JP2012522050A - まつげを処理するためのマスカラ組成物および方法 - Google Patents
まつげを処理するためのマスカラ組成物および方法 Download PDFInfo
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- JP2012522050A JP2012522050A JP2012503471A JP2012503471A JP2012522050A JP 2012522050 A JP2012522050 A JP 2012522050A JP 2012503471 A JP2012503471 A JP 2012503471A JP 2012503471 A JP2012503471 A JP 2012503471A JP 2012522050 A JP2012522050 A JP 2012522050A
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- Prior art keywords
- copolymer
- acrylate
- acrylates
- composition
- methacrylate
- Prior art date
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- 239000012178 vegetable wax Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 229940075420 xanthine Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
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Abstract
Description
本組成物は、複数種の水溶性または分散性フィルム形成性ポリマーを含有する水相を含む。推奨範囲は組成物の約0.1〜95%、好ましくは約0.5〜50%、より好ましくは約0.5〜20%である。好適なフィルム形成性ポリマーは、合成または天然のポリマーを含み得る。合成ポリマーの例としては、アクリル酸、メタクリル酸またはこれらの単純なC1-10アルキルエステル等のエチレン系不飽和モノマーから得られるもの;あるいはアクリルアミド、アクリル酸アンモニウム、アクリレート、メタクリレート、ブチルアクリルアミド、アクリル酸エチルヘキシル、オクチルアクリルアミド、ネオデカン酸ビニル、アクリル酸ステアリル、メタクリル酸メチル、アジピン酸、ブタジエン、酢酸ビニル、ビニルアルコール、ビニルピロリドン、アクリル酸、アクリル酸イソブチル、メタクリル酸イソブチル、アクリル酸ナトリウム、メタクリル酸ヒドロキシエチル、スチレン、アクリル酸アンモニウム、ブチルアクリルアミド、アクリル酸ナトリウム、アクリル酸ステアリル、無水マレイン酸、エチレン、プロピレン、イソホロンジイソシアネート、イソシアネート、ジイソシアネート、フタル酸、メタクリル酸エチル、トシルアミド等のホモもしくはコポリマーが挙げられる。
本発明の組成物は、好ましくはエマルジョンの形態であり、油中水型、または水中油型エマルジョンの形態であり得る。好適な油は揮発性または非揮発性であって良く、また有機油、シリコーン油、もしくは炭化水素油であって良い。本明細書で使用する場合、「油」という用語は一般に、室温(25℃)で注ぐことが可能な(pourable)油を意味する。油は、約0.1〜99%、好ましくは約0.5〜90%、より好ましくは約1〜85%の範囲で存在し得る。
本発明の組成物において使用する固体または半固体の乳化剤は、約0.01〜50%、好ましくは約0.05〜45%、より好ましくは約0.1〜35%の範囲の量で存在し得る。乳化剤は室温(例えば25℃)で固体または半固体であり、組成物の粘度を上昇させたり、濃くするために使用する。好適な固体または半固体の乳化剤は合成または天然由来のものであって良く、アルコキシル化C12-40直鎖もしくは分岐鎖脂肪アルコール等のアルコキシル化アルコール、アルコキシル化した天然の水素化したもしくは水素化していない固体もしくは半固体油、アルキレングリコール等が挙げられる。より具体的な例としては、2〜500の範囲の数のエチレンオキシド反復単位を有するラウレス、ステアレス、イソステアレス、ベヘネス等のアルコキシル化脂肪アルコール;約5〜200の範囲のアルキレンオキシドもしくはエチレンオキシド反復単位を有するポリエチレングリコール等のポリアルキレングリコール;天然源由来のエトキシ化水素化乳化剤、例えばヒマシ油;エトキシ化分岐鎖脂肪エトキシ化乳化剤等が挙げられる。好適な固体または半固体乳化剤のより具体的な例としては、PEG-20、ステアレス-2、ステアレス-21、ステアレス-100、PEG-40水素化ヒマシ油、PEG-6デシルテトラデセス-30等が挙げられる。
一実施形態において、本組成物は不透明ワックスを実質的に含まない。組成物が実質的に含まない不透明ワックスとしては、ビースワックス、カルナウバ、オゾケライト、合成ワックス、ヤマモモワックス、キャンデリラ、アカシア、セレシン、セチルエステル、フラワーワックス(flower wax)、シトラスワックス(citrus wax)、ホホバワックス、モクロウ、ポリエチレン、マイクロクリスタリン、米ぬか(rice bran)、ラノリンワックス、ミンク、モンタン、ヤマモモ(bayberry)、オウリキュリー(ouricury)、オゾケライト、パームカーネルワックス(palm kernel wax)、パラフィン、アボカドワックス、アップルワックス(apple wax)、シェラックワックス、サルビアワックス(clary wax)、ビール粕ワックス(spent grain wax)、グレープワックス(grape wax)等が挙げられる。
また、本組成物中に1種以上の保湿剤を含めることが好ましい場合がある。存在する場合、このような保湿剤は、組成物の総重量に基づいて約0.001〜25%、好ましくは約0.005〜20%、より好ましくは約0.1〜15%の範囲であり得る。好適な保湿剤の例としては、グリコール、糖類等が挙げられる。好適なグリコールはモノマーまたはポリマーの形態であり、ポリエチレンおよびポリプロピレングリコール、例えば4〜200の反復エチレンオキシド単位を有するポリエチレングリコールであるPEG 4-200;並びにC1-6アルキレングリコール、例えばプロピレングリコール、ブチレングリコール、ペンチレングリコール等が挙げられる。好適な糖類は、そのいくつかは多価アルコールでもあるが、好適な保湿剤でもある。このような糖類の例としては、グルコース、フルクトース、ハチミツ、水添ハチミツ、イノシトール、マルトース、マンニトール、マルチトール、ソルビトール、スクロース、キシリトール、キシロース等が挙げられる。好適なものはまた、尿素である。好ましくは、本発明の組成物において使用する保湿剤は、C1-6、好ましくはC2-4アルキレングリコール、最も特定すればブチレングリコールである。
本組成物はまた、好ましくは1種以上の顔料を含有する。顔料は、有機または無機であり得る。有機顔料は一般に、D&CおよびFD&C ブルー、ブラウン、グリーン、オレンジ、レッド、イエロー等と指定されているアゾ、インジゴイド、トリフェニルメタン、アントロキノン、およびキサンチン染料を含む、種々の芳香族化合物の型である。有機顔料は一般に、レーキと呼ばれる認定された着色添加物の不溶性の金属塩からなる。無機顔料としては、酸化鉄、ウルトラマリン、クロム、水酸化クロム、およびこれらの混合物が挙げられる。赤色、青色、黄色、褐色、黒色の酸化鉄、およびこれらの混合物が好適である。推奨範囲は約0.001〜40%、好ましくは約0.005〜35%、より好ましくは約0.01〜30%であり得る。
本組成物はまた、まつげを長く、強調する繊維を含有し得る。存在する場合、こうした繊維は、組成物の約0.01〜20%、好ましくは約0.05〜15%、より好ましくは約0.1〜10%の範囲であり得る。繊維は天然のものであっても合成したものであっても良く、ナイロン、シルク、ポリエチレン、ポリエチレンテレフタレート、ポリプロピレン、マイクロデニール(microdenier)繊維等が挙げられる。
一実施形態において、本組成物は油相フィルム形成性ポリマーを実質的に含まない。組成物に含まれない油相フィルム形成性ポリマーの例としては、トリメチルシロキシケイ酸等のシリコーン樹脂、メチルシルセスキオキサン、ポリアミド等のMT樹脂が挙げられる。
Claims (21)
- 水相に複数種の水溶性または分散性フィルム形成性ポリマーを含有し、かつ固体または半固体状の1種以上の乳化剤によって構造化されている、不透明ワックスを実質的に含まない水および油のエマルジョンマスカラ組成物。
- 乳化剤がアルコキシル化アルコール、アルコキシル化C12-20直鎖もしくは分岐鎖脂肪アルコール、またはこれらの混合物である、請求項1に記載の組成物。
- 乳化剤がPEG-20、ステアレス-2、ステアレス-21、PEG-40水添ヒマシ油、またはこれらの混合物から選択される、請求項1に記載の組成物。
- 更に繊維を含有する、請求項1に記載の組成物。
- 水溶性または分散性のフィルム形成性ポリマーが、アクリルアミド、アクリル酸アンモニウム、アクリレート、メタクリレート、ブチルアクリルアミド、アクリル酸エチルヘキシル、オクチルアクリルアミド、ネオデカン酸ビニル、アクリル酸ステアリル、メタクリル酸メチル、アジピン酸、ブタジエン、酢酸ビニル、ビニルアルコール、ビニルピロリドン、アクリル酸、アクリル酸イソブチル、メタクリル酸イソブチル、アクリル酸ナトリウム、メタクリル酸ヒドロキシエチル、スチレン、アクリル酸アンモニウム、ブチルアクリルアミド、アクリル酸ナトリウム、アクリル酸ステアリル、無水マレイン酸、エチレン、プロピレン、イソホロンジイソシアネート、イソシアネート、ジイソシアネート、フタル酸、メタクリル酸エチル、トシルアミド、もしくはこれらの混合物のホモポリマーまたはコポリマーである、請求項1に記載の組成物。
- フィルム形成性ポリマーが、メタクリル酸メチルクロスポリマー;ポリイミド-1;ジステアレス-100 IPDIコポリマー;加水分解コムギタンパク質/シスチンビス-PG-プロピルシラントリオールコポリマー;PVA;ポリスチレンスルホン酸ナトリウム;加水分解コムギタンパク質/PVP クロスポリマー;アクリレーツコポリマー;アクリレーツ/オクチルアクリルアミドコポリマー;メタクリル酸メチルクロスポリマー;PVP;PVA;またはこれらの混合物から選択される、請求項5に記載の組成物。
- 少なくとも1種の保湿剤を更に含有する、請求項6に記載の組成物。
- 少なくとも1種の非揮発性油を更に含有する、請求項6に記載の組成物。
- 非揮発性油が炭化水素を含む、請求項8に記載の組成物。
- 非揮発性炭化水素油がポリブテン、ポリイソブテン、ポリデセン、またはこれらの混合物を含む、請求項9に記載の組成物。
- フィルム形成性ポリマーが、アクリレーツコポリマー、アクリレーツ/オクチルアクリルアミドコポリマー、ポリビニルアルコール、ジステアレス-100 IPDIコポリマー、PVA、PVP、メタクリル酸メチルクロスポリマー、ポリスチレンスルホン酸ナトリウム、加水分解コムギタンパク質/PVPクロスポリマー、ポリイミド-1、およびこれらの混合物から選択される、請求項1に記載の組成物。
- 複数種の水溶性または分散性フィルム形成性ポリマーを含有する水相を含み、かつ油相フィルム形成性ポリマーを実質的に含まない、水および油のエマルジョンマスカラ組成物であって、固体または半固体状の1種以上の乳化剤によって構造化されている、上記組成物。
- 複数種の水溶性または分散性フィルム形成性ポリマーが、アクリルアミド、アクリル酸アンモニウム、アクリレート、メタクリレート、ブチルアクリルアミド、アクリル酸エチルヘキシル、オクチルアクリルアミド、ネオデカン酸ビニル、アクリル酸ステアリル、メタクリル酸メチル、アジピン酸、ブタジエン、酢酸ビニル、ビニルアルコール、ビニルピロリドン、アクリル酸、アクリル酸イソブチル、メタクリル酸イソブチル、アクリル酸ナトリウム、メタクリル酸ヒドロキシエチル、スチレン、アクリル酸アンモニウム、ブチルアクリルアミド、アクリル酸ナトリウム、アクリル酸ステアリル、無水マレイン酸、エチレン、プロピレン、イソホロンジイソシアネート、イソシアネート、ジイソシアネート、フタル酸、メタクリル酸エチル、トシルアミド、もしくはこれらの混合物のホモポリマーまたはコポリマーである、請求項12に記載の組成物。
- 複数種の水溶性または分散性フィルム形成性ポリマーが、アクリルアミド/アクリル酸アンモニウムコポリマー、アクリルアミドコポリマー;アクリルアミド/アクリル酸ナトリウムコポリマー;アクリルアミド/アクリロイルジメチルタウリンナトリウム/アクリル酸コポリマー;アクリレーツ/アクリルアミドコポリマー;アクリレーツ/メタクリル酸アンモニウムコポリマー;アクリレーツ/メタクリル酸ベヘニル/メタクリル酸ジメチコンコポリマー;アクリレーツ/ビスヒドロキシプロピルジメチコンクロスポリマー;アクリレーツ/t-ブチルアクリルアミドコポリマー;アクリレーツ/メタクリル酸C12-22アルキルコポリマー;アクリレーツ/メタクリル酸ジメチルアミノエチルコポリマー;アクリレーツ/アクリル酸エチルヘキシルコポリマー;アクリレーツ/アクリル酸エチルヘキシル/スチレンコポリマー;アクリレーツ/アクリル酸ヒドロキシエチル/アクリル酸メトキシエチルコポリマー;アクリレーツ/アクリル酸ステアリル/メタクリレートコポリマー;アクリレーツ/VPコポリマー;アクリレーツ/VAコポリマー;アクリレーツ/VAクロスポリマー;アクリレーツ/VP/メタクリル酸ジメチルアミノエチルコポリマー;アジピン酸ジエチレングリコール/グリセリンクロスポリマー;ステアリン酸アリル/VAコポリマー;アクリル酸アンモニウムコポリマー;アクリル酸アンモニウム/アクリル酸エチルヘキシルコポリマー;スチレン/アクリレーツコポリマーアンモニウム;VA/アクリレーツコポリマーアンモニウム;VA/クロトン酸コポリマーアンモニウム;メタクリル酸ベヘニル/メタクリル酸パーフルオロオクチルエチルコポリマー;アクリル酸ブチル/メタクリル酸エチルヘキシルコポリマー;アクリル酸ブチル/ジメタクリル酸グリコールコポリマー;アクリル酸ブチル/スチレンアクリレートコポリマー;イソブチレン/MAコポリマー;アクリル酸ラウリル/VAコポリマー;ポリアクリレート1;ポリアクリレート2;ポリアクリレート5;ポリアクリレート6;ポリアクリレート8;ポリアクリレート9;ポリアクリレート12;ポリアクリレート13;ポリアクリレート14;ポリアクリレート15;ポリアクリレート16;ポリアクリレート17;ポリアクリレート18;ポリアクリレート19;ポリアクリル酸;ポリアミド1;ポリアミド2;ポリエステル1;ポリエステル2;ポリエステル3;ポリエステル4;ポリエステル5;ポリアクリル酸エチル;ポリメタクリルアミド;ポリウレタン1;ポリウレタン2;ポリウレタン4;ポリウレタン5;ポリウレタン6;ポリウレタン7;ポリウレタン8;ポリウレタン10;ポリウレタン11;ポリウレタン12;ポリウレタン13;ポリウレタン14;ポリウレタン15;ポリウレタン16;ポリウレタン17;ポリウレタン20;ポリウレタン21;ポリ酢酸ビニル;ポリビニルアルコール;PVP,PVM/MAコポリマー;PVM/MAデカジエンコポリマー;PVP/MAコポリマー;PVP/VA/プロピオン酸ビニルコポリマー;PVP/VA/イタコネートコポリマー;PVM/MAコポリマー;アクリル酸ナトリウムコポリマー;スチレン/アクリレーツコポリマーナトリウム;スチレン/MAコポリマー;スチレン/VAコポリマー;VA/クロトネートコポリマー;VP/アクリル酸ジメチルアミノエチルコポリマー;メタクリル酸メチルクロスポリマー;ジステアレス-100 IPDIコポリマー;加水分解コムギタンパク質/シスチンビス-PG-プロピルシラントリオールコポリマー;PVA; ポリスチレンスルホン酸ナトリウム;加水分解コムギタンパク質/PVPクロスポリマー;アクリレーツコポリマー;またはこれらの混合物から選択される、請求項12に記載の組成物。
- 固体または半固体の乳化剤がアルコキシル化アルコールを含む、請求項13に記載の組成物。
- 固体または半固体の乳化剤がアルコキシル化脂肪アルコールを含む、請求項14に記載の組成物。
- 更に繊維を含有する、請求項14に記載の組成物。
- 複数種の水溶性もしくは分散性フィルム形成性ポリマーを含む水相を含有し、かつ固体もしくは半固体状の少なくとも1種の乳化剤によって構造化されている水および油のエマルジョンから構成される、不透明ワックスを実質的に含まないマスカラ組成物を適用することによって、まつげを長くし、着色し、またはカールさせる方法。
- 組成物が少なくとも1種の保湿剤を更に含有する、請求項17に記載の方法。
- 組成物が少なくとも1種の炭化水素油を更に含有する、請求項17に記載の方法。
- 炭化水素油がポリブテン、ポリイソブテン、ポリデセン、またはこれらの混合物を含む、請求項20に記載の方法。
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US12/414,816 US20100247470A1 (en) | 2009-03-31 | 2009-03-31 | Mascara Compositions And Methods For Treating Lashes |
PCT/US2010/027134 WO2010117552A2 (en) | 2009-03-31 | 2010-03-12 | Mascara compositions and method for treating lashes |
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EP (1) | EP2413897A4 (ja) |
JP (1) | JP5914324B2 (ja) |
KR (1) | KR101372772B1 (ja) |
AU (1) | AU2010235065B2 (ja) |
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KR20160137779A (ko) * | 2015-05-21 | 2016-12-01 | 한국콜마주식회사 | 볼륨감, 컬링력 및 컬링 유지력이 우수한 화장료 조성물 |
KR102406691B1 (ko) * | 2015-05-21 | 2022-06-13 | 한국콜마주식회사 | 볼륨감, 컬링력 및 컬링 유지력이 우수한 화장료 조성물 |
JP7341589B2 (ja) | 2019-03-20 | 2023-09-11 | エルジー ハウスホールド アンド ヘルスケア リミテッド | 非水系分散液、その製造方法及びそれを含む化粧料組成物 |
JP2022525246A (ja) * | 2020-03-24 | 2022-05-11 | イーエルシー マネージメント エルエルシー | 局所製剤の性能を改善するための噴霧可能な皮膜形成組成物 |
JP7284294B2 (ja) | 2020-03-24 | 2023-05-30 | イーエルシー マネージメント エルエルシー | 局所製剤の性能を改善するための噴霧可能な皮膜形成組成物 |
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AU2010235065B2 (en) | 2013-09-12 |
KR101372772B1 (ko) | 2014-03-10 |
WO2010117552A2 (en) | 2010-10-14 |
US20160310373A1 (en) | 2016-10-27 |
CA2756122A1 (en) | 2010-10-14 |
EP2413897A2 (en) | 2012-02-08 |
KR20110130451A (ko) | 2011-12-05 |
AU2010235065A1 (en) | 2011-10-20 |
CA2756122C (en) | 2013-07-16 |
EP2413897A4 (en) | 2015-04-22 |
JP5914324B2 (ja) | 2016-05-11 |
US20100247470A1 (en) | 2010-09-30 |
WO2010117552A3 (en) | 2011-01-13 |
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