JP2013526033A - 太陽光モジュール用バックシート及びその製造方法 - Google Patents
太陽光モジュール用バックシート及びその製造方法 Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 12
- 239000011247 coating layer Substances 0.000 claims abstract description 59
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000011737 fluorine Substances 0.000 claims abstract description 54
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 54
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 46
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000853 adhesive Substances 0.000 claims abstract description 32
- 238000000576 coating method Methods 0.000 claims abstract description 29
- 229920006267 polyester film Polymers 0.000 claims abstract description 27
- 239000008199 coating composition Substances 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 239000002033 PVDF binder Substances 0.000 claims abstract description 13
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims description 15
- 229920005822 acrylic binder Polymers 0.000 claims description 10
- 229920000877 Melamine resin Polymers 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 9
- ADTHJEKIUIOLBX-UHFFFAOYSA-N 1,1,3,4,4,5,5,6,6,6-decafluoro-3-(trifluoromethyl)hex-1-ene Chemical compound FC(C(F)(F)F)(C(C(C(F)(F)F)(C=C(F)F)F)(F)F)F ADTHJEKIUIOLBX-UHFFFAOYSA-N 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- WQJUXXKWIKZLQF-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)-(methoxymethyl)amino]methanol Chemical group COCN(CO)C1=NC(N)=NC(N)=N1 WQJUXXKWIKZLQF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004645 polyester resin Substances 0.000 claims description 4
- 229920001225 polyester resin Polymers 0.000 claims description 4
- 238000009998 heat setting Methods 0.000 claims description 2
- 239000003566 sealing material Substances 0.000 abstract description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 21
- 230000000704 physical effect Effects 0.000 description 12
- 239000005038 ethylene vinyl acetate Substances 0.000 description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- 229920002799 BoPET Polymers 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- -1 solar cell Polymers 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910007116 SnPb Inorganic materials 0.000 description 1
- 238000007611 bar coating method Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/049—Protective back sheets
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/16—Homopolymers or copolymers of vinylidene fluoride
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
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- C—CHEMISTRY; METALLURGY
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- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/20—Homopolymers or copolymers of hexafluoropropene
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- Y10T428/254—Polymeric or resinous material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Microelectronics & Electronic Packaging (AREA)
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Abstract
【選択図】なし
Description
ASTM D3359−97 Standard Test Methods For Measuring Adhesion By Tape Testを利用した。
A:コーティング層剥離現象無し
B:コーティング層剥離現象10%
C:コーティング層剥離現象14%
D:コーティング層剥離現象31%
−合格:A
−不合格:B、C、D
測定装備:ベリアン社製、Cary5000UV−visible spectrophotometerを用いて測定した。
−合格:1%以下
−不合格:1%以上
易接着性アクリル系エマルジョン(1)の製造
アクリル系バインダー樹脂(Primal−3208(ダウ社製)の固形分含量基準)4重量%、メラミン系架橋剤としてメトキシメチルメチロールメラミン1.5重量%、硬化触媒としてチオシアン酸アンモニウム0.15重量%及び水 94.35重量%を混合してアクリル系エマルジョンを製造した。
水分が100ppm以下に除去されたポリエチレンテレフタレートチップを溶融押出機に注入して溶融した後、T−ダイを用いて押出しながら、表面温度が20℃であるキャスティングドラムで急冷、固化し、2000μmの厚さを有するポリエチレンテレフタレートシートを製造した。
前記アクリル系コーティング層が形成された二軸延伸されたポリエステルフィルムのアクリル系コーティング層の上部にポリビニリデンフルオライド20重量%、二酸化チタン(ルチル型、粒径220nm)5重量%及び溶剤(ジメチルアセトアミド)75重量%をサンドミル法により分散したフッ素コーティング組成物を15μmの乾燥塗布厚みで塗布した。
前記実施例1で、バックシート製造時に二酸化チタンの含量を6重量%に調節したこと以外は実施例1と同様な方法で製造した。
前記実施例1で、バックシート製造時に二酸化チタンの含量を7重量%に調節したこと以外は実施例1と同様な方法で製造した。
前記実施例1で、バックシート製造時に二酸化チタンの含量を8重量%に調節したこと以外は実施例1と同様な方法で製造した。
前記実施例1で、バックシート製造時にポリビニリデンフルオライドの代わりにテトラフルオロエチレン−ヘキサフルオロプロピレン−ビニリデンフルオライド(THV)を用いて、150nmの粒径を有する二酸化チタンを用いること以外は実施例1と同様な方法で製造した。
前記実施例1で、バックシート製造時に二酸化チタンが含まれていないフッ素コーティング組成物を用いたこと以外は同様に製造した。
前記実施例1で、バックシート製造時にフッ素コーティング組成物としてポリビニリデンフルオライド20重量%、二酸化チタン(ルチル型、粒径220nm)4重量%及び溶剤(ジメチルアセトアミド)80重量%をサンドミル法で分散したフッ素コーティング組成物を15μmの乾燥塗布厚みで塗布した。
前記実施例1で、アクリル系コーティング層の乾燥塗布厚みを40nmに製造したこと以外は実施例1と同様に製造した。
コロナで表面処理された二軸延伸されたポリエステルフィルムの上部にポリビニリデンフルオライド20重量%、二酸化チタン(ルチル型、粒径220nm)5重量%及び溶剤(ジメチルアセトアミド)75重量%をサンドミル法で分散したフッ素コーティング組成物を15μmの乾燥塗布厚みで塗布した。
Claims (10)
- 一面または両面に易接着性アクリル系コーティング層が形成されたポリエステルフィルム層と、
前記アクリル系コーティング層の上部にポリビニリデンフルオライドまたはテトラフルオロエチレン−ヘキサフルオロプロピレン−ビニリデンフルオライドから選択されるフッ素樹脂と二酸化チタンを含有するフッ素コーティング組成物を塗布したフッ素コーティング層と、
を含む、太陽光モジュール用バックシート。 - 前記二酸化チタンは150〜300nmの粒径を有するルチル型である、請求項1に記載の太陽光モジュール用バックシート。
- 前記易接着性アクリル系コーティング層は、アクリル系バインダー樹脂2〜10重量%、メラミン系架橋剤0.2〜4重量%、硬化触媒0.02〜0.5重量%、及び水を合計100重量%になるように含有したアクリル系エマルジョンを用いてポリエステルフィルムの延伸工程でインラインコーティングされる、請求項1に記載の太陽光モジュール用バックシート。
- 前記メラミン系架橋剤はメトキシメチルメチロールメラミンである、請求項3に記載の太陽光モジュール用バックシート。
- 前記易接着性アクリル系コーティング層は乾燥塗布厚みが50〜300nmであり、フッ素コーティング層は乾燥塗布厚みが10〜30μmである、請求項1に記載の太陽光モジュール用バックシート。
- 前記延伸工程は二軸延伸工程であり、縦方向に延伸した後、アクリル系エマルジョンを塗布してから横方向に延伸する、請求項3に記載の太陽光モジュール用バックシート。
- a)ポリエステル樹脂を溶融押出してポリエステルシートを製造する段階と、
b)前記ポリエステルシートを縦方向に延伸する段階と、
c)前記縦方向に延伸されたポリエステルフィルムの一面または両面にアクリル系バインダー樹脂2〜10重量%、メラミン系架橋剤0.2〜4重量%、硬化触媒0.02〜0.5重量%、及び水を合計100重量%になるように含有したアクリル系エマルジョンを塗布して易接着性アクリル系コーティング層を形成した後、横方向に延伸する段階と、
d)前記二軸延伸されたポリエステルフィルムを熱固定する段階と、
e)前記易接着性アクリル系コーティング層の上部にポリビニリデンフルオライドまたはテトラフルオロエチレン−ヘキサフルオロプロピレン−ビニリデンフルオライドから選択されるフッ素樹脂と二酸化チタンを含有するフッ素コーティング組成物をオフラインで塗布してフッ素コーティング層を形成する段階と、
を含む、太陽光モジュール用バックシートの製造方法。 - 前記二酸化チタンは150〜300nmの粒径を有するルチル型であり、含量が30〜40重量%である、請求項7に記載の太陽光モジュール用バックシートの製造方法。
- 前記メラミン系架橋剤はメトキシメチルメチロールメラミンである、請求項7に記載の太陽光モジュール用バックシートの製造方法。
- 前記易接着性アクリル系コーティング層は乾燥塗布厚みが50〜300nmであり、フッ素コーティング層は乾燥塗布厚みが10〜30μmである、請求項7に記載の太陽光モジュール用バックシートの製造方法。
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CN103151407B (zh) * | 2013-01-30 | 2015-06-17 | 宁波长阳科技有限公司 | 一种太阳能电池背板及其制备方法 |
CN103579391B (zh) * | 2013-11-07 | 2017-02-15 | 英利集团有限公司 | 太阳能电池背板及具有其的太阳能电池组件 |
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