JP5620105B2 - 水溶性フィルム - Google Patents
水溶性フィルム Download PDFInfo
- Publication number
- JP5620105B2 JP5620105B2 JP2009537318A JP2009537318A JP5620105B2 JP 5620105 B2 JP5620105 B2 JP 5620105B2 JP 2009537318 A JP2009537318 A JP 2009537318A JP 2009537318 A JP2009537318 A JP 2009537318A JP 5620105 B2 JP5620105 B2 JP 5620105B2
- Authority
- JP
- Japan
- Prior art keywords
- film
- pvoh
- chitosan
- bisulfite
- metabisulfite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 60
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 60
- 229920001661 Chitosan Polymers 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 30
- 229910052783 alkali metal Inorganic materials 0.000 claims description 29
- 150000001340 alkali metals Chemical class 0.000 claims description 26
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 25
- 150000003863 ammonium salts Chemical class 0.000 claims description 25
- 238000004140 cleaning Methods 0.000 claims description 25
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 claims description 25
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- 238000006640 acetylation reaction Methods 0.000 claims description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
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- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
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- 230000007062 hydrolysis Effects 0.000 claims description 8
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
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- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
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- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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| EP2238174A1 (en) * | 2008-01-31 | 2010-10-13 | The Procter & Gamble Company | Acetylation of chitosan |
| MX345025B (es) | 2010-07-02 | 2017-01-12 | Procter & Gamble | Producto detergente. |
| CN103025930B (zh) | 2010-07-02 | 2014-11-12 | 宝洁公司 | 递送活性剂的方法 |
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- 2007-11-13 EP EP07854627.2A patent/EP2087028B1/en active Active
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| EP2087028A2 (en) | 2009-08-12 |
| JP2014177654A (ja) | 2014-09-25 |
| US8268914B2 (en) | 2012-09-18 |
| US20100105821A1 (en) | 2010-04-29 |
| CA2669397C (en) | 2013-03-19 |
| PL2087028T3 (pl) | 2015-04-30 |
| WO2008064014A3 (en) | 2008-07-10 |
| US20080176985A1 (en) | 2008-07-24 |
| HK1132755A1 (en) | 2010-03-05 |
| EP2087028B1 (en) | 2014-10-29 |
| CA2669397A1 (en) | 2008-05-29 |
| WO2008064014A2 (en) | 2008-05-29 |
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