JP2010531876A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2010531876A5 JP2010531876A5 JP2010514833A JP2010514833A JP2010531876A5 JP 2010531876 A5 JP2010531876 A5 JP 2010531876A5 JP 2010514833 A JP2010514833 A JP 2010514833A JP 2010514833 A JP2010514833 A JP 2010514833A JP 2010531876 A5 JP2010531876 A5 JP 2010531876A5
- Authority
- JP
- Japan
- Prior art keywords
- rare earth
- earth metal
- formula
- represented
- halo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052761 rare earth metal Inorganic materials 0.000 claims 9
- 150000002910 rare earth metals Chemical class 0.000 claims 8
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 150000001450 anions Chemical class 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 125000001475 halogen functional group Chemical group 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 claims 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims 2
- 239000011780 sodium chloride Substances 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 1
- -1 rare earth metal salt Chemical class 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Claims (3)
- 式(I):
Mはカチオンであり;
REは希土類金属であり;
Xは対アニオンであり;そして
R1、R2、R3およびR4は、それぞれ独立して、水素、炭素原子数1〜8のアルキル、アリール、ハロおよびアルコキシからなる群より選択される]
の希土類金属錯体の調製方法であって、前記方法が、
(i)式(II):
Mはカチオンであり;そして
R1、R2、R3およびR4は、それぞれ独立して、水素、炭素原子数1〜8のアルキル、アリール、ハロおよびアルコキシからなる群より選択される]
により表される、5,6−ジアリール−3−(2−ピリジル)−1,2,4−トリアジントリスルホン酸誘導体の三アルカリ塩;および
(ii)式:
RE3+X3 −
[式中、
REは希土類金属であり;そして
Xは対アニオンである]
により表される希土類金属塩;
を接触させる段階を含み、反応体(i)および(ii)を接触させる前記段階を、溶媒の存在下、前記式(I)の希土類金属錯体を生じるのに足る温度および時間で実施する、前記方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/823,734 US9834660B2 (en) | 2007-06-28 | 2007-06-28 | Rare earth metal complexes that excite in the long UV wavelength range |
US11/823,734 | 2007-06-28 | ||
PCT/US2008/008052 WO2009005733A2 (en) | 2007-06-28 | 2008-06-27 | Rare earth metal complexes that excite in the long uv wavelength range |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2010531876A JP2010531876A (ja) | 2010-09-30 |
JP2010531876A5 true JP2010531876A5 (ja) | 2011-08-04 |
JP5599308B2 JP5599308B2 (ja) | 2014-10-01 |
Family
ID=40158901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010514833A Expired - Fee Related JP5599308B2 (ja) | 2007-06-28 | 2008-06-27 | 長いuv波長範囲で励起する希土類金属錯体 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9834660B2 (ja) |
EP (1) | EP2160448B1 (ja) |
JP (1) | JP5599308B2 (ja) |
KR (1) | KR101494613B1 (ja) |
CN (1) | CN101688113B (ja) |
ES (1) | ES2717139T3 (ja) |
TW (1) | TW200916464A (ja) |
WO (1) | WO2009005733A2 (ja) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2917226B1 (fr) * | 2007-06-06 | 2009-09-11 | Inst Nat Sciences Appliq | Procede de marquage de materiaux a base de matrices organiques polymeriques thermoplastiques ou thermodurcissables |
JP2010188652A (ja) * | 2009-02-19 | 2010-09-02 | Mitsubishi Plastics Inc | 発光性ポリエステルフィルム |
UY32616A (es) | 2009-05-12 | 2010-12-31 | Sicpa Holding Sa | Documento seguro que comprende quelatos luminiscentes |
DE102011122240A1 (de) | 2011-12-23 | 2013-06-27 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal mit mehreren Komponenten |
PT2697072E (pt) | 2012-06-11 | 2015-04-30 | Sicpa Holding Sa | Métodos para impressão de funcionalidades táteis de segurança |
MX347496B (es) | 2012-09-28 | 2017-04-28 | Sicpa Holding Sa | Complejo lantánido luminiscente y artículos y tintas que contienen el complejo luminiscente. |
CN104797351B (zh) | 2012-11-09 | 2017-06-09 | 锡克拜控股有限公司 | 不可逆磁感应的图像或图案 |
KR20150093779A (ko) | 2012-12-07 | 2015-08-18 | 시크파 홀딩 에스에이 | 비-주기적 타일링 문서 보안 요소 |
AU2014261711B2 (en) | 2013-05-01 | 2017-04-20 | Sicpa Holding Sa | Security elements exhibiting a dynamic visual motion |
US10435578B2 (en) * | 2013-05-17 | 2019-10-08 | Spgprints B.V. | Printing ink composition comprising a metal complex with adjusted viscosity |
CN103806273B (zh) * | 2014-02-13 | 2015-12-30 | 北京化工大学常州先进材料研究院 | 一种基于光接枝表面改性制备荧光纳米纤维的方法 |
TW201601928A (zh) | 2014-03-31 | 2016-01-16 | 西克帕控股有限公司 | 包含對掌性液晶聚合物與發光物質的標記 |
US20170157974A1 (en) * | 2014-04-07 | 2017-06-08 | Hewlett-Packard Development Company, L.P. | Electrostatic printing systems |
US20170369715A1 (en) * | 2014-12-30 | 2017-12-28 | Momentive Performance Materials Inc. | Luminescent silicone coatings |
CN104559413B (zh) * | 2015-01-15 | 2017-01-11 | 宁波保税区韬鸿化工科技有限公司 | 负离子腻子粉 |
FR3031697B1 (fr) | 2015-01-16 | 2020-12-18 | Hologram Ind | Composant optique de securite. |
DE102015006753A1 (de) * | 2015-05-26 | 2016-12-01 | Giesecke & Devrient Gmbh | Tintenzusammensetzung, Verwendung derselben und Druckerzeugnis |
JP2018522257A (ja) | 2015-07-01 | 2018-08-09 | シクパ ホルディング ソシエテ アノニムSicpa Holding Sa | 郵便切手 |
CN110049876B (zh) | 2016-12-09 | 2021-06-15 | 锡克拜控股有限公司 | 低能量固化性平版印刷墨兼凸版印刷墨及印刷方法 |
HUE053316T2 (hu) | 2016-12-09 | 2021-06-28 | Sicpa Holding Sa | Alacsony energiával kikeményedõ ofszet és magasnyomású nyomdafestékek és nyomtatási folyamat |
CN106950207B (zh) * | 2017-03-15 | 2019-05-21 | 黑龙江大学 | 检测饮用水中锰离子的方法 |
CN106908440B (zh) * | 2017-03-15 | 2019-05-21 | 黑龙江大学 | 检测饮用水中银离子的方法 |
CN109385142B (zh) * | 2018-09-29 | 2021-12-14 | 广东轻工职业技术学院 | 一种荧光油墨及其制备方法和鉴别方法 |
CN113631918B (zh) | 2019-03-27 | 2023-09-26 | 株式会社岛津制作所 | 离子抑制器 |
AR120745A1 (es) | 2019-12-18 | 2022-03-16 | Sicpa Holding Sa | Tintas de impresión offset curables con radicales por uv-led y procesos de impresión |
EP3988320A1 (en) | 2021-12-20 | 2022-04-27 | Sicpa Holding SA | Security marking, corresponding engraved intaglio printing plate, and methods and devices for producing, encoding/decoding and authenticating said security marking |
CN114539521B (zh) * | 2022-02-25 | 2023-09-29 | 中国地质科学院矿产综合利用研究所 | 一种稀土催化降粘剂及其制备方法和应用 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4701420A (en) | 1985-04-01 | 1987-10-20 | Eastman Kodak Company | Analytical compositions, elements and methods utilizing reduction of ferric ion chelates to form detectable dyes |
US5320969A (en) * | 1992-10-22 | 1994-06-14 | Miles Inc. | Method, composition and device for the semiquantitative determination of specific gravity of a test sample |
JPH08239607A (ja) | 1995-03-03 | 1996-09-17 | Toyo Ink Mfg Co Ltd | 記録液 |
US5837042A (en) | 1996-06-10 | 1998-11-17 | Videojet Systems International, Inc. | Invisible fluorescent jet ink |
US6149719A (en) | 1998-10-28 | 2000-11-21 | Hewlett-Packard Company | Light sensitive invisible ink compositions and methods for using the same |
US7871713B2 (en) | 1998-12-25 | 2011-01-18 | Konica Corporation | Electroluminescent material, electroluminescent element and color conversion filter |
US6538805B1 (en) | 1999-02-19 | 2003-03-25 | Photon-X, Inc. | Codopant polymers for efficient optical amplification |
US6245711B1 (en) | 1999-10-29 | 2001-06-12 | Ncr Corporation | Thermal paper with security features |
US6395862B1 (en) | 2001-01-12 | 2002-05-28 | General Electric Company | Melt polycarbonate catalyst systems |
WO2003018710A1 (en) | 2001-08-23 | 2003-03-06 | Honeywell International, Inc. | Europium-ammonium tetra chelates |
DE10163295B4 (de) | 2001-12-21 | 2004-03-25 | Honeywell Specialty Chemicals Seelze Gmbh | Seltenerdmetall-Verbindungen und Gemische von diesen, Verfahren zu deren Herstellung sowie deren Verwendung |
AU2003206918B2 (en) | 2002-02-26 | 2007-12-06 | Ciba Specialty Chemicals Holding Inc. | Ink compositions containing lanthanide complexes |
JP2003268272A (ja) | 2002-03-18 | 2003-09-25 | Nippon Kayaku Co Ltd | インク組成物 |
DE60329294D1 (de) | 2002-07-17 | 2009-10-29 | Mitsubishi Chem Corp | Wasserlöslicher komplexfarbstoff, aufzeichnungsflüssigkeit sowie aufzeichnungsverfahren |
US20040132228A1 (en) | 2002-12-17 | 2004-07-08 | Honeywell International Inc. | Method and system for fabricating an OLED |
US6905538B2 (en) | 2002-12-30 | 2005-06-14 | Pitney Bowes Inc. | Invisible ink jet inks |
US7147801B2 (en) | 2003-03-13 | 2006-12-12 | Videojet Technologies Inc. | Ink jet ink composition and method for security marking |
JP4400911B2 (ja) | 2003-07-31 | 2010-01-20 | 日本化薬株式会社 | ユーロピウム化合物及びこれを含有するインク組成物 |
JP5204974B2 (ja) | 2003-10-23 | 2013-06-05 | 富士フイルム株式会社 | インクジェット用インクならびにインクセット |
US7192474B2 (en) | 2004-06-22 | 2007-03-20 | Pitney Bowes Inc. | IR absorbing photosensitive optically variable ink compositions and process |
JP2006298777A (ja) | 2005-04-15 | 2006-11-02 | National Institute Of Advanced Industrial & Technology | 蛍光希土類金属錯体及びその製造方法 |
JP2009084267A (ja) | 2007-08-16 | 2009-04-23 | Ishihara Sangyo Kaisha Ltd | 希土類錯体およびこれを用いた発光材料 |
-
2007
- 2007-06-28 US US11/823,734 patent/US9834660B2/en active Active
-
2008
- 2008-06-27 WO PCT/US2008/008052 patent/WO2009005733A2/en active Application Filing
- 2008-06-27 TW TW097124472A patent/TW200916464A/zh unknown
- 2008-06-27 CN CN200880022352.XA patent/CN101688113B/zh not_active Expired - Fee Related
- 2008-06-27 KR KR1020107001589A patent/KR101494613B1/ko active IP Right Grant
- 2008-06-27 EP EP08779844.3A patent/EP2160448B1/en not_active Not-in-force
- 2008-06-27 ES ES08779844T patent/ES2717139T3/es active Active
- 2008-06-27 JP JP2010514833A patent/JP5599308B2/ja not_active Expired - Fee Related