JP2013511385A - 結晶性の多孔性有無機混成体及びその製造方法 - Google Patents
結晶性の多孔性有無機混成体及びその製造方法 Download PDFInfo
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- JP2013511385A JP2013511385A JP2012539808A JP2012539808A JP2013511385A JP 2013511385 A JP2013511385 A JP 2013511385A JP 2012539808 A JP2012539808 A JP 2012539808A JP 2012539808 A JP2012539808 A JP 2012539808A JP 2013511385 A JP2013511385 A JP 2013511385A
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910017855 NH 4 F Inorganic materials 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- AFJBSFJEXMGPHF-UHFFFAOYSA-K [Cu+3].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O Chemical compound [Cu+3].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O AFJBSFJEXMGPHF-UHFFFAOYSA-K 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
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- 238000009835 boiling Methods 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
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- 230000002209 hydrophobic effect Effects 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
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- 238000001308 synthesis method Methods 0.000 description 2
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- VOYADQIFGGIKAT-UHFFFAOYSA-N 1,3-dibutyl-4-hydroxy-2,6-dioxopyrimidine-5-carboximidamide Chemical compound CCCCn1c(O)c(C(N)=N)c(=O)n(CCCC)c1=O VOYADQIFGGIKAT-UHFFFAOYSA-N 0.000 description 1
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- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
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- GTJRZGYSUGOPQL-UHFFFAOYSA-B [Ti+4].[Ti+4].[Ti+4].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O GTJRZGYSUGOPQL-UHFFFAOYSA-B 0.000 description 1
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- ZZCONUBOESKGOK-UHFFFAOYSA-N aluminum;trinitrate;hydrate Chemical compound O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZZCONUBOESKGOK-UHFFFAOYSA-N 0.000 description 1
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- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
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- 238000005886 esterification reaction Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
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- 229910002804 graphite Inorganic materials 0.000 description 1
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- 229910052736 halogen Inorganic materials 0.000 description 1
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
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- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
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- 125000005647 linker group Chemical group 0.000 description 1
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- LUYZTDPLLWFWQU-UHFFFAOYSA-L magnesium;terephthalate Chemical compound [Mg+2].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 LUYZTDPLLWFWQU-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- WLJVNTCWHIRURA-UHFFFAOYSA-M pimelate(1-) Chemical compound OC(=O)CCCCCC([O-])=O WLJVNTCWHIRURA-UHFFFAOYSA-M 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
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- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
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- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
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- 239000013259 porous coordination polymer Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000003373 pyrazinyl group Chemical group 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
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- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
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- 239000000741 silica gel Substances 0.000 description 1
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- 239000010944 silver (metal) Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
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- 238000003756 stirring Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- CXJNRRJXWSODHK-UHFFFAOYSA-J terephthalate;titanium(4+) Chemical compound [Ti+4].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 CXJNRRJXWSODHK-UHFFFAOYSA-J 0.000 description 1
- FTFRVSISARKWKE-UHFFFAOYSA-J terephthalate;zirconium(4+) Chemical compound [Zr+4].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 FTFRVSISARKWKE-UHFFFAOYSA-J 0.000 description 1
- ZRDBZUCODTYDBU-UHFFFAOYSA-H trimagnesium;benzene-1,2,3-tricarboxylate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1C([O-])=O ZRDBZUCODTYDBU-UHFFFAOYSA-H 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/282—Porous sorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
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Abstract
Description
ガラス反応器に鉄ナイトレート(Fe(NO3)3・6H2O)67mmol及び1,3,5-ベンゼントリカルボン酸(BTCA)44mmolを添加した後、蒸溜水を加え、反応物の最終のモル比は、Fe(NO3)3・6H2O:BTCA:H2O=1:0.66:11.3であった。前記反応物を室温で500rpmで20分間撹拌し、均一な反応物になるようにした。前記の前処理された反応物を含有したガラス反応器を反応温度120℃、8時間維持して結晶化反応を行なった後、室温で冷却洗浄(蒸溜水)及び乾燥して多孔性有無機混成体(鉄ベンゼントリカルボキシレート;Fe-BTC)を製造した。多孔性有無機混成体(Fe-BTC)製造時の反応圧力を測定してみた結果、前記反応温度120℃での内部圧力は1barであった。理論にこだわることではないが、このような低圧合成工程は、反応温度でFe-BTC結晶が溶媒を急速に吸収するからであると判断される。
さらに、HFを添加して混合物を製造することを除き、実施例1と同一の方法により、多孔性有無機混成体を製造した。反応物の最終のモル比は、Fe(NO3)3・6H2O:BTCA:H2O:HF=1:0.66:11.3:0.15であった。前記反応物を室温で500rpmで20分間撹拌し、均一な反応物になるようにした。前記前処理された反応物を含有したテフロン(登録商標)反応器を反応温度120℃、12時間維持して結晶化反応を行なった後、室温で冷却洗浄(蒸溜水)及び乾燥して多孔性有無機混成体(Fe-BTC)を製造した。多孔性有無機混成体(Fe-BTC)の製造時の反応圧力を測定してみた結果、前記反応温度120℃での内部圧力は1barであった。理論にこだわることではないが、このような結果は、120℃でFe-BTC結晶が溶媒を急速に吸着するからであるものと考えられる。
金属塩として鉄ナイトレートの代わりに鉄塩化物(FeCl3・6H2O)を用い、実施例1と同一の方法により多孔性有無機混成体(Fe-BTC)を製造した。X-線回折スペクトラムの形態が文献上[Chemical Communication 2820、2007]のFe-BTCと同一の構造であることを確認した。ICP分析の結果、得られた多孔性有無機混成体Fe-BTCは、フッ素が含まれていない化学式Fe3O(H2O)2Cl1-yOHy[C6H3-(CO2)3]2・nH2O(0<y<1、0<n<50)で表すことができる物質であることが確認された。
テフロン(登録商標)反応器にCr(NO3)3・9H2O、及び1,4-ベンゼンジカルボン酸(BDCA)を添加した後、蒸溜水を添加して反応物の最終のモル比がCr:BDCA:H2O=1:1:12となるようにした。前記反応物を含有したテフロン(登録商標)反応器を還流オーブンに入れ、210℃で11時間反応をさせた後、室温で冷却した後、遠心分離、蒸溜水を利用した洗浄、乾燥させて多孔性有無機混成体として表面積が3,800m2/gであるクロムテレフタルレート(クロムベンゼンジカルボキシレート;Cr-BDC)を得た。得られた有無機混成体Cr-BDC0.1gを70℃で30分真空乾燥させた後、水分の吸着実験を重量法で行なった。相対湿度60%で吸着剤重量当たり水分吸着量が1.2g/gであった(3時間以内)。
反応温度が100℃であることを除き、実施例1と同一の方法により、多孔性有無機混成体(Fe-BTC)を製造した。X-線回折スペクトラムの形態が文献上[Chemical Communication 2820、2007]のFe-BTCと同一の構造であるが、ICP分析の結果、得られた多孔性有無機混成体Fe-BTCは、フッ素が含まれていない化学式Fe3O(H2O)2OH[C6H3 -(CO2)3]2・nH2O(0<n<50)で表すことができる物質であることが確認された。
実施例1の鉄ナイトレートの代わりにアルミニウムナイトレート水和物を用いて有無機混成体を製造した。但し、製造されたAl-BTCを300℃窒素雰囲気で熱処理し、残留したBTCAリガンドを除去した窒素吸着量を測定した結果、比表面積が1,930m2/gであった。
テフロン(登録商標)反応器に金属鉄塩化物(FeCl3)40.8mmol及び1,3,5-ベンゼントリカルボン酸(BTCA)26.8mmolを添加した後、蒸溜水を加え、反応物の最終のモル比は、FeCl3:BTCA:H2O=1:0.66:34であった。前記反応物を室温で500rpmで20分間撹拌し、均一な反応物になるようにした。前記前処理された反応物を含有したテフロン(登録商標)反応器を反応温度160℃、8時間維持して結晶化反応を行なった後、室温で冷却、洗浄(蒸溜水)及び乾燥して多孔性有無機混成体(Fe-BTC)を形成した。
前記実施例7において、FeCl3の代わりに、VCl3を用いたことを除去し、実施例7と同一に多孔性有無機混成体を製造した。X-線回折スペクトラムから実施例7と同一の構造の物質が得られることを確認した。電子顕微鏡の写真から100nm程度の均一な粒径特性を有する多孔性有無機混成体が得られることを確認することができた。
前記実施例1において得られたFe-BTC粉末を、偏心プレス(Korsch社 EK0型)を用いてペレットを製造した。先ず、モールディングされる粒子間の粘着力を増加させるために、黒煙3重量%とFe-BTC97重量%を混合した後、24時間ボールミリングした。混合及びボールミリングの後、パウダーの結晶性は、純粋Fe-BTCと比べてほとんど変化されないことを確認した。前記ボールミリング粉末を偏心プレスを用いて成形した結果、結晶性が20%程度減少された直径3mmFe-BTCペレットを得ることができた。
前記実施例1のFe-BTC粉末に水10重量%入れて練り込んだFe-BTCスラリーをシリンダー型押出機に投入し、押出機の内部を真空状態に維持し、シリンダーの回転速度50rpm、300mm/分の成形速度で押出体を製造した。製造された押出体を80℃で12時間の間乾燥した後、焼成炉を利用して120℃から2時間熱処理した。最終の押出成形体のBET表面積は、1710m2/gであった。
多孔性有無機混成体(Fe-BTCA)は、テフロン(登録商標)反応器に鉄ナイトレート(Fe(NO3)3・6H2O)67mmol及び1,3,5-ベンゼントリカルボン酸(BTCA)44mmolを添加した後、蒸溜水を加え、反応物の最終のモル比は、Fe(NO3)3・6H2O:BTCA:H2O=1:0.66:278であった。前記反応物を室温で500rpmで20分間撹拌し、均一な反応物になるようにした。前記の前処理された反応物を含有したテフロン(登録商標)反応器を反応温度160℃、12時間維持し、結晶化反応を行なった後、室温で冷却洗浄(蒸溜水)及び乾燥して多孔性有無機混成体(Fe-BTC)を製造した。X-線回折スペクトラムの形態が文献上[Chemical Communication 2820、2007]のFe-BTCと同一の構造であることを確認した。ICP分析の結果、得られた多孔性有無機混成体Fe-BTCは、フッ素が含まれていない化学式Fe3O(H2O)2OH[C6H3-(CO2)3]2・nH2O(0<n<50)で表すことができる物質であることが確認された。窒素吸脱着実験の結果、表面積が1700m2/gであった。反応器1L当たり多孔性有無機混成体の収率が8gであった。
商業用水分吸着剤として用いられるカーボン(Ecopro Carbon比表面積=665m2/g、細孔体積=0.39ml/g)を準備した。前記カーボン吸着剤を100℃で30分間真空乾燥させた後、実施例2と同一の条件で水分吸着実験を進行した結果、水分吸着量は0.36g/gであった。すなわち、実施例2の吸着剤は、脱着温度を70℃にしたにもかかわらず、本発明による吸着剤は2.2倍以上の水分吸着量を示した。
商業用水分吸着剤として用いられるゼオライトY(アルドリチ社、Si/Al=5.6、比表面積=827m2/g、細孔体積=0.35ml/g)を準備した。前記ゼオライトY吸着剤を200℃で30分間真空乾燥させた後、実施例2と同一の条件で水分吸着実験を進行した結果、水分吸着量は0.35g/gであった。すなわち、実施例2の吸着剤は、脱着温度を70℃にしたにもかかわらず、本発明による吸着剤は2.2倍以上の水分吸着量を示した。
Claims (20)
- 下記ステップを含む結晶性の多孔性有無機混成体の製造方法:一つ以上の無機金属前駆体、一つ以上のリガンドとして作用することができる 有機化合物及び溶媒を含有する反応物混合液を製造するステップ(ステップ1);及び前記反応物混合液から反応を通じて結晶性の多孔性有無機混成体を形成するステップ(ステップ2)、ここで、前記反応は、3気圧以下の圧力で行なわれる。
- 前記反応物混合液のうち、無機金属前駆体に対する溶媒のモル比が100以下であることを特徴とする請求項1に記載の結晶性の多孔性有無機混成体の製造方法。
- 前記ステップ1の金属前駆体が Ti、Zr、Hf、V、Nb、Ta、Cr、Mo、W、Mn、Re、Fe、Ru、Os、Co、Rh、Ir、Ni、Pd、Pt、Cu、Ag、Au、Zn、Cd、Hg、Mg、Ca、Sr、Ba、Sc、Y、Al、Ga、In、Tl、Si、Ge、Sn、Pb、As、Sb及びBiからなる群より選ばれる一つ以上の金属またはこれを含む化合物であることを特徴とする請求項1に記載の結晶性の多孔性有無機混成体の製造方法。
- 前記ステップ1の金属前駆体がCr、Fe、Al、Cu、Mn、Ti、Zr、Sn及びVからなる群より選ばれる一つ以上の金属またはこれを含む化合物であることを特徴とする請求項1に記載の結晶性の多孔性有無機混成体の製造方法。
- 前記ステップ1のリガンドとして作用することができる有機化合物が、カルボキシル基、カルボン酸の陰イオン基、アミノ基(-NH2)、イミノ基(>C=NH)、アミド基(-CONH2)、スルホン酸基(-SO3H)、スルホン酸陰イオン基(-SO3-)、メタンジチオサン基(-CS2H)、メタンジチオサン陰イオン基(-CS2-)、ピリジン基及びピラジン基からなる群より選ばれる一つ以上の作用基を有する化合物またはこの混合物であることを特徴とする請求項1に記載の結晶性の多孔性有無機混成体の製造方法。
- カルボン酸の陰イオン基を有する化合物が、ベンゼンジカルボン酸、ナフタレンジカルボン酸、ベンゼントリカルボン酸 、ナフタレントリカルボン酸 、ベンゼントリ安息香酸、ピリジンジカルボン酸、ビピリジルカルボン酸、ギ酸、蓚酸、マロン酸、コハク酸、グルタル酸、ヘキサンジオ酸、ヘプタンジオ酸及びシクロヘキシルジカルボン酸からなる群より選ばれる一つ以上の化合物から由来されることを特徴とする請求項5に記載の結晶性の多孔性有無機混成体の製造方法。
- ステップ2で得られた多孔性有無機混成体を無機塩、酸度調節剤、溶媒またはこれらの混合物で処理することにより、結晶性の多孔性有無機混成体内の不純物を精製するステップ(ステップ3)をさらに含むことを特徴とする結晶性の多孔性有無機混成体の製造方法。
- 請求項1乃至7のいずれか一項による方法で製造され、前記結晶性の多孔性有無機混成体が、下記化学式で表される化合物またはこの水和物から選ばれる1種以上の化合物であることを特徴とする結晶性の多孔性有無機混成体:
M3X(H2O)2O[C6Z4-yZ'y(CO2)2]3(M=Fe、Mn、Cr、V、Al、Ti、ZrまたはMg;X=Cl、Br、I、FまたはOH;ZまたはZ'=H、NH2、Br、I、NO2またはOH;0≦y≦4);
M3O(H2O)2X[C6Z3-yZ'y-(CO2)3]2(M=Fe、Mn、Cr、V、Al、Ti、ZrまたはMg;X=Cl、Br、I、FまたはOH;ZまたはZ'=H、NH2、Br、I、NO2またはOH;0≦y≦3);
M3O(H2O)2X1-y(OH)y[C6H3-(CO2)3]2(0≦y≦1;M=Fe、Mn、Cr、V、Al、Ti、ZrまたはMg;X=Cl、Br、IまたはF);または
M3X1-y(OH)y(H2O)2O[C6H4(CO2)2]3(0≦y≦1;M=Fe、Mn、Cr、V、Al、Ti、ZrまたはMg;X=Cl、Br、IまたはF)。 - 請求項1乃至7のいずれか一項による方法で製造され、前記多孔性有無機混成体が、銅テレフタルレート、鉄テレフタルレート、マンガンテレフタルレート、クロムテレフタルレート、バナジウムテレフタルレート、アルミニウムテレフタルレート、銅ベンゼントリカルボキシレート、鉄ベンゼントリカルボキシレート、マンガンベンゼントリカルボキシレート、クロムベンゼントリカルボキシレート、バナジウムベンゼントリカルボキシレート、アルミニウムベンゼントリカルボキシレート、鉄ベンゼントリベンゾエート、クロムベンゼントリベンゾエート、アルミニウムベンゼントリベンゾエート、これらの誘導体、これらの溶媒化物、これらの水和物またはこれらの組み合わせを含むことを特徴とする結晶性の多孔性有無機混成体。
- 請求項1乃至7のいずれか一項による方法で製造され、テレフタルレート、ベンゼントリベンゾエート及びベンゼントリカルボキシレートからなる群より選ばれる2個以上のリガンドと金属元素を含むことを特徴とする結晶性の多孔性有無機混成体。
- 請求項1乃至7のいずれか一項による方法で製造され、前記多孔性有無機混成体が 、粉末、薄膜、メンブレイン、ペレット、ボール、フォーム(foam)、スラリー、ペースト、ペイント、ハニコム(honeycomb)、ビード、メッシュ、繊維、ダンボール(corrugated sheet)またはローターの形態で製造されることを特徴とする結晶性の多孔性有無機混成体。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を用いて水分を吸着することを特徴とする水分吸着剤。
- 前記水分吸着剤が10〜100℃で吸着剤1g当たり0.1〜3gの吸着物質を吸着することができることを特徴とする請求項12に記載の水分吸着剤。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含むことを特徴とする空気浄化用フィルター。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含み、蒸気相または粒子相の揮発性有機化合物(VOCs)の吸着のために用いられることを特徴とする吸着剤。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含み、シックハウス症候群を起こすホルムアルデヒド、アセトアルデヒド、タール、ニトロソアミン類、ポリサイクリックアロマティックハイドロカボン類からなる群より選ばれる一つ以上の蒸気相または粒子相物質の吸着のために用いられることを特徴とする吸着剤。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含むことを特徴とする不均一触媒。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含むことを特徴とする吸着式冷房及び空調器システム。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含むことを特徴とするヒートポンプ。
- 請求項1乃至7のいずれか一項による方法で製造される結晶性の多孔性有無機混成体を含むことを特徴とする下水処理装置。
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KR20190026352A (ko) * | 2017-09-05 | 2019-03-13 | 재단법인대구경북과학기술원 | 금속유기구조체의 상온 활성화를 위한 다단계 배위치환법 및 이에 따라 제조된 금속유기구조체 |
KR101978050B1 (ko) * | 2017-09-05 | 2019-09-03 | 재단법인대구경북과학기술원 | 금속유기구조체의 상온 활성화를 위한 다단계 배위치환법 및 이에 따라 제조된 금속유기구조체 |
JP2019112325A (ja) * | 2017-12-21 | 2019-07-11 | 株式会社豊田中央研究所 | アルミニウム有機構造体、それを用いた吸着材料、及びそれらの製造方法 |
JP7049595B2 (ja) | 2017-12-21 | 2022-04-07 | 株式会社豊田中央研究所 | アルミニウム有機構造体、それを用いた吸着材料、及びそれらの製造方法 |
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JP7170410B2 (ja) | 2018-03-29 | 2022-11-14 | 大阪瓦斯株式会社 | 調湿素子 |
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US8252950B2 (en) | 2012-08-28 |
KR101158456B1 (ko) | 2012-06-19 |
US8507399B2 (en) | 2013-08-13 |
EP2502671A2 (en) | 2012-09-26 |
US20110118490A1 (en) | 2011-05-19 |
EP2502671B1 (en) | 2018-03-21 |
KR20110055066A (ko) | 2011-05-25 |
WO2011062412A2 (ko) | 2011-05-26 |
WO2011062412A3 (ko) | 2011-11-10 |
JP2018021008A (ja) | 2018-02-08 |
US20120289399A1 (en) | 2012-11-15 |
EP2502671A4 (en) | 2013-05-29 |
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