JP2010227767A - ハニカムフィルタ - Google Patents
ハニカムフィルタ Download PDFInfo
- Publication number
- JP2010227767A JP2010227767A JP2009076130A JP2009076130A JP2010227767A JP 2010227767 A JP2010227767 A JP 2010227767A JP 2009076130 A JP2009076130 A JP 2009076130A JP 2009076130 A JP2009076130 A JP 2009076130A JP 2010227767 A JP2010227767 A JP 2010227767A
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- honeycomb filter
- partition wall
- plugged
- honeycomb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 65
- 239000010457 zeolite Substances 0.000 claims abstract description 65
- 238000005192 partition Methods 0.000 claims abstract description 60
- 239000012530 fluid Substances 0.000 claims abstract description 6
- 239000002344 surface layer Substances 0.000 claims abstract description 3
- 241000264877 Hippospongia communis Species 0.000 claims description 99
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 21
- 239000011148 porous material Substances 0.000 claims description 20
- 239000012528 membrane Substances 0.000 claims description 19
- 229910052878 cordierite Inorganic materials 0.000 claims description 15
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- 229910000505 Al2TiO5 Inorganic materials 0.000 claims description 9
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 claims description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052703 rhodium Inorganic materials 0.000 claims description 4
- 239000010948 rhodium Substances 0.000 claims description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 3
- 238000000638 solvent extraction Methods 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000009467 reduction Effects 0.000 abstract description 13
- 239000002245 particle Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 description 27
- 239000010410 layer Substances 0.000 description 23
- 239000007789 gas Substances 0.000 description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
- 239000002002 slurry Substances 0.000 description 16
- 239000002994 raw material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 238000006722 reduction reaction Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 8
- 229910010271 silicon carbide Inorganic materials 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004071 soot Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- 239000004927 clay Substances 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000013618 particulate matter Substances 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- 230000001603 reducing effect Effects 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000002276 dielectric drying Methods 0.000 description 2
- -1 foamed resin Chemical class 0.000 description 2
- 238000007602 hot air drying Methods 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910003465 moissanite Inorganic materials 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101001126084 Homo sapiens Piwi-like protein 2 Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 102100029365 Piwi-like protein 2 Human genes 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GYMWQLRSSDFGEQ-ADRAWKNSSA-N [(3e,8r,9s,10r,13s,14s,17r)-13-ethyl-17-ethynyl-3-hydroxyimino-1,2,6,7,8,9,10,11,12,14,15,16-dodecahydrocyclopenta[a]phenanthren-17-yl] acetate;(8r,9s,13s,14s,17r)-17-ethynyl-13-methyl-7,8,9,11,12,14,15,16-octahydro-6h-cyclopenta[a]phenanthrene-3,17-diol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.O/N=C/1CC[C@@H]2[C@H]3CC[C@](CC)([C@](CC4)(OC(C)=O)C#C)[C@@H]4[C@@H]3CCC2=C\1 GYMWQLRSSDFGEQ-ADRAWKNSSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000023402 cell communication Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000009777 vacuum freeze-drying Methods 0.000 description 1
Images
Classifications
-
- B01J35/56—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/9454—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
- C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
- C04B35/478—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on aluminium titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62218—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic films, e.g. by using temporary supports
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
- C04B38/0009—Honeycomb structures characterised by features relating to the cell walls, e.g. wall thickness or distribution of pores in the walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20753—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9205—Porosity
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Abstract
【解決手段】流体の流路となる複数のセルを区画形成する多孔質の隔壁を備え、一方の端部が開口され且つ他方の端部が目封止された所定のセルと、前記一方の端部が目封止され且つ前記他方の端部が開口された残余のセルとが交互に配設されたハニカムフィルタであって、ゼオライトを主成分とする膜が、前記所定のセル側隔壁表層にコートされたハニカムフィルタである。
【選択図】図2
Description
4NH3+4NO+O2→4N2+6H2O (1)
2NH3+NO+NO2→2N2+3H2O (2)
8NH3+6NO2→7N2+12H2O (3)
図1は、本発明に係るハニカムフィルタの一実施形態を模式的に示す図であり、ハニカムフィルタの正面図である。図2は、本発明に係るハニカムフィルタの一実施形態を模式的に示す図であり、ハニカムフィルタの断面図である。図3は、図2におけるQ部分を拡大して示すとともに他を排して表した本発明に係るハニカムフィルタの部分断面図である。
ゼオライトを主成分とする膜(コート層)12のゼオライトの種類としては、ZSM−5、βゼオライト、モルデナイト、フェリエライト、A型、X型、Y型ゼオライトを例示することができる。ZSM−5またはβゼオライトを含むものが好ましい。
ハニカムフィルタ1を得るために、予め、ハニカム構造体を、焼成体として作製する。ハニカム構造体は、コート層12を設ける前に、セル3の端部を目封止部10によって目封止し、目封止ハニカム構造体として作製しておくことが好ましい。ハニカム構造体(目封止ハニカム構造体)を得るための手段は限定されない。ハニカム構造体は、例えば、以下の方法によって作製することが出来る。
(目封止ハニカムフィルタの作製)
コージェライト化原料として、アルミナ、水酸化アルミニウム、カオリン、タルク、及びシリカを使用し、コージェライト化原料100質量部に、造孔材を13質量部、分散媒を35質量部、有機バインダを6質量部、分散剤を0.5質量部、それぞれ添加し、混合、混練して坏土を調製した。分散媒として水を使用し、造孔材としては平均粒子径10μmのコークスを使用し、有機バインダとしてはヒドロキシプロピルメチルセルロースを使用し、分散剤としてはエチレングリコールを使用した。
気孔率45%と65%のコーディエライト製ハニカム構造体を用意した。ZSM−5(SiO2/Al2O3=36)のゼオライトを56%、コロイダルシリカ4%、酢酸銅(Cu(CH3COO)2)3%、水37%のスラリーを作製し、吸引方式にてスラリーをハニカム構造体に塗布した。ゼオライト含有スラリー塗布後、90℃で2時間乾燥させた後、電気路に入れ、昇温速度200℃/時間、650℃で4時間乾燥させ、その後400℃/hで室温まで戻した。
スート付圧損について評価した結果を図5に示す。スート付け前(初期)圧力損失は、何もコートをしていないもの(Bare)に比べ、やや高いものの、スス堆積時の圧力損失は小さい結果となった(図5参照)。Bareでは隔壁(リブ)内部までススが入り込んでいたが、ゼオライトコートをした場合、リブの表面のみにススが堆積していることから、スートがリブ内部に入りにくい構造になっており、そのために圧力損失がBareに比べて小さくなったものと推定している。
次にハニカム構造体(母材)のセル構造を変え、ガス流入側のセルの開口面積を、ガス流出側の開口面積より広くするセル構造をもつハニカム構造体を作製し、ゼオライト層をコートした。結果を表1に示す。表1のなかにA:Bと表記してあるが、Aは、DPFのガス流入側端面において封じられている流通孔1個当たりの、流通孔の長手方向に対する垂直断面における平均面積を表す。また、BはDPFの流出端面において封じされている流通孔1個当たりの前記垂直断面における平均面積を表している。実施例1では、A:Bが1:1であるが、A:Bの比においてBを大きくすること(すなわち、入口側セルの開口面積を出口側セルの開口面積より大きくすること)により、Light off temperatureをより低くできることがわかった。
ゼオライトコート層の厚さを変えて評価を実施した。結果を表1に示す。隔壁リブ厚300μmに対し、コート層の厚さを0.5%(1.5μm)から200%相当(600μm)にした。実施例5においては、コート層が薄いために、実施例1よりLight off temperatureが高いものの、実施例5〜8全てで比較例1より低い結果であり、ゼオライトコートの効果を確認した。
次に、SiO2/Al2O3比を変えて、同様な試験を実施した。結果を表2に示す。この結果、Light off TemperatureはSiO2/Al2O3比を上げるにつれて、Light off temperatureが低くなる傾向があったが、比較例1よりはLight off temperatureが低い結果となった。
ゼオライトの種類をZSM−5からβゼオライトに変更した。結果を表2に示す。Light off temperatureは比較例1より低く、NOX還元に有効であることがわかった。
添加金属種の変更を実施した。結果を表2に示す。ゼオライト中に鉄、ニッケル、鉄と銅を添加した。鉄については、ゼオライトZSM−5を56%、コロイダルシリカを4%、錯体[Fe(CO)4]2−3%、水37%からなる水溶液を作製し、これを母材に塗布して作製した。また、ニッケルについては、鉄と同様に錯体イオンを用いてスラリーを作製し、母材に塗布した。さらに、鉄と銅を1.5%ずつ含むスラリーを酢酸銅及び鉄の錯体イオンを利用して作製し、これを母材に塗布した。結果、Light off temperatureは3元触媒を用いた比較例1より低く、NOX還元に有効であることがわかった。
次に母材の隔壁の細孔特性を変えた。また、母材の隔壁の細孔がPMにより埋まらないようにするために、コート層のメディアン径は母材の隔壁のメディアン径より小さくなるようにした。結果を表2に示す。NOXの還元性を評価したところ、比較例1よりLight off temperatureが低く、NOX還元に有効であることがわかった。また、実施例16及び17のように母材の隔壁の気孔率を60%以下とした場合、熱処理によるクラックは発生しなかった。このことから、母材の隔壁の気孔率としては、60%以下が好ましいことがわかった。
母材をSiCおよびAT材に変えた。結果を表2に示す。母材が異なるため、単純にCdと比較できないが、Light off temperatureが低く、NOX還元に有効であることがわかった。
Claims (9)
- 流体の流路となる複数のセルを区画形成する多孔質の隔壁を備え、一方の端部が開口され且つ他方の端部が目封止された所定のセルと、前記一方の端部が目封止され且つ前記他方の端部が開口された残余のセルとが交互に配設されたハニカムフィルタであって、
ゼオライトを主成分とする膜が、前記所定のセル側隔壁表層にコートされたハニカムフィルタ。 - 前記隔壁がコーディエライト(Cd)、SiC、およびチタン酸アルミニウム(AT)から成る群の少なくともいずれか一種を含む請求項1に記載のハニカムフィルタ。
- 前記隔壁は、メジアン径が3μm以上60μm以下、気孔率が30%以上60%以下である請求項1または2に記載のハニカムフィルタ。
- 前記隔壁の流入端面において目封止されている流通孔1個当たりの、流通孔の長手方向に対する垂直断面における平均面積が流出端面において目封止されている流通孔1個あたりの、前記垂直断面積における平均面積以下である請求項1〜3のいずれか一項に記載のハニカムフィルタ。
- 前記ゼオライトを主成分とする膜のメジアン径が0.02μm以上60μm以下、気孔率が30%以上60%以下であり、かつ、前記隔壁の平均細孔径が前記ゼオライトを主成分とする膜のメジアン径よりも大きい請求項1〜4のいずれか一項に記載のハニカムフィルタ。
- 前記ゼオライトを主成分とする膜の厚さが前記隔壁の厚さの0.5%以上200%以下である請求項1〜5のいずれか一項に記載のハニカムフィルタ。
- 前記ゼオライトを主成分とする膜を構成するゼオライトがZSM−5、βゼオライト、モルデナイト、フェリエライト、A型ゼオライト、X型ゼオライト、およびY型ゼオライトからなる群の少なくともいずれか一種を含む請求項1〜6のいずれか一項に記載のハニカムフィルタ。
- 前記ゼオライトを主成分とする膜を構成するゼオライトのSiO2/Al2O3比が1以上500以下である請求項1〜7のいずれか一項に記載のハニカムフィルタ。
- 前記ゼオライトを主成分とする膜がチタン、バナジウム、クロム、マンガン、鉄、コバルト、ニッケル、銅、ロジウム、パラジウム、銀、および白金からなる群の少なくともいずれか一種を含む請求項1〜8のいずれか一項に記載のハニカムフィルタ。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009076130A JP2010227767A (ja) | 2009-03-26 | 2009-03-26 | ハニカムフィルタ |
US12/713,227 US20100242424A1 (en) | 2009-03-26 | 2010-02-26 | Honeycomb filter |
DE102010009449.8A DE102010009449B4 (de) | 2009-03-26 | 2010-02-26 | Wabenfilter |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009076130A JP2010227767A (ja) | 2009-03-26 | 2009-03-26 | ハニカムフィルタ |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2010227767A true JP2010227767A (ja) | 2010-10-14 |
Family
ID=42664246
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009076130A Pending JP2010227767A (ja) | 2009-03-26 | 2009-03-26 | ハニカムフィルタ |
Country Status (3)
Country | Link |
---|---|
US (1) | US20100242424A1 (ja) |
JP (1) | JP2010227767A (ja) |
DE (1) | DE102010009449B4 (ja) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0654477A (ja) * | 1992-07-28 | 1994-02-25 | Sanyo Electric Co Ltd | モータの軸受装置 |
JP2012086197A (ja) * | 2010-10-22 | 2012-05-10 | Tosoh Corp | 高耐熱水性scr触媒及びその製造方法 |
WO2013027570A1 (ja) * | 2011-08-19 | 2013-02-28 | 住友化学株式会社 | ハニカム構造体の製造方法 |
WO2014014059A1 (ja) * | 2012-07-20 | 2014-01-23 | 住友化学株式会社 | ハニカムフィルタ |
JP2014018768A (ja) * | 2012-07-20 | 2014-02-03 | Sumitomo Chemical Co Ltd | 排ガス浄化システム |
WO2014104179A1 (ja) | 2012-12-27 | 2014-07-03 | 住友化学株式会社 | ハニカムフィルタ及びその製造方法、並びに、チタン酸アルミニウム系セラミックス及びその製造方法 |
WO2014156294A1 (ja) * | 2013-03-29 | 2014-10-02 | 日本碍子株式会社 | 構造体 |
JP2014196523A (ja) * | 2013-03-29 | 2014-10-16 | 日本碍子株式会社 | 金属含有膜の製造方法 |
JP2015509824A (ja) * | 2012-03-14 | 2015-04-02 | 日本碍子株式会社 | 膜分離用前処理装置、膜分離システム及び膜分離方法 |
JP2015112559A (ja) * | 2013-12-12 | 2015-06-22 | 株式会社キャタラー | パティキュレートフィルタ |
JPWO2013136869A1 (ja) * | 2012-03-16 | 2015-08-03 | 日本碍子株式会社 | 分離膜の製造方法、分離膜複合体の製造方法、及び分離膜複合体 |
WO2016088796A1 (ja) * | 2014-12-02 | 2016-06-09 | 住友化学株式会社 | ハニカムフィルタ |
JP2017170396A (ja) * | 2016-03-25 | 2017-09-28 | 日本碍子株式会社 | ハニカム構造体 |
JP2017171553A (ja) * | 2016-03-25 | 2017-09-28 | 日本碍子株式会社 | ハニカム構造体 |
JP2019516541A (ja) * | 2016-04-01 | 2019-06-20 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 排気ガス浄化用フィルター |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015520675A (ja) | 2012-06-01 | 2015-07-23 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Publiclimited Company | バナジン酸塩を含む選択的触媒還元ウォールフロー型フィルター |
US9347357B2 (en) * | 2012-09-27 | 2016-05-24 | Ngk Insulators, Ltd. | Honeycomb catalyst body |
JP6140509B2 (ja) | 2013-04-04 | 2017-05-31 | 日本碍子株式会社 | ウォールフロー型排ガス浄化フィルタ |
JP6581934B2 (ja) * | 2016-03-24 | 2019-09-25 | 日本碍子株式会社 | ハニカムフィルタ |
WO2018037637A1 (ja) * | 2016-08-26 | 2018-03-01 | エヌ・イーケムキャット株式会社 | ハニカム構造体、ハニカム構造型触媒および製造方法 |
JP6567035B2 (ja) * | 2017-12-28 | 2019-08-28 | 本田技研工業株式会社 | 排気浄化フィルタ |
DE102019100097B4 (de) * | 2019-01-04 | 2021-12-16 | Umicore Ag & Co. Kg | Verfahren zur Herstellung von katalytisch aktiven Wandflussfiltern |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004000896A (ja) * | 2002-03-25 | 2004-01-08 | Ngk Insulators Ltd | ハニカムフィルター |
JP2007501353A (ja) * | 2003-08-05 | 2007-01-25 | エンゲルハード・コーポレーシヨン | Scr濾過器を用いた排気処理システムおよび方法 |
JP2007285295A (ja) * | 2006-03-24 | 2007-11-01 | Ngk Insulators Ltd | 排気ガス浄化システム |
JP2007296514A (ja) * | 2006-04-07 | 2007-11-15 | Ngk Insulators Ltd | 触媒体とその製造方法 |
WO2008136232A1 (ja) * | 2007-04-27 | 2008-11-13 | Ngk Insulators, Ltd. | ハニカムフィルタ |
JP2008296218A (ja) * | 2002-03-29 | 2008-12-11 | Ngk Insulators Ltd | 多孔質ハニカム構造体の製造方法 |
JP2009011908A (ja) * | 2007-07-03 | 2009-01-22 | Tokyo Yogyo Co Ltd | ハニカム構造体 |
JP2009057922A (ja) * | 2007-08-31 | 2009-03-19 | Honda Motor Co Ltd | 排ガス浄化装置 |
JP2010519020A (ja) * | 2007-02-23 | 2010-06-03 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | アンモニア遮断効果を有する、触媒により活性化されたディーゼル粒子フィルター |
JP2010534290A (ja) * | 2007-07-19 | 2010-11-04 | コーニング インコーポレイテッド | セラミック・ハニカム構造体の再生方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH024896A (ja) | 1988-06-22 | 1990-01-09 | Nippon Oil & Fats Co Ltd | 耐荷重性潤滑油 |
US6606856B1 (en) * | 2000-03-03 | 2003-08-19 | The Lubrizol Corporation | Process for reducing pollutants from the exhaust of a diesel engine |
US6912847B2 (en) * | 2001-12-21 | 2005-07-05 | Engelhard Corporation | Diesel engine system comprising a soot filter and low temperature NOx trap |
JP2004000901A (ja) * | 2002-03-29 | 2004-01-08 | Ngk Insulators Ltd | 多孔質ハニカム構造体 |
CN100345611C (zh) * | 2002-09-13 | 2007-10-31 | 揖斐电株式会社 | 蜂窝状结构体 |
DE102004024519A1 (de) | 2004-05-18 | 2005-12-15 | Adam Opel Ag | Minimierung von PAK-Emissionen bei der Regeneration von Partikelfiltern |
JP5073303B2 (ja) | 2006-03-24 | 2012-11-14 | 日本碍子株式会社 | 触媒コンバータ及び触媒コンバータの製造方法 |
DE102006061685A1 (de) | 2006-12-28 | 2008-07-03 | Robert Bosch Gmbh | Filterelement und Filter zur Abgasnachbehandlung einer Brennkraftmaschine |
JP5076192B2 (ja) | 2007-01-12 | 2012-11-21 | 国立大学法人 岡山大学 | 未燃カーボンを用いてディーゼルエンジン排ガス中の窒素酸化物を浄化するための触媒と方法 |
US7501174B2 (en) * | 2007-03-01 | 2009-03-10 | Prs Mediterranean Ltd. | High performance geosynthetic article |
JP2012509764A (ja) * | 2008-11-26 | 2012-04-26 | コーニング インコーポレイテッド | 被覆された微粒子フィルタおよび方法 |
-
2009
- 2009-03-26 JP JP2009076130A patent/JP2010227767A/ja active Pending
-
2010
- 2010-02-26 US US12/713,227 patent/US20100242424A1/en not_active Abandoned
- 2010-02-26 DE DE102010009449.8A patent/DE102010009449B4/de active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004000896A (ja) * | 2002-03-25 | 2004-01-08 | Ngk Insulators Ltd | ハニカムフィルター |
JP2008296218A (ja) * | 2002-03-29 | 2008-12-11 | Ngk Insulators Ltd | 多孔質ハニカム構造体の製造方法 |
JP2007501353A (ja) * | 2003-08-05 | 2007-01-25 | エンゲルハード・コーポレーシヨン | Scr濾過器を用いた排気処理システムおよび方法 |
JP2007285295A (ja) * | 2006-03-24 | 2007-11-01 | Ngk Insulators Ltd | 排気ガス浄化システム |
JP2007296514A (ja) * | 2006-04-07 | 2007-11-15 | Ngk Insulators Ltd | 触媒体とその製造方法 |
JP2010519020A (ja) * | 2007-02-23 | 2010-06-03 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | アンモニア遮断効果を有する、触媒により活性化されたディーゼル粒子フィルター |
WO2008136232A1 (ja) * | 2007-04-27 | 2008-11-13 | Ngk Insulators, Ltd. | ハニカムフィルタ |
JP2009011908A (ja) * | 2007-07-03 | 2009-01-22 | Tokyo Yogyo Co Ltd | ハニカム構造体 |
JP2010534290A (ja) * | 2007-07-19 | 2010-11-04 | コーニング インコーポレイテッド | セラミック・ハニカム構造体の再生方法 |
JP2009057922A (ja) * | 2007-08-31 | 2009-03-19 | Honda Motor Co Ltd | 排ガス浄化装置 |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0654477A (ja) * | 1992-07-28 | 1994-02-25 | Sanyo Electric Co Ltd | モータの軸受装置 |
JP2012086197A (ja) * | 2010-10-22 | 2012-05-10 | Tosoh Corp | 高耐熱水性scr触媒及びその製造方法 |
WO2013027570A1 (ja) * | 2011-08-19 | 2013-02-28 | 住友化学株式会社 | ハニカム構造体の製造方法 |
JP2013039812A (ja) * | 2011-08-19 | 2013-02-28 | Sumitomo Chemical Co Ltd | ハニカム構造体の製造方法 |
JP2015509824A (ja) * | 2012-03-14 | 2015-04-02 | 日本碍子株式会社 | 膜分離用前処理装置、膜分離システム及び膜分離方法 |
JPWO2013136869A1 (ja) * | 2012-03-16 | 2015-08-03 | 日本碍子株式会社 | 分離膜の製造方法、分離膜複合体の製造方法、及び分離膜複合体 |
JP2014018768A (ja) * | 2012-07-20 | 2014-02-03 | Sumitomo Chemical Co Ltd | 排ガス浄化システム |
WO2014014059A1 (ja) * | 2012-07-20 | 2014-01-23 | 住友化学株式会社 | ハニカムフィルタ |
WO2014104179A1 (ja) | 2012-12-27 | 2014-07-03 | 住友化学株式会社 | ハニカムフィルタ及びその製造方法、並びに、チタン酸アルミニウム系セラミックス及びその製造方法 |
JP6041902B2 (ja) * | 2012-12-27 | 2016-12-14 | 住友化学株式会社 | ハニカムフィルタ及びその製造方法 |
WO2014156294A1 (ja) * | 2013-03-29 | 2014-10-02 | 日本碍子株式会社 | 構造体 |
JP2014196523A (ja) * | 2013-03-29 | 2014-10-16 | 日本碍子株式会社 | 金属含有膜の製造方法 |
JPWO2014156294A1 (ja) * | 2013-03-29 | 2017-02-16 | 日本碍子株式会社 | 構造体 |
US10328391B2 (en) | 2013-03-29 | 2019-06-25 | Ngk Insulators, Ltd. | Structural body |
JP2015112559A (ja) * | 2013-12-12 | 2015-06-22 | 株式会社キャタラー | パティキュレートフィルタ |
WO2016088796A1 (ja) * | 2014-12-02 | 2016-06-09 | 住友化学株式会社 | ハニカムフィルタ |
JP2017170396A (ja) * | 2016-03-25 | 2017-09-28 | 日本碍子株式会社 | ハニカム構造体 |
JP2017171553A (ja) * | 2016-03-25 | 2017-09-28 | 日本碍子株式会社 | ハニカム構造体 |
US10369545B2 (en) | 2016-03-25 | 2019-08-06 | Ngk Insulators, Ltd. | Honeycomb structure |
US10653998B2 (en) | 2016-03-25 | 2020-05-19 | Ngk Insulators, Ltd. | Honeycomb structure |
JP2019516541A (ja) * | 2016-04-01 | 2019-06-20 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 排気ガス浄化用フィルター |
Also Published As
Publication number | Publication date |
---|---|
DE102010009449A1 (de) | 2010-09-30 |
DE102010009449B4 (de) | 2023-06-22 |
US20100242424A1 (en) | 2010-09-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2010227767A (ja) | ハニカムフィルタ | |
JP6809942B2 (ja) | ハニカム構造体 | |
JP5726414B2 (ja) | 触媒担持フィルタ、及び排ガス浄化システム | |
JP6577895B2 (ja) | ハニカム構造体 | |
JP5919215B2 (ja) | ハニカム触媒体 | |
JP6023395B2 (ja) | 触媒担持フィルタ | |
JP5037809B2 (ja) | ハニカム構造体 | |
JP6092068B2 (ja) | 触媒担持型ハニカムフィルタ | |
EP2133148A1 (en) | Exhaust gas purification filter and method of producing the same | |
JP2013053589A (ja) | ウォールフロー型排ガス浄化フィルタ | |
JP2008296141A (ja) | ハニカムフィルタ | |
EP2108448A2 (en) | Honeycomb catalyst body | |
CN111749756B (zh) | 颗粒过滤器及装罐结构体 | |
CN111818984A (zh) | 蜂窝过滤器和蜂窝过滤器的制造方法 | |
JP4320702B2 (ja) | 排気ガス浄化装置 | |
US11819830B2 (en) | Porous ceramic structure and method of producing porous ceramic structure | |
US11731111B2 (en) | Porous ceramic structure and method of producing porous ceramic structure | |
JP4426381B2 (ja) | ハニカム構造体及びその製造方法 | |
JP5478308B2 (ja) | フィルタ及びその製造方法 | |
CN111148890B (zh) | 微粒过滤器上的scr催化涂层 | |
EP2221099A1 (en) | Honeycomb structure | |
CN111686753B (zh) | 多孔质陶瓷结构体 | |
CN110314706B (zh) | 催化剂负载用蜂窝结构体及其制造方法 | |
JP2016131918A (ja) | 排ガス浄化フィルタの製造方法、排ガス浄化フィルタ及び排ガス浄化装置 | |
JP2014184422A (ja) | 触媒コートフィルタ及び触媒コートフィルタ用担体 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20101119 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110216 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110222 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110411 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120321 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120507 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121127 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130117 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20131105 |