JP2012148525A - 感熱記録材料 - Google Patents
感熱記録材料 Download PDFInfo
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- JP2012148525A JP2012148525A JP2011010425A JP2011010425A JP2012148525A JP 2012148525 A JP2012148525 A JP 2012148525A JP 2011010425 A JP2011010425 A JP 2011010425A JP 2011010425 A JP2011010425 A JP 2011010425A JP 2012148525 A JP2012148525 A JP 2012148525A
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- 239000000463 material Substances 0.000 title claims abstract description 60
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- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- DJWFNQUDPJTSAD-UHFFFAOYSA-N n-octadecyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCCCCCCCC DJWFNQUDPJTSAD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
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- BRNPAEUKZMBRLQ-UHFFFAOYSA-N octadecyl 3,4,5-trihydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 BRNPAEUKZMBRLQ-UHFFFAOYSA-N 0.000 description 1
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- CGEXUOTXYSGBLV-UHFFFAOYSA-N phenyl benzenesulfonate Chemical compound C=1C=CC=CC=1S(=O)(=O)OC1=CC=CC=C1 CGEXUOTXYSGBLV-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
【解決手段】支持体上に電子供与性染料前駆体及び電子受容性顕色剤を含有する感熱記録層を設けた感熱記録材料において、該感熱記録層が電子受容性顕色剤として4,4′−ジヒドロキシジフェニルスルホン、発色反応を促進する低融点の熱可溶成分としてジフェニルスルホン、結合剤としてアクリロニトリルを必須成分とするコアとメタアクリルアミドを必須成分とするシェルからなるコアシェル構造を有する水分散性高分子重合体を含有し、かつJIS−P−8117で規定されるガーレー透気抵抗度が170秒以上である感熱記録材料。
【選択図】なし
Description
(1)塗工用紙の作製
(中間層用塗工液)
焼成カオリン 100部
50%スチレンブタジエンエマルジョン 24部
水 200部
上記の中間層用塗工液を、坪量50g/m2の上質紙に、固形分塗工量として10g/m2となるように塗工、乾燥して、塗工用紙を作製した。作製した塗工用紙のガーレー透気抵抗度は82秒であった。
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、顕色剤分散液を得た。
4,4′−ジヒドロキシジフェニルスルホン 30部
10%スルホン酸変性ポリビニルアルコール水溶液 30部
(日本合成化学工業(株)、ゴーセランL−3266)
水 40部
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、染料前駆体分散液を得た。
3−ジブチルアミノ−6−メチル−7−アニリノフルオラン 15部
10%スルホン酸変性ポリビニルアルコール水溶液 15部
水 20部
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、増感剤分散液を得た。
ジフェニルスルホン 45部
10%スルホン酸変性ポリビニルアルコール水溶液 45部
水 60部
上記の分散液を使用して、下記に示す配合で混合し、十分攪拌して感熱記録層塗液を得た。
顕色剤分散液 100部
染料前駆体分散液 50部
増感剤分散液 150部
10%コアシェル型アクリルエマルジョン 300部
(三井化学(株)、BM−1000)
30%水酸化アルミニウム水分散液 150部
50%ステアリン酸亜鉛水分散液 30部
水 50部
上記塗工用紙に、上記感熱記録層塗液を染料前駆体の塗工量で0.22g/m2となるように塗工して乾燥した後、カレンダー処理を行って感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部を200部に減らし、10%ポリビニルアルコール水溶液100部を添加した以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%コアシェル型アクリルエマルジョン(三井化学(株)、OM−1050)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(6)感熱記録材料の作製において、カレンダー処理を行った後、更にスーパーカレンダー処理(線圧80kN/m、2ニップ)を行った以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(6)感熱記録材料の作製において、カレンダー処理を行った後、更にスーパーカレンダー処理(線圧120kN/m、2ニップ)を行った以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%ポリビニルアルコール水溶液300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%アクリルエマルジョン(ジョンソンポリマー(株)、PDX−7616A、コアシェル構造を有さないアクリルエマルジョン)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%スチレンブタジエンエマルジョン(日本ゼオン(株)、Nipol F43)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部を75部に減らし、10%ポリビニルアルコール水溶液225部を添加した以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(4)増感剤分散液の調製において、ジフェニルスルホン45部に代えて、2−ベンジルオキシナフタレン45部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(1)塗工用紙の作製において、中間層用塗工液で用いた50%スチレンブタジエンエマルジョン24部を120部に増やした以外は同様にして塗工用紙を作製し、これに比較例1の感熱記録層塗液を比較例1と同様に塗工して感熱記録材料を作製した。なお、作製した塗工用紙のガーレー透気抵抗度は161秒であった。
作製した各感熱記録材料それぞれについて、印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅0.8msecで通電して印字した。印字部分における発色濃度を、濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.7以上
○:印字部分の発色濃度が0.6以上0.7未満
△:印字部分の発色濃度が0.5以上0.6未満
×:印字部分の発色濃度が0.5未満
作製した各感熱記録材料それぞれについて、50℃・95%RHの環境下で24時間静置した後に、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、更に印字部分を目視で観察して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.75以上
○:印字部分の発色濃度が0.55以上0.75未満
△:印字部分の発色濃度が0.55以上0.75未満であるが、ムラが目立つ
×:印字部分の発色濃度が0.55未満
作製した各感熱記録材料それぞれについて、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字した感熱記録材料を70℃・DRYの環境下に24時間静置した後、印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.6以上
○:印字部分の発色濃度が0.5以上0.6未満
△:印字部分の発色濃度が0.4以上0.5未満
×:印字部分の光学濃度が0.4未満
作製した各感熱記録材料それぞれについて、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字した感熱記録材料を50℃・95%RHの環境下に24時間静置した後、印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、更に印字部分を目視で観察して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.8以上
○:印字部分の発色濃度が0.6以上0.8未満
△:印字部分の発色濃度が0.6以上0.8未満であり、印字面にかすれが発生する
×:印字部分の光学濃度が0.6未満
作製した各感熱記録材料それぞれのガーレー透気抵抗度は、JIS−P−8117に基づいて測定した。
Claims (1)
- 支持体上に電子供与性染料前駆体及び電子受容性顕色剤を含有する感熱記録層を設けた感熱記録材料において、該感熱記録層が電子受容性顕色剤として4,4′−ジヒドロキシジフェニルスルホン、発色反応を促進する低融点の熱可溶成分としてジフェニルスルホン、結合剤としてアクリロニトリルを必須成分とするコアとメタアクリルアミドを必須成分とするシェルからなるコアシェル構造を有する水分散性高分子重合体を含有し、かつJIS−P−8117で規定されるガーレー透気抵抗度が170秒以上であることを特徴とする感熱記録材料。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102016219091A1 (de) | 2015-10-02 | 2017-04-06 | Mitsubishi Paper Mills Limited | Thermisches Aufzeichnungsmaterial |
JP2017206010A (ja) * | 2016-05-20 | 2017-11-24 | ダウ グローバル テクノロジーズ エルエルシー | 弾性散在層を含む熱的に印刷可能な紙製品 |
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JP2000318322A (ja) * | 1999-03-05 | 2000-11-21 | Nippon Paper Industries Co Ltd | 感熱記録シート |
JP2001260544A (ja) * | 2000-03-22 | 2001-09-25 | Nicca Chemical Co Ltd | 感熱記録材料 |
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JP2002347344A (ja) * | 2001-05-25 | 2002-12-04 | Nippon Paper Industries Co Ltd | レーザー記録型感熱記録体 |
JP2008073930A (ja) * | 2006-09-20 | 2008-04-03 | Mitsubishi Paper Mills Ltd | 感熱記録材料及び感熱記録材料積層体 |
JP2008080568A (ja) * | 2006-09-26 | 2008-04-10 | Mitsubishi Paper Mills Ltd | 感熱記録材料及び感熱記録材料積層体 |
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JPH06115247A (ja) * | 1992-09-30 | 1994-04-26 | Mitsubishi Paper Mills Ltd | 感熱記録材料 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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DE102016219091A1 (de) | 2015-10-02 | 2017-04-06 | Mitsubishi Paper Mills Limited | Thermisches Aufzeichnungsmaterial |
DE102016219091B4 (de) | 2015-10-02 | 2021-12-02 | Mitsubishi Paper Mills Limited | Thermisches Aufzeichnungsmaterial |
JP2017206010A (ja) * | 2016-05-20 | 2017-11-24 | ダウ グローバル テクノロジーズ エルエルシー | 弾性散在層を含む熱的に印刷可能な紙製品 |
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