JP2007270374A - 撥水撥油性布帛およびその製造方法 - Google Patents
撥水撥油性布帛およびその製造方法 Download PDFInfo
- Publication number
- JP2007270374A JP2007270374A JP2006096610A JP2006096610A JP2007270374A JP 2007270374 A JP2007270374 A JP 2007270374A JP 2006096610 A JP2006096610 A JP 2006096610A JP 2006096610 A JP2006096610 A JP 2006096610A JP 2007270374 A JP2007270374 A JP 2007270374A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oil
- crosslinking agent
- repellent
- repellent fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 153
- 239000004744 fabric Substances 0.000 title claims abstract description 148
- 239000005871 repellent Substances 0.000 title claims abstract description 140
- 230000002940 repellent Effects 0.000 title claims abstract description 111
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 95
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 31
- 239000011737 fluorine Substances 0.000 claims abstract description 31
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012948 isocyanate Substances 0.000 claims abstract description 20
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 16
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 111
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 66
- 238000000034 method Methods 0.000 claims description 42
- 238000012360 testing method Methods 0.000 claims description 39
- 239000000835 fiber Substances 0.000 claims description 38
- 239000005056 polyisocyanate Substances 0.000 claims description 28
- 229920001228 polyisocyanate Polymers 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 26
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 17
- 230000000903 blocking effect Effects 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 11
- -1 aliphatic isocyanate compound Chemical class 0.000 claims description 10
- 239000007921 spray Substances 0.000 claims description 10
- 150000001718 carbodiimides Chemical class 0.000 claims description 9
- 125000003827 glycol group Chemical group 0.000 claims description 9
- 238000002835 absorbance Methods 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 238000004043 dyeing Methods 0.000 claims description 4
- 238000010998 test method Methods 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
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- 238000004949 mass spectrometry Methods 0.000 claims description 2
- 239000003657 drainage water Substances 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 description 17
- 238000012545 processing Methods 0.000 description 16
- 238000001514 detection method Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000000691 measurement method Methods 0.000 description 4
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 238000000589 high-performance liquid chromatography-mass spectrometry Methods 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- ZHZPKMZKYBQGKG-UHFFFAOYSA-N 6-methyl-2,4,6-tris(trifluoromethyl)oxane-2,4-diol Chemical compound FC(F)(F)C1(C)CC(O)(C(F)(F)F)CC(O)(C(F)(F)F)O1 ZHZPKMZKYBQGKG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 101710145505 Fiber protein Proteins 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 241001365789 Oenanthe crocata Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- UZUFPBIDKMEQEQ-UHFFFAOYSA-N perfluorononanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F UZUFPBIDKMEQEQ-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 238000004394 yellowing prevention Methods 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006096610A JP2007270374A (ja) | 2006-03-31 | 2006-03-31 | 撥水撥油性布帛およびその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006096610A JP2007270374A (ja) | 2006-03-31 | 2006-03-31 | 撥水撥油性布帛およびその製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011161111A Division JP2011214216A (ja) | 2011-07-22 | 2011-07-22 | 撥水撥油性布帛 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007270374A true JP2007270374A (ja) | 2007-10-18 |
| JP2007270374A5 JP2007270374A5 (enrdf_load_stackoverflow) | 2009-03-05 |
Family
ID=38673463
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006096610A Pending JP2007270374A (ja) | 2006-03-31 | 2006-03-31 | 撥水撥油性布帛およびその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2007270374A (enrdf_load_stackoverflow) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010196196A (ja) * | 2009-02-25 | 2010-09-09 | Tokushu Paper Mfg Co Ltd | シート状物 |
| JP2011214216A (ja) * | 2011-07-22 | 2011-10-27 | Komatsu Seiren Co Ltd | 撥水撥油性布帛 |
| WO2012160711A1 (ja) * | 2011-05-26 | 2012-11-29 | 株式会社 きものブレイン | シルク繊維の加工方法 |
| JP2013036136A (ja) * | 2011-08-08 | 2013-02-21 | Komatsu Seiren Co Ltd | 撥水撥油ｓｒ性布帛 |
| WO2013061954A1 (ja) * | 2011-10-25 | 2013-05-02 | 旭化成ケミカルズ株式会社 | ブロックポリイソシアネートの水分散体、繊維処理剤組成物、及び布帛 |
| WO2013187360A1 (ja) | 2012-06-11 | 2013-12-19 | セーレン株式会社 | 伸縮性コーティング布帛及びその製造方法 |
| JP2014062348A (ja) * | 2012-09-24 | 2014-04-10 | Teijin Frontier Co Ltd | 撥水布帛 |
| JPWO2012147582A1 (ja) * | 2011-04-25 | 2014-07-28 | 帝人フロンティア株式会社 | 布帛および繊維製品 |
| JP2014148775A (ja) * | 2013-02-04 | 2014-08-21 | Asahi Kasei Fibers Corp | 耐久撥水性ポリエステル繊維布帛及びその製造方法 |
| JP2014152401A (ja) * | 2013-02-04 | 2014-08-25 | Asahi Kasei Fibers Corp | 耐久制電撥水性ポリエステル繊維布帛及びその製造方法 |
| JP2014194098A (ja) * | 2013-03-29 | 2014-10-09 | Toray Ind Inc | 繊維構造物 |
| JP2014198913A (ja) * | 2013-03-29 | 2014-10-23 | 一村産業株式会社 | 撥水性布帛及びその製造方法 |
| JP2015086489A (ja) * | 2013-10-31 | 2015-05-07 | 帝人フロンティア株式会社 | しみ防止布帛および繊維製品 |
| CN106215881A (zh) * | 2016-09-07 | 2016-12-14 | 济南大学 | 一种三聚氰胺改性多孔磁性葡聚糖微球的制备方法 |
| JP2017071888A (ja) * | 2011-08-04 | 2017-04-13 | 旭化成株式会社 | 耐久撥水性ポリアミド繊維布帛及びその製造方法 |
| WO2017205328A1 (en) | 2016-05-23 | 2017-11-30 | Microban Products Company | Odor adsorbent composition and method for use in polymers |
| WO2020203432A1 (ja) | 2019-04-01 | 2020-10-08 | 美津濃株式会社 | 水着 |
| WO2020203434A1 (ja) | 2019-04-01 | 2020-10-08 | 東レ株式会社 | ポリウレタン弾性糸を含む繊維構造物 |
| US10834922B2 (en) | 2014-11-26 | 2020-11-17 | Microban Products Company | Surface disinfectant with residual biocidal property |
| US10842147B2 (en) | 2014-11-26 | 2020-11-24 | Microban Products Company | Surface disinfectant with residual biocidal property |
| CN112323497A (zh) * | 2020-11-24 | 2021-02-05 | 京准化工技术(上海)有限公司 | 一种六碳氟系耐洗涤防水防透湿剂及其制备方法和应用 |
| US10925281B2 (en) | 2014-11-26 | 2021-02-23 | Microban Products Company | Surface disinfectant with residual biocidal property |
| US11033023B2 (en) | 2014-11-26 | 2021-06-15 | Microban Products Company | Surface disinfectant with residual biocidal property |
| CN113338031A (zh) * | 2021-06-15 | 2021-09-03 | 上海荟姿新材料科技有限公司 | 一种织物整理剂及其在织物中的应用 |
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| JPS6140340A (ja) * | 1984-07-31 | 1986-02-26 | Dainippon Ink & Chem Inc | ポリウレタン用安定剤 |
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| JPH10212404A (ja) * | 1997-01-29 | 1998-08-11 | Dainippon Ink & Chem Inc | 耐久性の改良された水性樹脂組成物ならびに防汚性コート剤および離型性コート剤 |
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| JP2003171880A (ja) * | 2001-12-07 | 2003-06-20 | Nicca Chemical Co Ltd | 撥水撥油性繊維製品の製造方法 |
| JP2004300630A (ja) * | 2003-03-31 | 2004-10-28 | Nicca Chemical Co Ltd | 撥水撥油性を有する繊維製品の製造方法及び撥水撥油剤 |
| JP2007247089A (ja) * | 2006-03-15 | 2007-09-27 | Toray Ind Inc | 繊維構造物 |
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2006
- 2006-03-31 JP JP2006096610A patent/JP2007270374A/ja active Pending
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| JPS6140340A (ja) * | 1984-07-31 | 1986-02-26 | Dainippon Ink & Chem Inc | ポリウレタン用安定剤 |
| JPS63154720A (ja) * | 1986-12-19 | 1988-06-28 | Dainippon Ink & Chem Inc | 耐光性、耐窒素酸化物性に優れたウレタン樹脂の製造方法 |
| JPH10212404A (ja) * | 1997-01-29 | 1998-08-11 | Dainippon Ink & Chem Inc | 耐久性の改良された水性樹脂組成物ならびに防汚性コート剤および離型性コート剤 |
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| JP2004300630A (ja) * | 2003-03-31 | 2004-10-28 | Nicca Chemical Co Ltd | 撥水撥油性を有する繊維製品の製造方法及び撥水撥油剤 |
| JP2007247089A (ja) * | 2006-03-15 | 2007-09-27 | Toray Ind Inc | 繊維構造物 |
Cited By (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010196196A (ja) * | 2009-02-25 | 2010-09-09 | Tokushu Paper Mfg Co Ltd | シート状物 |
| JPWO2012147582A1 (ja) * | 2011-04-25 | 2014-07-28 | 帝人フロンティア株式会社 | 布帛および繊維製品 |
| US9725847B2 (en) | 2011-04-25 | 2017-08-08 | Teijin Frontier Co., Ltd. | Cloth containing an organic fiber and having a fluorine compound attached to the cloth, and textile product comprising the cloth |
| WO2012160711A1 (ja) * | 2011-05-26 | 2012-11-29 | 株式会社 きものブレイン | シルク繊維の加工方法 |
| JP2012246580A (ja) * | 2011-05-26 | 2012-12-13 | Kimono Brain:Kk | シルク繊維の加工方法 |
| JP2011214216A (ja) * | 2011-07-22 | 2011-10-27 | Komatsu Seiren Co Ltd | 撥水撥油性布帛 |
| JP2017071888A (ja) * | 2011-08-04 | 2017-04-13 | 旭化成株式会社 | 耐久撥水性ポリアミド繊維布帛及びその製造方法 |
| JP2013036136A (ja) * | 2011-08-08 | 2013-02-21 | Komatsu Seiren Co Ltd | 撥水撥油ｓｒ性布帛 |
| CN106008904A (zh) * | 2011-10-25 | 2016-10-12 | 旭化成株式会社 | 封端多异氰酸酯的水分散体、纤维处理剂组合物以及布帛 |
| KR101593855B1 (ko) | 2011-10-25 | 2016-02-12 | 아사히 가세이 케미칼즈 가부시키가이샤 | 블록 폴리이소시아네이트의 수분산체, 섬유 처리제 조성물 및 패브릭 |
| CN103890034A (zh) * | 2011-10-25 | 2014-06-25 | 旭化成化学株式会社 | 封端多异氰酸酯的水分散体、纤维处理剂组合物以及布帛 |
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| CN103890034B (zh) * | 2011-10-25 | 2016-05-18 | 旭化成化学株式会社 | 封端多异氰酸酯的水分散体、纤维处理剂组合物以及布帛 |
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