JP2013515063A5 - - Google Patents

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JP2013515063A5
JP2013515063A5 JP2012546047A JP2012546047A JP2013515063A5 JP 2013515063 A5 JP2013515063 A5 JP 2013515063A5 JP 2012546047 A JP2012546047 A JP 2012546047A JP 2012546047 A JP2012546047 A JP 2012546047A JP 2013515063 A5 JP2013515063 A5 JP 2013515063A5
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Japan
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reaction zone
olefinically unsaturated
unsaturated compound
catalyst
ratio
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JP2012546047A
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JP5912084B2 (ja
JP2013515063A (ja
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Priority claimed from PCT/US2010/060523 external-priority patent/WO2011087696A1/en
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JP2012546047A 2009-12-22 2010-12-15 オレフィン分圧の制御による、混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御 Active JP5912084B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28914909P 2009-12-22 2009-12-22
US61/289,149 2009-12-22
PCT/US2010/060523 WO2011087696A1 (en) 2009-12-22 2010-12-15 Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure

Publications (3)

Publication Number Publication Date
JP2013515063A JP2013515063A (ja) 2013-05-02
JP2013515063A5 true JP2013515063A5 (https=) 2014-02-06
JP5912084B2 JP5912084B2 (ja) 2016-04-27

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JP2012546047A Active JP5912084B2 (ja) 2009-12-22 2010-12-15 オレフィン分圧の制御による、混合リガンドヒドロホルミル化プロセスにおけるノルマル：イソアルデヒド比の制御

Country Status (7)

Country Link
US (1) US8664451B2 (https=)
EP (2) EP2516371B2 (https=)
JP (1) JP5912084B2 (https=)
CN (2) CN102741209B (https=)
TW (1) TWI518064B (https=)
WO (1) WO2011087696A1 (https=)
ZA (1) ZA201204576B (https=)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102741210B (zh) † 2009-12-22 2016-02-24 陶氏技术投资有限责任公司 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
EP2516371B2 (en) † 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
US9539566B2 (en) * 2012-08-29 2017-01-10 Dow Technology Investments Llc Catalyst preparation process
DE102015202722A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen
DE102014209536A1 (de) 2014-05-20 2015-11-26 Evonik Degussa Gmbh Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen
DE102014209533A1 (de) 2014-05-20 2015-12-17 Evonik Degussa Gmbh Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion
RU2562971C1 (ru) * 2014-10-10 2015-09-10 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Способ непрерывного гидроформилирования олефинов с3-с21 в альдегиды
RU2584952C1 (ru) * 2015-03-26 2016-05-20 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") Гидрид-карбонильный полифосфитный комплекс родия со смешанными фосфорорганическими лигандами для катализа процесса гидроформилирования олефинов
KR102092803B1 (ko) * 2016-01-13 2020-03-24 주식회사 엘지화학 인계 리간드를 포함하는 촉매 조성물을 이용한 하이드로포밀화 방법
MX2018009690A (es) * 2016-02-11 2018-09-11 Dow Technology Investments Llc Procesos para convertir olefinas en alcoholes, eteres o combinaciones de los mismos.
EP3466540B1 (en) * 2017-05-29 2022-04-06 LG Chem, Ltd. Catalyst composition for hydroformylation reaction and method for preparing aldehyde using same
KR102131788B1 (ko) 2017-05-29 2020-07-09 주식회사 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드 제조방법
JP2021525165A (ja) 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒失活を遅らせるための方法、および／またはテトラホスフィン配位子の使用を遅らせるための方法
WO2019231613A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
WO2019231611A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods of controlling hydroformylation processes
US11976017B2 (en) 2019-12-19 2024-05-07 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
JP7707517B2 (ja) * 2020-06-02 2025-07-15 三菱ケミカル株式会社 アルデヒドの製造方法
MX2023010493A (es) 2021-03-31 2023-09-18 Dow Technology Investments Llc Procesos de hidroformilacion.
CN113402367A (zh) * 2021-06-16 2021-09-17 上海华谊（集团）公司 连续氢甲酰化反应中调节正异比的方法
GB202213997D0 (en) * 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3415906A (en) 1964-05-29 1968-12-10 Hooker Chemical Corp Phosphite phospholane and phosphorinane compounds
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4169861A (en) 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
US4567302A (en) 1984-07-20 1986-01-28 Angus Chemical Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4885401A (en) 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5059710A (en) 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US4873213A (en) * 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins
US5114473A (en) 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
US5277532A (en) 1989-07-31 1994-01-11 Cefin S.P.A. Mechanical acceleration device in can welding machines
US5210318A (en) 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
DE4026406A1 (de) 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5179055A (en) 1990-09-24 1993-01-12 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
US5102505A (en) 1990-11-09 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Mixed aldehyde product separation by distillation
TW213465B (https=) 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
DE4204808A1 (de) † 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5312996A (en) † 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5288918A (en) * 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5364950A (en) 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5763677A (en) † 1995-12-06 1998-06-09 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation processes
EP0839787A1 (en) 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
DE19717359B4 (de) † 1996-04-30 2014-10-30 Mitsubishi Chemical Corp. Bisphosphitverbindungen und Verfahren zu deren Herstellung
US5892119A (en) 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5874640A (en) † 1996-11-26 1999-02-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US6090987A (en) 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
JP3921853B2 (ja) † 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
US6294700B1 (en) 2000-03-15 2001-09-25 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
EP1249439A1 (en) † 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process
KR20060096433A (ko) 2003-10-21 2006-09-11 바스프 악티엔게젤샤프트 알데히드의 연속식 제조 방법
DE102004033410A1 (de) † 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
KR100547587B1 (ko) 2004-06-12 2006-01-31 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
KR100596365B1 (ko) 2004-06-12 2006-07-03 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
CN1993311B (zh) 2004-08-02 2010-06-23 陶氏技术投资有限责任公司 加氢甲酰基化过程的稳定化
DE102004055832A1 (de) * 2004-11-19 2006-06-01 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von Aldehyden
BRPI0619982A2 (pt) † 2005-12-15 2011-10-25 The Penn State Research Foundation ligantes de tetrafósforo para hidroformilação catalìtica e reações relacionadas
US7586010B2 (en) 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
CN101657407B (zh) * 2007-03-20 2014-02-12 陶氏技术投资有限公司 改善对产物同分异构体的控制的加氢甲酰基化方法
JP5298119B2 (ja) * 2007-04-09 2013-09-25 エルジー・ケム・リミテッド ホスファイト配位子を含む触媒組成物およびこれを用いたヒドロホルミル化方法
CN101293818B (zh) 2007-04-28 2010-07-07 中国石油化工股份有限公司 混合丁烯氢甲酰化的两段反应方法
CN101565353B (zh) 2008-04-25 2013-01-02 中国石油化工股份有限公司 一种2-丙基庚醇的制备方法
EP2516371B2 (en) † 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
CA2784943C (en) † 2009-12-22 2016-09-06 Dow Technology Investments Llc Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
CN102741210B (zh) † 2009-12-22 2016-02-24 陶氏技术投资有限责任公司 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率

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