JP2012017752A - Vacuum heat insulation member and refrigerator using same - Google Patents

Vacuum heat insulation member and refrigerator using same Download PDF

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Publication number
JP2012017752A
JP2012017752A JP2010153542A JP2010153542A JP2012017752A JP 2012017752 A JP2012017752 A JP 2012017752A JP 2010153542 A JP2010153542 A JP 2010153542A JP 2010153542 A JP2010153542 A JP 2010153542A JP 2012017752 A JP2012017752 A JP 2012017752A
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heat insulating
vacuum heat
density
insulating material
refrigerator
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JP2010153542A
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JP2012017752A5 (en
JP5492685B2 (en
Inventor
Yushi Arai
祐志 新井
Kuninari Araki
邦成 荒木
Hisashi Echigoya
恒 越後屋
Takashi Izeki
崇 井関
Yasuto Terauchi
康人 寺内
Hiroyuki Yamazaki
裕之 山崎
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Hitachi Appliances Inc
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Hitachi Appliances Inc
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Priority to JP2010153542A priority Critical patent/JP5492685B2/en
Priority to CN201080067854.1A priority patent/CN102971571B/en
Priority to KR1020127032150A priority patent/KR101495127B1/en
Priority to PCT/JP2010/064293 priority patent/WO2012004901A1/en
Publication of JP2012017752A publication Critical patent/JP2012017752A/en
Publication of JP2012017752A5 publication Critical patent/JP2012017752A5/ja
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • F25D23/065Details
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • F16L59/065Arrangements using an air layer or vacuum using vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • F25D2201/12Insulation with respect to heat using an insulating packing material
    • F25D2201/124Insulation with respect to heat using an insulating packing material of fibrous type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • F25D2201/14Insulation with respect to heat using subatmospheric pressure

Abstract

PROBLEM TO BE SOLVED: To provide a vacuum heat insulation member and a refrigerator provided therewith in which loads on a core member and an outer covering member are reduced, resulting in heat insulation performance being able to be secured for a long period of time.SOLUTION: The vacuum heat insulation member is equipped with the core member; and the outer covering member, which houses the core member, and the interior of which is depressurized. Cutouts are provided in first pieces of material of the core member. A second piece of material the density of which is lower than that of the first pieces of material, and the thickness-wise deformation rate of which is larger than that of the same, is placed in overall contact with the first pieces of material. The second piece of material is bent toward the cutouts in such a way as to form recesses.

Description

本発明は真空断熱材及びこれを用いた冷蔵庫に関する。   The present invention relates to a vacuum heat insulating material and a refrigerator using the same.

本技術分野の背景技術として、特開2008−64323号公報(特許文献1)がある。特許文献1には、外箱と内箱間に発泡断熱材を充填した断熱箱体と、外箱の内面側に配される放熱パイプと、芯材を外被材で覆って内部が減圧されるとともに放熱パイプが嵌められる溝部を設けた真空断熱パネルとを備えた冷蔵庫において、真空断熱パネルは、溝部を形成した面の裏面に溝部に対向して形成されるとともに溝部よりも長手方向に垂直な幅が広い凸部を有する構成が記載されている。   As a background art in this technical field, there is JP-A-2008-64323 (Patent Document 1). In Patent Document 1, a heat insulating box body filled with a foam heat insulating material between an outer box and an inner box, a heat radiating pipe arranged on the inner surface side of the outer box, and a core material covered with a jacket material, the inside is decompressed. And a vacuum heat insulating panel provided with a groove part into which a heat radiating pipe is fitted, the vacuum heat insulating panel is formed on the back surface of the surface on which the groove part is formed so as to face the groove part and is perpendicular to the longitudinal direction than the groove part. A configuration having a wide convex portion is described.

特開2008−64323号公報JP 2008-64323 A

しかしながら、特許文献1では、真空断熱材を形成した後に、金型によりプレス加工を行うことで真空断熱材に溝部を形成している。すると、真空断熱材の性能において加工部における芯材の無機繊維が切断等される。これにより、断熱性能が悪化する。また、外被材がプレス加工により延伸され破れやガスバリヤ性の低下が生じることで、断熱性能が悪化するという問題があった。   However, in patent document 1, after forming a vacuum heat insulating material, the groove part is formed in a vacuum heat insulating material by pressing with a metal mold | die. Then, in the performance of the vacuum heat insulating material, the inorganic fiber of the core material in the processed part is cut or the like. Thereby, heat insulation performance deteriorates. In addition, there is a problem that the heat insulation performance deteriorates because the jacket material is stretched by press working and is torn and gas barrier property is lowered.

そこで本発明は、芯材や外被材への負荷を低減することで、長期に亘って断熱性能を確保できる真空断熱材及びこれを備えた冷蔵庫を提供することを目的とする。   Then, an object of this invention is to provide the vacuum heat insulating material which can ensure heat insulation performance over a long period of time by reducing the load to a core material and a jacket material, and a refrigerator provided with the same.

上記課題を解決するために、例えば特許請求の範囲に記載の構成を採用する。本願発明は上記課題を解決する手段を複数含んでいるが、その一例を挙げるならば、芯材と、該芯材を収納して内部を減圧する外被材とを備えた真空断熱材において、前記芯材は第一の材料に切り欠き部を設け、該第一の材料よりも密度が低く厚み方向の変形率が大きい第二の材料を前記第一の材料の上に重ねて、前記第二の材料は凹部を形成するように前記切り欠き部側に湾曲したことを特徴とする。   In order to solve the above problems, for example, the configuration described in the claims is adopted. The invention of the present application includes a plurality of means for solving the above-described problems. To give an example, a vacuum heat insulating material provided with a core material and a jacket material that houses the core material and depressurizes the inside, The core material is provided with a notch in the first material, and a second material having a density lower than that of the first material and a large deformation rate in the thickness direction is overlaid on the first material, The second material is characterized by being curved toward the notch so as to form a recess.

芯材や外被材への負荷を低減することで、長期に亘って断熱性能を確保できる真空断熱材及びこれを備えた冷蔵庫を提供することができる。   By reducing the load on the core material and the jacket material, it is possible to provide a vacuum heat insulating material that can ensure heat insulating performance over a long period of time and a refrigerator including the same.

本発明の実施例に係る冷蔵庫の正面図。The front view of the refrigerator which concerns on the Example of this invention. 図1のA−A断面図。AA sectional drawing of FIG. 本発明に用いた真空断熱材の概略断面図。The schematic sectional drawing of the vacuum heat insulating material used for this invention. 本発明の実施例1を示す真空断熱材の芯材構成説明図。BRIEF DESCRIPTION OF THE DRAWINGS Core material structure explanatory drawing of the vacuum heat insulating material which shows Example 1 of this invention. 本発明の実施例2を示す真空断熱材の芯材構成説明図。The core-material structure explanatory drawing of the vacuum heat insulating material which shows Example 2 of this invention. 本発明の実施例3を示す真空断熱材外箱設置説明図。The vacuum heat insulating material outer box installation explanatory drawing which shows Example 3 of this invention. 本発明の各実施例に係る芯材材料の評価結果を示す図表。The chart which shows the evaluation result of the core material which concerns on each Example of this invention.

以下、本発明の実施形態について、図1及び図2を用いて説明する。図1は本実施形態を示す冷蔵庫の正面図であり、図2は図1のA−A断面図を示している。   Hereinafter, embodiments of the present invention will be described with reference to FIGS. 1 and 2. FIG. 1 is a front view of a refrigerator showing the present embodiment, and FIG. 2 is a cross-sectional view taken along line AA of FIG.

本実施形態の冷蔵庫1は、図2に示すように、上部に冷蔵室2、下部に野菜室5を有している。また、冷蔵室2と野菜室5との間には、下段冷凍室4を備えている。下段冷凍室4と冷蔵室2の間には、左右に並べて製氷室3aと上段冷凍室3bを備えている。   The refrigerator 1 of this embodiment has the refrigerator compartment 2 in the upper part, and the vegetable compartment 5 in the lower part, as shown in FIG. Further, a lower freezer compartment 4 is provided between the refrigerator compartment 2 and the vegetable compartment 5. Between the lower freezer compartment 4 and the refrigerator compartment 2, an ice making room 3a and an upper freezer room 3b are provided side by side.

上記各貯蔵室には、図1に示すように、前面開口を開閉する扉がそれぞれ設けられている。冷蔵室2には、ヒンジ10等を中心に回動する回転式の冷蔵室扉6a,6bが設けられている。   As shown in FIG. 1, each of the storage chambers is provided with a door that opens and closes the front opening. The refrigerating room 2 is provided with rotating refrigerating room doors 6a and 6b that rotate around the hinge 10 and the like.

製氷室3a,上段冷凍室3b,下段冷凍室4及び野菜室5には、それぞれ引き出し式の製氷室扉7a,上段冷凍室扉7b,下段冷凍室扉8,野菜室扉9を配置する。これらの引き出し式の扉を引き出すと、各貯蔵室に収納した貯蔵容器が共に引き出される。   In the ice making room 3a, the upper freezing room 3b, the lower freezing room 4 and the vegetable room 5, a drawer type ice making room door 7a, an upper freezing room door 7b, a lower freezing room door 8 and a vegetable room door 9 are arranged. When these drawer type doors are pulled out, the storage containers housed in the respective storage chambers are pulled out together.

各扉には、冷蔵庫1本体に気密的に密着するためのシール部材11を備え、各扉の貯蔵室側の開口外周縁に取り付けられている。また、冷蔵室2と製氷室3a及び上段冷凍室3bとの間を断熱区画するために、断熱仕切り12を配置している。この断熱仕切り12は、厚さ30〜50mm程度の断熱壁で、スチロフォーム,発泡断熱材(硬質ウレタンフォーム),真空断熱材等、それぞれを単独使用又は複数の断熱材を組み合わせて設けられている。また、同様に、下段冷凍室4と野菜室5の間には、区画断熱するための断熱仕切り14を設けている。   Each door includes a seal member 11 for hermetically adhering to the refrigerator 1 body, and is attached to the outer peripheral edge of the door on the storage chamber side. In addition, a heat insulating partition 12 is arranged to insulate the refrigerator compartment 2 from the ice making chamber 3a and the upper freezer compartment 3b. The heat insulating partition 12 is a heat insulating wall having a thickness of about 30 to 50 mm, and is provided with a single material or a combination of a plurality of heat insulating materials such as a styrofoam, a foam heat insulating material (hard urethane foam), a vacuum heat insulating material, and the like. . Similarly, a heat insulating partition 14 is provided between the lower freezer compartment 4 and the vegetable compartment 5 to insulate the compartment.

製氷室3a及び上段冷凍室3bと下段冷凍室4の間は、温度帯が同じであるため区画断熱する仕切りではなく、シール部材11受面を形成した仕切り部材13を設けている。   Between the ice making chamber 3a and the upper freezing chamber 3b and the lower freezing chamber 4, since the temperature zone is the same, a partition member 13 having a seal member 11 receiving surface is provided instead of a partition heat insulation.

基本的に冷蔵,冷凍等の貯蔵温度帯の異なる部屋の仕切りには断熱仕切りを設置している。なお、箱体20内には上から冷蔵室2,製氷室3a及び上段冷凍室3b,下段冷凍室4,野菜室5の貯蔵室をそれぞれ区画形成しているが、各貯蔵室の配置については特にこれに限定するものではない。また、冷蔵室扉6a,6b,製氷室扉7a,上段冷凍室扉7b,下段冷凍室扉8,野菜室扉9に関しても、回転による開閉,引き出しによる開閉及び扉の分割数等、特に限定するものではない。   Insulation partitions are basically installed in the partitions of rooms with different storage temperature zones such as refrigeration and freezing. In addition, although the storage room of the refrigerator compartment 2, the ice-making room 3a, the upper stage freezer compartment 3b, the lower stage freezer compartment 4, and the vegetable compartment 5 is each dividedly formed in the box 20, the arrangement | positioning of each storage room is carried out. The invention is not particularly limited to this. Further, the refrigerator doors 6a and 6b, the ice making door 7a, the upper freezer door 7b, the lower freezer door 8, and the vegetable door 9 are also specifically limited, such as opening / closing by rotation, opening / closing by drawer, and the number of divided doors. It is not a thing.

箱体20は、外箱21と内箱22とを備え、外箱21と内箱22とによって形成される空間に断熱部を設けて箱体20内の各貯蔵室と外部とを断熱している。この外箱21と内箱22との空間に真空断熱材を配置し、真空断熱材以外の空間には硬質ウレタンフォーム等の発泡断熱材23を充填してある。真空断熱材50については後述する。   The box 20 includes an outer box 21 and an inner box 22, and a heat insulating part is provided in a space formed by the outer box 21 and the inner box 22 to insulate each storage chamber in the box 20 from the outside. Yes. A vacuum heat insulating material is disposed in the space between the outer box 21 and the inner box 22, and a space other than the vacuum heat insulating material is filled with a foam heat insulating material 23 such as hard urethane foam. The vacuum heat insulating material 50 will be described later.

また、冷蔵庫1の各貯蔵室を所定の温度に冷却するために、製氷室3a,上段冷凍室3b,下段冷凍室4(冷凍温度帯室)の背側には、冷却器28が備えられている。この冷却器28は、圧縮機30と凝縮機31,キャピラリーチューブ(図示せず)とを接続し、冷凍サイクルを構成している。冷却器28の上方には、この冷却器28にて冷却された冷気を冷蔵庫1内に循環して所定の低温度を保持する送風機27が配設されている。   Further, in order to cool each storage room of the refrigerator 1 to a predetermined temperature, a cooler 28 is provided on the back side of the ice making room 3a, the upper freezing room 3b, and the lower freezing room 4 (freezing temperature zone room). Yes. The cooler 28 connects a compressor 30, a condenser 31, and a capillary tube (not shown) to constitute a refrigeration cycle. Above the cooler 28, a blower 27 that circulates the cold air cooled by the cooler 28 in the refrigerator 1 and maintains a predetermined low temperature is disposed.

また、冷蔵庫1の冷蔵室2と製氷室3a及び上段冷凍室3b、冷凍室4と野菜室5を区画する断熱仕切り12,14は、発泡ポリスチレン33と真空断熱材50cを備えている。断熱仕切り12,14については、硬質ウレタンフォーム等の発泡断熱材を充填しても良く、特に発泡ポリスチレン33と真空断熱材50cに限定するものではない。   Moreover, the heat insulation partitions 12 and 14 which divide the refrigerator compartment 2, the ice making room 3a, the upper freezer compartment 3b, the freezer compartment 4, and the vegetable compartment 5 of the refrigerator 1 are provided with the expanded polystyrene 33 and the vacuum heat insulating material 50c. About the heat insulation partitions 12 and 14, you may fill with foam heat insulating materials, such as a rigid urethane foam, and it does not specifically limit to the foamed polystyrene 33 and the vacuum heat insulating material 50c.

また、箱体20の天面後方部には、冷蔵庫1の運転を制御するための基板や電源基板等の電気部品41を収納するための凹部40が形成されている。また、電気部品41を覆うカバー42が設けられている。カバー42の高さは、外観意匠性と内容積確保を考慮して、外箱21の天面21aとほぼ同じ高さになるように配置している。特に限定するものではないが、カバー42の高さが外箱21の天面21aよりも突き出る場合は、10mm以内の範囲に収めることが望ましい。   Moreover, the recessed part 40 for accommodating electrical components 41, such as a board | substrate for controlling the driving | operation of the refrigerator 1, and a power supply board, is formed in the top surface rear part of the box 20. As shown in FIG. Further, a cover 42 that covers the electrical component 41 is provided. The height of the cover 42 is arranged so as to be substantially the same height as the top surface 21a of the outer box 21 in consideration of appearance design and securing the internal volume. Although it does not specifically limit, when the height of the cover 42 protrudes from the top surface 21a of the outer box 21, it is desirable to keep in the range within 10 mm.

凹部40は発泡断熱材23側に電気部品41を収納する空間だけ窪んだ状態で配置されるため、断熱厚さを確保するため必然的に内容積が犠牲になってしまう。内容積をより大きくとると、凹部40と内箱22間の発泡断熱材23の厚さが薄くなってしまう。このため、凹部40の発泡断熱材23中に真空断熱材50aを配置して、断熱性能を確保しつつ強化している。本実施例では、真空断熱材50aを電気部品41の下部に跨るように略Z形状に成形した1枚の真空断熱材50aとしている。尚、カバー42は耐熱性を考慮して鋼板製とする。   Since the recessed portion 40 is disposed in a state where only the space for storing the electrical component 41 is recessed on the foamed heat insulating material 23 side, the internal volume is inevitably sacrificed in order to ensure the heat insulating thickness. If the internal volume is increased, the thickness of the foam heat insulating material 23 between the recess 40 and the inner box 22 will be reduced. For this reason, the vacuum heat insulating material 50a is arrange | positioned in the foam heat insulating material 23 of the recessed part 40, and it is strengthening, ensuring heat insulation performance. In the present embodiment, the vacuum heat insulating material 50a is a single vacuum heat insulating material 50a formed in a substantially Z shape so as to straddle the lower part of the electrical component 41. The cover 42 is made of a steel plate in consideration of heat resistance.

また、箱体20の背面下部に配置された圧縮機30や凝縮機31は、発熱の大きい部品である。そのため、庫内への熱侵入を防止するため、内箱22側への投影面に真空断熱材50dを配置している。また、側面21eや背面21bにも、真空断熱材50b等を配置することで、箱体20の断熱性を高めている。   Moreover, the compressor 30 and the condenser 31 arrange | positioned at the back lower part of the box 20 are components with big heat_generation | fever. Therefore, a vacuum heat insulating material 50d is disposed on the projection surface toward the inner box 22 in order to prevent heat from entering the interior. Moreover, the heat insulation of the box 20 is improved by arranging the vacuum heat insulating material 50b and the like on the side surface 21e and the back surface 21b.

次に、本実施形態の真空断熱材50について、図3を用いてその構成を説明する。真空断熱材50は、芯材51と該芯材51を圧縮状態に保持するための内包材52、前記内包材52で圧縮状態に保持した芯材51を被覆するガスバリヤ層を有する外被材53、及び吸着剤(図示せず)とを有する。   Next, the structure of the vacuum heat insulating material 50 of this embodiment will be described with reference to FIG. The vacuum heat insulating material 50 includes a core material 51, an inner packaging material 52 for holding the core material 51 in a compressed state, and an outer jacket material 53 having a gas barrier layer covering the core material 51 held in a compressed state by the inner packaging material 52. And an adsorbent (not shown).

外被材53は、真空断熱材50の外側に配置され、同じ大きさのラミネートフィルムの稜線から一定の幅の部分を熱溶着により貼り合わせた袋状で構成されている。なお、本実施例において、芯材51についてはバインダー等で接着や結着していない柔軟性を有する無機繊維の積層体としており、平均繊維径4μmのグラスウールを用いる。芯材51については、無機系繊維材料の積層体を使用することにより、アウトガスが少なくなるため、断熱性能的に有利であるが、特にこれに限定するものではなく、例えばセラミック繊維やロックウール,グラスウール以外のガラス繊維等の無機繊維等でもよい。芯材51の種類によっては内包材52が不要の場合もある。   The jacket material 53 is disposed outside the vacuum heat insulating material 50, and is configured in a bag shape in which portions having a certain width are bonded to each other from the ridge line of the same size laminate film by thermal welding. In the present embodiment, the core material 51 is a laminate of flexible inorganic fibers that are not bonded or bound with a binder or the like, and glass wool having an average fiber diameter of 4 μm is used. About the core material 51, since outgas is reduced by using a laminate of inorganic fiber materials, it is advantageous in terms of heat insulation performance. However, the core material 51 is not particularly limited to this. For example, ceramic fibers, rock wool, Inorganic fibers such as glass fibers other than glass wool may be used. Depending on the type of the core material 51, the inner packaging material 52 may be unnecessary.

また、芯材51については、無機系繊維材料の他に、有機系樹脂繊維材料を用いることができる。有機系樹脂繊維の場合、耐熱温度等を満足していれば特に使用に際して制約されるものではない。具体的には、ポリスチレンやポリエチレンテレフタレート,ポリプロピレン等をメルトブローン法やスパンボンド法等で1〜30μm程度の繊維径になるように繊維化するのが一般的であるが、繊維化できる有機系樹脂や繊維化方法であれば特に問うものではない。   Moreover, about the core material 51, an organic resin fiber material other than an inorganic fiber material can be used. In the case of organic resin fibers, there are no particular restrictions on use as long as the heat-resistant temperature is satisfied. Specifically, it is common to fiberize polystyrene, polyethylene terephthalate, polypropylene, etc. to a fiber diameter of about 1 to 30 μm by a melt blown method or a spun bond method, If it is a fiberization method, it will not ask in particular.

外被材53のラミネート構成については、ガスバリヤ性を有し、熱溶着可能であれば特に限定するものではないが、本実施形態においては、表面保護層,複層のガスバリヤ層,熱溶着層の3層構成からなるラミネートフィルムとしている。表面保護層は、保護材の役割を持つ樹脂フィルムとしている。   The laminate structure of the jacket material 53 is not particularly limited as long as it has gas barrier properties and can be thermally welded. In this embodiment, the surface protective layer, the multiple gas barrier layers, and the thermally welded layer are not limited. The laminate film has a three-layer structure. The surface protective layer is a resin film that serves as a protective material.

ガスバリヤ層は、樹脂フィルムに金属蒸着層を設けた層と、酸素バリヤ性の高い樹脂フィルムに金属蒸着層を設けた層とを有し、互いの金属蒸着層同士が向かい合うように貼り合わせている。   The gas barrier layer has a layer in which a metal vapor deposition layer is provided on a resin film and a layer in which a metal vapor deposition layer is provided on a resin film having a high oxygen barrier property, and is bonded so that the metal vapor deposition layers face each other. .

熱溶着層は、表面層と同様に吸湿性の低いフィルムを用いている。   The heat welding layer uses a film having a low hygroscopicity like the surface layer.

具体的には、表面保護層として、二軸延伸タイプのポリプロピレン,ポリアミド,ポリエチレンテレフタレート等の各フィルムを用いる。   Specifically, a biaxially stretched polypropylene, polyamide, polyethylene terephthalate film or the like is used as the surface protective layer.

ガスバリヤ層として、アルミニウム蒸着付きの二軸延伸ポリエチレンテレフタレートフィルムと、アルミニウム蒸着付きの二軸延伸エチレンビニルアルコール共重合体樹脂フィルム又はアルミニウム蒸着付きの二軸延伸ポリビニルアルコール樹脂フィルム、或いはアルミ箔を用いる。   As the gas barrier layer, a biaxially stretched polyethylene terephthalate film with aluminum vapor deposition, a biaxially stretched ethylene vinyl alcohol copolymer resin film with aluminum vapor deposition, a biaxially stretched polyvinyl alcohol resin film with aluminum vapor deposition, or an aluminum foil is used.

熱溶着層として、未延伸タイプのポリエチレン,ポリプロピレン等の各フィルムとする。   As the heat welding layer, unstretched polyethylene, polypropylene, or other films are used.

この3層構成のラミネートフィルムの層構成や材料については、特にこれらに限定するものではない。例えばガスバリヤ層として、金属箔、或いは樹脂系のフィルムに無機層状化合物,ポリアクリル酸等の樹脂系ガスバリヤコート材,DLC(ダイヤモンドライクカーボン)等によるガスバリヤ膜を設けたものや、熱溶着層に酸素バリヤ性の高いポリブチレンテレフタレートフィルム等を用いても良い。   The layer configuration and material of the three-layer laminate film are not particularly limited thereto. For example, as a gas barrier layer, a metal foil or a resin film provided with a gas barrier film made of an inorganic layered compound, a resin gas barrier coating material such as polyacrylic acid, DLC (diamond-like carbon), etc. A polybutylene terephthalate film having a high barrier property may be used.

表面保護層は、ガスバリヤ層の保護材であるが、真空断熱材50の製造工程における真空排気効率を良くするためにも、好ましくは吸湿性の低い樹脂を配置するのが良い。   The surface protective layer is a protective material for the gas barrier layer, but in order to improve the vacuum exhaust efficiency in the manufacturing process of the vacuum heat insulating material 50, it is preferable to dispose a resin having a low hygroscopic property.

また、ガスバリヤ層に使用する金属箔以外の樹脂系フィルムは、吸湿することによってガスバリヤ性が著しく悪化してしまうため、熱溶着層についても吸湿性の低い樹脂を配置する。これにより、ガスバリヤ性の悪化を抑制すると共に、ラミネートフィルム全体の吸湿量を抑制するものである。また、真空断熱材50の真空排気工程においても、外被材53が持ち込む水分量を小さくできるため、真空排気効率が大幅に向上し、断熱性能の高性能化につながっている。   Moreover, since resin barrier films other than metal foil used for a gas barrier layer will deteriorate gas barrier property remarkably by absorbing moisture, resin with low hygroscopic property is arrange | positioned also about a heat welding layer. Thereby, while suppressing deterioration of gas barrier property, the moisture absorption amount of the whole laminate film is suppressed. Also, in the vacuum evacuation process of the vacuum heat insulating material 50, the amount of moisture brought into the jacket material 53 can be reduced, so that the vacuum evacuation efficiency is greatly improved, leading to higher performance of heat insulation performance.

なお、各フィルムのラミネート(貼り合せ)は、二液硬化型ウレタン接着剤を介してドライラミネート法によって貼り合わせるのが一般的であるが、接着剤の種類や貼り合わせ方法には特にこれに限定するものではなく、ウェットラミネート法,サーマルラミネート法等の他の方法によるものでもよい。   In addition, the lamination (bonding) of each film is generally performed by a dry laminating method via a two-component curable urethane adhesive, but the type of adhesive and the bonding method are particularly limited to this. However, other methods such as a wet laminating method and a thermal laminating method may be used.

また、内包材52については、熱溶着可能なポリエチレンフィルム、吸着剤は物理吸着タイプの合成ゼオライトを用いている。   In addition, for the encapsulating material 52, a heat-weldable polyethylene film and a physical adsorption type synthetic zeolite are used as the adsorbent.

しかし、いずれもこれらの材料に限定するものではなく、内包材52についてはポリプロピレンフィルム,ポリエチレンテレフタレートフィルム,ポリブチレンテレフタレートフィルム等、吸湿性が低く熱溶着でき、アウトガスが少ないものであれば良く、吸着剤については水分やガスを吸着するもので、物理吸着,化学反応型吸着のどちらでも良い。   However, these are not limited to these materials, and the inner packaging material 52 may be a polypropylene film, a polyethylene terephthalate film, a polybutylene terephthalate film, etc., as long as it has low hygroscopicity and can be thermally welded and has a small outgas. The agent adsorbs moisture and gas and may be either physical adsorption or chemical reaction type adsorption.

(実施例1)
次に、本発明の実施例1について図4を参照しながら説明する。
Example 1
Next, Embodiment 1 of the present invention will be described with reference to FIG.

図4は、実施例1を示す真空断熱材の芯材構成説明図である。真空断熱材50の芯材は、第一の材料51bに切り欠き部51cを設けている。また、第一の材料51bよりも密度が低く厚み方向の変形率が大きい第二の材料51aを、第一の材料51bの上に重ねて、第二の材料51aは凹部54を形成するように切り欠き部51c側に湾曲した構成である。   FIG. 4 is an explanatory diagram of a core material configuration of a vacuum heat insulating material according to the first embodiment. The core material of the vacuum heat insulating material 50 is provided with a notch 51c in the first material 51b. Further, a second material 51a having a density lower than that of the first material 51b and a large deformation rate in the thickness direction is overlaid on the first material 51b so that the second material 51a forms a recess 54. It is the structure curved to the notch part 51c side.

第二の材料51aは、厚み方向に変形が大きい低密度材料として、無機繊維のグラスウール繊維集合体とする。   The second material 51a is a glass wool fiber aggregate of inorganic fibers as a low-density material with large deformation in the thickness direction.

第一の材料51bは、厚み方向に変形が小さい高密度材料として、有機繊維のポリスチレン繊維集合体を用いたものである。   The first material 51b uses a polystyrene fiber aggregate of organic fibers as a high-density material with small deformation in the thickness direction.

第一の材料51bと第二の材料51aとを合わせて、内包材52及び外被材53で真空包装することで、内部は負圧となり、芯材51が外部から均等に圧力を受ける。このとき、第一の材料51bは切り欠き部51cを備えており、第一の材料51bよりも密度が低い第二の材料51aが押されて、切り欠き部51cに入り込む形状となる。なお、第一の材料51bを第二の材料51aよりも小さい形状とすることで、第二の材料51aの一端側又は両端側が湾曲して、凹部を構成することもできる。   By combining the first material 51b and the second material 51a and vacuum-packaging them with the inner packaging material 52 and the outer covering material 53, the inside becomes a negative pressure, and the core material 51 receives the pressure equally from the outside. At this time, the first material 51b has a notch 51c, and the second material 51a having a lower density than the first material 51b is pushed into the notch 51c. In addition, the 1st material 51b can be made into the shape smaller than the 2nd material 51a, and the one end side or both ends side of the 2nd material 51a can curve, and can also comprise a recessed part.

また、切り欠き部の最大深さを第一の材料51bの圧縮変形後の厚さとほぼ同一とする。この場合、第二の材料51aの凹部54を形成するように湾曲した部分は、第一の材料51bの一側面とほぼ同一面となり、凹部54の反対側に必要以上に突出することを抑制することができる。   Further, the maximum depth of the notch is made substantially the same as the thickness of the first material 51b after compression deformation. In this case, the curved portion of the second material 51a that is curved so as to form the recess 54 is substantially flush with one side surface of the first material 51b, and it is prevented from protruding more than necessary on the opposite side of the recess 54. be able to.

次に、本実施例における第一の材料51b及び第二の材料51a、すなわち、高密度材料と低密度材料の検討結果を図7に示す。   Next, FIG. 7 shows the examination results of the first material 51b and the second material 51a in this example, that is, the high-density material and the low-density material.

図7において、No.1は、高密度材料を密度1050kg/m3のABS樹脂板、低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 In FIG. 7, No.1 is, ABS resin plate density 1050 kg / m 3 dense material was a low density material with glass wool fiber aggregate density 11.5 kg / m 3.

No.2は、高密度材料を密度88kg/m3のポリスチレン繊維集合体、低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 In No. 2, a high density material was a polystyrene fiber aggregate having a density of 88 kg / m 3 , and a low density material was a glass wool fiber aggregate having a density of 11.5 kg / m 3 .

No.3は、高密度材料を密度44kg/m3のポリスチレン繊維集合体、低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 In No. 3, a high-density material was a polystyrene fiber aggregate having a density of 44 kg / m 3 , and a low-density material was a glass wool fiber aggregate having a density of 11.5 kg / m 3 .

No.4は、高密度材料を密度25kg/m3の連通した発泡ウレタン、低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 For No. 4, high-density material was foamed urethane with a density of 25 kg / m 3 and low-density material was a glass wool fiber aggregate with a density of 11.5 kg / m 3 .

No.5は、高密度材料を密度44kg/m3のポリスチレン繊維集合体、低密度材料を密度23kg/m3のプレス圧縮したグラスウール繊維集合体とした。 In No. 5, a high-density material was a polystyrene fiber aggregate having a density of 44 kg / m 3 , and a low-density material was a press-compressed glass wool fiber aggregate having a density of 23 kg / m 3 .

No.6は、高密度材料を密度16kg/m3のポリスチレン繊維集合体、低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 In No. 6, a high-density material was a polystyrene fiber aggregate having a density of 16 kg / m 3 , and a low-density material was a glass wool fiber aggregate having a density of 11.5 kg / m 3 .

No.7は、高密度材料及び低密度材料を密度11.5kg/m3のグラスウール繊維集合体とした。 No. 7 was a glass wool fiber aggregate having a density of 11.5 kg / m 3 consisting of a high-density material and a low-density material.

これらの検討の結果、No.1のように、高密度材料に対して低密度材料の密度比が1%となっても、凹部形状を形成することができる。しかし、高密度材料の密度が高い場合は、真空断熱材としたときの熱の伝わりが高く、熱伝導率は悪化してしまう。   As a result of these studies, a concave shape can be formed even if the density ratio of the low-density material to the high-density material is 1% as in No. 1. However, when the density of the high-density material is high, the heat transfer when the vacuum heat insulating material is used is high, and the thermal conductivity is deteriorated.

一方、No.7のように、高密度材料に対して低密度材料の密度比が100%になると、凹部形状が安定して形成できない。   On the other hand, as in No. 7, when the density ratio of the low density material to the high density material is 100%, the concave shape cannot be stably formed.

これにより、高密度材料に対し低密度材料の密度比が13〜72%の場合(No.2〜No.6)、凹部形状の成形性が良く、熱伝導率の良好な値が得られる。また、好ましくは高密度材料に対し低密度材料の密度比が26〜52%(No.3〜No.5)とすることで、より成形性,熱伝導率の良好な真空断熱材を得ることができる。   Thereby, when the density ratio of the low-density material to the high-density material is 13 to 72% (No. 2 to No. 6), the shape of the concave shape is good, and a good value of thermal conductivity is obtained. Further, preferably, the density ratio of the low-density material to the high-density material is set to 26 to 52% (No. 3 to No. 5) to obtain a vacuum heat insulating material with better moldability and thermal conductivity. Can do.

なお、本実施例の高密度材料として、ポリスチレン繊維集合体を用いたが、ポリエチレンテレフタレート,ポリエチレン,ポリプロピレン,ポリカーボネート,ポリアミド,ポリビニルアルコール繊維集合体や、発泡ウレタン,ポリスチレン等を用いることも可能である。   In addition, although the polystyrene fiber aggregate was used as the high-density material of this example, polyethylene terephthalate, polyethylene, polypropylene, polycarbonate, polyamide, polyvinyl alcohol fiber aggregate, foamed urethane, polystyrene, or the like can also be used. .

また、低密度材料として、繊維集合体と同じ種類の繊維集合体でも、バインダーやグラスウールシート等の密度が異なる材料を用いることで凹形状を形成することが可能である。   In addition, as a low-density material, even in the same type of fiber aggregate as the fiber aggregate, it is possible to form a concave shape by using a material having a different density such as a binder or a glass wool sheet.

(実施例2)
次に、図5を参照して実施例2について説明する。図5は、第一の材料51b(ポリスチレン繊維集合体)の一部の層を、第二の材料51a(グラスウール繊維集合体)の大きさよりも小さくしたものである。すなわち、第二の材料51aと重なる第一の材料51bの層に、所定間隔の隙間を設けた構成である。または、第二の材料51aと重なる第一の材料51bの層に、第一の材料51bの圧縮変形後の厚さとほぼ同一の切り欠き部を設けた構成とする。
(Example 2)
Next, Example 2 will be described with reference to FIG. In FIG. 5, a part of the first material 51b (polystyrene fiber aggregate) is made smaller than the size of the second material 51a (glass wool fiber aggregate). That is, it is the structure which provided the clearance gap of the predetermined space | interval in the layer of the 1st material 51b which overlaps with the 2nd material 51a. Or it is set as the structure which provided the notch part substantially the same as the thickness after the compression deformation of the 1st material 51b in the layer of the 1st material 51b which overlaps with the 2nd material 51a.

第二の材料51aの凹部54の大きさは、第一の材料51bの厚さにより決まるため、第一の材料51bの層の厚さを少なくすることで、容易に凹部54の大きさを変えることができる。これにより、第二の材料51aの層において、プレス加工等ではスプリングバックにより成形が困難である小さい凹部54も成形することができる。   Since the size of the concave portion 54 of the second material 51a is determined by the thickness of the first material 51b, the size of the concave portion 54 can be easily changed by reducing the thickness of the layer of the first material 51b. be able to. Thereby, in the layer of the second material 51a, it is possible to form a small concave portion 54 that is difficult to be formed by a spring back by pressing or the like.

(実施例3)
次に、図6を参照して実施例3について説明する。図6は、冷蔵庫の外箱21と内箱22との間に、真空断熱材50を設置した時の断面図である。外箱21と内箱22との間には、真空断熱材50を備えている。さらに、冷媒を放熱する放熱パイプ60が、鋼板製の外箱21に接するように、外箱21と真空断熱材50との間に配置している。これにより、放熱パイプ60からの熱が鋼板製の外箱21を伝わって外部に放熱されるので、庫内に熱影響が及ばないように抑制できる。
(Example 3)
Next, Embodiment 3 will be described with reference to FIG. FIG. 6 is a cross-sectional view when the vacuum heat insulating material 50 is installed between the outer box 21 and the inner box 22 of the refrigerator. A vacuum heat insulating material 50 is provided between the outer box 21 and the inner box 22. Furthermore, the heat radiating pipe 60 for radiating the refrigerant is disposed between the outer box 21 and the vacuum heat insulating material 50 so as to contact the outer box 21 made of steel plate. Thereby, since the heat from the heat radiating pipe 60 is transmitted to the outside through the outer casing 21 made of a steel plate, it can be suppressed so as not to affect the inside of the cabinet.

また、放熱パイプ60は、凹部54に設置する。   The heat radiating pipe 60 is installed in the recess 54.

これにより、平面状の外箱21に放熱パイプ60を配置して、この放熱パイプ60を覆うように真空断熱材50を設置できる。また、外箱21に溝加工等を施さずに、放熱パイプ60の上から真空断熱材50を設置することができる。したがって、真空断熱材50を外箱21に沿った大きな外径寸法で配置することができるので、真空断熱材50によるカバー率が大きくなり、熱漏えいの少ない断熱性能の向上した冷蔵庫1が提供できる。   Thereby, the heat radiating pipe 60 can be arranged in the planar outer box 21, and the vacuum heat insulating material 50 can be installed so as to cover the heat radiating pipe 60. In addition, the vacuum heat insulating material 50 can be installed from above the heat radiating pipe 60 without grooving the outer box 21 or the like. Therefore, since the vacuum heat insulating material 50 can be arranged with a large outer diameter along the outer box 21, the coverage by the vacuum heat insulating material 50 is increased, and the refrigerator 1 with improved heat insulating performance with less heat leakage can be provided. .

以上より、本発明の実施形態によれば、芯材は第一の材料に切り欠き部を設け、この第一の材料よりも密度が低く厚み方向の変形率が大きい第二の材料を第一の材料の上に重ねて、第二の材料は凹部を形成するように切り欠き部側に湾曲したことを特徴とする。すなわち、真空包装したときに外気からの圧力により、厚み方向に変形が大きい第二の材料が第一の材料の切り欠き部に沿った形状となり、凹部を設けることができる。   As described above, according to the embodiment of the present invention, the core material is provided with a notch in the first material, and the second material having a lower density and a higher deformation rate in the thickness direction than the first material is used as the first material. The second material is characterized by being curved toward the notch portion so as to form a recess. That is, the second material that is largely deformed in the thickness direction becomes a shape along the notch portion of the first material due to the pressure from the outside air when vacuum packaging is performed, and a recess can be provided.

これにより、真空断熱材とした後にプレス加工を行う必要がない。よって、芯材の無機繊維が切断されることや、外被材がプレス加工により延伸されて破れやガスバリヤ性が低下する等の断熱性能の低下要因を防ぐことができる。また、冷蔵庫の外箱に設置する放熱パイプ部にも断熱性能を長期維持した真空断熱材を用いることで、冷蔵庫の省エネルギー性を向上できる。   Thereby, it is not necessary to perform a press work after setting it as a vacuum heat insulating material. Therefore, it is possible to prevent factors that lower the heat insulation performance, such as the inorganic fibers of the core material being cut, the outer jacket material being stretched by press working, and being torn or the gas barrier properties being lowered. Moreover, the energy-saving property of a refrigerator can be improved by using the vacuum heat insulating material which maintained heat insulation performance for a long time also in the heat radiating pipe part installed in the outer box of a refrigerator.

1 冷蔵庫
20 箱体
21 外箱
22 内箱
23 発泡断熱材
40,54 凹部
50,50a,50b,50c,50d 真空断熱材
51 芯材
51a 第二の材料(グラスウール繊維集合体)
51b 第一の材料(ポリスチレン繊維集合体)
51c 切り欠き部
52 内包材
53 外被材
60 放熱パイプ
61 アルミテープ
62 発泡ウレタン
DESCRIPTION OF SYMBOLS 1 Refrigerator 20 Box 21 Outer box 22 Inner box 23 Foam heat insulating material 40, 54 Recess 50, 50a, 50b, 50c, 50d Vacuum heat insulating material 51 Core material 51a Second material (glass wool fiber aggregate)
51b First material (polystyrene fiber aggregate)
51c Notch 52 Inner material 53 Outer material 60 Heat radiation pipe 61 Aluminum tape 62 Urethane foam

Claims (6)

芯材と、該芯材を収納して内部を減圧する外被材とを備えた真空断熱材において、
前記芯材は第一の材料に切り欠き部を設け、該第一の材料よりも密度が低く厚み方向の変形率が大きい第二の材料を前記第一の材料の上に重ねて、前記第二の材料は凹部を形成するように前記切り欠き部側に湾曲したことを特徴とする真空断熱材。
In a vacuum heat insulating material provided with a core material and a jacket material that houses the core material and depressurizes the inside,
The core material is provided with a notch in the first material, and a second material having a density lower than that of the first material and a large deformation rate in the thickness direction is overlaid on the first material, A vacuum heat insulating material, wherein the second material is curved toward the notch so as to form a recess.
前記第二の材料としてグラスウール又は樹脂繊維集合体を用いることを特徴とする、請求項1記載の真空断熱材。   The vacuum heat insulating material according to claim 1, wherein glass wool or a resin fiber aggregate is used as the second material. 前記第一の材料として樹脂繊維集合体又は発泡ウレタンを用いることを特徴とする、請求項1記載の真空断熱材。   The vacuum heat insulating material according to claim 1, wherein a resin fiber aggregate or urethane foam is used as the first material. 前記第一の材料に対する前記第二の材料の密度比は13〜72%であることを特徴とする、請求項1乃至3のいずれかに記載の真空断熱材。   The vacuum heat insulating material according to any one of claims 1 to 3, wherein a density ratio of the second material to the first material is 13 to 72%. 前記切り欠き部の最大深さは、前記第一の材料の圧縮変形後の厚さとほぼ同一となることを特徴とする、請求項1乃至3のいずれかに記載の真空断熱材。   The vacuum heat insulating material according to any one of claims 1 to 3, wherein a maximum depth of the notch is substantially the same as a thickness of the first material after compression deformation. 外箱と内箱との間に真空断熱材を備え、
冷媒を放熱する放熱パイプを外箱と真空断熱材との間に配置した冷蔵庫において、
前記真空断熱材は、芯材と、該芯材を収納して内部を減圧する外被材とを備え、
前記芯材は第一の材料に切り欠き部を設け、該第一の材料よりも密度が低く厚み方向の変形率が大きい第二の材料を前記第一の材料の上に重ねて、前記第二の材料は凹部を形成するように前記切り欠き部側に湾曲して、
前記凹部に前記放熱パイプが位置することを特徴とする冷蔵庫。
A vacuum heat insulating material is provided between the outer box and the inner box,
In the refrigerator in which the heat radiating pipe that radiates the refrigerant is disposed between the outer box and the vacuum heat insulating material,
The vacuum heat insulating material includes a core material, and a jacket material that houses the core material and depressurizes the inside.
The core material is provided with a notch in the first material, and a second material having a density lower than that of the first material and a large deformation rate in the thickness direction is overlaid on the first material, The second material is curved toward the notch so as to form a recess,
The refrigerator is characterized in that the heat radiating pipe is located in the recess.
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