオンである。一実施形態では、末端アミノシリコーンは、上述のような式IIIに一致し、式中、Gはメチルであり、aは1であり、bは1であり、nは200〜1000の数であり、R1は一般式CqH2qLに一致する一価のラジカルであって、式中、qは2〜8の値を有する整数であり、Lは基:−N(R2)CH2−CH2−N(R2)2、−N(R2)2、−N(R2)3A-、−N(R2)CH2−CH2−NR2H2A-から選択され、式中、R2は約C1〜約C20のアルキルラジカルであり、A-はハロゲン化物イオンである。
分枝状化合物は、メタセシスによって合成することができる。有用な機序はまた、Suguro及びMori(1979),Agric.Biol.Chem.,43(4),869、Yuasa及びTsuruta(2004),Flavour Fragr.J.,19,199でも論じられている。更には、遺伝子組み換えバクテリアを介した製造が、米国特許第2010/0105955号、同第2010/0105963号、国際公開第2007/136752号、同第2008/119082号、同第2009/111672号、及び米国特許第61/289039号で説明されている。
反応物質、及びその後続の生成物は、油から誘導することができる:トリオレエート(スキーム1に示す)、ダイズ(水素添加)、ナタネ、キャノーラ、パーム、パーム核、ココナツ、ジャトロファ、高エルカ酸ナタネ、綿実、タロー、イエローグリース、トウモロコシ、ヒマワリ、ババス、及びこれらの混合物。メタセシス反応で使用されるオレフィンは、単一の分枝オレフィン、分枝オレフィンの混合物、あるいは分枝オレフィンと、芳香族アルキル、パラフィン、分枝パラフィン、及びシクロアルカンなどの他の非反応性不純物との混合物とすることができる。
上記の手引きを参照されたい。
Claims (15)
- 毛髪の洗浄方法であって、
(a)前記毛髪に組成物を適用する工程と、
(b)水性溶媒を使用して、前記組成物を溶解して泡立てる工程と、
(c)水性溶媒で前記毛髪をすすぐ工程と、
を含み、
前記すすぎ工程の間に、毛髪1グラム(乾燥重量)当り、合計約100グラム〜約300グラムの水性溶媒が使用され、
前記組成物が、約3重量%〜約35重量%の、少なくとも2種の式Iの化合物の混合物を含み、
前記化合物のうちの少なくとも1つに関しては、R1がHである場合、R2は1、2、又は3つの(C1〜C3)アルキル分枝を有し、R1がメチル又はエチルである場合、R2は0、1、又は2つの(C1〜C3)アルキル分枝を有する、方法。 - 前記すすぎ工程の間に、毛髪1グラム(乾燥重量)当り、合計約120グラム〜約270グラムの、好ましくは140グラム〜約250グラムの、より好ましくは150グラム〜約240グラムの、更により好ましくは約160グラム〜約230グラムの、更により好ましくは約170グラム〜約210グラムの、最も好ましくは180グラム〜約200グラムの水性溶媒が使用される、請求項1に記載の方法。
- 前記組成物が、式Iによる少なくとも1つの直鎖状化合物、及び式Iによる少なくとも1つの分枝状化合物を含み、前記式Iによる直鎖状化合物中、R1はHであり、R2は(C1〜Cn)アルキル、又は(C1〜Cn)アルケニルであり、前記炭素鎖上に分枝を含まない、請求項1又は2に記載の方法。
- 直鎖状化合物対分枝状化合物の重量比(直鎖:分枝)が、約10:1〜約1:2、好ましくは約5:1〜約1:1、より好ましくは約4.5:1〜約1.75:1、最も好ましくは約3.5:1〜約2.5:1である、請求項3に記載の方法。
- 前記分枝状化合物が、末端付近分枝状化合物、中鎖分枝状化合物、及びこれらの混合物からなる群から選択され、好ましくは、前記分枝状化合物が、末端付近分枝状化合物である、請求項3又は4に記載の方法。
- 前記組成物が、美容的に許容可能な水性キャリアを更に含み、注ぐことが可能な液体の形態である、請求項1〜5のいずれか一項に記載の方法。
- 前記水性溶媒が、少なくとも約50重量%の、より好ましくは少なくとも約60重量%の、更により好ましくは少なくとも約70重量%の、更により好ましくは少なくとも約80重量%の、最も好ましくは少なくとも約90重量%の水である、請求項1〜6のいずれか一項に記載の方法。
- 前記組成物が、約4重量%〜約34重量%の、好ましくは約5重量%〜約30重量%の、より好ましくは約10重量%〜約28重量%の、最も好ましくは約20重量%〜約25重量%の、請求項1に記載されるような少なくとも2種の式Iの化合物の混合物を含む、請求項1〜7のいずれか一項に記載の方法。
- 溶解工程が、約0.1秒〜約300秒の、好ましくは約50秒〜約250秒の、より好ましくは約100秒〜約200秒の、更により好ましくは約120秒〜約180秒の、最も好ましくは約150秒〜約160秒の分散時間を含む、請求項1〜8のいずれか一項に記載の方法。
- 前記泡立てる工程が、合計0.19グラムの界面活性剤を含む組成物の泡の容積を合計200mLに到達させるために、約0.1秒〜約80秒の、好ましくは約2秒〜約60秒の、より好ましくは約5秒〜約50秒の、最も好ましくは約10秒〜約30秒の泡立て時間を含む、請求項1〜9のいずれか一項に記載の方法。
- 前記組成物がカチオン性ポリマーを更に含み、前記カチオン性ポリマーがカチオン性界面活性剤であり、前記カチオン性界面活性剤がベヘニルトリメチルアンモニウムクロリド、ベヘニルトリメチルアンモニウムメチルスルファート、若しくはベヘニルトリメチルアンモニウムエチルスルファート、及びステアリルトリメチルアンモニウムクロリド、ステアリルトリメチルアンモニウムメチルスルファート、若しくはステアリルトリメチルアンモニウムエチルスルファートからなる群から選択される、請求項1〜10のいずれか一項に記載の方法。
- 前記組成物が、ポリアクリレート会合性増粘剤、及びトリヒドロキシステアリン高分子増粘剤を、約0.5重量%未満で含み、好ましくは実質的に含まない、請求項1〜11のいずれか一項に記載の方法。
- 前記直鎖状化合物が、12〜14個の炭素原子を含むアニオン性界面活性剤の塩である、請求項3〜12のいずれか一項に記載の方法。
- 毛髪洗浄用組成物であって、約0.1秒〜約300秒の分散時間で水性溶媒中に溶解し、前記組成物は、約3重量%〜約35重量%の、請求項1に記載されるような少なくとも2種の式Iの化合物の混合物を含む、組成物。
- 毛髪洗浄用組成物の使用であって、前記組成物が、約0.1秒〜約300秒の分散時間で水性溶媒中に溶解し、前記組成物が、約3重量%〜約35重量%の、請求項1に記載されるような少なくとも2種の式Iの化合物の混合物を含む、使用。
Applications Claiming Priority (3)
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US36451910P | 2010-07-15 | 2010-07-15 | |
US61/364,519 | 2010-07-15 | ||
PCT/US2011/044012 WO2012009539A2 (en) | 2010-07-15 | 2011-07-14 | Method of cleansing hair |
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JP2013533261A true JP2013533261A (ja) | 2013-08-22 |
JP5763762B2 JP5763762B2 (ja) | 2015-08-12 |
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JP2013519819A Expired - Fee Related JP5715250B2 (ja) | 2010-07-15 | 2011-07-14 | 末端近傍分岐型アルコールを含むリンスオフ型コンディショニング組成物 |
JP2013519827A Expired - Fee Related JP5763762B2 (ja) | 2010-07-15 | 2011-07-14 | 毛髪の洗浄方法 |
JP2013519822A Active JP5852648B2 (ja) | 2010-07-15 | 2011-07-14 | 鎖端付近分枝型化合物(nearterminal−branchedcompound)を含む組成物及びその製造方法 |
JP2013519820A Expired - Fee Related JP5715251B2 (ja) | 2010-07-15 | 2011-07-14 | 末端近傍分岐型化合物を含むパーソナルケア組成物 |
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JP2013519819A Expired - Fee Related JP5715250B2 (ja) | 2010-07-15 | 2011-07-14 | 末端近傍分岐型アルコールを含むリンスオフ型コンディショニング組成物 |
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JP2013519822A Active JP5852648B2 (ja) | 2010-07-15 | 2011-07-14 | 鎖端付近分枝型化合物(nearterminal−branchedcompound)を含む組成物及びその製造方法 |
JP2013519820A Expired - Fee Related JP5715251B2 (ja) | 2010-07-15 | 2011-07-14 | 末端近傍分岐型化合物を含むパーソナルケア組成物 |
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US (4) | US8765651B2 (ja) |
EP (4) | EP2593073A2 (ja) |
JP (4) | JP5715250B2 (ja) |
CN (3) | CN103228253B (ja) |
BR (3) | BR112013000601A2 (ja) |
CA (3) | CA2803380A1 (ja) |
HK (1) | HK1185796A1 (ja) |
MX (4) | MX2013000593A (ja) |
RU (3) | RU2012154736A (ja) |
WO (4) | WO2012009523A2 (ja) |
ZA (3) | ZA201209477B (ja) |
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