JP5700648B2 - 感熱記録材料 - Google Patents
感熱記録材料 Download PDFInfo
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- JP5700648B2 JP5700648B2 JP2011010425A JP2011010425A JP5700648B2 JP 5700648 B2 JP5700648 B2 JP 5700648B2 JP 2011010425 A JP2011010425 A JP 2011010425A JP 2011010425 A JP2011010425 A JP 2011010425A JP 5700648 B2 JP5700648 B2 JP 5700648B2
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- 239000000463 material Substances 0.000 title claims description 57
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 36
- 239000011258 core-shell material Substances 0.000 claims description 21
- 238000011161 development Methods 0.000 claims description 18
- 239000011230 binding agent Substances 0.000 claims description 14
- 239000002243 precursor Substances 0.000 claims description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
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- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000035699 permeability Effects 0.000 claims description 4
- 150000003457 sulfones Chemical class 0.000 claims description 3
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 60
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 3
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- WLTCCDHHWYAMCG-UHFFFAOYSA-N 2-phenylmethoxynaphthalene Chemical compound C=1C=C2C=CC=CC2=CC=1OCC1=CC=CC=C1 WLTCCDHHWYAMCG-UHFFFAOYSA-N 0.000 description 2
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 2
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
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- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
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- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
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- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FEEPBTVZSYQUDP-UHFFFAOYSA-N heptatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O FEEPBTVZSYQUDP-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- GKFFBAQBFJBIDR-UHFFFAOYSA-N methyl 2,2-bis(4-hydroxyphenyl)acetate Chemical compound C=1C=C(O)C=CC=1C(C(=O)OC)C1=CC=C(O)C=C1 GKFFBAQBFJBIDR-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JKRIULAJORWCLQ-UHFFFAOYSA-N n-(3-hydroxyphenyl)-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1=CC=CC(O)=C1 JKRIULAJORWCLQ-UHFFFAOYSA-N 0.000 description 1
- JKQZPAGBJKFTQC-UHFFFAOYSA-N n-(3-hydroxyphenyl)benzenesulfonamide Chemical compound OC1=CC=CC(NS(=O)(=O)C=2C=CC=CC=2)=C1 JKQZPAGBJKFTQC-UHFFFAOYSA-N 0.000 description 1
- NAKOXCFVLYYSFK-UHFFFAOYSA-N n-(3-hydroxyphenyl)naphthalene-1-sulfonamide Chemical compound OC1=CC=CC(NS(=O)(=O)C=2C3=CC=CC=C3C=CC=2)=C1 NAKOXCFVLYYSFK-UHFFFAOYSA-N 0.000 description 1
- RQAQWBFHPMSXKR-UHFFFAOYSA-N n-(4-chlorophenyl)-3-(phosphonooxy)naphthalene-2-carboxamide Chemical compound OP(O)(=O)OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=C(Cl)C=C1 RQAQWBFHPMSXKR-UHFFFAOYSA-N 0.000 description 1
- KZYVUYRZKKNESR-UHFFFAOYSA-N n-(4-hydroxynaphthalen-1-yl)-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1=CC=C(O)C2=CC=CC=C12 KZYVUYRZKKNESR-UHFFFAOYSA-N 0.000 description 1
- AJVUJXJDOGXUDS-UHFFFAOYSA-N n-(4-hydroxynaphthalen-1-yl)benzenesulfonamide Chemical compound C12=CC=CC=C2C(O)=CC=C1NS(=O)(=O)C1=CC=CC=C1 AJVUJXJDOGXUDS-UHFFFAOYSA-N 0.000 description 1
- JLCBNJAVTYPOHV-UHFFFAOYSA-N n-(4-hydroxynaphthalen-1-yl)naphthalene-1-sulfonamide Chemical compound C12=CC=CC=C2C(O)=CC=C1NS(=O)(=O)C1=CC=CC2=CC=CC=C12 JLCBNJAVTYPOHV-UHFFFAOYSA-N 0.000 description 1
- KLZBAALATNLLOK-UHFFFAOYSA-N n-(4-hydroxynaphthalen-1-yl)naphthalene-2-sulfonamide Chemical compound C12=CC=CC=C2C(O)=CC=C1NS(=O)(=O)C1=CC=C(C=CC=C2)C2=C1 KLZBAALATNLLOK-UHFFFAOYSA-N 0.000 description 1
- GMOBYFRCKHKXDW-UHFFFAOYSA-N n-(4-hydroxyphenyl)-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1=CC=C(O)C=C1 GMOBYFRCKHKXDW-UHFFFAOYSA-N 0.000 description 1
- WHZPMLXZOSFAKY-UHFFFAOYSA-N n-(4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=CC=C1 WHZPMLXZOSFAKY-UHFFFAOYSA-N 0.000 description 1
- UNYQJVDUBYREST-UHFFFAOYSA-N n-(4-hydroxyphenyl)naphthalene-1-sulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=CC2=CC=CC=C12 UNYQJVDUBYREST-UHFFFAOYSA-N 0.000 description 1
- XJOAWESFAKLCSU-UHFFFAOYSA-N n-(4-hydroxyphenyl)naphthalene-2-sulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=C(C=CC=C2)C2=C1 XJOAWESFAKLCSU-UHFFFAOYSA-N 0.000 description 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- DJWFNQUDPJTSAD-UHFFFAOYSA-N n-octadecyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCCCCCCCC DJWFNQUDPJTSAD-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- BRNPAEUKZMBRLQ-UHFFFAOYSA-N octadecyl 3,4,5-trihydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 BRNPAEUKZMBRLQ-UHFFFAOYSA-N 0.000 description 1
- GJNDMSSZEBNLPU-UHFFFAOYSA-N octadecylurea Chemical compound CCCCCCCCCCCCCCCCCCNC(N)=O GJNDMSSZEBNLPU-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- CGEXUOTXYSGBLV-UHFFFAOYSA-N phenyl benzenesulfonate Chemical compound C=1C=CC=CC=1S(=O)(=O)OC1=CC=CC=C1 CGEXUOTXYSGBLV-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 1
- 229950000975 salicylanilide Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 150000003413 spiro compounds Chemical class 0.000 description 1
- 150000004897 thiazines Chemical class 0.000 description 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 125000001834 xanthenyl group Chemical class C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Description
(1)塗工用紙の作製
(中間層用塗工液)
焼成カオリン 100部
50%スチレンブタジエンエマルジョン 24部
水 200部
上記の中間層用塗工液を、坪量50g/m2の上質紙に、固形分塗工量として10g/m2となるように塗工、乾燥して、塗工用紙を作製した。作製した塗工用紙のガーレー透気抵抗度は82秒であった。
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、顕色剤分散液を得た。
4,4′−ジヒドロキシジフェニルスルホン 30部
10%スルホン酸変性ポリビニルアルコール水溶液 30部
(日本合成化学工業(株)、ゴーセランL−3266)
水 40部
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、染料前駆体分散液を得た。
3−ジブチルアミノ−6−メチル−7−アニリノフルオラン 15部
10%スルホン酸変性ポリビニルアルコール水溶液 15部
水 20部
以下の配合を混合し、ビーズミルで体積平均粒子径が0.7μmになるまで湿式粉砕して、増感剤分散液を得た。
ジフェニルスルホン 45部
10%スルホン酸変性ポリビニルアルコール水溶液 45部
水 60部
上記の分散液を使用して、下記に示す配合で混合し、十分攪拌して感熱記録層塗液を得た。
顕色剤分散液 100部
染料前駆体分散液 50部
増感剤分散液 150部
10%コアシェル型アクリルエマルジョン 300部
(三井化学(株)、BM−1000)
30%水酸化アルミニウム水分散液 150部
50%ステアリン酸亜鉛水分散液 30部
水 50部
上記塗工用紙に、上記感熱記録層塗液を染料前駆体の塗工量で0.22g/m2となるように塗工して乾燥した後、カレンダー処理を行って感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部を200部に減らし、10%ポリビニルアルコール水溶液100部を添加した以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%コアシェル型アクリルエマルジョン(三井化学(株)、OM−1050)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(6)感熱記録材料の作製において、カレンダー処理を行った後、更にスーパーカレンダー処理(線圧80kN/m、2ニップ)を行った以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(6)感熱記録材料の作製において、カレンダー処理を行った後、更にスーパーカレンダー処理(線圧120kN/m、2ニップ)を行った以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%ポリビニルアルコール水溶液300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%アクリルエマルジョン(ジョンソンポリマー(株)、PDX−7616A、コアシェル構造を有さないアクリルエマルジョン)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部に代えて、10%スチレンブタジエンエマルジョン(日本ゼオン(株)、Nipol F43)300部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(5)感熱記録層塗液の調製において、10%コアシェル型アクリルエマルジョン(三井化学(株)、BM−1000)300部を75部に減らし、10%ポリビニルアルコール水溶液225部を添加した以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(4)増感剤分散液の調製において、ジフェニルスルホン45部に代えて、2−ベンジルオキシナフタレン45部を用いた以外は実施例1と同様にして感熱記録材料を作製した。
実施例1の(1)塗工用紙の作製において、中間層用塗工液で用いた50%スチレンブタジエンエマルジョン24部を120部に増やした以外は同様にして塗工用紙を作製し、これに比較例1の感熱記録層塗液を比較例1と同様に塗工して感熱記録材料を作製した。なお、作製した塗工用紙のガーレー透気抵抗度は161秒であった。
作製した各感熱記録材料それぞれについて、印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅0.8msecで通電して印字した。印字部分における発色濃度を、濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.7以上
○:印字部分の発色濃度が0.6以上0.7未満
△:印字部分の発色濃度が0.5以上0.6未満
×:印字部分の発色濃度が0.5未満
作製した各感熱記録材料それぞれについて、50℃・95%RHの環境下で24時間静置した後に、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、更に印字部分を目視で観察して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.75以上
○:印字部分の発色濃度が0.55以上0.75未満
△:印字部分の発色濃度が0.55以上0.75未満であるが、ムラが目立つ
×:印字部分の発色濃度が0.55未満
作製した各感熱記録材料それぞれについて、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字した感熱記録材料を70℃・DRYの環境下に24時間静置した後、印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.6以上
○:印字部分の発色濃度が0.5以上0.6未満
△:印字部分の発色濃度が0.4以上0.5未満
×:印字部分の光学濃度が0.4未満
作製した各感熱記録材料それぞれについて、23℃・65%RHの環境下で印字テスト機〔大倉電機製:TH−PMD〕を用いて、ドット密度8ドット/mm、ヘッド抵抗1510Ωのサーマルヘッドを使用し、ヘッド電圧21V、パルス幅1.4msecで通電して印字した。印字した感熱記録材料を50℃・95%RHの環境下に24時間静置した後、印字部の発色濃度を濃度計[装置名:RD19、GretagMacbeth社製](ブラックモード)にて測定し、更に印字部分を目視で観察して、以下の基準に従い評価した。
◎:印字部分の発色濃度が0.8以上
○:印字部分の発色濃度が0.6以上0.8未満
△:印字部分の発色濃度が0.6以上0.8未満であり、印字面にかすれが発生する
×:印字部分の光学濃度が0.6未満
作製した各感熱記録材料それぞれのガーレー透気抵抗度は、JIS−P−8117に基づいて測定した。
Claims (1)
- 支持体上に電子供与性染料前駆体及び電子受容性顕色剤を含有する感熱記録層を設けた感熱記録材料において、該感熱記録層が電子受容性顕色剤として4,4′−ジヒドロキシジフェニルスルホン、発色反応を促進する低融点の熱可溶成分としてジフェニルスルホン、結合剤としてアクリロニトリルを必須成分とするコアとメタアクリルアミドを必須成分とするシェルからなるコアシェル構造を有する水分散性高分子重合体を含有し、かつJIS−P−8117で規定されるガーレー透気抵抗度が170秒以上700秒以下であることを特徴とする感熱記録材料。
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JPH06115247A (ja) * | 1992-09-30 | 1994-04-26 | Mitsubishi Paper Mills Ltd | 感熱記録材料 |
JP3752891B2 (ja) * | 1999-03-05 | 2006-03-08 | 日本製紙株式会社 | 感熱記録シート |
JP2001260544A (ja) * | 2000-03-22 | 2001-09-25 | Nicca Chemical Co Ltd | 感熱記録材料 |
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JP3738704B2 (ja) * | 2001-05-25 | 2006-01-25 | 日本製紙株式会社 | レーザー記録型感熱記録体 |
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