JP2012082954A - Vacuum heat insulation material and refrigerator using the same - Google Patents

Vacuum heat insulation material and refrigerator using the same Download PDF

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JP2012082954A
JP2012082954A JP2011180105A JP2011180105A JP2012082954A JP 2012082954 A JP2012082954 A JP 2012082954A JP 2011180105 A JP2011180105 A JP 2011180105A JP 2011180105 A JP2011180105 A JP 2011180105A JP 2012082954 A JP2012082954 A JP 2012082954A
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laminate
core material
heat insulating
vacuum heat
laminated body
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JP5544338B2 (en
Inventor
Yasuto Terauchi
康人 寺内
Kuninari Araki
邦成 荒木
Hisashi Echigoya
恒 越後屋
Takashi Izeki
崇 井関
Yushi Arai
祐志 新井
Hiroyuki Yamazaki
裕之 山崎
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Hitachi Appliances Inc
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Hitachi Appliances Inc
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • F25D2201/14Insulation with respect to heat using subatmospheric pressure

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Refrigerator Housings (AREA)
  • Thermal Insulation (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a vacuum heat insulation material which has a recess which accommodates a heat radiation pipe or the like while suppressing the deterioration of heat insulation performance, and to provide a refrigerator using the material.SOLUTION: In the vacuum heat insulation material 50f which has a core member 51 made of a fiber laminate, and an outer cover member which accommodates the core member 51 and whose interior is depressurized, the core member 51 has a first laminated body 51b, and a second laminated body 51c and third laminated body 51d which are arranged at a predetermined interval on the first laminated body 51b. The first laminated body 51b is deformed so as to fill the space between the second laminated body 51c and third laminated body 51d, and the recess 58a is formed on the side of the first laminated body 51b.

Description

本発明は、真空断熱材及びこれを用いた冷蔵庫に関する。   The present invention relates to a vacuum heat insulating material and a refrigerator using the same.

本技術分野の背景技術として、特開2008−64323号公報(特許文献1)がある。この公報には、「外箱と内箱間に発泡断熱材を充填した断熱箱体と、外箱の内面側に配される放熱パイプと、芯材を外包材で覆って内部が減圧されるとともに放熱パイプが嵌められる溝部を設けた真空断熱パネルとを備えた冷蔵庫において、真空断熱パネルは、溝部を形成した面の裏面に溝部に対向して形成されるとともに溝部よりも長手方向に垂直な幅が広い凸部を有することを特徴としている」と記載されている。   As a background art in this technical field, there is JP-A-2008-64323 (Patent Document 1). In this publication, “a heat insulating box body filled with a foam heat insulating material between an outer box and an inner box, a heat radiating pipe arranged on the inner surface side of the outer box, and a core material is covered with an outer packaging material to reduce the inside. And a vacuum heat insulating panel provided with a groove portion into which a heat radiating pipe is fitted, the vacuum heat insulating panel is formed on the back surface of the surface on which the groove portion is formed so as to face the groove portion and is perpendicular to the longitudinal direction than the groove portion. It is characterized by having a wide protrusion. "

特開2008−64323号公報JP 2008-64323 A

特許文献1は、真空引きされた真空断熱パネルが、上金型及び下金型によってプレス加工されて、放熱パイプが嵌められる溝部及び凸部を形成している。プレス加工によって溝部及び凸部を形成する場合、例えば、プレス加工時に、金型に埃などが付着していると真空断熱材が傷付けられ、リークする場合がある。また、プレス加工により芯材が切断されて、断熱性能が低下する。   In Patent Document 1, a vacuum-insulated panel that has been evacuated is pressed by an upper mold and a lower mold to form grooves and protrusions into which heat-dissipating pipes are fitted. When forming a groove part and a convex part by press work, for example, when dust or the like adheres to the mold during press work, the vacuum heat insulating material may be damaged and leak. Moreover, a core material is cut | disconnected by press work and heat insulation performance falls.

また、溝部を形成した面の裏面に溝部に対向して形成されるとともに溝部よりも長手方向に垂直な幅が広い凸部を有するため、凸部で外包材が大きく伸ばされて、クラックなどが発生して信頼性が低下する。   In addition, since the rear surface of the surface on which the groove portion is formed is opposed to the groove portion and has a convex portion that is wider in the longitudinal direction than the groove portion, the outer packaging material is greatly extended at the convex portion, and cracks and the like are generated. It occurs and reliability decreases.

そこで本発明は、断熱性能の低下を抑制しつつ放熱パイプ等を収納する凹所を有する真空断熱材及びこれを用いた冷蔵庫を提供することを目的とする。   Then, an object of this invention is to provide the vacuum heat insulating material which has a recess which accommodates a heat radiating pipe etc., suppressing the fall of heat insulation performance, and a refrigerator using the same.

上記課題を解決するために、例えば特許請求の範囲に記載の構成を採用する。一例として、繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧した真空断熱材において、前記芯材は第一の積層体と、該第一の積層体上に所定間隔で配置した第二の積層体及び第三の積層体と、を有し、前記第一の積層体は前記第二の積層体及び前記第三の積層体の空間を埋めるように変形し、前記第一の積層体側に凹所が形成する。   In order to solve the above problems, for example, the configuration described in the claims is adopted. As an example, in a vacuum heat insulating material that has a core material of a fiber laminate and a jacket material that houses the core material, and the inside of the jacket material is depressurized, the core material includes the first laminate, A second laminated body and a third laminated body arranged at a predetermined interval on the first laminated body, wherein the first laminated body is formed of the second laminated body and the third laminated body. It deforms so as to fill the space, and a recess is formed on the first laminate side.

本発明によれば、断熱性能の低下を抑制しつつ放熱パイプ等を収納する凹所を有する真空断熱材及びこれを用いた冷蔵庫を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the vacuum heat insulating material which has a recess which accommodates a heat radiating pipe etc., suppressing the fall of heat insulation performance, and a refrigerator using this can be provided.

本発明の実施形態に係る冷蔵庫の正面図。The front view of the refrigerator which concerns on embodiment of this invention. 本発明の実施形態に係る冷蔵庫の縦断面図(図1のA−A断面図)。The longitudinal cross-sectional view (AA sectional drawing of FIG. 1) of the refrigerator which concerns on embodiment of this invention. 本発明の実施形態に係る真空断熱材の概略断面図。The schematic sectional drawing of the vacuum heat insulating material which concerns on embodiment of this invention. (a)は実施例1の真空断熱材の芯材配置説明図、(b)は図4(a)を矢印Cから目視した図、(c)は実施例1の真空断熱材の概略断面図。(A) is core material arrangement explanatory drawing of the vacuum heat insulating material of Example 1, (b) is the figure which looked at Drawing 4 (a) from arrow C, (c) is a schematic sectional view of the vacuum heat insulating material of Example 1. . (a)は実施例2の真空断熱材の芯材配置説明図、(b)は実施例2の真空断熱材の概略断面図。(A) is core material explanatory drawing of the vacuum heat insulating material of Example 2, (b) is a schematic sectional drawing of the vacuum heat insulating material of Example 2. FIG. (a)は実施例3の真空断熱材の芯材配置説明図、(b)は実施例3の真空断熱材の概略断面図。(A) is core material explanatory drawing of the vacuum heat insulating material of Example 3, (b) is a schematic sectional drawing of the vacuum heat insulating material of Example 3. FIG. 実施例4に係る放熱パイプ及び真空断熱材の配置の説明図。Explanatory drawing of arrangement | positioning of the heat radiating pipe which concerns on Example 4, and a vacuum heat insulating material. (a)は実施例5の真空断熱材の芯材配置説明図、(b)は実施例5の芯材断面図(図8(a)のD−D断面図)、(c)は実施例5の真空断熱材の概略断面図、(d)は実施例5の真空断熱材の配置の説明図。(A) is core material explanatory drawing of the vacuum heat insulating material of Example 5, (b) is core material sectional drawing of Example 5 (DD sectional drawing of Fig.8 (a)), (c) is Example. FIG. 5 is a schematic cross-sectional view of the vacuum heat insulating material of FIG. 5, and FIG.

以下、本発明の実施形態について、図1〜図4を用いて説明する。図1は本実施形態に係る冷蔵庫の正面図であり、図2は図1のA−A断面図を示している。また、図3は本実施形態の真空断熱材の断面概略図を示したものである。   Hereinafter, embodiments of the present invention will be described with reference to FIGS. FIG. 1 is a front view of a refrigerator according to the present embodiment, and FIG. 2 is a cross-sectional view taken along the line AA in FIG. Moreover, FIG. 3 shows the cross-sectional schematic of the vacuum heat insulating material of this embodiment.

冷蔵庫1は、図2に示すように、上から冷蔵室2,製氷室3a及び上段冷凍室3b,下段冷凍室4,野菜室5を有している。各貯蔵室は、前面開口を開閉する扉を備える。冷蔵室2には、ヒンジ10を中心に回動する回転式の冷蔵室扉6a,6bを備える。冷蔵室扉6a,6b以外は、引き出し式の扉であり、製氷室扉7a,上段冷凍室扉7b,下段冷凍室扉8,野菜室扉9を配置する。これらの引き出し式扉を引き出すと、各貯蔵室の収納容器が扉と共に引き出されてくる。各扉には、冷蔵庫1と密閉して開口を閉塞するためのパッキン11が、各扉の貯蔵室側の外側縁に取り付けられている。   As shown in FIG. 2, the refrigerator 1 includes a refrigerator room 2, an ice making room 3 a, an upper freezer room 3 b, a lower freezer room 4, and a vegetable room 5 from the top. Each storage room includes a door that opens and closes the front opening. The refrigerating room 2 includes rotary refrigerating room doors 6 a and 6 b that rotate about the hinge 10. The doors other than the refrigerator doors 6a and 6b are drawer type doors, and an ice making door 7a, an upper freezer compartment door 7b, a lower freezer compartment door 8, and a vegetable compartment door 9 are arranged. When these drawer-type doors are pulled out, the storage container of each storage room is pulled out together with the door. In each door, a packing 11 for sealing with the refrigerator 1 and closing the opening is attached to the outer edge of each door on the storage chamber side.

また、冷蔵室2と製氷室3a及び上段冷凍室3bとの間を区画断熱するために断熱仕切り12を配置している。また、下段冷凍室4と野菜室5の間には、区画断熱するための断熱仕切り14を設けている。   In addition, a heat insulating partition 12 is disposed to partition and insulate between the refrigerator compartment 2, the ice making chamber 3a, and the upper freezer compartment 3b. Moreover, between the lower freezer compartment 4 and the vegetable compartment 5, the heat insulation partition 14 for partition heat insulation is provided.

製氷室3a,上段冷凍室3b及び下段冷凍室4は、温度帯が同じであるため、断熱区画する仕切り断熱壁ではなく、パッキン11の受面を有する仕切り部材13を設けている。   Since the ice making chamber 3a, the upper freezing chamber 3b, and the lower freezing chamber 4 have the same temperature zone, a partition member 13 having a receiving surface for the packing 11 is provided instead of the partition heat insulating wall for heat insulating division.

基本的に冷蔵,冷凍等の貯蔵温度帯の異なる部屋の仕切りには、断熱仕切りを設置している。   Insulation partitions are basically installed in the partitions of rooms with different storage temperature zones such as refrigeration and freezing.

なお、各貯蔵室の配置については、特にこれに限定するものではない。また、冷蔵室扉6a,6b,製氷室扉7a,上段冷凍室扉7b,下段冷凍室扉8,野菜室扉9に関しても、開閉可能であれば、回転扉又は引き出し扉以外であってもよく、扉の分割数等、特に限定するものではない。   In addition, about the arrangement | positioning of each store room, it does not specifically limit to this. Further, the refrigerator doors 6a and 6b, the ice making door 7a, the upper freezer compartment door 7b, the lower freezer compartment door 8 and the vegetable compartment door 9 may be other than the revolving door or the drawer door as long as they can be opened and closed. The number of door divisions is not particularly limited.

箱体20は、外箱21と内箱22とを備え、外箱21と内箱22とによって形成される空間に断熱部を設けており、箱体20内の各貯蔵室と外部とを断熱している。この外箱21と内箱22の間の空間には、真空断熱材50(50a,50b,50c,50d)を配置し、真空断熱材50以外の空間には硬質ウレタンフォーム等の発泡断熱材23を充填している。   The box 20 includes an outer box 21 and an inner box 22, and a heat insulating portion is provided in a space formed by the outer box 21 and the inner box 22, thereby insulating each storage chamber in the box 20 from the outside. is doing. A vacuum heat insulating material 50 (50a, 50b, 50c, 50d) is disposed in the space between the outer box 21 and the inner box 22, and a foam heat insulating material 23 such as rigid urethane foam is provided in a space other than the vacuum heat insulating material 50. Filled.

また、冷蔵庫1の各貯蔵室を所定の温度に冷却するために、冷凍温度帯室(製氷室3a,上段冷凍室3b,下段冷凍室4)の背面には、冷却器収納室28a内に冷却器28が備えられている。また、野菜室5の後方には、機械室30aが設けられており、機械室30a内に圧縮機30及び凝縮器31が配置されている。冷却器28,圧縮機30,凝縮機31及び図示しないキャピラリーチューブを冷媒配管で接続して、冷凍サイクルを構成している。   In addition, in order to cool each storage chamber of the refrigerator 1 to a predetermined temperature, the refrigerator temperature chamber (the ice making chamber 3a, the upper freezer chamber 3b, the lower freezer chamber 4) is cooled in the cooler storage chamber 28a. A container 28 is provided. Moreover, the machine room 30a is provided behind the vegetable room 5, and the compressor 30 and the condenser 31 are arrange | positioned in the machine room 30a. The refrigeration cycle is configured by connecting the cooler 28, the compressor 30, the condenser 31, and a capillary tube (not shown) with refrigerant piping.

冷却器28の上方には、冷却器28にて冷却された冷気を冷蔵庫1の各貯蔵室内に循環して所定の温度を保持する送風機27が設けられている。   Above the cooler 28, there is provided a blower 27 that circulates the cool air cooled by the cooler 28 into each storage chamber of the refrigerator 1 and maintains a predetermined temperature.

また、冷蔵庫1の冷蔵室2と製氷室3a及び上段冷凍室3b,冷凍室4と野菜室5をそれぞれ断熱区画する断熱仕切り12,14は、発泡ポリスチレン33と真空断熱材50cを備えている。なお、特に発泡ポリスチレン33に限定するものではなく、硬質ウレタンフォーム等の発泡断熱材23と真空断熱材50cであってもよい。   Moreover, the heat insulation partitions 12 and 14 which thermally insulate the refrigerator compartment 2, the ice making room 3a, the upper freezer compartment 3b, the freezer compartment 4 and the vegetable compartment 5 of the refrigerator 1, respectively, are provided with a polystyrene foam 33 and a vacuum heat insulator 50c. In addition, it does not specifically limit to the foamed polystyrene 33, The foam heat insulating material 23 and vacuum heat insulating materials 50c, such as hard urethane foam, may be sufficient.

また、箱体20の上面壁21a後方部には、冷蔵庫1の運転を制御するための基板や電源基板等の電気部品41を収納するための凹部40が形成されている。さらに凹部40には、電気部品41を覆うカバー42が設けられている。カバー42の高さは、外観意匠性と内容積確保を考慮して、外箱21の上面壁21aとほぼ同じ高さになるように配置している。特に限定するものではないが、カバー42の高さが外箱21の上面壁21aよりも突出する場合は、10mm以内の範囲に収めることが望ましい。これに伴い、凹部40は発泡断熱材23側に電気部品41を収納する空間だけ窪んだ状態で配置される。そのため、断熱厚さ分、必然的に内容積が犠牲になってしまう。一方、内容積をより大きくしようとすると、凹部40と内箱22間の断熱厚さが薄くなってしまう。そこで、発泡断熱材23中には、上面壁21aの凹部40に沿うように、略Z形状に折り曲げた真空断熱材50aを配置して、断熱性能を確保,強化している。なお、カバー42は耐熱性を考慮して鋼板製としている。   Moreover, the recessed part 40 for accommodating electrical components 41, such as a board | substrate for controlling the driving | operation of the refrigerator 1, and a power supply board, is formed in the upper part wall 21a rear part of the box 20. As shown in FIG. Further, the recess 40 is provided with a cover 42 that covers the electrical component 41. The height of the cover 42 is arranged so as to be almost the same height as the upper surface wall 21a of the outer box 21 in consideration of appearance design and securing of the inner volume. Although it does not specifically limit, when the height of the cover 42 protrudes from the upper surface wall 21a of the outer box 21, it is desirable to keep in the range within 10 mm. Accordingly, the recess 40 is arranged in a state where only the space for storing the electrical component 41 is recessed on the foamed heat insulating material 23 side. Therefore, the inner volume is inevitably sacrificed by the heat insulation thickness. On the other hand, if the inner volume is increased, the heat insulation thickness between the recess 40 and the inner box 22 is reduced. Therefore, in the foam heat insulating material 23, a vacuum heat insulating material 50a bent in a substantially Z shape is disposed along the concave portion 40 of the upper surface wall 21a to secure and enhance the heat insulating performance. The cover 42 is made of a steel plate in consideration of heat resistance.

また、箱体20の背面壁21b下部に位置する機械室30aには、発熱の大きい部品である圧縮機30や凝縮機31が配置される。そのため、貯蔵室内への熱侵入を防止するため、底面壁21d側には機械室30aの形状に沿って折り曲げた真空断熱材50dを配置している。   Further, a compressor 30 and a condenser 31 that are components that generate large amounts of heat are disposed in the machine room 30a located below the back wall 21b of the box 20. Therefore, in order to prevent heat from entering the storage chamber, a vacuum heat insulating material 50d bent along the shape of the machine chamber 30a is disposed on the bottom wall 21d side.

また、箱体20の背面壁21b及び側面壁(図示せず)にも、真空断熱材50bをそれぞれ配置しており、断熱性能を向上している。さらに、各扉にも発泡断熱材とともに真空断熱材50eをそれぞれ配置すれば、断熱性能はさらに向上する。   Moreover, the vacuum heat insulating material 50b is each arrange | positioned also to the back wall 21b and side wall (not shown) of the box 20, and the heat insulation performance is improved. Furthermore, if the vacuum heat insulating material 50e is arranged on each door together with the foam heat insulating material, the heat insulating performance is further improved.

次に、真空断熱材50について、図3を用いてその基本構成を説明する。真空断熱材50は、芯材51、該芯材51を圧縮状態に保持するための内包材52、内包材52で圧縮状態に保持した芯材51を被覆するガスバリヤ層を有する外被材53、及び吸着剤54を有する構成である。   Next, the basic structure of the vacuum heat insulating material 50 will be described with reference to FIG. The vacuum heat insulating material 50 includes a core material 51, an inner packaging material 52 for holding the core material 51 in a compressed state, an outer jacket material 53 having a gas barrier layer covering the core material 51 held in a compressed state by the inner packaging material 52, And an adsorbent 54.

外被材53は、真空断熱材50の外郭として配置され、同じ大きさのラミネートフィルムの稜線から一定の幅の部分を熱溶着により貼り合わせた袋状で構成されている。   The jacket material 53 is arranged as an outline of the vacuum heat insulating material 50, and is configured in a bag shape in which a portion having a certain width is bonded by thermal welding from the ridgeline of the laminate film having the same size.

芯材51は、バインダー等で接着や結着していない柔軟性を有する無機繊維の積層体として、平均繊維径4μmのグラスウールを用いた。なお、芯材51に、無機系繊維材料の積層体を使用することにより、アウトガスが少なくなるため、断熱性能的に有利であるが、特にこれに限定するものではない。例えば、セラミック繊維やロックウール、グラスウール以外のガラス繊維等の無機繊維等でもよい。なお、芯材51の種類によっては内包材52が不要の場合もある。   As the core material 51, glass wool having an average fiber diameter of 4 μm was used as a laminate of flexible inorganic fibers not bonded or bound with a binder or the like. In addition, since outgas is reduced by using a laminated body of inorganic fiber materials for the core material 51, it is advantageous in terms of heat insulation performance, but is not particularly limited thereto. For example, inorganic fibers such as ceramic fibers, rock wool, and glass fibers other than glass wool may be used. Depending on the type of the core material 51, the inner packaging material 52 may be unnecessary.

また、芯材51については、無機系繊維材料の他に、有機系樹脂繊維材料を用いることができる。有機系樹脂繊維の場合、耐熱温度等の使用条件を満たしていれば、特に使用に際しては制約されるものではない。具体的には、ポリスチレンやポリエチレンテレフタレート,ポリプロピレン等をメルトブローン法やスパンボンド法で1〜30μm程度の繊維径になるように繊維化するのが一般的であるが、繊維化できる有機系樹脂や繊維化方法であれば特に問うものではない。   Moreover, about the core material 51, an organic resin fiber material other than an inorganic fiber material can be used. In the case of organic resin fibers, there are no particular restrictions on use as long as the use conditions such as the heat-resistant temperature are satisfied. Specifically, it is common to fiberize polystyrene, polyethylene terephthalate, polypropylene, etc. to a fiber diameter of about 1 to 30 μm by a melt blown method or a spunbond method. There is no particular question if it is a conversion method.

外被材53のラミネート構成については、ガスバリヤ性を有し、熱溶着可能であれば特に限定するものではないが、本実施形態においては、表面保護層,ガスバリヤ層,熱溶着層の少なくとも3層を有するラミネートフィルムとしている。   The laminate structure of the jacket material 53 is not particularly limited as long as it has gas barrier properties and can be thermally welded. In the present embodiment, at least three layers of a surface protective layer, a gas barrier layer, and a heat welding layer are used. A laminate film having

表面保護層は、突き刺し等の外的衝撃から減圧状態を保護する役割を持つ樹脂フィルムとする。   The surface protective layer is a resin film having a role of protecting the reduced pressure state from an external impact such as piercing.

ガスバリヤ層は、樹脂フィルムに金属蒸着層を設け、さらに金属蒸着層同士に向かい合うように酸素バリヤ性の高い樹脂フィルムに金属蒸着層を設けて貼り合わせている。   The gas barrier layer is formed by providing a metal vapor deposition layer on a resin film, and further providing a metal vapor deposition layer on a resin film having a high oxygen barrier property so as to face each other.

熱溶着層は、表面保護層と同様に吸湿性の低いフィルムを用いる。   A film having a low hygroscopic property is used for the heat-welding layer in the same manner as the surface protective layer.

さらに具体的には、表面保護層を二軸延伸タイプのポリプロピレン,ポリアミド,ポリエチレンテレフタレート等の各フィルムとする。   More specifically, the surface protective layer is a biaxially stretched film of polypropylene, polyamide, polyethylene terephthalate, or the like.

ガスバリヤ層は、アルミニウム蒸着付きの二軸延伸ポリエチレンテレフタレートフィルム,アルミニウム蒸着付きの二軸延伸エチレンビニルアルコール共重合体樹脂フィルム又はアルミニウム蒸着付きの二軸延伸ポリビニルアルコール樹脂フィルム、或いはアルミ箔とする。   The gas barrier layer is a biaxially stretched polyethylene terephthalate film with aluminum vapor deposition, a biaxially stretched ethylene vinyl alcohol copolymer resin film with aluminum vapor deposition, a biaxially stretched polyvinyl alcohol resin film with aluminum vapor deposition, or an aluminum foil.

熱溶着層は、未延伸タイプのポリエチレン,ポリプロピレンとする。   The heat welding layer is made of unstretched polyethylene or polypropylene.

なお、フィルムの層構成や材料については、特にこれらに限定するものではない。例えば、ガスバリヤ層として、金属箔、或いは樹脂系のフィルムに無機層状化合物,ポリアクリル酸等の樹脂系ガスバリヤコート材,DLC(ダイヤモンドライクカーボン)等によるガスバリヤ膜を設けたもの、熱溶着層として、酸素バリヤ性の高いポリブチレンテレフタレートフィルム等を用いてもよい。   Note that the layer structure and materials of the film are not particularly limited to these. For example, as a gas barrier layer, a metal foil or a resin-based film provided with a gas-barrier film such as an inorganic layered compound, a resin-based gas barrier coating material such as polyacrylic acid, DLC (diamond-like carbon), etc. A polybutylene terephthalate film having a high oxygen barrier property may be used.

表面保護層はガスバリヤ層を保護する機能を有するが、真空断熱材の製造工程における真空排気効率を高めるために、好ましくは吸湿性の低い樹脂を配置するのがよい。   The surface protective layer has a function of protecting the gas barrier layer, but in order to increase the vacuum exhaust efficiency in the manufacturing process of the vacuum heat insulating material, it is preferable to dispose a resin having a low hygroscopic property.

また、ガスバリヤ層に使用する金属箔以外の樹脂系フィルムは、吸湿することによってガスバリヤ性が著しく悪化してしまう。そのため、熱溶着層についても吸湿性の低い樹脂を配置することで、ガスバリヤ性の悪化を抑制すると共に、ラミネートフィルム全体の吸湿量を抑制できる。これにより、真空断熱材50の真空排気工程においても、外被材53が持ち込む水分量を小さくできるため、真空排気効率が大幅に向上し、断熱性能が向上する。   In addition, the resin barrier film other than the metal foil used for the gas barrier layer is significantly deteriorated in gas barrier properties due to moisture absorption. Therefore, by arranging a resin having low hygroscopicity for the heat-welded layer, it is possible to suppress the deterioration of gas barrier properties and to suppress the hygroscopic amount of the entire laminate film. Thereby, also in the vacuum evacuation process of the vacuum heat insulating material 50, since the moisture content which the jacket material 53 brings can be made small, vacuum exhaust efficiency improves significantly and heat insulation performance improves.

なお、各フィルムのラミネート(貼り合わせ)は、二液硬化型ウレタン接着剤を介してドライラミネート法によって貼り合わせるのが一般的であるが、接着剤の種類や貼り合わせ方法は特にこれに限定するものではなく、ウェットラミネート法,サーマルラミネート法等の他の方法によるものでもよい。   In addition, the lamination (bonding) of each film is generally performed by a dry laminating method via a two-component curable urethane adhesive, but the type of adhesive and the bonding method are particularly limited to this. It may be based on other methods such as a wet laminating method and a thermal laminating method.

また、内包材52については、本実施例では熱溶着可能なポリエチレンフィルム、吸着剤54については物理吸着タイプの合成ゼオライトを用いたが、いずれもこれらの材料に限定するものではない。一例として、内包材52についてはポリプロピレンフィルム,ポリエチレンテレフタレートフィルム,ポリブチレンテレフタレートフィルム等、吸湿性が低く熱溶着でき、アウトガスが少ないものであればよく、吸着剤54については水分やガスを吸着するもので、物理吸着,化学反応型吸着のどちらでもよい。   In this embodiment, the encapsulating material 52 is a polyethylene film that can be thermally welded, and the adsorbent 54 is a physical adsorption type synthetic zeolite. However, the material is not limited to these materials. As an example, the inner packaging material 52 may be a polypropylene film, a polyethylene terephthalate film, a polybutylene terephthalate film, etc., as long as it has low hygroscopicity and can be heat-welded and has little outgas. Thus, either physical adsorption or chemical reaction type adsorption may be used.

次に、本発明の実施例1について、図4を用いて説明する。図4は、真空断熱材に凹所が成形されるメカニズムを説明する為の図である。図4(a)は切断された複数の芯材を内包材52に収納した状態を示す図であり、図4(b)は図4(a)の矢印Cから目視した図であり、図4(c)は、真空成形されて製作される真空断熱材の概略断面図である。   Next, Example 1 of the present invention will be described with reference to FIG. FIG. 4 is a view for explaining a mechanism for forming a recess in the vacuum heat insulating material. 4A is a view showing a state in which a plurality of cut core materials are housed in the inner packaging material 52, and FIG. 4B is a view as seen from an arrow C in FIG. 4A. (C) is a schematic sectional drawing of the vacuum heat insulating material manufactured by vacuum forming.

まず、図4(a),(b)において、ロール状に予め作成された無機繊維の積層体をカットして、複数の芯材51a〜51dを重ねて配置する。   First, in FIGS. 4A and 4B, a laminated body of inorganic fibers prepared in advance in a roll shape is cut, and a plurality of core members 51a to 51d are stacked and arranged.

本実施例では、厚さ100mmの芯材51a(第四の積層体)の上に、同程度の厚さ(100mm程度)の芯材51b(第一の積層体)を積層している。さらに、芯材51bの上には、同程度の厚さ(100mm程度)の芯材51c(第二の積層体)及び芯材51d(第三の積層体)を、所定間隔を空けて重ねる。本実施例では、芯材51c及び芯材51dの間に50mm程度の間隔を空けており、芯材51b,芯材51c及び芯材51dで形成された凹形状の空間60aが存在する。   In this embodiment, a core material 51b (first laminated body) having the same thickness (about 100 mm) is laminated on a core material 51a (fourth laminated body) having a thickness of 100 mm. Furthermore, a core material 51c (second laminated body) and a core material 51d (third laminated body) having the same thickness (about 100 mm) are stacked on the core material 51b at a predetermined interval. In this embodiment, an interval of about 50 mm is provided between the core material 51c and the core material 51d, and there is a concave space 60a formed by the core material 51b, the core material 51c, and the core material 51d.

この状態で、芯材51a,51b,51c,51d(以下、芯材全体を指す場合は「芯材51」という)を内包材52a(肉厚20μm前後のポリエチレン製の合成樹脂フィルム)内に収納する。この時、一定間隔(空間60a)を保つために治具を使用して、袋状の内包材52aの開口から収納してもよい。   In this state, the core materials 51a, 51b, 51c, 51d (hereinafter referred to as “core material 51” when referring to the entire core material) are stored in the inner packaging material 52a (polyethylene synthetic resin film having a thickness of about 20 μm). To do. At this time, in order to maintain a constant interval (space 60a), a jig may be used to store from the opening of the bag-shaped inner packaging material 52a.

内包材52aへ収納した芯材51は、プレス機を使って圧縮してから内包材52a内を減圧する。そして、内包材52a内に収納した芯材51の位置がずれないように、内包材52aの開口全体を熱溶着機で溶着密封して、芯材51を仮圧縮した状態にする。また、この状態で芯材51を一時保管することも可能である。   The core material 51 accommodated in the inner packaging material 52a is compressed using a press machine, and then the inner packaging material 52a is decompressed. Then, the entire opening of the inner packaging material 52a is welded and sealed with a thermal welding machine so that the core material 51 accommodated in the inner packaging material 52a is not displaced, so that the core material 51 is temporarily compressed. In addition, the core material 51 can be temporarily stored in this state.

次いで、内包材52aの内部に仮圧縮した状態の芯材51を外被材53a内に収納する。芯材51は圧縮されているので、外被材53aを損傷することなく、スムーズに外被材53a内に挿入できる。その後、内包材52aの熱溶着を一部開封すると、芯材51は圧縮が解除されて、外被材53a内で外側に広がる。この状態で、外被材53a及び内包材52a内を減圧して、外被材53a及び内包材52aの開口を溶着密封することにより、真空断熱材50fが製作される。   Next, the core material 51 in a state of being temporarily compressed is contained in the outer covering material 53a inside the inner packaging material 52a. Since the core material 51 is compressed, it can be smoothly inserted into the jacket material 53a without damaging the jacket material 53a. Thereafter, when part of the heat-sealing of the inner packaging material 52a is opened, the core material 51 is released from the compression and spreads outward in the outer jacket material 53a. In this state, the inside of the jacket material 53a and the inner packaging material 52a is decompressed, and the openings of the jacket material 53a and the inner packaging material 52a are welded and sealed, whereby the vacuum heat insulating material 50f is manufactured.

このように、圧縮−減圧−溶着密封工程を経ることで、真空断熱材50fの厚み方向には凹所58aが形成される。その構成について、図4(c)に真空断熱材50fの概略断面図を示す。減圧工程で外被材53及び内包材52aは、外側より芯材51を圧縮する。
このとき、本実施例では、芯材51a(第四の積層体)及び芯材51b(第一の積層体)は、外側より圧縮されて、芯材51c(第二の積層体)及び芯材51d(第三の積層体)の間の部分に入り込むように変形する。
Thus, the recess 58a is formed in the thickness direction of the vacuum heat insulating material 50f through the compression-decompression-welding sealing step. About the structure, schematic sectional drawing of the vacuum heat insulating material 50f is shown in FIG.4 (c). In the decompression step, the jacket material 53 and the inner packaging material 52a compress the core material 51 from the outside.
At this time, in this embodiment, the core material 51a (fourth laminated body) and the core material 51b (first laminated body) are compressed from the outside, and the core material 51c (second laminated body) and the core material are compressed. It deform | transforms so that it may enter into the part between 51d (3rd laminated bodies).

すなわち、第一の積層体(及び第四の積層体)の上に、第一の積層体(及び第四の積層体)よりも面積の小さい第二の積層体(及び第三の積層体)を重ねて外被材内に収納して内部を減圧すると、第一の積層体(及び第四の積層体)は空間60aを埋めるように圧縮変形する。   That is, the second laminated body (and the third laminated body) having an area smaller than that of the first laminated body (and the fourth laminated body) on the first laminated body (and the fourth laminated body). When the inner layers are stored in the jacket material and the inside is depressurized, the first stacked body (and the fourth stacked body) are compressed and deformed so as to fill the space 60a.

減圧時、芯材51は外被材53a(及び内包材52a)によって外側に広がろうとする弾性変形が規制されている。そして、減圧が進行すると、芯材51の繊維間に存在する隙間は次第に減少して、外側から内側に圧縮変形する。   At the time of decompression, the core member 51 is restricted from elastic deformation that tends to spread outward by the outer covering member 53a (and the inner covering member 52a). And when pressure reduction progresses, the clearance gap which exists between the fibers of the core material 51 reduces gradually, and compresses and deforms from the outer side to the inner side.

仮に、芯材51がほぼ同一の厚みからなる積層体の場合、減圧によって均等に圧力が加わるので、形成される真空断熱材は平板状になる。   If the core material 51 is a laminated body having substantially the same thickness, the pressure is evenly applied by the reduced pressure, so that the formed vacuum heat insulating material has a flat plate shape.

一方、芯材51c及び芯材51dの間に空間60aが存在するような積層体の場合、図4(c)に示すように、空間60aの反対側に凹所58aが形成される。   On the other hand, in the case of a laminate in which a space 60a exists between the core material 51c and the core material 51d, a recess 58a is formed on the opposite side of the space 60a as shown in FIG.

凹所58aは、以下のようにして形成される。芯材51を外被材53aで覆って、減圧チャンバー内に設置して減圧した状態では、外被材53aの内部と外部の圧力がほぼ同一のため、芯材51の厚みはすぐに変化しない。その後、減圧完了してから外被材53aの開口を溶着密封して、減圧チャンバー内を大気圧に戻すと、外被材53aの内部と外部の圧力差により、芯材51の厚みが圧縮される。   The recess 58a is formed as follows. In a state where the core material 51 is covered with the jacket material 53a and installed in the decompression chamber and the pressure is reduced, the pressure inside and outside the jacket material 53a is almost the same, so the thickness of the core material 51 does not change immediately. . After that, when the decompression is completed, the opening of the jacket material 53a is welded and sealed, and the inside of the decompression chamber is returned to the atmospheric pressure, the thickness of the core material 51 is compressed by the pressure difference between the inside and the outside of the jacket material 53a. The

芯材51の全体の厚みが小さくなる際に、芯材51c及び芯材51dと外被材53aとの間の空間60aを埋めるように、芯材51a及び芯材51bの層が空間60aに引き込まれるように繊維が曲線状に変形する。   When the entire thickness of the core material 51 is reduced, the layers of the core material 51a and the core material 51b are drawn into the space 60a so as to fill the space 60a between the core material 51c and the core material 51d and the jacket material 53a. The fiber is deformed into a curved shape.

より詳細に説明すると、まず、所定間隔を空けて配置した芯材51c及び芯材51dに跨るように重ねた芯材51a及び芯材51bには、減圧によって均等に圧力が加わる。すると、芯材51a及び芯材51bは、積層した繊維間の隙間を埋めるように圧縮が進行する。   More specifically, first, the core material 51a and the core material 51b that are stacked so as to straddle the core material 51c and the core material 51d that are arranged at a predetermined interval are equally pressurized by decompression. Then, compression progresses so that the core material 51a and the core material 51b may fill the gap between the laminated fibers.

ここで、芯材51c及び芯材51dに重なっている部分は変形が規制されるが、芯材51c及び芯材51dに重なっていない部分(空間60aの下方)では変形を規制するものがない状態である。すると、芯材51a及び芯材51bは空間60aに入り込み、空間60aを埋めることで安定した真空状態になろうとする。すなわち、空間60aに入り込んだ芯材51a及び芯材51bは、外被材53a及び内包材52aによって変形が規制されて、次第に内部の気体が減少することで、空間60aに芯材51a及び芯材51bが入り込んだ状態で減圧が終了する。これにより、真空断熱材50fには、空間60aの反対側の面に凹所58aが形成される。   Here, the portion overlapping the core material 51c and the core material 51d is restricted from being deformed, but the portion not overlapping the core material 51c and the core material 51d (below the space 60a) is in a state where no deformation is restricted. It is. Then, the core material 51a and the core material 51b enter the space 60a and fill the space 60a to achieve a stable vacuum state. That is, the deformation of the core material 51a and the core material 51b that have entered the space 60a is restricted by the covering material 53a and the inner packaging material 52a, and the internal gas gradually decreases, so that the core material 51a and the core material in the space 60a. The pressure reduction ends with 51b entering. As a result, a recess 58a is formed in the vacuum heat insulating material 50f on the opposite surface of the space 60a.

本実施例によれば、プレス加工により芯材が切断されて断熱性能が低下することがない。また、凹所の裏面に凸部が形成されにくく、凸部で外被材が伸ばされてクラックなどが発生することを抑制できる。よって、断熱性能の低下を抑制しつつ放熱パイプ等を収納する凹所を有する真空断熱材となる。   According to the present embodiment, the core material is not cut by press working and the heat insulation performance is not deteriorated. Moreover, it is hard to form a convex part in the back surface of a recess, and it can suppress that a jacket material is extended by a convex part and a crack etc. generate | occur | produce. Therefore, it becomes a vacuum heat insulating material which has a recessed part which accommodates a heat radiating pipe etc., suppressing the fall of heat insulation performance.

次に、実施例2について説明する。実施例1では、図4に示すように、芯材51c及び芯材51dの向かい合う面が、ほぼ平行に配置されている。この場合、芯材51bは、空間60aを埋めようと変形するが、芯材51c及び芯材51dと重なる部分では変形に追随できず、凹所58aが成形された反対面に2箇所の筋59が生じる場合がある。この筋59は、外被材53aの信頼性を損なう場合がある。   Next, Example 2 will be described. In the first embodiment, as illustrated in FIG. 4, the facing surfaces of the core material 51 c and the core material 51 d are arranged substantially in parallel. In this case, the core material 51b is deformed so as to fill the space 60a, but cannot follow the deformation in a portion overlapping the core material 51c and the core material 51d, and two streaks 59 are formed on the opposite surface on which the recess 58a is formed. May occur. The streaks 59 may impair the reliability of the jacket material 53a.

そこで、実施例2では、図5に示すように、最外層の芯材51g及び芯材51hは所定間隔を空けて配置するとともに、向かい合う面がそれぞれ20〜70°の傾斜面51g1,51h1を有する。芯材51g(第二の積層体)及び芯材51h(第三の積層体)は、芯材51g及び芯材51hに跨る大きさの芯材51f(第一の積層体)の上に重ねて配置され、芯材51fはさらに同程度の大きさの芯材51e(第四の積層体)の上に重ねて配置された積層構造である。   Therefore, in Example 2, as shown in FIG. 5, the core material 51g and the core material 51h of the outermost layer are arranged at a predetermined interval, and the opposing surfaces have inclined surfaces 51g1 and 51h1 of 20 to 70 °, respectively. . The core material 51g (second laminate) and the core material 51h (third laminate) are stacked on the core material 51f (first laminate) having a size straddling the core material 51g and the core material 51h. The core material 51f has a stacked structure in which the core material 51f is further stacked on the core material 51e (fourth stacked body) having the same size.

図5(a)には、2つの芯材51g及び芯材51hの向かい合う面が、それぞれ50°の角度の傾斜面51g1,51h1を有する例を示す。傾斜面51g1,51h1は、外被材53b側よりも芯材51f側が幅広となるように傾斜している。この構成において、芯材51e及び芯材51fは、芯材51g及び芯材51hの間の空間60bを埋めるように、空間60bに入り込む。そして、空間60bの反対側、すなわち、芯材51e側に凹所58bが形成される。このとき、芯材51e及び芯材51fは、傾斜面51g1,51h1に沿って変形するため、芯材51g及び芯材51hに重なる部分も、空間60bに入り込むような変形に追随し易くなる。   FIG. 5A shows an example in which the opposing surfaces of the two core members 51g and 51h have inclined surfaces 51g1 and 51h1 having an angle of 50 °, respectively. The inclined surfaces 51g1 and 51h1 are inclined so that the core material 51f side is wider than the jacket material 53b side. In this configuration, the core material 51e and the core material 51f enter the space 60b so as to fill the space 60b between the core material 51g and the core material 51h. And the recessed part 58b is formed in the other side of the space 60b, ie, the core material 51e side. At this time, since the core material 51e and the core material 51f are deformed along the inclined surfaces 51g1 and 51h1, the portions overlapping the core material 51g and the core material 51h can easily follow the deformation that enters the space 60b.

これにより、図5(b)に示すように、芯材51g及び芯材51h側の外被材53bには、筋が形成されにくいため、外被材53bの信頼性が更に向上する。   As a result, as shown in FIG. 5B, the core material 51g and the core material 51b on the side of the core material 51h are less likely to form streaks, so the reliability of the jacket material 53b is further improved.

また、向かい合う面がそれぞれ20〜70°の傾斜面とすれば、芯材51e及び芯材51fが傾斜面に沿って曲線上に変形しやすくなり、凹所58bが適切に形成される。   Further, if the faces facing each other are inclined surfaces of 20 to 70 °, the core material 51e and the core material 51f are easily deformed along a curved surface, and the recess 58b is appropriately formed.

次に、実施例3について説明する。実施例3は、図6に示すように、最外層に2つの芯材51k及び芯材51lが所定間隔を空けて配置されており、向かい合う面の一部にそれぞれ傾斜面51k1,51l1を有する。本実施例では、35°の角度の傾斜としている。また、傾斜面51k1,51l1よりも外側の部分は、互いにほぼ平行に向かい合う対向面51k2,51l2を有する。   Next, Example 3 will be described. In the third embodiment, as shown in FIG. 6, two core members 51k and a core member 51l are arranged at a predetermined interval in the outermost layer, and have inclined surfaces 51k1 and 5111 on part of the facing surfaces. In this embodiment, the inclination is 35 °. Further, the portion outside the inclined surfaces 51k1 and 51l1 has opposing surfaces 51k2 and 51l2 facing each other substantially in parallel.

このように、最外層の積層体(芯材51k,51l)は外面に臨む部分を除く一部に角度を付けた傾斜面を有することにより、芯材51i及び芯材51jは、芯材51k及び芯材51lの間の空間60cを埋めるように、空間60cに入り込む。そして、空間60cの反対側には凹所58cが形成される。   As described above, the outermost layered laminate (core members 51k and 51l) has an inclined surface with an angle formed on a part thereof excluding a portion facing the outer surface, whereby the core material 51i and the core material 51j are formed of the core material 51k and the core material 51k. The space 60c is entered so as to fill the space 60c between the core members 51l. A recess 58c is formed on the opposite side of the space 60c.

このとき、芯材51i及び芯材51jは、傾斜面51k1,51l1に沿って変形するため、芯材51k及び芯材51lに重なる部分も、空間60cに入り込むような変形に追随し易くなる。また、芯材51k及び芯材51lの外面は、対向面51k2,51l2が接することで、芯材51i及び芯材51jは内包材52cまで達することを抑制している。   At this time, since the core material 51i and the core material 51j are deformed along the inclined surfaces 51k1 and 5111, the portions overlapping the core material 51k and the core material 51l can easily follow the deformation that enters the space 60c. Further, the outer surfaces of the core material 51k and the core material 51l are in contact with the opposing surfaces 51k2 and 5112, so that the core material 51i and the core material 51j are prevented from reaching the inner packaging material 52c.

これにより、図6(b)に示すように、芯材51k及び芯材51l側の外被材53cには、筋が形成されにくいため、外被材53cの信頼性が更に向上する。   As a result, as shown in FIG. 6B, the core material 51k and the core material 51c on the side of the core material 51l are less likely to form streaks, thereby further improving the reliability of the jacket material 53c.

なお、使用される芯材の仕様や真空成形時の真空引き時間などによっても、減圧時の芯材の変形の仕方は変わる。そのため、所定間隔を空けて配置した最外層の積層体の向かい合う面は、これらの条件にあわせて、一部の面を曲線状にカットすることでも、図4(c)に示す筋59の発生を抑制できる。   Note that the manner of deformation of the core material at the time of depressurization also changes depending on the specifications of the core material used and the evacuation time during vacuum forming. For this reason, the opposing surfaces of the outermost layer stacks arranged at a predetermined interval may be cut into a curved surface in accordance with these conditions to generate the streaks 59 shown in FIG. Can be suppressed.

また、真空断熱材に形成される凹所の幅寸法は、最外層に向かい合って配置した積層体間の間隔を調整することで、コントロールすることができる。そして、凹所の深さ寸法は、所定間隔を空けて配置した最外層の積層体の向かい合う面の傾斜角度を調整することでコントロールすることができる。   Moreover, the width dimension of the recess formed in the vacuum heat insulating material can be controlled by adjusting the interval between the laminated bodies arranged facing the outermost layer. The depth dimension of the recess can be controlled by adjusting the angle of inclination of the opposing surfaces of the outermost layered laminate arranged at a predetermined interval.

また、真空断熱材に2つ以上の凹所を形成する場合には、最外層に所定間隔を空けて、3つ以上の積層体を配置すればよい。この場合、配置間隔及び積層体の対向面の傾斜角度を変えることで、凹所の幅及び深さをコントロールすることができる。   In addition, when two or more recesses are formed in the vacuum heat insulating material, it is only necessary to arrange three or more laminates with a predetermined interval in the outermost layer. In this case, the width and depth of the recess can be controlled by changing the arrangement interval and the inclination angle of the facing surface of the laminate.

なお、3つ以上の積層体を所定間隔で配置する場合、内包材内に収納する時に、積層体間の間隔を保つための位置決め、及び外被材に筋が形成されることを抑制するために、積層体の周囲に保護部材をさらに配置してもよい。   When three or more laminates are arranged at a predetermined interval, positioning for keeping the interval between the laminates and suppressing the formation of streaks on the jacket material when housed in the inner packaging material In addition, a protective member may be further arranged around the laminate.

次に、実施例4について説明する。実施例4では、凹所が形成された真空断熱材を冷蔵庫に配置した例を説明する。箱体20に使用する真空断熱材は、内箱22又は外箱21に貼り付けて、内箱22と外箱21との間には発泡断熱材23が充填発泡される。   Next, Example 4 will be described. Example 4 demonstrates the example which has arrange | positioned the vacuum heat insulating material in which the recess was formed in the refrigerator. The vacuum heat insulating material used for the box 20 is attached to the inner box 22 or the outer box 21, and the foam heat insulating material 23 is filled and foamed between the inner box 22 and the outer box 21.

本実施例では、特に外箱21の背面壁21bに配置する真空断熱材50b及び側面壁21eに配置する真空断熱材50gについて説明する。   In the present embodiment, the vacuum heat insulating material 50b disposed on the back wall 21b of the outer box 21 and the vacuum heat insulating material 50g disposed on the side wall 21e will be described.

外箱21の内面(背面壁21b,側面壁21e)には、内部を冷媒が流れる放熱パイプ90を配置している。放熱パイプ90は、冷媒の放熱性を向上させるために、アルミテープ91で鋼板製の外箱21内面に貼り付けて固定している。   On the inner surface (back wall 21b, side wall 21e) of the outer box 21, a heat radiating pipe 90 through which the refrigerant flows is arranged. The heat radiating pipe 90 is affixed and fixed to the inner surface of the outer box 21 made of a steel plate with an aluminum tape 91 in order to improve the heat dissipation of the refrigerant.

真空断熱材50b,50gには、深さ4mm程度の凹所が形成されており、直径4mm程度である放熱パイプ90を凹所内に配置することができる。   A recess having a depth of about 4 mm is formed in the vacuum heat insulating materials 50b and 50g, and a heat radiating pipe 90 having a diameter of about 4 mm can be disposed in the recess.

本実施例では、実施例1乃至3で説明したように、金型によるプレス成形加工を行うことなく、真空断熱材に放熱パイプを嵌める凹所を形成している。よって、真空断熱材の断熱性能を低下させることなく、信頼性の向上した真空断熱材及びこれを用いた冷蔵庫を提供することができる。   In the present embodiment, as described in the first to third embodiments, the recess for fitting the heat radiating pipe is formed in the vacuum heat insulating material without performing the press molding process using the mold. Therefore, it is possible to provide a vacuum heat insulating material with improved reliability and a refrigerator using the same without reducing the heat insulating performance of the vacuum heat insulating material.

次に、実施例5について、図8を参照して説明する。本実施例では、図8(a),(d)に示すように、冷蔵庫内に配置した部品との接触防止及び間隔を確保するために、中央部に部分的な凹所を形成している。   Next, Example 5 will be described with reference to FIG. In this embodiment, as shown in FIGS. 8 (a) and 8 (d), a partial recess is formed in the central portion in order to prevent contact and spacing with the components arranged in the refrigerator. .

図8(a)に示すように、最外層の芯材51p(第二の積層体)は、所定の空間60dを有して配置される。芯材51pは、芯材51n(第一の積層体)の上に重ねられており、さらに芯材51nは芯材51m(第三の積層体)の上に重ねられている。すなわち、芯材51nは最外層の芯材51pの空間60dを跨るように配置されている。   As shown in FIG. 8A, the outermost core material 51p (second laminated body) is arranged with a predetermined space 60d. The core material 51p is overlaid on the core material 51n (first laminated body), and the core material 51n is overlaid on the core material 51m (third laminated body). That is, the core material 51n is disposed so as to straddle the space 60d of the outermost core material 51p.

芯材51pは、空間60dの向かい合う面がそれぞれ50°の角度の傾斜面51p1,51p2,51p3,51p4を有する。本実施例では、最外層の芯材51pを多角形状に切取っているが、これは、配置されている部品の形状に合わせて、円形等にしてもよい。   The core material 51p has inclined surfaces 51p1, 51p2, 51p3, and 51p4 in which the opposing surfaces of the space 60d are each at an angle of 50 °. In the present embodiment, the core material 51p of the outermost layer is cut into a polygonal shape, but this may be a circular shape or the like in accordance with the shape of the arranged component.

減圧工程で、内包材52dは外側より芯材51m,51n,51pを圧縮する。ここで、最外層の芯材51mに多角形状の空間60dを有する場合、空間60dに対向する芯材51m及び芯材51nが外側より圧縮されて、空間60d側に曲折して入り込む。そして、真空断熱材50iには空間60dの反対側の面に凹所61が形成される。   In the decompression step, the inner packaging material 52d compresses the core materials 51m, 51n, 51p from the outside. Here, when the outermost core material 51m has a polygonal space 60d, the core material 51m and the core material 51n facing the space 60d are compressed from the outside and bent into the space 60d side. A recess 61 is formed in the vacuum heat insulating material 50i on the surface opposite to the space 60d.

なお、凹所61の反対側の面に筋が生じないように、真空成形時の芯材の追随の仕方に応じて、芯材を曲線状にカットしてもよい。また、実施例4のように、放熱パイプ90の形状に合わせた凹所を更に設けてもよい。   It should be noted that the core material may be cut into a curved shape according to how the core material follows during vacuum forming so that no streaks are generated on the opposite surface of the recess 61. Moreover, you may provide further the recessed part matched with the shape of the thermal radiation pipe 90 like Example 4. FIG.

このようにして凹所61が形成された真空断熱材50iを、図8(d)に示すように冷蔵庫に配置する。   Thus, the vacuum heat insulating material 50i in which the recess 61 is formed is arrange | positioned in a refrigerator as shown in FIG.8 (d).

例えば、外箱側に凸となる照明部品収納部62を内箱22に有する場合、真空断熱材の50iの厚さが一定だと、真空断熱材50iと照明部品収納部62が接触する。そのため、真空断熱材50iの厚さを薄くしなければならないが、薄くしてしまうと断熱性能も低下してしまう。そこで、部分的な凹所61を形成することで、真空断熱材50iは全体として厚くすることが可能となり、薄くなる部分は最小限の凹所61のみとなる。   For example, when the inner box 22 has a lighting component storage portion 62 that is convex toward the outer box side, the vacuum heat insulating material 50i and the lighting component storage portion 62 come into contact with each other if the thickness of the vacuum heat insulating material 50i is constant. For this reason, the thickness of the vacuum heat insulating material 50i must be reduced. However, if the thickness is reduced, the heat insulating performance is also deteriorated. Therefore, by forming the partial recess 61, the vacuum heat insulating material 50i can be thickened as a whole, and the thinned portion is only the minimum recess 61.

また、外箱21と内箱22とによって形成される空間に、硬質ウレタンフォーム等の発泡断熱材23を充填する時に、照明部品収納部62と真空断熱材50iの距離を確保することで、ウレタンの流動性の低下を抑えることができ、断熱性能の低下を抑制することができる。   In addition, when the space formed by the outer box 21 and the inner box 22 is filled with the foam heat insulating material 23 such as hard urethane foam, the distance between the lighting component storage portion 62 and the vacuum heat insulating material 50i is ensured, thereby making the urethane. The fluidity | liquidity fall of can be suppressed, and the fall of heat insulation performance can be suppressed.

なお、照明部品収納部62は、側面壁に有する場合でも上面壁に有する場合でもよく、公知の照明配置構造に対応して真空断熱材に凹所を形成すればよい。   In addition, the illumination component storage part 62 may be provided on the side wall or the upper surface wall, and a recess may be formed in the vacuum heat insulating material corresponding to a known illumination arrangement structure.

なお、減圧工程において、芯材は内包材及び外被材から圧縮するように押しつけられる力が加わる。   In the decompression step, a force is applied to the core material so as to compress it from the inner packaging material and the outer covering material.

この場合、減圧が進行して芯材と内包材、及び内包材と外被材との摩擦抵抗が大きくなると、芯材,内包材及び外被材間で滑り変形しにくくなる。すると、外被材には引張又は圧縮の応力が加わり、金属蒸着層等のガスバリヤ層にクラックが生じる場合がある。   In this case, when the pressure reduction progresses and the frictional resistance between the core material and the inner packaging material and between the inner packaging material and the outer jacket material increases, sliding deformation between the core material, the inner packaging material, and the outer jacket material becomes difficult. Then, tensile or compressive stress is applied to the jacket material, and a crack may occur in a gas barrier layer such as a metal vapor deposition layer.

そこで、減圧工程前又は減圧開始直後から減圧の途中までの間、芯材,内包材及び外被材間の摩擦抵抗が大きくなる前に、外被材の外側から、金型等で凹所の形成位置を部分的に押し出すようにする。これにより、摩擦抵抗が大きくなる前に、外被材が凹所近傍に滑るように位置するので、ガスバリヤ層のクラックの発生を抑制できる。   Therefore, before the decompression process or immediately after the start of decompression, until the middle of decompression, before the frictional resistance between the core material, the inner packaging material and the jacket material increases, The forming position is partially extruded. Thereby, before the frictional resistance is increased, the covering material is positioned so as to slide in the vicinity of the recess, so that generation of cracks in the gas barrier layer can be suppressed.

以上のように、本発明は、金型によるプレス成形加工を実質的に必要とせず、部品との距離を確保するための目的に応じた凹所を形成することができる。また、真空断熱材の信頼性を低下させることなく、断熱性能の低下も抑制して凹所を形成することができ、生産性の向上した真空断熱材及びこれを用いた冷蔵庫を提供することができる。   As described above, the present invention does not substantially require press molding with a mold, and can form a recess according to the purpose for securing the distance from the component. Moreover, without lowering the reliability of the vacuum heat insulating material, it is possible to form a recess while suppressing a decrease in heat insulating performance, and to provide a vacuum heat insulating material with improved productivity and a refrigerator using the same. it can.

1 冷蔵庫
20 箱体
21 外箱
21a 上面壁
21b 背面壁
21d 底面壁
21e 側面壁
22 内箱
23 発泡断熱材
50,50a〜50i 真空断熱材
51 芯材
51a,51e,51i 芯材(第四の積層体)
51b,51f,51j,51n 芯材(第一の積層体)
51c,51g,51k,51p 芯材(第二の積層体)
51d,51h,51l,51m 芯材(第三の積層体)
51g1,51h1,51k1,51l1 傾斜面
51k2,51l2 対向面
52,52a〜52d 内包材
53,53a〜53d 外被材
54 吸着剤
58,58a〜58c,61 凹所
59 筋
60,60a〜60d 空間
62 照明部品収納部
90 放熱パイプ
DESCRIPTION OF SYMBOLS 1 Refrigerator 20 Box 21 Outer box 21a Top wall 21b Back wall 21d Bottom wall 21e Bottom wall 21e Side wall 22 Inner box 23 Foam insulation 50, 50a-50i Vacuum insulation 51 Core 51a, 51e, 51i Core (fourth lamination | stacking) body)
51b, 51f, 51j, 51n Core material (first laminate)
51c, 51g, 51k, 51p Core material (second laminate)
51d, 51h, 51l, 51m Core material (third laminate)
51g1, 51h1, 51k1, 51l1 Inclined surface 51k2, 51l2 Opposing surfaces 52, 52a to 52d Inner packaging material 53, 53a to 53d Outer material 54 Adsorbent 58, 58a to 58c, 61 Recess 59 Muscle 60, 60a to 60d Space 62 Lighting component storage 90 heat dissipation pipe

Claims (7)

繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧した真空断熱材において、
前記芯材は第一の積層体と、該第一の積層体上に所定間隔で配置した第二の積層体及び第三の積層体と、を有し、
前記第一の積層体は前記第二の積層体及び前記第三の積層体の空間を埋めるように変形し、前記第一の積層体側に凹所が形成されたことを特徴とする真空断熱材。
In a vacuum heat insulating material having a core material of a fiber laminate, and a jacket material that houses the core material, and having reduced the pressure inside the jacket material,
The core has a first laminate, and a second laminate and a third laminate disposed on the first laminate at predetermined intervals,
The vacuum laminate is characterized in that the first laminate is deformed so as to fill a space between the second laminate and the third laminate, and a recess is formed on the first laminate side. .
繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧した真空断熱材において、
前記芯材は第一の積層体と、該第一の積層体上に所定間隔で配置した第二の積層体及び第三の積層体と、を有し、
前記第二の積層体及び第三の積層体の向かい合う面は前記外被材側よりも前記第一の積層体側が幅広となり、前記第一の積層体は前記第二の積層体及び前記第三の積層体の空間を埋めるように変形し、前記第一の積層体側に凹所が形成されたことを特徴とする真空断熱材。
In a vacuum heat insulating material having a core material of a fiber laminate, and a jacket material that houses the core material, and having reduced the pressure inside the jacket material,
The core has a first laminate, and a second laminate and a third laminate disposed on the first laminate at predetermined intervals,
The opposing surfaces of the second laminate and the third laminate are wider on the first laminate side than on the jacket material side, and the first laminate is the second laminate and the third laminate. A vacuum heat insulating material which is deformed so as to fill a space of the laminated body, and has a recess formed on the first laminated body side.
前記第二の積層体及び第三の積層体の向かい合う面は傾斜面を有し、該傾斜面に沿って前記第一の積層体が変形し、前記凹所が形成されたことを特徴とする、請求項2記載の真空断熱材。   The opposing surfaces of the second laminate and the third laminate have an inclined surface, the first laminate is deformed along the inclined surface, and the recess is formed. The vacuum heat insulating material according to claim 2. 前記傾斜面の角度は20〜70°であることを特徴とする、請求項3記載の真空断熱材。   The vacuum heat insulating material according to claim 3, wherein an angle of the inclined surface is 20 to 70 °. 繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧した真空断熱材において、
前記芯材は第一の積層体と、該第一の積層体上に配置した第二の積層体と、を有し、
前記第二の積層体は前記外被材側よりも前記第一の積層体側が幅広となる空間を有し、前記第一の積層体は前記第二の積層体の前記空間を埋めるように変形し、前記第一の積層体側に凹所が形成されたことを特徴とする真空断熱材。
In a vacuum heat insulating material having a core material of a fiber laminate, and a jacket material that houses the core material, and having reduced the pressure inside the jacket material,
The core material has a first laminate and a second laminate disposed on the first laminate,
The second laminated body has a space in which the first laminated body side is wider than the outer cover material side, and the first laminated body is deformed so as to fill the space of the second laminated body. A vacuum heat insulating material, wherein a recess is formed on the first laminate side.
外箱の内側に配置された真空断熱材と、該真空断熱材と前記外箱との間に配置された放熱パイプと、を備えた冷蔵庫において、
前記真空断熱材は、繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧して、
前記芯材は第一の積層体と、該第一の積層体上に所定間隔で配置した第二の積層体及び第三の積層体と、を有し、
前記第二の積層体及び第三の積層体の向かい合う面は前記外被材側よりも前記第一の積層体側が幅広となり、前記第一の積層体は前記第二の積層体及び前記第三の積層体の空間を埋めるように変形し、前記第一の積層体側に凹所が形成され、該凹所に前記放熱パイプが配置されたことを特徴とする冷蔵庫。
In a refrigerator comprising a vacuum heat insulating material disposed inside an outer box, and a heat radiating pipe disposed between the vacuum heat insulating material and the outer box,
The vacuum heat insulating material has a core material of a fiber laminate, and a jacket material that houses the core material, and depressurizes the inside of the jacket material,
The core has a first laminate, and a second laminate and a third laminate disposed on the first laminate at predetermined intervals,
The opposing surfaces of the second laminate and the third laminate are wider on the first laminate side than on the jacket material side, and the first laminate is the second laminate and the third laminate. A refrigerator which is deformed so as to fill a space of the laminate, wherein a recess is formed on the first laminate, and the heat radiating pipe is disposed in the recess.
内箱の外側に配置された真空断熱材と、該真空断熱材と前記内箱との間に配置された部品収納部と、を備えた冷蔵庫において、
前記真空断熱材は、繊維積層体の芯材と、該芯材を収納する外被材とを有し、前記外被材内を減圧して、
前記芯材は第一の積層体と、該第一の積層体上に配置した第二の積層体と、を有し、
前記第一の積層体は前記第二の積層体の前記空間を埋めるように変形し、前記第一の積層体側に凹所が形成され、該凹所に前記部品収納部が配置されたことを特徴とする冷蔵庫。
In a refrigerator comprising a vacuum heat insulating material disposed outside an inner box, and a component storage unit disposed between the vacuum heat insulating material and the inner box,
The vacuum heat insulating material has a core material of a fiber laminate, and a jacket material that houses the core material, and depressurizes the inside of the jacket material,
The core material has a first laminate and a second laminate disposed on the first laminate,
The first laminated body is deformed so as to fill the space of the second laminated body, a recess is formed on the first laminated body side, and the component storage portion is disposed in the recess. Features a refrigerator.
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