JP2007177092A - 塩素系漂白剤組成物 - Google Patents
塩素系漂白剤組成物 Download PDFInfo
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- JP2007177092A JP2007177092A JP2005377817A JP2005377817A JP2007177092A JP 2007177092 A JP2007177092 A JP 2007177092A JP 2005377817 A JP2005377817 A JP 2005377817A JP 2005377817 A JP2005377817 A JP 2005377817A JP 2007177092 A JP2007177092 A JP 2007177092A
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- alkali metal
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- chlorine
- bleach composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 31
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000000460 chlorine Substances 0.000 title claims abstract description 26
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 26
- -1 hypochlorous acid alkali metal salt Chemical class 0.000 claims abstract description 33
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 14
- 239000000194 fatty acid Substances 0.000 claims abstract description 14
- 229930195729 fatty acid Natural products 0.000 claims abstract description 14
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 14
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims abstract description 5
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 11
- 125000005529 alkyleneoxy group Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000003752 hydrotrope Substances 0.000 claims description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 2
- 238000003860 storage Methods 0.000 abstract description 12
- 230000002688 persistence Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 230000014759 maintenance of location Effects 0.000 description 15
- 239000005708 Sodium hypochlorite Substances 0.000 description 11
- 238000004061 bleaching Methods 0.000 description 10
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 10
- 239000006260 foam Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 235000011121 sodium hydroxide Nutrition 0.000 description 7
- 238000005187 foaming Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000007599 discharging Methods 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- CHZLVSBMXZSPNN-UHFFFAOYSA-N 2,4-dimethylbenzenesulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C(C)=C1 CHZLVSBMXZSPNN-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- CVLHGLWXLDOELD-UHFFFAOYSA-N 4-(Propan-2-yl)benzenesulfonic acid Chemical compound CC(C)C1=CC=C(S(O)(=O)=O)C=C1 CVLHGLWXLDOELD-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052571 earthenware Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- PDEDQSAFHNADLV-UHFFFAOYSA-M potassium;disodium;dinitrate;nitrite Chemical compound [Na+].[Na+].[K+].[O-]N=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PDEDQSAFHNADLV-UHFFFAOYSA-M 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000008259 solid foam Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
【解決手段】(a)次亜塩素酸アルカリ金属塩、(b)アルカリ金属の水酸化物、(c)ドデシルジメチルアミンオキサイド、(d)テトラデシルジメチルアミンオキサイド、(e)脂肪酸又はそのアルカリ金属塩を含有し、(c)成分と(d)成分の質量比(c)/(d)が0.1〜0.7の範囲である塩素系漂白剤組成物。
【選択図】なし
Description
(式中、AOは炭素数2〜4のアルキレンオキシ基、nはアルキレンオキシ基の平均付加モル数を示す。X1、X2は、それぞれ水素原子、−SO3H、−CH2COOH、あるいはこれらのアルカリ金属塩を示し、X1、X2が同時に水素原子になることはない。)
(a)次亜塩素酸ナトリウムが2.5質量%、(b)水酸化ナトリウムが0.6質量%、ドデシルジメチルアミンオキサイドが0.2質量%、テトラデシルジメチルアミンオキサイドが0.4質量%、脂肪酸が0.4質量%、及び残部はイオン交換水からなる液体塩素系漂白剤組成物を調製し、これを市販のトリガー付き容器〔カビとりハイター(花王(株))のもの〕に充填して壁に向かって噴霧したところ、しっかりとした泡が壁面に付着、滞留した。
表1に示す液体塩素系漂白剤組成物を調製した。これらの組成物について、粘度の測定、泡の付着滞留性の評価、保存安定性の確認を下記の方法で評価した。結果を表1に示す。
表1に調製した液体塩素系漂白剤組成物を花王(株)製カビとりハイターのトリガー(噴霧量1ml/回)を用いて、10cm×10cmの陶器タイルが張られた浴室壁のタイル目地に沿って10cm離れたところから、横幅10cmの範囲内に横に4回噴霧し、泡が付着した位置から1分後に泡が垂れ落ちた位置までの面積を算出した。数値が小さい程、付着滞留性が高いことを示している。なお、数値上の表現による相違は少ないが、目視のよる相違は明らかである。
表1に調製した塩素系漂白剤組成物100mLを、−5℃で1ヶ月間静置した後、組成物の外観を下記の基準で目視評価した。
(評価基準)
○:分離などせずに均一で透明な液体である。
×:白濁や分離を生じたり、沈殿物を生成するなど不均一な液体である。
表1に調製した塩素系漂白剤組成物を、B型粘度計(TOKIMEC製)を使用して、20℃で測定した。
・水酸化ナトリウム:48%液体苛性ソーダ〔南海化学工業(株)製〕を用いた。表中の数値は、遊離した水酸化ナトリウム量を示す。
・ドデシルジメチルアミンオキサイド:アンヒトール20N、花王(株)製。
・テトラデシルジメチルアミンオキサイド、ファーミン DM4098〔ミリスチルアミン、花王(株)製〕と過酸化水素水(日本パーオキサイド社製)から合成したサンプル。
・脂肪酸:ルナックL−70(カプリン酸10、ラウリン酸76、ミリスチン酸14の組成比である脂肪酸の混合品)、花王(株)製。
・アルキルベンゼンスルホン酸ナトリウム:ネオペレックスG−25、花王(株)製。
・メタキシレンスルホン酸:SXA−60、三菱瓦斯化学(株)製。
・化合物1:溶媒中でポリエチレングリコール1540(一般式(1)においてAOがエチレンオキシ基、X1、X2がそれぞれ水素原子、n=35のもの、三洋化成工業(株)製)と無水硫酸とを反応させて、水酸化ナトリウムで中和したサンプル。
Claims (3)
- (a)次亜塩素酸アルカリ金属塩、(b)アルカリ金属の水酸化物、(c)ドデシルジメチルアミンオキサイド、(d)テトラデシルジメチルアミンオキサイド、(e)脂肪酸又はそのアルカリ金属塩を含有し、(c)成分と(d)成分の質量比(c)/(d)が0.1〜0.7の範囲である塩素系漂白剤組成物。
- 更に(f)下記一般式(1)に表される化合物を含有する請求項1記載の塩素系漂白剤組成物。
X1−O(AO)n−X2 (1)
(式中、AOは炭素数2〜4のアルキレンオキシ基、nはアルキレンオキシ基の平均付加モル数を示す。X1、X2は、それぞれ水素原子、−SO3H、−CH2COOH、あるいはこれらのアルカリ金属塩を示し、X1、X2が同時に水素原子になることはない。) - 更に(g)アルキルベンゼンスルホン酸塩及び(h)ベンゼン環を有するハイドロトロープ剤の少なくともいずれかを含有する請求項1又は2記載の塩素系漂白剤組成物。
Priority Applications (1)
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JP2005377817A JP4818719B2 (ja) | 2005-12-28 | 2005-12-28 | 塩素系漂白剤組成物 |
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JP2005377817A JP4818719B2 (ja) | 2005-12-28 | 2005-12-28 | 塩素系漂白剤組成物 |
Publications (2)
Publication Number | Publication Date |
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JP2007177092A true JP2007177092A (ja) | 2007-07-12 |
JP4818719B2 JP4818719B2 (ja) | 2011-11-16 |
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JP2005377817A Expired - Fee Related JP4818719B2 (ja) | 2005-12-28 | 2005-12-28 | 塩素系漂白剤組成物 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009001966A1 (ja) * | 2007-06-27 | 2008-12-31 | Kao Corporation | スプレー式漂白剤 |
WO2009001474A1 (ja) * | 2007-06-26 | 2008-12-31 | Kao Corporation | 洗浄剤組成物 |
JP2010150319A (ja) * | 2008-12-24 | 2010-07-08 | Kao Corp | 排水管用液体洗浄剤組成物 |
JP2013249383A (ja) * | 2012-05-31 | 2013-12-12 | Niitaka:Kk | 発泡洗浄剤組成物及び洗浄方法 |
JP2018203853A (ja) * | 2017-06-02 | 2018-12-27 | 花王株式会社 | 硬質表面用液体洗浄剤組成物 |
JP2020007438A (ja) * | 2018-07-06 | 2020-01-16 | 攝津製油株式会社 | 液体洗浄剤組成物、洗浄剤、及び洗浄方法 |
JP2020125445A (ja) * | 2019-02-06 | 2020-08-20 | 花王株式会社 | 硬質表面用液体洗浄剤組成物 |
Families Citing this family (1)
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CN107937175A (zh) * | 2017-11-08 | 2018-04-20 | 深圳市前海荣格生物技术有限公司 | 一种强碱性粘稠状管道疏通剂组合物及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002080892A (ja) * | 2000-09-11 | 2002-03-22 | Kao Corp | 洗浄剤組成物 |
JP2005206772A (ja) * | 2003-12-22 | 2005-08-04 | Johnson Co Ltd | 漂白剤組成物 |
-
2005
- 2005-12-28 JP JP2005377817A patent/JP4818719B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2002080892A (ja) * | 2000-09-11 | 2002-03-22 | Kao Corp | 洗浄剤組成物 |
JP2005206772A (ja) * | 2003-12-22 | 2005-08-04 | Johnson Co Ltd | 漂白剤組成物 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009001474A1 (ja) * | 2007-06-26 | 2008-12-31 | Kao Corporation | 洗浄剤組成物 |
WO2009001966A1 (ja) * | 2007-06-27 | 2008-12-31 | Kao Corporation | スプレー式漂白剤 |
JP2009030035A (ja) * | 2007-06-27 | 2009-02-12 | Kao Corp | スプレー式漂白剤 |
US8048841B2 (en) | 2007-06-27 | 2011-11-01 | Kao Corporation | Spray-type bleaching agent |
JP2010150319A (ja) * | 2008-12-24 | 2010-07-08 | Kao Corp | 排水管用液体洗浄剤組成物 |
JP2013249383A (ja) * | 2012-05-31 | 2013-12-12 | Niitaka:Kk | 発泡洗浄剤組成物及び洗浄方法 |
JP2018203853A (ja) * | 2017-06-02 | 2018-12-27 | 花王株式会社 | 硬質表面用液体洗浄剤組成物 |
JP2020007438A (ja) * | 2018-07-06 | 2020-01-16 | 攝津製油株式会社 | 液体洗浄剤組成物、洗浄剤、及び洗浄方法 |
JP7245614B2 (ja) | 2018-07-06 | 2023-03-24 | セッツ株式会社 | 液体洗浄剤組成物、洗浄剤、及び洗浄方法 |
JP2020125445A (ja) * | 2019-02-06 | 2020-08-20 | 花王株式会社 | 硬質表面用液体洗浄剤組成物 |
JP7299807B2 (ja) | 2019-02-06 | 2023-06-28 | 花王株式会社 | 硬質表面用液体洗浄剤組成物 |
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