JP2010509491A5 - - Google Patents
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- Publication number
- JP2010509491A5 JP2010509491A5 JP2009537318A JP2009537318A JP2010509491A5 JP 2010509491 A5 JP2010509491 A5 JP 2010509491A5 JP 2009537318 A JP2009537318 A JP 2009537318A JP 2009537318 A JP2009537318 A JP 2009537318A JP 2010509491 A5 JP2010509491 A5 JP 2010509491A5
- Authority
- JP
- Japan
- Prior art keywords
- film
- chitosan
- pvoh
- bisulfite
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 13
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004971 Cross linker Substances 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 239000004014 plasticizer Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004606 Fillers/Extenders Substances 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 229920001661 Chitosan Polymers 0.000 claims 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 7
- 229910052783 alkali metal Inorganic materials 0.000 claims 7
- 150000001340 alkali metals Chemical class 0.000 claims 7
- 150000003863 ammonium salts Chemical class 0.000 claims 7
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims 7
- 238000000034 method Methods 0.000 claims 5
- 239000000243 solution Substances 0.000 claims 4
- 230000021736 acetylation Effects 0.000 claims 3
- 238000006640 acetylation reaction Methods 0.000 claims 3
- 230000007062 hydrolysis Effects 0.000 claims 3
- 238000006460 hydrolysis reaction Methods 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000002002 slurry Substances 0.000 claims 2
- 238000005266 casting Methods 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003381 solubilizing effect Effects 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 229920003169 water-soluble polymer Polymers 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/559,262 US20080110370A1 (en) | 2006-11-13 | 2006-11-13 | Water-soluble film |
| US11/559,262 | 2006-11-13 | ||
| US88583807P | 2007-01-19 | 2007-01-19 | |
| US60/885,838 | 2007-01-19 | ||
| US11/733,595 | 2007-04-10 | ||
| US11/733,595 US20080176985A1 (en) | 2006-11-13 | 2007-04-10 | Water-soluble film |
| PCT/US2007/084566 WO2008064014A2 (en) | 2006-11-13 | 2007-11-13 | Water-soluble film |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014137515A Division JP2014177654A (ja) | 2006-11-13 | 2014-07-03 | 水溶性フィルム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010509491A JP2010509491A (ja) | 2010-03-25 |
| JP2010509491A5 true JP2010509491A5 (https=) | 2010-12-24 |
| JP5620105B2 JP5620105B2 (ja) | 2014-11-05 |
Family
ID=39273096
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009537318A Expired - Fee Related JP5620105B2 (ja) | 2006-11-13 | 2007-11-13 | 水溶性フィルム |
| JP2014137515A Abandoned JP2014177654A (ja) | 2006-11-13 | 2014-07-03 | 水溶性フィルム |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014137515A Abandoned JP2014177654A (ja) | 2006-11-13 | 2014-07-03 | 水溶性フィルム |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20080176985A1 (https=) |
| EP (1) | EP2087028B1 (https=) |
| JP (2) | JP5620105B2 (https=) |
| CA (1) | CA2669397C (https=) |
| PL (1) | PL2087028T3 (https=) |
| WO (1) | WO2008064014A2 (https=) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2238174A1 (en) * | 2008-01-31 | 2010-10-13 | The Procter & Gamble Company | Acetylation of chitosan |
| MX345025B (es) | 2010-07-02 | 2017-01-12 | Procter & Gamble | Producto detergente. |
| CN103025930B (zh) | 2010-07-02 | 2014-11-12 | 宝洁公司 | 递送活性剂的方法 |
| US20180163325A1 (en) | 2016-12-09 | 2018-06-14 | Robert Wayne Glenn, Jr. | Dissolvable fibrous web structure article comprising active agents |
| BR112013000101A2 (pt) | 2010-07-02 | 2016-05-17 | Procter & Gamble | filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos |
| CN102971126B (zh) | 2010-07-02 | 2016-03-23 | 宝洁公司 | 由非织造纤维网制备膜的方法 |
| US10087401B2 (en) | 2012-03-16 | 2018-10-02 | Monosol, Llc | Water soluble compositions incorporating enzymes, and method of making same |
| US9394092B2 (en) | 2012-04-16 | 2016-07-19 | Monosol, Llc | Powdered pouch and method of making same |
| US10829621B2 (en) | 2013-01-11 | 2020-11-10 | Monosol, Llc | Edible water-soluble film |
| US10144837B2 (en) | 2014-05-06 | 2018-12-04 | Basf Coatings Gmbh | Method for delivering aluminum into waterborne tint base or paint and refinish mixer system |
| JP5781676B1 (ja) * | 2014-09-12 | 2015-09-24 | 株式会社アイセロ | 水溶性フィルム、包装袋、内容物放出体、及び水溶性フィルムの製造方法 |
| TWI689547B (zh) | 2014-10-13 | 2020-04-01 | 美商摩諾索公司 | 具有塑化劑摻合物的水溶性聚乙烯醇膜、相關方法及相關物品 |
| RU2712693C2 (ru) | 2014-10-13 | 2020-01-30 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка из поливинилспиртовой смеси, родственные способы и родственные изделия |
| BR112017006796A2 (pt) | 2014-10-13 | 2017-12-26 | Procter & Gamble | artigos compreendendo filme de mistura de álcool polivinílico solúvel em água e métodos relacionados |
| MX2017004922A (es) | 2014-10-13 | 2017-06-22 | Procter & Gamble | Articulos que comprenden pelicula de alcohol polivinilico soluble en agua con mezcla de plastificante y metodos relacionados. |
| TWI677525B (zh) | 2014-10-13 | 2019-11-21 | 美商摩諾索公司 | 水溶性聚乙烯醇摻合物膜、相關方法及相關物品 |
| CN104744716B (zh) * | 2015-04-03 | 2018-03-09 | 广州康华微创生物科技有限公司 | 一种壳聚糖与改性聚乙烯醇复合膜的制备方法 |
| DE102015213943A1 (de) * | 2015-07-23 | 2017-01-26 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel umfassend wenigstens zwei Phasen |
| CN113845675A (zh) * | 2015-09-11 | 2021-12-28 | 三菱化学株式会社 | 水溶性薄膜及药剂包装体 |
| JPWO2017043514A1 (ja) * | 2015-09-11 | 2018-06-21 | 日本合成化学工業株式会社 | フィルムロール及び薬剤包装体 |
| WO2017043505A1 (ja) * | 2015-09-11 | 2017-03-16 | 日本合成化学工業株式会社 | 水溶性フィルム及び薬剤包装体 |
| WO2017043509A1 (ja) | 2015-09-11 | 2017-03-16 | 日本合成化学工業株式会社 | 水溶性フィルム、薬剤包装体及び水溶性フィルムの製造方法 |
| WO2017043506A1 (ja) * | 2015-09-11 | 2017-03-16 | 日本合成化学工業株式会社 | 水溶性フィルム及び薬剤包装体 |
| JP6888256B2 (ja) * | 2015-11-12 | 2021-06-16 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
| JP6888257B2 (ja) * | 2015-12-22 | 2021-06-16 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
| FR3049605B1 (fr) * | 2016-04-05 | 2018-03-23 | Arkema France | Procede d'obtention de films fins et articles filmogenes |
| RU2760028C2 (ru) | 2016-04-13 | 2021-11-22 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка, пакеты из пленки и способы их получения и применения |
| DE102016004463B4 (de) | 2016-04-15 | 2018-03-08 | Martin-Luther-Universität Halle-Wittenberg | Verpackung von Milch in auflösbaren Portionskapseln und Verfahren zu deren Herstellung durch Kristallisation |
| DE102016004464A1 (de) | 2016-04-15 | 2017-10-19 | Martin-Luther-Universität Halle-Wittenberg | Verpackung von Milch in auflösbaren Portionskapseln und Verfahren zu deren Herstellung duch lonen-Hydrokolloid-lnteraktionen |
| WO2017218414A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble |
| US10479965B2 (en) | 2016-06-13 | 2019-11-19 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| HUE068143T2 (hu) | 2016-06-13 | 2024-12-28 | Procter & Gamble | Különbözõ filmek kombinációjából készült, vízoldható, háztartási tisztítókészítményeket tartalmazó egyadagos termékek |
| WO2017218408A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| CN109311574A (zh) | 2016-06-13 | 2019-02-05 | 蒙诺苏尔有限公司 | 水溶性小包装 |
| WO2017218443A1 (en) | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| MX380853B (es) | 2017-01-27 | 2025-03-12 | Procter & Gamble | Composiciones en la forma de estructuras solidas solubles |
| JP6882519B2 (ja) | 2017-01-27 | 2021-06-02 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 発泡性凝集粒子を含む溶解性固形構造体形態の組成物 |
| WO2018213003A1 (en) | 2017-05-16 | 2018-11-22 | The Procter & Gamble Company | Conditioning hair care compositions in the form of dissolvable solid structures |
| US11053466B2 (en) | 2018-01-26 | 2021-07-06 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| US20190233785A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| CN111556891B (zh) | 2018-01-26 | 2021-11-05 | 宝洁公司 | 包含酶的水溶性单位剂量制品 |
| US11142730B2 (en) | 2018-01-26 | 2021-10-12 | The Procter & Gamble Company | Water-soluble articles and related processes |
| WO2019168829A1 (en) | 2018-02-27 | 2019-09-06 | The Procter & Gamble Company | A consumer product comprising a flat package containing unit dose articles |
| CN112334522B (zh) | 2018-05-02 | 2023-09-08 | 蒙诺苏尔有限公司 | 水溶性聚乙烯醇掺合物膜、相关方法和相关制品 |
| US10982176B2 (en) | 2018-07-27 | 2021-04-20 | The Procter & Gamble Company | Process of laundering fabrics using a water-soluble unit dose article |
| US11666514B2 (en) | 2018-09-21 | 2023-06-06 | The Procter & Gamble Company | Fibrous structures containing polymer matrix particles with perfume ingredients |
| US12234431B2 (en) | 2018-10-03 | 2025-02-25 | The Procter & Gamble Company | Water-soluble unit dose articles comprising water-soluble fibrous structures and particles |
| WO2020159860A1 (en) | 2019-01-28 | 2020-08-06 | The Procter & Gamble Company | Recycleable, renewable, or biodegradable package |
| JP7513623B2 (ja) | 2019-03-19 | 2024-07-09 | ザ プロクター アンド ギャンブル カンパニー | 布地上の悪臭を低減する方法 |
| EP3712237A1 (en) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
| CN114206307B (zh) | 2019-06-28 | 2024-08-23 | 宝洁公司 | 包含阴离子表面活性剂的可溶性固体纤维制品 |
| CN110790885B (zh) * | 2019-08-30 | 2022-05-03 | 武汉理工大学 | 一种聚乙烯醇/壳聚糖季铵盐抗菌自愈水凝胶及其制备方法和应用 |
| PY2134250A (es) | 2020-05-01 | 2022-01-28 | Pivot Bio Inc | Formulaciones líquidas estables para microorganismos fijadores de nitrógeno |
| MX2023001042A (es) | 2020-07-31 | 2023-02-16 | Procter & Gamble | Bolsa fibrosa soluble en agua que contiene granulos para el cuidado del cabello. |
| JP7605842B2 (ja) | 2020-08-19 | 2024-12-24 | ザ プロクター アンド ギャンブル カンパニー | 直接添加マイクロカプセルを含有する可撓性多孔質溶解性固体シート物品及びそれを作製するための方法 |
| JP2023545473A (ja) * | 2020-11-17 | 2023-10-30 | ザ プロクター アンド ギャンブル カンパニー | 自動食器洗浄組成物 |
| WO2023034763A1 (en) | 2021-08-30 | 2023-03-09 | The Procter & Gamble Company | Dissolvable solid structure comprising first and second polymeric structurants |
| WO2023072457A1 (en) * | 2021-10-25 | 2023-05-04 | Unilever Ip Holdings B.V. | Films and capsules |
| MX2024005474A (es) | 2021-12-17 | 2024-05-22 | Procter & Gamble | Articulos de champu fibroso solido disoluble que contienen sales. |
| UY40141A (es) | 2022-02-09 | 2023-08-15 | Pivot Bio Inc | Microbio fijador de nitrógeno formulado en seco y envasado en una película soluble en agua para una |
| MX2024010903A (es) | 2022-03-10 | 2024-09-17 | Procter & Gamble | Estructura solida disoluble que tiene primera y segunda capas. |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3692725A (en) * | 1970-10-28 | 1972-09-19 | Kimberly Clark Co | Stabilized binder for water-flushable non-woven webs |
| US4801636A (en) * | 1987-03-24 | 1989-01-31 | The Clorox Company | Rinse soluble polymer film composition for wash additives |
| JP2662901B2 (ja) | 1990-12-19 | 1997-10-15 | 大日精化工業株式会社 | 風合い改良剤組成物 |
| JP3195817B2 (ja) | 1992-01-17 | 2001-08-06 | 株式会社クラレ | 耐水性組成物 |
| KR0159976B1 (ko) | 1994-06-21 | 1999-01-15 | 전동원 | 생분해성 키토산/셀룰로즈 복합체 필름의 제조방법 |
| JP3609898B2 (ja) * | 1996-06-03 | 2005-01-12 | 株式会社クラレ | 薬剤包装用水溶性フィルム |
| DE19636510A1 (de) * | 1996-09-09 | 1998-03-12 | Clariant Gmbh | Polyvinylalkohol-Kompositionen |
| CA2304526A1 (en) | 1998-07-29 | 2000-02-10 | Benckiser N.V. | Composition for use in a washing machine |
| CA2338710C (en) * | 1998-07-29 | 2009-10-27 | Guido Waeschenbach | A tablet comprising a basic composition and particle comprising core and envelope |
| DK1129163T3 (da) * | 1998-11-13 | 2011-03-21 | Danisco Us Inc | Granulat med lav massefylde i fluidiseret lag |
| GB2365018A (en) | 2000-07-24 | 2002-02-13 | Procter & Gamble | Water soluble pouches |
| ATE528386T1 (de) * | 2001-05-14 | 2011-10-15 | Procter & Gamble | Reinigungsmittel |
| GB0114850D0 (en) | 2001-06-18 | 2001-08-08 | Unilever Plc | Water soluble package and liquid contents thereof |
| GB0114847D0 (en) | 2001-06-18 | 2001-08-08 | Unilever Plc | Water soluble package and liquid contents thereof |
| JP3917435B2 (ja) * | 2002-02-12 | 2007-05-23 | 大日精化工業株式会社 | 水性溶液組成物 |
| CA2435735C (en) | 2002-07-31 | 2008-10-14 | Rohm And Haas Company | Triggered response compositions |
| GB0222964D0 (en) * | 2002-10-03 | 2002-11-13 | Unilever Plc | Polymeric film for water soluble package |
| JP4056859B2 (ja) * | 2002-11-11 | 2008-03-05 | 日本合成化学工業株式会社 | 水溶性フィルム |
| ES2299682T3 (es) * | 2003-05-23 | 2008-06-01 | THE PROCTER & GAMBLE COMPANY | Composicion limpiadora para usar en una lavadora o un lavavajillas. |
| JP4630396B2 (ja) * | 2003-12-16 | 2011-02-09 | 日本合成化学工業株式会社 | 水溶性フィルム |
| RU2006129938A (ru) * | 2004-01-19 | 2008-02-27 | Найджел ХЭМИЛТОН (GB) | Способ и система для записи поисковых путей через один или несколько поисковых механизмов в сети связи |
| JP4222280B2 (ja) | 2004-09-16 | 2009-02-12 | ヤマハ株式会社 | 演奏情報出力装置及び楽器及び演奏情報を出力するための方法及び該方法をコンピュータで実行するためのプログラム。 |
| US8728449B2 (en) | 2005-01-22 | 2014-05-20 | Monosol Llc | Water-soluble film article having salt layer, and method of making the same |
| ATE481444T1 (de) | 2005-05-13 | 2010-10-15 | Procter & Gamble | Funktionalisierte folien |
| WO2008063468A2 (en) | 2006-11-13 | 2008-05-29 | The Procter & Gamble Company | Water-soluble detergent pouch |
-
2007
- 2007-04-10 US US11/733,595 patent/US20080176985A1/en not_active Abandoned
- 2007-11-13 EP EP07854627.2A patent/EP2087028B1/en active Active
- 2007-11-13 WO PCT/US2007/084566 patent/WO2008064014A2/en not_active Ceased
- 2007-11-13 PL PL07854627T patent/PL2087028T3/pl unknown
- 2007-11-13 US US12/513,024 patent/US8268914B2/en active Active
- 2007-11-13 CA CA2669397A patent/CA2669397C/en not_active Expired - Fee Related
- 2007-11-13 JP JP2009537318A patent/JP5620105B2/ja not_active Expired - Fee Related
-
2014
- 2014-07-03 JP JP2014137515A patent/JP2014177654A/ja not_active Abandoned
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